Hazard Codes | O,Xi |
Risk Statements | 5-8-36/37/38 |
Safety Statements | 17-26-36 |
RIDADR | UN 1479 5.1/PG 2 |
WGK Germany | 3 |
F | 3-10 |
HazardClass | 5.1 |
PackingGroup | III |
tetrapropylammonium hydroxide
tetrapropylammonium perruthennate
Conditions | Yield |
---|---|
Stage #1: rhodium(III) chloride hydrate With sodium bromate; sodium carbonate In water at 30 - 40℃; for 5h; Stage #2: tetrapropylammonium hydroxide at 30℃; for 5h; Temperature; | 99.7% |
Stage #1: rhodium(III) chloride hydrate With sodium bromate; sodium carbonate In water at 20℃; for 2h; Stage #2: tetrapropylammonium hydroxide In water at 20℃; for 0.05h; | 67% |
tetrapropylammonium perruthennate
Conditions | Yield |
---|---|
With sodium carbonate In water mixt. of RuCl3 and NaBrO3, Na2CO3 in water stirred until color changed to yellow green, addn. of n-Pr4NOH with stirring, deep green pptn.; extd. with alcohol free CH2Cl2, dried over anhydrous Na2CO3, concd. in vac., recrystd. from CCl4; elem. anal.; | 99% |
ruthenium tetroxide
tetrapropylammonium perruthennate
Conditions | Yield |
---|---|
With K2CO3 stirred at 0°C for 3 h; washed with ice-cold H2O, dried in vac.; elem. anal.; | 96% |
sodium periodate
tetrapropylammonium perruthennate
Conditions | Yield |
---|---|
In water stirring of hydrated RuCl3 and NaIO4 in H2O overnight; addn. to an aq. soln. of n-Pr4NOH containing NaOH at 0-5°C under an atmosphere of O2;; ppt. was removed every 20 min, washed with ice-cold water, and dried under vac.;; | 87% |
sodium periodate
tetrapropylammonium hydroxide
tetrapropylammonium perruthennate
Conditions | Yield |
---|---|
Stage #1: tetrapropylammonium hydroxide With sodium hydroxide In water Stage #2: sodium periodate; ruthenium(III) chloride trihydrate In water at 20℃; for 16h; | 33% |
tetrapropylammonium hydroxide
tetrapropylammonium perruthennate
Conditions | Yield |
---|---|
With sodium periodate; sodium hydroxide In water at 20℃; for 16h; | 33% |
tetrapropylammonium perruthennate
Conditions | Yield |
---|---|
With sodium carbonate In water mixt. of RuO2 and NaBrO3, Na2CO3 in water stirred until color changed to yellow green, addn. of n-Pr4NOH with stirring, deep green pptn.; extd. with alcohol free CH2Cl2, dried over anhydrous Na2CO3, concd. in vac., recrystd. from CCl4; |
tetrapropylammonium hydroxide
tetrapropylammonium perruthennate
Conditions | Yield |
---|---|
Stage #1: ruthenium(III) chloride trihydrate With sodium bromate; sodium carbonate In water at 20℃; for 2h; Stage #2: tetrapropylammonium hydroxide In water at 20℃; for 0.05h; |
tetrapropylammonium perruthennate
4-hydroxycyclohexyl carboxylic acid ethyl ester
4-methylmorpholine N-oxide
ethyl 4-oxocyclohexane-1-carboxylate
Conditions | Yield |
---|---|
In ethyl acetate; acetonitrile | 98% |
In dichloromethane | 13.46 g (85%) |
tetrapropylammonium perruthennate
(2Z)-3-(4-hydroxy-2-buten-2-yl)-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-(n-propyloxy)naphthalene
(2Z)-3-[5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-(n-propyloxy)naphthalen-3-yl]but-2-en-1-al
Conditions | Yield |
---|---|
With 4-methylmorpholine N-oxide In dichloromethane | 98% |
tert-butyl N-(4-hydroxycyclohexyl)carbamate
tetrapropylammonium perruthennate
4-methylmorpholine N-oxide
N-(tert-butoxycarbonyl)-4-aminocyclohexanone
Conditions | Yield |
---|---|
molecular sieves In dichloromethane; ethyl acetate | 96% |
tetrapropylammonium perruthennate
4-methylmorpholine N-oxide
(4S)-4-(2-methyl-3(RS)-hydroxybut-2-yl)-2,2-dimethyl[1,3]dioxane
(4S)-4-(2-methyl-3-oxobut-2-yl)-2,2-dimethyl[1,3]dioxane
Conditions | Yield |
---|---|
molecular sieve In dichloromethane | 94.5% |
tetrapropylammonium perruthennate
4-(1,3-dioxoisoindolin-2-yl)-3-hydroxybutyl acetate
4-methylmorpholine N-oxide
4-(1,3-dioxoisoindolin-2-yl)-3-oxobutyl acetate
Conditions | Yield |
---|---|
SiO2 In dichloromethane | 92% |
tetrapropylammonium perruthennate
1-(2-Hydroxy-3-methoxymethoxy-butyl)-2-oxo-6-m-tolyl-4-trifluoromethyl-1,2-dihydro-pyridine-3-carbonitrile
1-(3-Methoxymethoxy-2-oxo-butyl)-2-oxo-6-m-tolyl-4-trifluoromethyl-1,2-dihydro-pyridine-3-carbonitrile
Conditions | Yield |
---|---|
With 4-methylmorpholine N-oxide; silica gel In 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran | 90% |
tetrapropylammonium perruthennate
4-hydroxymethyl-4-(5-benzyloxy-3-fluorophenyl)-3,4,5,6-tetrahydro-2H-pyran
Conditions | Yield |
---|---|
With 4-methylmorpholine N-oxide In hexane; ethyl acetate | 86% |
tetrapropylammonium perruthennate
di-tert-butyl dicarbonate
trans-4-hydroxycyclohexylamine
trans-4-aminocyclohexanol hydrochloride
4-methylmorpholine N-oxide
N-(tert-butoxycarbonyl)-4-aminocyclohexanone
Conditions | Yield |
---|---|
molecular sieves In tetrahydrofuran; sodium hydroxide; dichloromethane | 84% |
tetrapropylammonium perruthennate
Conditions | Yield |
---|---|
silica gel In dichloromethane; 4-methylmorpholine N-oxide | 83% |
tetrapropylammonium perruthennate
8-(hydroxymethyl)dibenzo[b,f][1,4]oxazepin-11(10H)-one
11-oxo-10,11-dihydrodibenzo[b,f][1,4]oxazepine-8-carbaldehyde
Conditions | Yield |
---|---|
With hydrogenchloride; silica gel In ethyl acetate; acetonitrile | 83% |
tetrapropylammonium perruthennate
(6S)-N-benzyl-2-azabicyclo[2.2.2]octan-6-ol
4-methylmorpholine N-oxide
2-benzyl-2-azabicyclo[2.2.2]octan-6-one
Conditions | Yield |
---|---|
In ethyl acetate; acetonitrile | 81% |
tetrapropylammonium perruthennate
2-(2-Chloro-5-methoxy-phenyl)-1-(2-chloro-pyridin-4-yl)-propan-1-ol
4-methylmorpholine N-oxide
2-(2-chloro-5-methoxy-phenyl)-1-(2-chloro-pyridin-4-yl)-propan-1-one
Conditions | Yield |
---|---|
silica gel In dichloromethane | 81% |
(1H-indol-4-yl)methanol
tetrapropylammonium perruthennate
4-formyl indole
Conditions | Yield |
---|---|
With 4-methylmorpholine N-oxide; silica gel In dichloromethane | 80% |
Conditions | Yield |
---|---|
In dichloromethane | 76% |
tetrapropylammonium perruthennate
3-tert-butyldimethylsilyloxy-1-propanol
3-(tert-butyldimethylsilanyloxy)propionaldehyde
Conditions | Yield |
---|---|
With 4-methylmorpholine N-oxide; silica gel In dichloromethane; acetonitrile | 66% |
With 4-methylmorpholine N-oxide; silica gel In dichloromethane; acetonitrile | 66% |
tetrapropylammonium perruthennate
4-methylmorpholine N-oxide
2-(3,4-dihydro-1(2H)-benzopyran-4-yl)ethanol
2-(3,4-dihydro-2H-1-benzopyran-4-yl)ethanal
Conditions | Yield |
---|---|
silica gel In dichloromethane; ethyl acetate | 64% |
tetrapropylammonium perruthennate
1-{4-[1-(3-Fluoro-benzyl)-1H-indazol-5-ylamino]-pyrrolo[2,1 f][1,2,4]triazin-5-ylmethyl}-(3R)-pyrrolidin-3-ol
1-{4[1-(3-Fluoro-benzyl)-1H-indazol-5-ylamino]-pyrrolo[2,1-f][1,2,4]triazin-5-ylmethyl}-pyrrolidin-3-one
Conditions | Yield |
---|---|
With 4-methylmorpholine N-oxide; silica gel In 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran; ethyl acetate | 61% |
tetrapropylammonium perruthennate
4-methylmorpholine N-oxide
Conditions | Yield |
---|---|
In Å molecular sieves; diethyl ether; ethyl acetate; acetonitrile | 55% |
In diethyl ether; silica gel; ethyl acetate; acetonitrile | 55% |
tetrapropylammonium perruthennate
(3E,7E)-homofarnesol
4-methylmorpholine N-oxide
homofarnesaldehyde
Conditions | Yield |
---|---|
silica gel In acetonitrile | 50% |
tetrapropylammonium perruthennate
methyl 5-(3-hydroxypropyl)-4-methylthiophene-2-carboxylate
4-methylmorpholine N-oxide
methyl 4-methyl-5-(3-oxopropyl) thiophene-2-carboxylate
Conditions | Yield |
---|---|
In dichloromethane | 49% |
pyridine
tetrapropylammonium perruthennate
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 16h; Inert atmosphere; | 45% |
3-(hydroxymethy)piperidine
tetrapropylammonium perruthennate
di-tert-butyl dicarbonate
4-methylmorpholine N-oxide
3-formylpiperidine-1-carboxylic acid tert-butyl ester
Conditions | Yield |
---|---|
molecular sieves In tetrahydrofuran; dichloromethane | 43% |
tetrapropylammonium perruthennate
Conditions | Yield |
---|---|
With 4-methylmorpholine N-oxide; silica gel In dichloromethane | 40% |
4-methoxypyridine
tetrapropylammonium perruthennate
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 16h; Inert atmosphere; | 38% |
tetrapropylammonium perruthennate
2-cyclopropyl-6-hydroxymethyl-4,4-dimethyl-1,2,3,4-tetrahydroisoquinoline
4-methylmorpholine N-oxide
2-cyclopropyl-4,4-dimethyl-1,2,3,4-tetrahydroisoquinoline-6-carbaldehyde
Conditions | Yield |
---|---|
In hexane; dichloromethane; acetonitrile | 37% |
In hexane; dichloromethane; acetonitrile | 37% |
tetrapropylammonium perruthennate
4-trifluoromethylpyridine
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 16h; Inert atmosphere; | 36% |
Molecular Structure of Tetrapropylammonium tetraoxoruthenate (CAS No.114615-82-6):
Molecular Formula: C12H28N.RuO4
Molecular Weight: 351.425
CAS No: 114615-82-6
H bond acceptors: 5
H bond donors: 1
Freely Rotating Bonds: 8
Polar Surface Area: 74.27 Å2
InChI: InChI=1/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;/rC12H28N.O4Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;1-5(2,3)4/h5-12H2,1-4H3;/q+1;-1
InChIKey: NQSIKKSFBQCBSI-DQAXOFGLAB
Std. InChI: InChI=1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;
Std. InChIKey: NQSIKKSFBQCBSI-UHFFFAOYSA-N
Product Categories: Boron, Nitrile, Thio, TM-Cpds;Ammonium Polyhalides, etc. (Quaternary);Catalysts for Organic Synthesis;Classes of Metal Compounds;Environmentally-friendly Oxidation;Homogeneous Catalysts;Metal Complexes;Oxidation;Quaternary Ammonium Compounds;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Complexes (Environmentally-friendly Oxidation);Transition Metal Compounds
Systematic Name: Oxido-trioxo-ruthenium ; Etrapropylammonium
Hazard Codes: O,Xi
Risk Statements: 5-8-36/37/38
R5 :Heating may cause an explosion.
R8 :Contact with combustible material may cause fire.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 17-26-36
S17:Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
RIDADR: UN 1479 5.1/PG 2
WGK Germany: 3
F: 3-10
HazardClass: 5.1
PackingGroup: III
Tetrapropylammonium tetraoxoruthenate (CAS No.114615-82-6), its synonyms are Tetrapropylammonium perruthenate ; N,N,N-Tripropylpropan-1-aminium oxido(trioxo)ruthenium .
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