Tris(2-(2-methoxyethoxy)ethyl)amine supplier

Name
Tris(2-(2-methoxyethoxy)ethyl)amine
EINECS 274-590-5
CAS No. 70384-51-9
Article Data14
CAS DataBase
Density 1.005 g/cm³
Solubility Miscible with water
Melting Point <-100°C
Formula C₁₅H₃₃NO₆
Boiling Point 373.7 °C at 760 mmHg
Molecular Weight 323.43
Flash Point 98.6 °C
Transport Information UN 2735 8/PG 3
Appearance clear pale yellow to brown liquid
Safety 26-36/37/39-45
Risk Codes 34
Molecular Structure
Hazard Symbols C
Synonyms 2,5,11,14-Tetraoxa-8-azapentadecane,8-[2-(2-methoxyethoxy)ethyl]- (6CI,7CI);TDA 1;Triethanolaminetris(2-methoxyethyl) ether;Tris(3,6-dioxaheptyl)amine;
PSA 58.62000
LogP 0.27740

Synthetic route

: 6482-24-2
2-Bromoethyl methyl ether

: 283-56-7
2,8,9-trioxa-5-aza-1-borabicyclo[3.3.3]undecane

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

Conditions

Conditions	Yield
With tetrabutyl-ammonium chloride; sodium hydroxide In sulfolane at 60 - 120℃; Reagent/catalyst;	92.7%

: 627-42-9
2-chloroethyl methyl ether

: 283-56-7
2,8,9-trioxa-5-aza-1-borabicyclo[3.3.3]undecane

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

Conditions

Conditions	Yield
With tetrabutylammomium bromide; potassium hydroxide In dimethyl sulfoxide at 60 - 120℃; Catalytic behavior; Reagent/catalyst; Solvent; Inert atmosphere; Autoclave; Large scale;	86.3%

: 52808-36-3
1-chloro-2-(2-methoxyethoxy)ethane

: 31576-51-9
2-(2-methoxyethoxy)ethanamine

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

Conditions

Conditions	Yield
With sodium carbonate at 110℃; for 24h; Temperature;	85.48%

: 52808-36-3
1-chloro-2-(2-methoxyethoxy)ethane

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

Conditions

Conditions	Yield
With ammonia In methanol

: 111-77-3
2-(2-methoxyethoxy)ethyl alcohol

A: 5732-47-8
8-aza-2,5,11,14-tetraoxa-pentadecane

B: 70384-51-9
Tris(3,6-dioxaheptyl)amine

Conditions

Conditions	Yield
With ammonia; hydrogen; nickel at 185℃; 1.) 3h, 2.) 2h;	A 3241 % B 15125 g
With ammonia; hydrogen; nickel at 185℃; 1.) 3h, 2.) 2h;	A 3241 g B 15125 g

: 111-77-3
2-(2-methoxyethoxy)ethyl alcohol

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: SOCl2, Py 2: NH3 / methanol View Scheme
aluminum nickel
Multi-step reaction with 2 steps 1: thionyl chloride / N,N-dimethyl-formamide / 3 h / 28 - 60 °C 2: sodium carbonate / 24 h / 110 °C View Scheme
Multi-step reaction with 3 steps 1: thionyl chloride / N,N-dimethyl-formamide / 3 h / 28 - 60 °C 2: ammonia / 6 h / 130 °C / 11251.1 Torr / Autoclave 3: sodium carbonate / 24 h / 110 °C View Scheme

: 102-71-6
triethanolamine

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: toluene / 1 h / Reflux; Inert atmosphere; Large scale 2: potassium hydroxide; tetrabutylammomium bromide / dimethyl sulfoxide / 60 - 120 °C / Inert atmosphere; Autoclave; Large scale View Scheme
Multi-step reaction with 2 steps 1: toluene / 1 h / Reflux 2: potassium hydroxide; tetrabutylammomium bromide / dimethyl sulfoxide / 60 - 120 °C / Inert atmosphere; Autoclave; Large scale View Scheme
Multi-step reaction with 2 steps 1: toluene / 1 h / Reflux 2: potassium hydroxide; tetrabutylammomium bromide / dimethyl sulfoxide / 60 - 120 °C / Inert atmosphere; Autoclave; Large scale View Scheme
Multi-step reaction with 2 steps 1: toluene / 1 h / Reflux; Inert atmosphere; Large scale 2: sodium hydroxide; tetrabutyl-ammonium chloride / sulfolane / 60 - 120 °C View Scheme
Multi-step reaction with 2 steps 1: toluene / 1 h / Reflux 2: sodium hydroxide; tetrabutyl-ammonium chloride / sulfolane / 60 - 120 °C View Scheme

: 328-50-7
α-ketoglutaric acid

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: AKG-diTMEEA

Conditions

Conditions	Yield
In acetone at 35 - 45℃;	100%

: 15214-89-8
2-acrylamido-2-methylpropanesulfonic acid

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: tris-[2-(2-methoxy-ethoxy)-ethyl]-amine; compound with 2-acryloylamino-2-methyl-propane-1-sulfonic acid

Conditions

Conditions	Yield
at 25℃; for 8h;	99%

: 39121-78-3
3-Acryloyloxypropane-1-sulfonic acid

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 1509627-70-6
C15H33NO6*C6H10O5S

Conditions

Conditions	Yield
In water at 20℃; for 10h; Inert atmosphere; Schlenk technique;	99%

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 117571-22-9
(2-hydroxyphenyl)acetic acid disodium salt

: 117571-21-8
potassium 2-iodo-5-methylbenzoate

: 117571-23-0
2-<2-(carboxymethyl)phenoxy>-5-methylbenzoic acid

Conditions

Conditions	Yield
With hydrogenchloride; copper(l) chloride In 1,4-dioxane; sodium hydroxide	91%

...Expand

: 3,3-Dibutyl-2,3-dihydro-5H-7-fluoro-1,5-benzothiazepine-4-one

: 696-62-8
para-iodoanisole

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 3,3-dibutyl-2,3-dihydro-7-fluoro-5-(4'-methoxyphenyl)-1,5-benzothiazepine-4-one

Conditions

Conditions	Yield
With CuI; potassium carbonate	90%

...Expand

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 108-00-9
N,N-dimethylethylenediamine

: 1493-27-2
ortho-nitrofluorobenzene

: 25238-55-5
N1,N1-dimethyl-N2-(2-nitrophenyl)ethane-1,2-diamine

Conditions

Conditions	Yield
With potassium carbonate	90%

...Expand

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 104-15-4
toluene-4-sulfonic acid

: 8-amino-8-(2-(2-methoxyethoxy)ethyl)-2,5,11,14-tetraoxa-8-azapentadecan-8-ium4-methylbenzenesulfonate

Conditions

Conditions	Yield
With iodosylbenzene; ammonium carbamate In acetonitrile at 25℃; for 2h;	89%

: 4997-36-8
3-formyl-10-methylphenothiazine

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 1374005-27-2
(E)-3-(10-methyl-10H-phenothiazin-3-yl)acrylaldehyde

Conditions

Conditions	Yield
With (1,3-dioxolan-2-yl-methyl)triphenylphosphonium bromide; potassium carbonate In dichloromethane for 20h; Reflux;	88.6%

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 75-03-6
ethyl iodide

: N-ethyl-2-(2-methoxyethoxy)-N,N-bis(2-(2-methoxyethoxy)ethyl)ethan-1-aminium iodide

Conditions

Conditions	Yield
In acetonitrile at 50℃; Inert atmosphere;	88%

: 1000-50-6
butyldimethylsilyl chloride

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: tetramethyldibutyldisilane

Conditions

Conditions	Yield
With sodium iodide	85%

: 610-39-9
3,4-Dinitrotoluene

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 108-00-9
N,N-dimethylethylenediamine

A: 138423-04-8
N,N-Dimethyl-2-(5-methyl-2-nitroanilino)ethanamine

B: 144674-99-7
N,N,N-Trimethyl-2-(5-methyl-2-nitroanilino)ethanaminium Iodide

Conditions

Conditions	Yield
In dimethyl sulfoxide	A 80% B n/a

...Expand

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: N,N-bis(2-(2-methoxyethoxy)ethyl)formamide

Conditions

Conditions	Yield
With pyridine; copper(l) chloride In acetonitrile at 100℃; under 7500.75 - 22502.3 Torr; for 24h; Autoclave; regioselective reaction;	75%

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 62-53-3
aniline

: 189077-66-5
N-(2-(2-methoxyethoxy)ethyl)aniline

Conditions

Conditions	Yield
With 1-hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II) In tert-Amyl alcohol at 150℃; for 24h; Inert atmosphere;	74%

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 925-90-6
ethylmagnesium bromide

: C15H33NO6*2C2H5BrMg

Conditions

Conditions	Yield
In diethyl ether; cyclohexane for 1h;	72%

: 461-72-3
2,4-imidazolidinedione

: 3587-60-8
Benzyloxymethyl chloride

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 151918-26-2
3-benzyloxymethyl-imidazolidine-2,4-dione

Conditions

Conditions	Yield
With potassium hydroxide In water; 4-methyl-2-pentanone	70%

...Expand

: 446-35-5
2,4-Difluoronitrobenzene

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 108-00-9
N,N-dimethylethylenediamine

: 144674-98-6
N,N,N-Trimethyl-2-(5-β-hydroxyethoxy-2-nitroanilino)ethanaminium Iodide

Conditions

Conditions	Yield
With potassium carbonate In N-methyl-acetamide; ethylene glycol; dimethyl sulfoxide	70%

...Expand

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 40949-94-8
potassium hexamethylsilazane

: C21H51KN2O6Si2

Conditions

Conditions	Yield
In hexane Inert atmosphere; Schlenk technique;	69%

: 1-(6-bromohexyl)-2,3-dihydroxybenzene

: 123014-42-6
1-(6-bromohexyl)-2,3-dimethoxybenzene

: 1595-01-3
1-hexyl-4-methyl-benzene

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 100-39-0
benzyl bromide

: 134472-49-4
1,2-bis-(phenylmethoxy)-3-(6-bromohexyl)benzene

Conditions

Conditions	Yield
With hydrogenchloride; boron tribromide; potassium carbonate In dichloromethane; water; toluene	67%

...Expand

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 1826-67-1
vinyl magnesium bromide

: C15H33NO6*2C2H3BrMg

Conditions

Conditions	Yield
In tetrahydrofuran; cyclohexane for 1h;	64%

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 3-butyl-7-chloro-8-methoxy-2,3-dihydro-1,5-benzothiazepin-4(5H)-one

: 3-butyl-7-chloro-5-(4-fluorophenyl)-8-methoxy-2,3-dihydro-1,5-benzothiazepin-4(5H)-one

Conditions

Conditions	Yield
With potassium carbonate	64%

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: [4-(4-bromobutoxy)phenyl][4-(hexyloxy)phenyl]diazene

: C37H62N3O8(1+)*Br(1-)

Conditions

Conditions	Yield
In acetonitrile for 96h; Reflux;	62%

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 2,4-dibromo-N-(1-((4-fluorophenyl)amino)hexan-2-yl)-5-methoxybenzenesulfonamide

: 7-bromo-3-butyl-5-(4-fluorophenyl)-8-methoxy-2,3,4,5-tetrahydro-1,2,5-benzothiadiazepine 1,1-dioxide

Conditions

Conditions	Yield
With potassium carbonate	55%

: cesium bis(trimethylsilyl)amide

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: tris{2-(2-methoxyethoxy)ethyl}amine*cesium bis(trimethylsilyl)amide

Conditions

Conditions	Yield
In hexane for 0.166667h; Schlenk technique; Inert atmosphere;	49%

tris[2-(2-methoxyethoxy]amine: tris[2-(2-methoxyethoxy]amine

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 16463-38-0
potassium 2-chlorobenzoate

: 118537-94-3
sodium 2-allyl-4-methylphenolate

: 117571-24-1
2-(2-allyl-4-methylphenoxy)benzoic acid

Conditions

Conditions	Yield
copper(l) chloride In methoxybenzene	47%

...Expand

: 60699-01-6
6-(bromomethyl)-1,3,8-trimethoxyanthracene-9,10-dione

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 2-(2-methoxyethoxy)-N-(2-(2-methoxyethoxy)ethyl)-N-((4,5,7-trimethoxy-9,10-anthraquinone-2-yl)methyl)ethanaminium bromide

Conditions

Conditions	Yield
for 24h; Reflux;	31.4%

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: C22H29BrN2O2

: C37H62N3O8(1+)*Br(1-)

Conditions

Conditions	Yield
In acetonitrile for 72h; Reflux;	25%

Tris(2-(2-methoxyethoxy)ethyl)amine Specification

The Ethanamine,2-(2-methoxyethoxy)-N,N-bis[2-(2-methoxyethoxy)ethyl]-, with CAS registry number 70384-51-9, has the systematic name of 2-(2-methoxyethoxy)-N,N-bis[2-(2-methoxyethoxy)ethyl]ethanamine. This chemical is a kind of clear pale yellow to brown liquid. And its classification code is TSCA Flag P [A commenced PMN (Premanufacture Notice) substance]. What's more, its EINECS is 274-590-5.

Physical properties of Ethanamine,2-(2-methoxyethoxy)-N,N-bis[2-(2-methoxyethoxy)ethyl]-: (1)ACD/LogP: -3.49; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -4.91; (4)ACD/LogD (pH 7.4): -3.61; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 7; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 18; (12)Polar Surface Area: 58.62 Å²; (13)Index of Refraction: 1.445; (14)Molar Refractivity: 85.73 cm³; (15)Molar Volume: 321.5 cm³; (16)Polarizability: 33.98×10^-24cm³; (17)Surface Tension: 33.3 dyne/cm; (18)Enthalpy of Vaporization: 62.1 kJ/mol; (19)Vapour Pressure: 8.78E-06 mmHg at 25°C.

Uses of Ethanamine,2-(2-methoxyethoxy)-N,N-bis[2-(2-methoxyethoxy)ethyl]-: it can be used to produce C₁₅H₃₃NO₆^.2C₂H₅BrMg. This reaction will need solvents cyclohexane, diethyl ether. The reaction time is 1 hour(s). The yield is about 72 %.

When you are using this chemical, please be cautious about it as the following:
The Ethanamine,2-(2-methoxyethoxy)-N,N-bis[2-(2-methoxyethoxy)ethyl]- may cause burns. When use it, wear suitable protective clothing, gloves and eye/face protection. If contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

You can still convert the following datas into molecular structure:
(1)SMILES: O(C)CCOCCN(CCOCCOC)CCOCCOC
(2)InChI: InChI=1/C15H33NO6/c1-17-10-13-20-7-4-16(5-8-21-14-11-18-2)6-9-22-15-12-19-3/h4-15H2,1-3H3
(3)InChIKey: XGLVDUUYFKXKPL-UHFFFAOYAF
(4)Std. InChI: InChI=1S/C15H33NO6/c1-17-10-13-20-7-4-16(5-8-21-14-11-18-2)6-9-22-15-12-19-3/h4-15H2,1-3H3
(5)Std. InChIKey: XGLVDUUYFKXKPL-UHFFFAOYSA-N

Product Name

Tris(2-(2-methoxyethoxy)ethyl)amine

Synthetic route

Tris(2-(2-methoxyethoxy)ethyl)amine Specification

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