Product Name

  • Name

    Tetrabenzylthiuramdisulfide

  • EINECS 404-310-0
  • CAS No. 10591-85-2
  • Article Data16
  • CAS DataBase
  • Density 1.288 g/cm3
  • Solubility 10μg/L at 21℃
  • Melting Point 124 °C
  • Formula C30H28N2S4
  • Boiling Point 687 °C at 760 mmHg
  • Molecular Weight 544.83
  • Flash Point 369.3 °C
  • Transport Information
  • Appearance Light yellow powder(granule)
  • Safety 61
  • Risk Codes 53
  • Molecular Structure Molecular Structure of 10591-85-2 (Tetrabenzylthiuramdisulfide)
  • Hazard Symbols R53:;
  • Synonyms Disulfide,bis(dibenzylthiocarbamoyl) (8CI);Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2),tetrakis(phenylmethyl)- (9CI);Accel TBZT;Accel TBZTD;Benzyl Tuex;Cure-riteTBzD;N,N,N',N'-Tetrabenzylthiuram disulfide;NSC 608475;Nocceler TBzTD;Perkacit TBzTD;Sanceler TBzTD;Tetrabenzylthiuram disulfide;
  • PSA 121.26000
  • LogP 8.34240

Synthetic route

carbon disulfide
75-15-0

carbon disulfide

dibenzylamine
103-49-1

dibenzylamine

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
Stage #1: carbon disulfide; dibenzylamine In water at 20 - 30℃; for 3h;
Stage #2: With dihydrogen peroxide for 1h; Reagent/catalyst; Temperature; Solvent; Reflux;		99.91%
Stage #1: carbon disulfide; dibenzylamine With haematoxylin In ethanol at 30 - 40℃; for 0.833333h;
Stage #2: In ethanol for 0.833333h; Reagent/catalyst; Solvent; Temperature; Irradiation;		98.51%
at 0 - 70℃; Temperature; Concentration;96.8%
N,N-dibenzyl dithiocarbamate
99-22-9

N,N-dibenzyl dithiocarbamate

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
With oxygen In water at 20 - 30℃; under 750.075 Torr; for 0.666667h; Pressure; Flow reactor;99.9%
carbon disulfide
75-15-0

carbon disulfide

benzylamine
100-46-9

benzylamine

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
With dihydrogen peroxide; sodium hydroxide at 35 - 40℃; for 3h;98.5%
dibenzyldithiocarbamate anion

dibenzyldithiocarbamate anion

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
With sulfuric acid In dimethyl sulfoxide at 50℃; Temperature; Reagent/catalyst;97.3%
With sodium nitrate; hexacyanoferrate(III) In water; acetone at 25℃; Equilibrium constant; Rate constant; ΔH(excit.), ΔS(excit.), var. metal complexes and salts;
sodium dibenzyldithiocarbamate
55310-46-8

sodium dibenzyldithiocarbamate

C18H19NOS4

C18H19NOS4

A

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

B

sodium O-ethyl dithiocarbonate
140-90-9

sodium O-ethyl dithiocarbonate

Conditions
ConditionsYield
With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l;
...Expand
sodium dibenzyldithiocarbamate
55310-46-8

sodium dibenzyldithiocarbamate

C22H28N2S4

C22H28N2S4

A

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

B

sodium N,N'-diisopropyldithiocarbamate
4092-82-4

sodium N,N'-diisopropyldithiocarbamate

Conditions
ConditionsYield
With sodium nitrate; potassium hexacyanoferrate(III) In water; acetone at 25℃; Rate constant; Equilibrium constant; μ 0.2 mol/l;
...Expand
dibenzyldithiocarbamate radical

dibenzyldithiocarbamate radical

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
With sodium nitrate In water; acetone at 25℃; Equilibrium constant;
N,N-iminodiethanoldithiocarbamic acid
1528-72-9

N,N-iminodiethanoldithiocarbamic acid

hexacyanoferrate(III)

hexacyanoferrate(III)

A

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

B

hexacyanoferrate(II)

hexacyanoferrate(II)

Conditions
ConditionsYield
With sodium nitrate In water; acetone Kinetics; Electrochem. Process; 25°C, different acetone/H2O mixtures (30, 40, 50, 80, 90% acetone);
With sodium nitrate In water Kinetics; Electrochem. Process; 25°C;
...Expand
octacyanomolybdate(V)

octacyanomolybdate(V)

N,N-dibenzyl dithiocarbamate
99-22-9

N,N-dibenzyl dithiocarbamate

A

octacyanomolybdate(IV) ion

octacyanomolybdate(IV) ion

B

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
With sodium nitrate In dimethyl sulfoxide Electrochem. Process; 25°C, 30% aq.acetone;
With sodium nitrate In water; acetone Kinetics; Electrochem. Process; 25°C, 30% aq.acetone, at different ph (9-12);
...Expand
N,N-dibenzyl dithiocarbamate
99-22-9

N,N-dibenzyl dithiocarbamate

hexacyanoferrate(III)

hexacyanoferrate(III)

A

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

B

hexacyanoferrate(II)

hexacyanoferrate(II)

Conditions
ConditionsYield
With sodium nitrate In water; acetone Kinetics; Electrochem. Process; 25°C, 30% aq.acetone, at different pH (9-12);
...Expand
potassium dibenzyldithiocarbamate trihydrate
20293-68-9

potassium dibenzyldithiocarbamate trihydrate

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
With hydrogenchloride; sodium nitrite In methanol; water at 0 - 5℃;
With hydrogenchloride; sodium nitrite In methanol; ethanol; water Cooling;
indole
120-72-9

indole

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

1H-indol-1-yl dibenzylcarbamodithioate

1H-indol-1-yl dibenzylcarbamodithioate

Conditions
ConditionsYield
With potassium tert-butylate In 1,2-dichloro-ethane at 20℃; for 1h;83%
With potassium tert-butylate In 1,2-dichloro-ethane at 25℃; for 1h;83%
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

trimethylamine-gallane adduct
19528-13-3

trimethylamine-gallane adduct

tris(N,N-dibenzyldithiocarbamato)gallium(III) complex

tris(N,N-dibenzyldithiocarbamato)gallium(III) complex

Conditions
ConditionsYield
In toluene under Ar; std. Schlenk techniques; soln. of Me3N*GaH3 added gradually to soln. of (Bz2NC(S)S)2 at room temp.; soln. allowed to stir at room temp. for 16 h; filtered; solvent vol. reduced in vac.; recrystd. at room temp.; elem. anal.;69%
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

dibenzyldithiocarbamate radical

dibenzyldithiocarbamate radical

Conditions
ConditionsYield
With sodium nitrate In water; acetone at 25℃; Equilibrium constant;
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

N,N-dibenzyl-1,1,1-trifluoromethanamine
143490-28-2

N,N-dibenzyl-1,1,1-trifluoromethanamine

Conditions
ConditionsYield
With silver fluoride In various solvent(s) at 20℃; for 3h;
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

C15H14FNS

C15H14FNS

Conditions
ConditionsYield
With silver fluoride In various solvent(s) at 20℃; for 0.5h;
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

tetramethylammonium trifluoromethyltellurate(0)

tetramethylammonium trifluoromethyltellurate(0)

tetramethylammonium trifluoromethylbis(dibenzyldithiocarbamato)tellurate(II)

tetramethylammonium trifluoromethylbis(dibenzyldithiocarbamato)tellurate(II)

Conditions
ConditionsYield
In acetonitrile at 20℃; for 1h;
C2F5Te(1-)*C4H12N(1+)

C2F5Te(1-)*C4H12N(1+)

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

tetramethylammonium pentafluoroethylbis(dibenzyldithiocarbamato)tellurate(II)

tetramethylammonium pentafluoroethylbis(dibenzyldithiocarbamato)tellurate(II)

Conditions
ConditionsYield
In acetonitrile at 20℃; for 1h;
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

C16H14F3NS2Te
942626-67-7

C16H14F3NS2Te

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: acetonitrile / 1 h / 20 °C
2: Ag[BF4] / acetonitrile / 0.5 h / 20 °C
View Scheme
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

C17H14F5NS2Te

C17H14F5NS2Te

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: acetonitrile / 1 h / 20 °C
2: Ag[BF4] / acetonitrile / 0.5 h / 20 °C
View Scheme
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

4,4-Dibenzyl-thiosemicarbazid
21076-54-0

4,4-Dibenzyl-thiosemicarbazid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NaCN / ethanol / Heating
2: N2H4*H2O / ethanol / Heating
View Scheme

Tetrabenzylthiuramdisulfide Specification

The CAS registry number of Tetrabenzylthiuramdisulfide is 10591-85-2. The systematic name is 1,1',1'',1'''-[disulfanediylbis(carbonothioylnitrilodimethanediyl)]tetrabenzene. In addition, the molecular formula is C30H28N2S4 and the molecular weight is 544.82. What's more, it should be stored in sealed container, and put them in a cool and dry place. It can be used in organic synthesis.

Physical properties about Tetrabenzylthiuramdisulfide are: (1)ACD/LogP: 8.77; (2)# of Rule of 5 Violations: 2; (3)#H bond acceptors: 2; (4)#Freely Rotating Bonds: 11; (5)Polar Surface Area: 121.26 Å2; (6)Index of Refraction: 1.713; (7)Molar Refractivity: 165.81 cm3; (8)Molar Volume: 422.8 cm3; (9)Polarizability: 65.73 ×10-24cm3; (10)Surface Tension: 66 dyne/cm; (11)Density: 1.288 g/cm3; (12)Flash Point: 369.3 °C; (13)Enthalpy of Vaporization: 100.72 kJ/mol; (14)Boiling Point: 687 °C at 760 mmHg; (15)Vapour Pressure: 1E-18 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
This chemcal may cause long-term adverse effects in the aquatic environment. You should avoid release to the environment. In addition, you can refer to special instructions safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: S=C(SSC(=S)N(Cc1ccccc1)Cc2ccccc2)N(Cc3ccccc3)Cc4ccccc4
(2)InChI: InChI=1/C30H28N2S4/c33-29(31(21-25-13-5-1-6-14-25)22-26-15-7-2-8-16-26)35-36-30(34)32(23-27-17-9-3-10-18-27)24-28-19-11-4-12-20-28/h1-20H,21-24H2
(3)InChIKey: WITDFSFZHZYQHB-UHFFFAOYAS

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