Product Name

  • Name

    Tin(II) fluoride

  • EINECS 231-999-3
  • CAS No. 7783-47-3
  • Density 4.57 g/mL at 25 °C(lit.)
  • Solubility soluble in water
  • Melting Point 215 °C
  • Formula SnF2
  • Boiling Point 19.5 °C at 760 mmHg
  • Molecular Weight 156.707
  • Flash Point
  • Transport Information UN 2923
  • Appearance white crystals or powder
  • Safety 26-39
  • Risk Codes 22-38-41
  • Molecular Structure Molecular Structure of 7783-47-3 (Tin(II) fluoride)
  • Hazard Symbols HarmfulXn,CorrosiveC
  • Synonyms Difluorostannylene;Fluoristan;Gel-Tin;Stannous fluoride;Stannous fluoride (SnF2);Stop;Tinbifluoride;Tin difluoride;Tin(II) fluoride;
  • PSA 0.00000
  • LogP 0.45960

Synthetic route

18-crown-6 (crown ether)

18-crown-6 (crown ether)

tin (II) fluoride
7783-47-3

tin (II) fluoride

2,4,4-trimethylpentan-1-ol
16325-63-6

2,4,4-trimethylpentan-1-ol

epichlorohydrin
106-89-8

epichlorohydrin

isooctanol glycidyl ether
68134-07-6

isooctanol glycidyl ether

Conditions
ConditionsYield
With sodium hydroxide
tin (II) fluoride
7783-47-3

tin (II) fluoride

hydroperoxy chloride
67952-07-2

hydroperoxy chloride

Butane-1,4-diol
110-63-4

Butane-1,4-diol

epichlorohydrin
106-89-8

epichlorohydrin

1,4-butanediol diglycidyl ether

1,4-butanediol diglycidyl ether

Conditions
ConditionsYield
With sodium hydroxide; tin In 5,5-dimethyl-1,3-cyclohexadiene
tin (II) fluoride
7783-47-3

tin (II) fluoride

epichlorohydrin
106-89-8

epichlorohydrin

hexan-1-ol
111-27-3

hexan-1-ol

1-hexanol glycidyl ether

1-hexanol glycidyl ether

Conditions
ConditionsYield
With sodium hydroxide
potassium dihydrogenphosphate

potassium dihydrogenphosphate

tin (II) fluoride
7783-47-3

tin (II) fluoride

4,4'-isopropylidenedicyclohexanol
13804-54-1, 13804-57-4, 13804-58-5, 80-04-6

4,4'-isopropylidenedicyclohexanol

epichlorohydrin
106-89-8

epichlorohydrin

2,2'-bis(4-hydroxycyclohexyl)propane glycidyl ether
13410-58-7

2,2'-bis(4-hydroxycyclohexyl)propane glycidyl ether

Conditions
ConditionsYield
With sodium hydroxide In toluene
tin(IV) fluoride
7783-62-2

tin(IV) fluoride

tin (II) fluoride
7783-47-3

tin (II) fluoride

F6Sn2, α
56089-53-3

F6Sn2, α

Conditions
ConditionsYield
In neat (no solvent, solid phase) stoich. amts. mixed in a dry glove box, mixt. introduced into gold tubes, heated under vac. at 100°C, sealed in dry Ar, heated between 250 and 600°C; charact. by powder X-ray patterns;
tin(IV) fluoride
7783-62-2

tin(IV) fluoride

tin (II) fluoride
7783-47-3

tin (II) fluoride

Sn3F8

Sn3F8

Conditions
ConditionsYield
In neat (no solvent, solid phase) stoich. amts. mixed in a dry glove box, mixt. introduced into gold tubes, heated under vac. at 100°C, sealed in dry Ar, heated between 250 and 600°C; charact. by powder X-ray patterns;
tin(IV) fluoride
7783-62-2

tin(IV) fluoride

tin (II) fluoride
7783-47-3

tin (II) fluoride

Sn7F16

Sn7F16

Conditions
ConditionsYield
In neat (no solvent, solid phase) stoich. amts. mixed in a dry glove box, mixt. introduced into gold tubes, heated under vac. at 100°C, sealed in dry Ar, heated between 250 and 600°C; charact. by powder X-ray patterns;
tin(IV) fluoride
7783-62-2

tin(IV) fluoride

tin (II) fluoride
7783-47-3

tin (II) fluoride

Sn10F34

Sn10F34

Conditions
ConditionsYield
In neat (no solvent, solid phase) stoich. amts. mixed in a dry glove box, mixt. introduced into gold tubes, heated under vac. at 100°C, sealed in dry Ar, heated between 250 and 600°C; charact. by powder X-ray patterns;
tin (II) fluoride
7783-47-3

tin (II) fluoride

Pt6(CO)6(dppm)3

Pt6(CO)6(dppm)3

[Pt6(μ3-SnF3)(μ-CO)6(μ-dppm)3]

[Pt6(μ3-SnF3)(μ-CO)6(μ-dppm)3]

Conditions
ConditionsYield
With NaF or KF
tin (II) fluoride
7783-47-3

tin (II) fluoride

[(C6H5)4(CH2)P2]3Pt6(CO)6(2+)

[(C6H5)4(CH2)P2]3Pt6(CO)6(2+)

[Pt6(μ3-SnF3)(μ-CO)6(μ-dppm)3]

[Pt6(μ3-SnF3)(μ-CO)6(μ-dppm)3]

Conditions
ConditionsYield
With NaF or KF

Tin(II) fluoride Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 208.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory.

Tin(II) fluoride Standards and Recommendations

OSHA PEL: TWA 2 mg(Sn)/m3; 2.5 mg(F)/m3
ACGIH TLV: TWA 2 mg(Sn)/m3; TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
NIOSH REL: TWA 2.5 mg(F)/m3

Tin(II) fluoride Specification

With the CAS registry number 7783-47-3, the product name and IUPAC name of this chemical are the same which is called Tin(II) fluoride. Known by the common name stannous fluoride, it is a chemical compound with the formula SnF2. It belongs to the product category of Inorganics. Its EINECS registry number is 231-999-3. 

Physical properties of Tin(II) fluoride: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 2; (3)Rotatable Bond Count: 0; (4)Exact Mass: 157.899003; (5)MonoIsotopic Mass: 157.899003; (6)Topological Polar Surface Area: 0; (7)Heavy Atom Count: 3; (8)Formal Charge: 0; (9)Complexity: 2.8; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 1.

Preparation of Tin(II) fluoride: this chemical can be prepared by evaporating a solution of SnO in 40% HF.

Uses of Tin(II) fluoride: This chemical is used as an ingredient in toothpastes that are typically more expensive than those that use sodium fluoride. Used in combination with calcium minerals, sodium fluoride is ineffective while stannous fluoride remains effective in strengthening tooth enamel. Stannous fluoride has also been shown to be more effective than sodium fluoride in controlling gingivitis. Stannous fluoride was used, under the trade name "Fluoristan," in the original formulation of the toothpaste Crest, though it was later replaced with sodium monofluorophosphate, or "Fluoristat."

When you are using this chemical, please be cautious about it as the following:
This chemical may cause damage to health and may destroy living tissue on contact. It is harmful if swallowed. In addition, it is irritating to skin. There will be a risk of serious damage to eyes. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear eye/face protection.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: F[Sn]F
(2)InChI: InChI=1S/2FH.Sn/h2*1H;/q;;+2/p-2
(3)InChIKey: ANOBYBYXJXCGBS-UHFFFAOYSA-L

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 16150ug/kg (16.15mg/kg)   Deutsche Zahnaerztliche Zeitschrift. Vol. 34, Pg. 484, 1979.
mouse LD50 oral 184mg/kg (184mg/kg)   Oyo Yakuri. Pharmacometrics. Vol. 2, Pg. 411, 1968.
rat LD50 oral 360mg/kg (360mg/kg) BEHAVIORAL: FOOD INTAKE (ANIMAL) National Technical Information Service. Vol. OTS0555162,

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