Product Name

  • Name

    Vinyl propionate

  • EINECS
  • CAS No. 105-38-4
  • Article Data19
  • CAS DataBase
  • Density 0.919g/mLat 25°C(lit.)
  • Solubility
  • Melting Point -80oC(lit.)
  • Formula C5H8 O2
  • Boiling Point 94-95°C(lit.)
  • Molecular Weight 100.117
  • Flash Point 43°F
  • Transport Information
  • Appearance
  • Safety Mildly toxic by ingestion and inhalation. A skin and eye irritant. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame. To fight fire, use alcohol foam, mist, fog. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
  • Risk Codes R11
  • Molecular Structure Molecular Structure of 105-38-4 (Vinyl propionate)
  • Hazard Symbols F,Xn
  • Synonyms Propionicacid, vinyl ester (6CI,8CI); NSC 5275; Vinyl propanoate; Vinyl propionate
  • PSA 26.30000
  • LogP 1.08310

Synthetic route

bis(formylmethyl)mercury
4387-13-7

bis(formylmethyl)mercury

propionyl chloride
79-03-8

propionyl chloride

vinyl propionate
105-38-4

vinyl propionate

Conditions
ConditionsYield
In tetrahydrofuran Heating;90%
vinyl acetate
108-05-4

vinyl acetate

propionic acid
802294-64-0

propionic acid

vinyl propionate
105-38-4

vinyl propionate

Conditions
ConditionsYield
With sulfuric acid; mercury(II) diacetate; copper (I) acetate at 20℃; for 2h; 30 deg C, 72 h;30%
With [fac-Ru(CO)3(η2-CH3CH2COO)(η1-CH3CH2COO)] at 100℃; Kinetics; Reagent/catalyst;
With sulfuric acid; mercury(II) diacetate
propionic acid
802294-64-0

propionic acid

acetylene
74-86-2

acetylene

vinyl propionate
105-38-4

vinyl propionate

Conditions
ConditionsYield
With copper(I) monacetylide at 200℃; under 8826.09 Torr;
With zinc(II) propionate; pyrographite at 250℃;
With mercury(II) sulfate at 95 - 105℃;
With mercury salt-boron fluoride at 27 - 30℃;
With mercury salt-boron fluoride at 27 - 30℃;
2-acetoxyethyl propionate

2-acetoxyethyl propionate

A

vinyl acetate
108-05-4

vinyl acetate

B

vinyl propionate
105-38-4

vinyl propionate

Conditions
ConditionsYield
With methanolate In gas
With methanolate In gas Product distribution; also with base F(1-);
ethylene glycol dipropionate

ethylene glycol dipropionate

vinyl propionate
105-38-4

vinyl propionate

Conditions
ConditionsYield
at 550 - 560℃; Pyrolysis;
vinyl acetate
108-05-4

vinyl acetate

vinyl propionate
105-38-4

vinyl propionate

Conditions
ConditionsYield
With propionic acid; tin(IV) chloride
ethene
74-85-1

ethene

propionic acid
802294-64-0

propionic acid

benzene
71-43-2

benzene

A

styrene
292638-84-7

styrene

B

(E)-1,2-diphenyl-ethene
103-30-0

(E)-1,2-diphenyl-ethene

C

vinyl propionate
105-38-4

vinyl propionate

D

phenol
108-95-2

phenol

Conditions
ConditionsYield
With air; 1,3-diphenylpropanedione; palladium diacetate at 90℃; under 1900.13 Torr; for 8h; Product distribution; Further Variations:; Pressures; Reagents; Solvents; Temperatures; ethylene/air ratio;A 0.213 mmol
B 0.043 mmol
C 0.038 mmol
D 0.030 mmol
...Expand

Vinyl Propionate Chemical Properties

Chemistry informtion about  Vinyl Propionate (105-38-4) is:
IUPAC Name: Ethenyl propanoate
Synonyms: Ethenylpropanoate ; Propanoicacid,Ethenylester ; Vinyl ; Vinylester Kyseliny Propionove ; Vinylesterkyselinypropionove ; Vinylpropanoate ; Vinyl Propionate ; Propionic Acid Vinyl Ester
MF: C5H11NO2
MW: 117.15
EINECS: 207-332-7
Melting Point: −80 °C(lit.)
Density: 0.913 g/cm3
Flash Point: 13.1 °C
Boiling Point: 93 °C at 760 mmHg
Vapour Pressure: 50.4 mmHg at 25°C 
Enthalpy of Vaporization: 33.28 kJ/mol
Refractive Index: n20/D 1.403(lit.)
Storage temp.: 2-8°C
BRN: 1741731 
Following is the molecular structure of  Vinyl Propionate (105-38-4) is:

Vinyl Propionate Toxicity Data With Reference

1.    

skn-rat 500 mg MLD

     AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 2 (1950),582.
2.    

skn-rbt 10 mg/24H open MLD

     AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.
3.    

eye-rbt 10 mg MLD

     AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 2 (1950),582.
4.    

sce-hmn:lym 400 µmol/L

     MUREAV    Mutation Research. 279 (1992),75.
5.    

orl-rat LD50:4760 mg/kg

     AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.
6.    

ihl-rat LCLo:4000 ppm/4H

     AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.

Vinyl Propionate Consensus Reports

Reported in EPA TSCA Inventory.

Vinyl Propionate Safety Profile

Mildly toxic by ingestion and inhalation. A skin and eye irritant. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame. To fight fire, use alcohol foam, mist, fog. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
Hazard Codes:
F: Flammable 
Xn: Harmful
Risk Statements:
R11: Highly flammable. 
R21: Harmful in contact with skin.
R36/38: Irritating to eyes and skin.
Safety Statements:
S9: Keep container in a well-ventilated place. 
S16: Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S29: Do not empty into drains.
S33: Take precautionary measures against static discharges.
S36/37: Wear suitable protective clothing and gloves.
RIDADR: UN 3272 3/PG 2
WGK Germany: 1
RTECS: UF8575000
F:
F 8: Photosensitive.
F 10: Keep under argon. 
F 23: Sensitive to air.
HazardClass: 3
PackingGroup: II

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