Vinylcyclohexane supplier | CasNO.695-12-5

Name
VINYLCYCLOHEXANE
EINECS 211-779-3
CAS No. 695-12-5
Article Data113
CAS DataBase
Density 0.865 g/cm³
Solubility Insoluble in water.
Melting Point 121 °C
Formula C₈H₁₄
Boiling Point 126.9 °C at 760 mmHg
Molecular Weight 110.199
Flash Point 21.1 °C
Transport Information UN 3295 3/PG 2
Appearance clear colourless liquid
Safety 16
Risk Codes 10
Molecular Structure
Hazard Symbols R11:Highly flammable.;
Synonyms Cyclohexane,vinyl- (6CI,8CI);Cyclohexylethene;Cyclohexylethylene;Ethenylcyclohexane;NSC73939;Vinylcyclohexane;
PSA 0.00000
LogP 2.75270

Synthetic route

: 81372-29-4
1-<2-trimethylsilyl)ethyl>cyclohexanol

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
With borontrifluoride acetic acid In dichloromethane at 25℃; for 0.0833333h;	95%

: 931-48-6
2-cyclohexylacetylene

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
With hydrogen In hexane at 20℃; under 760.051 Torr; for 14h;	92%
With silver(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate; C19H13I2N3O2Ru; hydrogen In isopropyl alcohol at 80℃; under 3750.38 Torr; for 1h; Autoclave; Schlenk technique; chemoselective reaction;	89%
With hydrogen In toluene at 20℃; under 38002.6 Torr; for 12h; Autoclave; chemoselective reaction;	72%

: (lithiomethyl)dimesitylborane

: 2043-61-0
cyclohexanecarbaldehyde

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
With trifluoroacetic anhydride	76%

: 19493-09-5
Methylenetriphenylphosphorane

: 2043-61-0
cyclohexanecarbaldehyde

A: 695-12-5
vinylcyclohexane

B: 791-28-6
Triphenylphosphine oxide

Conditions

Conditions	Yield
In tetrahydrofuran 1) 2 h, reflux, 2) 12 h, r.t.;	A 68% B n/a

...Expand

: C10H15O2P

: 2043-61-0
cyclohexanecarbaldehyde

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
In 1,4-dioxane at 120℃; for 15h; Schlenk technique; Inert atmosphere;	65%

: 333-27-7
methyl trifluoromethanesulfonate

: 2043-61-0
cyclohexanecarbaldehyde

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
With scandium tris(trifluoromethanesulfonate) In acetonitrile Wittig Olefination; Inert atmosphere; Glovebox; Electrochemical reaction;	57%

: 98-86-2
acetophenone

A: 292638-84-7
styrene

B: 695-12-5
vinylcyclohexane

C: 100-41-4
ethylbenzene

Conditions

Conditions	Yield
With sodium tetrahydroborate; hydrogen; nickel dichloride In isopropyl alcohol at 60 - 70℃; for 12h;	A 56% B 14% C 28%

...Expand

: 5664-20-0
vinylidenecyclohexane

A: 695-12-5
vinylcyclohexane

B: 1003-64-1
ethylidenecyclohexane

Conditions

Conditions	Yield
Stage #1: vinylidenecyclohexane With triethylsilane; indium(III) chloride; triethyl borane In hexane; acetonitrile at 20℃; for 2h; Inert atmosphere; Stage #2: With hydrogenchloride; water In hexane; acetonitrile regioselective reaction;	A 10% B 32%
With water; diisobutylaluminium hydride 1.) hexane, 15 h, 25°C; 2.) 0°C; Multistep reaction;

: 24371-94-6
cyclohexylmercury chloride

: 7486-35-3
tri-n-butyl(vinyl)tin

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
In dimethyl sulfoxide Irradiation (UV/VIS); mixt. of substrate and mercurial is irradiated in nitrogen-purged solvent in Pyrex tube with 350-nm Rayonet photoreactor for 24 h; mixt. is poured into water, extd., extract is washed twice with aq. sodium thiosulfate, dried over anhyd. Na2SO4, concd.; (1)H-NMR;	8%

: 292638-84-7
styrene

A: 695-12-5
vinylcyclohexane

B: 1678-91-7
ethyl-cyclohexane

C: 100-41-4
ethylbenzene

Conditions

Conditions	Yield
With hydrogen; (η3-C3H5)Co[P(OMe)3]3 for 20.5h; Ambient temperature;	A 2.8% B 0.3% C 1.5%

...Expand

: 21722-83-8
cyclohexyl ethyl acetate

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
at 480℃;

: 13487-27-9
1-cyclohexylethan-1-yl acetate

A: 695-12-5
vinylcyclohexane

B: 1003-64-1
ethylidenecyclohexane

Conditions

Conditions	Yield
at 450℃;

: 80203-35-6
(2-iodoethyl)cyclohexane

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
With quinoline

: 99977-91-0
dithiocarbonic acid O-(1-cyclohexyl-ethyl ester)-S-methyl ester

A: 695-12-5
vinylcyclohexane

B: 1003-64-1
ethylidenecyclohexane

Conditions

Conditions	Yield
at 250℃;

: 3483-39-4
Cyclohexyloxirane

A: 695-12-5
vinylcyclohexane

B: 1193-81-3
rac-1-cyclohexylethanol

Conditions

Conditions	Yield
With 4,4'-di(tert-butyl)-[1,1-biphenyl]yllithium 1) THF, -78 deg C, 5 min 2) MeOH, -78 deg C; Multistep reaction;

: 108-05-4
vinyl acetate

: 110-82-7
cyclohexane

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
	19 % Chromat.

: 931-48-6
2-cyclohexylacetylene

A: 695-12-5
vinylcyclohexane

B: 111-65-9
octane

Conditions

Conditions	Yield
With bis(cyclopentadienyl)titanium dichloride; sodium tetrahydroborate; 18-crown-6 ether; dihydrogen peroxide; sodium methylate 1.) THF, 65 deg C, 3 h, 2.) CH3OH, 0.5 h; Yield given. Multistep reaction. Yields of byproduct given;

: 1678-91-7
ethyl-cyclohexane

A: 695-12-5
vinylcyclohexane

B: 1453-24-3
1-ethylcyclohexene

C: 1003-64-1
ethylidenecyclohexane

D: 3742-42-5, 75382-76-2
4-ethylcyclohexene

E: 2808-71-1
3-ethyl-1-cyclohexene

Conditions

Conditions	Yield
trans-carbonylchlorobis(trimethylphosphine)rhodium under 50 Torr; for 72h; Mechanism; Irradiation;

...Expand

: 931-89-5
(E)-cyclooctene

A: 931-88-4, 931-87-3
(Z)-Cyclooctene

B: 695-12-5
vinylcyclohexane

C: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
at 512℃; Rate constant; further temperatures;

...Expand

: 100-40-3
4-ethenylcyclohexene

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
With η5-C9H11Fe(CO)2(isobutylene)+BF-; hydrogen; sodium iodide; palladium on activated charcoal Multistep reaction;

: 6917-84-6
Di-(cyclohexyl)-n-butylboran

: 1826-67-1
vinyl magnesium bromide

A: 592-41-6
1-hexene

B: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
With iodine Product distribution; 1.) THF, room temperature, 1 h, 2.) THF, -78 deg C; other trialkylboranes;

...Expand

: 1892-09-7
2-chloro-1-cyclohexyl-1-ethanone

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
With lithium aluminium tetrahydride; aluminium trichloride; lithium 1.) Et2O, 2.) THF; Yield given. Multistep reaction;

: 6051-13-4
2-cyclohexylpropanoic acid

A: 695-12-5
vinylcyclohexane

B: 1003-64-1
ethylidenecyclohexane

Conditions

Conditions	Yield
With pyridine; lead(IV) acetate; copper diacetate In benzene for 4h; Heating;

: 21722-83-8
cyclohexyl ethyl acetate

A: 695-12-5
vinylcyclohexane

B: 64-19-7
acetic acid

Conditions

Conditions	Yield
at 400℃; Kinetics; Thermodynamic data; var. temp., pressure; ΔH(excit.);

: 1193-81-3
rac-1-cyclohexylethanol

A: 695-12-5
vinylcyclohexane

B: 1003-64-1
ethylidenecyclohexane

Conditions

Conditions	Yield
With dimethyl sulfoxide at 175℃; for 24h; Yield given. Yields of byproduct given;
5 % ruthenium on Al2O3; zirconium(IV) oxide at 376 - 398℃; Product distribution / selectivity;

: 70784-10-0
trans,trans-4'-butyl<1,1'-bicyclohexyl>-4-carbonitrile

: C16H20(2)H2O

A: 695-12-5
vinylcyclohexane

: (1R,2R)-2-Cyclohexyl-1-phenyl-cyclobutanol

: (1R,2S)-2-Cyclohexyl-1-phenyl-cyclobutanol

D: 98-86-2
acetophenone

Conditions

Conditions	Yield
at 30℃; Product distribution; Irradiation; Norrish II photoreactivity; different solvents, different temperatures;

...Expand

: 79753-67-6
(2-cyclohexylidene-ethyl)dimethyl(phenyl)silane

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
With trifluoroacetic acid In tetrachloromethane for 20h; Ambient temperature;	95 % Spectr.

: 73733-09-2
bicyclo<5.1.0>octan-2-one tosylhydrazone

A: 695-12-5
vinylcyclohexane

B: 65909-92-4
1-octen-7-yne

C: 37680-26-5
bicyclo<4.2.0>oct-6-ene

Conditions

Conditions	Yield
With sodium methylate at 160 - 170℃; under 0.5 Torr;	A 10 % Chromat. B 65 % Chromat. C 25 % Chromat.
With sodium methylate at 160 - 170℃; under 0.5 Torr; Mechanism; Product distribution;	A 10 % Chromat. B 65 % Chromat. C 25 % Chromat.

...Expand

: 76200-08-3
exo-7-chloromethylbicyclo<4.1.0>heptane

A: 695-12-5
vinylcyclohexane

B: 14135-43-4
exo-7-methylbicyclo<4.1.0>heptane

Conditions

Conditions	Yield
With triphenylstannane In pentane at 25℃; for 24h; Irradiation; Yield given. Yields of byproduct given;
With triphenylstannane In pentane at 25℃; for 24h; Product distribution; Rate constant; Mechanism; Irradiation; several amount of reagent;

: 1-chloro-2-vinylcyclohexane

: 695-12-5
vinylcyclohexane

Conditions

Conditions	Yield
With triphenylstannane for 24h; Irradiation;

: 695-12-5
vinylcyclohexane

: 61414-09-3, 87858-06-8, 125874-67-1, 59411-58-4
1-cyclohexylethane-1,2-diol

Conditions

Conditions	Yield
With 4-methylmorpholine N-oxide In water; acetone at 20℃; for 3.5h; Inert atmosphere;	100%
Stage #1: vinylcyclohexane With sodium periodate; acetic acid; lithium bromide at 95℃; for 18h; Prevost-Woodward reaction; Stage #2: With potassium carbonate In methanol at 25℃; for 24h;	85%
With osmium(VIII) oxide; N-methyl-2-indolinone In water; acetone; acetonitrile Ambient temperature;	83%

: 695-12-5
vinylcyclohexane

: C8H14O

Conditions

Conditions	Yield
With titanium(IV) isopropylate; Pentafluorobenzoic acid; C32H22F10N2O2; dihydrogen peroxide In water; 1,2-dichloro-ethane at 20℃; for 45h; Inert atmosphere; enantioselective reaction;	100%

: 695-12-5
vinylcyclohexane

: 3483-39-4
Cyclohexyloxirane

Conditions

Conditions	Yield
With peracetic acid; C80H84Mn2N8O4*4ClO4(1-) In acetonitrile at 0℃; for 0.5h;	99%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 18h;	97%
With bis-trimethylsilanyl peroxide; rhenium(VII) oxide In dichloromethane for 7h;	95%

: 695-12-5
vinylcyclohexane

: 65-85-0
benzoic acid

: 1403879-55-9
2-bromo-2-cyclohexylethyl benzoate

Conditions

Conditions	Yield
With N-bromophthalimide; 4-methylmorpholine N-oxide; sodium sulfate In dichloromethane at 20℃; for 22h; diastereoselective reaction;	99%
With N-Bromosuccinimide; 5,6-difluoro-2-(1-phenylethyl)benzo[d][1,2]selenazol-3(2H)-one In dichloromethane at 20℃; for 10h;	68%

: 695-12-5
vinylcyclohexane

: 868-85-9
Dimethyl phosphite

: dimethyl (2-cyclohexylethyl)phosphonate

Conditions

Conditions	Yield
With 2,2-dimethoxy-2-phenylacetophenone In neat (no solvent) for 0.5h; Solvent; UV-irradiation;	99%

: 695-12-5
vinylcyclohexane

: 1003-64-1
ethylidenecyclohexane

Conditions

Conditions	Yield
bis(cyclopentadienyl)titanium dichloride; lithium aluminium tetrahydride at 180℃; for 2h;	98%
With sodium azide on γ-alumina at 20℃;
With [(dppb)Pt(C6F5)(H2O)]OTf In chloroform at 50℃; for 24h;	97 %Chromat.

: 695-12-5
vinylcyclohexane

: 1-(5,6-Dihydro-4H-pyran-2-yl)-2,2-dimethyl-propan-1-one

: 1-[3-(2-Cyclohexyl-ethyl)-5,6-dihydro-4H-pyran-2-yl]-2,2-dimethyl-propan-1-one

Conditions

Conditions	Yield
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene at 135℃; for 12h;	98%

: 695-12-5
vinylcyclohexane

: 1779-48-2
phenylphosphinic acid

: (2-cyclohexylethyl)(phenyl)phosphinic acid

Conditions

Conditions	Yield
With 2,2-dimethoxy-2-phenylacetophenone In water for 2h; Solvent; UV-irradiation; Green chemistry;	98%

: 695-12-5
vinylcyclohexane

: 873-55-2
sodium benzenesulfonate

: 126002-58-2
((2-cyclohexylethyl)sulfonyl)benzene

Conditions

Conditions	Yield
With [Ir(dF(CF3)ppy)2(dtbbpy)]PF6; water; acetic acid In dichloromethane at 20℃; for 10h; Inert atmosphere; Irradiation; regioselective reaction;	98%

: 695-12-5
vinylcyclohexane

: 14428-98-9, 98325-59-8, 98359-08-1
(E)-1-phenyl-N-(1-phenylethylidene)methanamine

: 1-[2-(2-cyclohexyl-ethyl)-phenyl]-ethanone

Conditions

Conditions	Yield
Stage #1: vinylcyclohexane; (E)-1-phenyl-N-(1-phenylethylidene)methanamine With [RhCl(Ph3P)2] for 0.25h; microwave irradiation; Stage #2: Acid hydrolysis;	97%

: 695-12-5
vinylcyclohexane

: 150-76-5
4-methoxy-phenol

: 1173929-13-9
4-methoxy-2-(1-cyclohexylethyl)phenol

Conditions

Conditions	Yield
With decacarbonyldirhenium(0) In toluene at 150℃; for 24h; Inert atmosphere; Sealed tube; regioselective reaction;	97%

: 695-12-5
vinylcyclohexane

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 2-cyclohexyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethane

Conditions

Conditions	Yield
With (iPrPNN)CoCl2; sodium triethylborohydride In tetrahydrofuran; toluene at 25℃; for 0.25h; Inert atmosphere; Glovebox; Schlenk technique; chemoselective reaction;	97%
Stage #1: vinylcyclohexane; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane With 6-di-tert-butylphosphinomethyl-2,2'-bipyridine In tetrahydrofuran for 0.0166667h; Inert atmosphere; Glovebox; Schlenk technique; Stage #2: With sodium triethylborohydride In tetrahydrofuran at 25℃; for 0.5h; Inert atmosphere; Glovebox; Schlenk technique;	93%
With silver hexafluoroantimonate at 60℃; for 24h; Schlenk technique; Glovebox; Inert atmosphere;	92%

: 695-12-5
vinylcyclohexane

: 4559-70-0
Diphenylphosphine oxide

: (2-cyclohexylethyl)diphenylphosphine oxide

Conditions

Conditions	Yield
With 2,2-dimethoxy-2-phenylacetophenone In N,N-dimethyl-formamide for 2h; Solvent; UV-irradiation; Green chemistry;	97%

: 695-12-5
vinylcyclohexane

: 7648-30-8
ethyl 2,2-difluoro-2-iodoacetate

: ethyl 4-cyclohexyl-2,2-difluoro-4-iodobutanoate

Conditions

Conditions	Yield
With diethylzinc In hexane; acetonitrile at -20℃; for 16h; Schlenk technique; Inert atmosphere;	97%
With potassium carbonate In acetone at 20℃; for 16h; Schlenk technique; Inert atmosphere; Irradiation; Green chemistry;	96%
With potassium carbonate In acetone at 20℃; for 16h; Irradiation;	96%

: 695-12-5
vinylcyclohexane

: 2314-97-8
iodotrifluoromethane

: C9H13F3

Conditions

Conditions	Yield
With (dppf)Ni(o-tol)Cl; sodium t-butanolate In Hexafluorobenzene at 50℃; for 16h; Inert atmosphere; Schlenk technique; Sealed tube;	97%

: 695-12-5
vinylcyclohexane

: 59411-58-4, 61414-09-3, 125874-67-1, 87858-06-8
(R)-1-cyclohexylethane-1,2-diol

Conditions

Conditions	Yield
With methanesulfonamide; AD-mix β; water In ethanol at 4℃; for 24h; Sharpless Dihydroxylation;	96%
Stage #1: vinylcyclohexane With 2,2'-bis(1,3,2-benzodioxaborole); (bicyclo[2.2.1]hepta-2,5-diene)-(2,4-pentanedionato)rhodium (I); (S)-1-(2-diphenylphosphino-1-naphthyl)isoquinoline In tetrahydrofuran at 20℃; for 6h; Stage #2: With sodium hydroxide; dihydrogen peroxide Product distribution / selectivity;	81%
Stage #1: vinylcyclohexane With 1,8-diazabicyclo[5.4.0]undec-7-ene; (2R,3S,4R)-2-(((tert-butyldimethylsilyl)oxy)methyl)tetrahydro-2H-pyran-3,4-diol; 2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane In tetrahydrofuran at 20℃; for 48h; Inert atmosphere; Sealed tube; Stage #2: With water; dihydrogen peroxide; sodium hydroxide at 0 - 20℃; for 4h; Inert atmosphere; Sealed tube; enantioselective reaction;	68%

: 695-12-5
vinylcyclohexane

: 401515-97-7
2-pyridylmethyl formate

: pyridin-2-ylmethyl 3-cyclohexylpropanoate

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; dodecacarbonyl-triangulo-triruthenium In N,N-dimethyl-formamide at 70℃; for 12h;	96%
With dodecacarbonyl-triangulo-triruthenium In N,N-dimethyl-formamide at 135℃; for 12h;	87%
With 1,3-bis(1-adamantyl)benzimidazoliumchloride, 1,3-dicyclohexylbenzimidazolium chloride; ruthenium(II) (norbanadiene)Cl2; potassium tert-butylate In tetrahydrofuran at 90℃; for 12h; Reagent/catalyst; Concentration; regioselective reaction;	87%

: 695-12-5
vinylcyclohexane

: 76-02-8
Trichloroacetyl chloride

: 1029080-53-2
2,2-dichloro-3-(cyclohexyl)cyclobutanone

Conditions

Conditions	Yield
With copper; zinc; trichlorophosphate In diethyl ether at 40℃; for 2h;	96%
With zinc/copper couple; trichlorophosphate In diethyl ether Reflux;

: 695-12-5
vinylcyclohexane

: 1104636-73-8
6-methyl-2-vinyl-1,3,6,2-dioxazaborocane-4,8-dione

: 2-(2-cyclohexylvinyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

Conditions

Conditions	Yield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane at 40℃; for 24h; Inert atmosphere; stereoselective reaction;	96%

: 695-12-5
vinylcyclohexane

: 2977-45-9
2,2-dimethyl-3,4-dihydro-2H-naphthalen-1-one

: C20H28O

Conditions

Conditions	Yield
With Fe(PMe3)4 at 70℃; for 20h; Inert atmosphere; regioselective reaction;	96%

: 695-12-5
vinylcyclohexane

: 1263301-67-2
[1-chloro-2-(pentafluoro-λ6-sulfanyl)ethyl]cyclohexane

Conditions

Conditions	Yield
Stage #1: vinylcyclohexane With pentafluorosulfanyl chloride In dichloromethane at -40℃; Stage #2: With triethyl borane In hexane; dichloromethane at -40 - 20℃; Stage #3: With water; sodium hydrogencarbonate In hexane; dichloromethane	95%

: 366-18-7
[2,2]bipyridinyl

: 695-12-5
vinylcyclohexane

: 1402856-01-2
3,3'-bis(2-cyclohexylethyl)-2,2'-bipyridine

Conditions

Conditions	Yield
With rhodium(III) acetylacetonate; 1,3-bis(mesityl)imidazolium chloride; sodium t-butanolate In toluene at 130℃; for 2h; regioselective reaction;	95%

: 695-12-5
vinylcyclohexane

: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

: 1464148-71-7
(3,3,4,4,5,5,6,6,6-nonafluoro-1-iodohexyl)cyclohexane

Conditions

Conditions	Yield
With tri-tert-butyl phosphine; tris(pentafluorophenyl)borate In dichloromethane at 20℃; for 12h; regioselective reaction;	95%
With sodium dithionite; C8ClF16O4S(1-)*C8H20N(1+); sodium hydrogencarbonate In water at 20℃; for 12h;	90%
With tri-tert-butyl phosphine In dichloromethane at 30℃; for 1h; Inert atmosphere; Irradiation; Sealed tube;	87%
With potassium carbonate In acetone at 20℃; for 16h; Schlenk technique; Inert atmosphere; Irradiation; Green chemistry;	79%
With tri-tert-butyl phosphine; tris(pentafluorophenyl)borate In dichloromethane at 20℃; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Sealed tube;

: 695-12-5
vinylcyclohexane

: 775-12-2
diphenylsilane

: (2-cyclohexylethyl)diphenylsilane

Conditions

Conditions	Yield
With sodium methylate In tetrahydrofuran Heating;	95%
With [(2-Ph2PC6H4)2PhSiCo(H)(Cl)(PMe3)] In neat (no solvent) at 70℃; for 30h; Reagent/catalyst; Temperature; Schlenk technique; Inert atmosphere; regioselective reaction;	95%
With (1,3-diadamantylimidazol-2-ylidene)(PPh3)CoCl In toluene at 70℃; for 30h;	89%

: 695-12-5
vinylcyclohexane

: 81602-60-0
1,2-dibromo-1-cyclohexylethane

Conditions

Conditions	Yield
With bromine In chloroform at 0 - 20℃; for 1h; Inert atmosphere;	94%
With bromine
With bromine In tetrachloromethane
With bromine In dichloromethane at 0 - 5℃;
With urea hydrogen peroxide adduct; trifluoroacetic acid; lithium bromide at 100℃; for 1h;

: 695-12-5
vinylcyclohexane

: 19591-17-4
o-iodoacetanilide

: 1-(3-cyclohexylindolin-1-yl)ethan-1-one

Conditions

Conditions	Yield
With bis(1,5-cyclooctadiene)nickel (0); tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; triethylamine; 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene In acetone at 35℃; for 48h; Heck Reaction; Inert atmosphere; Irradiation;	94%

: 695-12-5
vinylcyclohexane

: 2,3-dihydro-1H-benzo[b]silole

: (S)-1-(2-cyclohexylethyl)-2,3-dihydro-1H-benzo[b]silole

Conditions

Conditions	Yield
With C47H47N2O2Sc In benzene-d6 at 75℃; Schlenk technique; Sealed tube; enantioselective reaction;	94%

: 695-12-5
vinylcyclohexane

: 1182669-71-1
N-(2-methylbenzoyl)-8-aminoquinoline

: 2-(2-cyclohexylethyl)-6-methyl-N-(quinolin-8-yl)benzamide

Conditions

Conditions	Yield
With ortho-methylbenzoic acid; di-μ-acetato-bis(η4-1,5-cyclooctadiene)dirhodium(I) In toluene at 160℃; for 12h; Sealed tube;	94%

: 695-12-5
vinylcyclohexane

: 105-56-6
ethyl 2-cyanoacetate

: 2-cyano-4-cyclohexyl-butyric acid ethyl ester

Conditions

Conditions	Yield
With pyridine; Eosin Y; 1,3-dioxoisoindolin-2-yl 3,3-dimethylbutanoate at 23℃; for 14h; Inert atmosphere; Sealed tube; Irradiation;	93%
With dibenzoyl peroxide (heating);

Vinylcyclohexane Specification

The CAS register number of Vinylcyclohexane is 695-12-5. It also can be called as Cyclohexane, vinyl- and the IUPAC name about this chemical is ethenylcyclohexane. The molecular formula about this chemical is C₈H₁₄and the molecular weight is 110.20. Classification code about this chemical is Reproductive Effect. This chemical is flammable. When you are using it, please keep away from sources of ignition.

Physical properties about Vinylcyclohexane are: (1)ACD/LogP: 3.90; (2)ACD/LogD (pH 5.5): 3.9; (3)ACD/LogD (pH 7.4): 3.9; (4)ACD/BCF (pH 5.5): 541.15; (5)ACD/BCF (pH 7.4): 541.15; (6)ACD/KOC (pH 5.5): 3148.54; (7)ACD/KOC (pH 7.4): 3148.54 ; (8)#Freely Rotating Bonds: 1; (9)Index of Refraction: 1.515; (10)Molar Refractivity: 38.45 cm³; (11)Molar Volume: 127.3 cm³; (12)Polarizability: 15.24x10^-24cm³; (13)Surface Tension: 28.8 dyne/cm; (14)Flash Point: 21.1 °C; (15)Enthalpy of Vaporization: 34.96 kJ/mol; (16)Boiling Point: 126.9 °C at 760 mmHg; (17)Vapour Pressure: 13.8 mmHg at 25°C.

Preparation: this chemical can be prepared by 1-(2-trimethylsilanyl-ethyl)-cyclohexanol. This reaction will need reagent BF₃*AcOH and solvent CH₂Cl₂. The reaction time is 5 min with reaction temperature of 25 °C. The yield is about 95%.

Uses of Vinylcyclohexane: it can be used to produce 1-cyclohexyl-ethanone at temperature of 60 ℃. This reaction will need reagent PdCl(NO₂)(CH₃CN)₂and solvent benzene.

You can still convert the following datas into molecular structure:
(1)SMILES: C=C\C1CCCCC1
(2)InChI: InChI=1/C8H14/c1-2-8-6-4-3-5-7-8/h2,8H,1,3-7H2
(3)InChIKey: LDLDYFCCDKENPD-UHFFFAOYAK
(4)Std. InChI: InChI=1S/C8H14/c1-2-8-6-4-3-5-7-8/h2,8H,1,3-7H2
(5)Std. InChIKey: LDLDYFCCDKENPD-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LC50	inhalation	27gm/m³/2H (27000mg/m³)		"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 22, 1986.
mouse	LDLo	oral	4gm/kg (4000mg/kg)	LIVER: FATTY LIVER DEGERATION KIDNEY, URETER, AND BLADDER: OTHER CHANGES	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(7), Pg. 28, 1965.
rat	LC50	inhalation	20500mg/m³ (20500mg/m³)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) LUNGS, THORAX, OR RESPIRATION: CYANOSIS	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(7), Pg. 28, 1965.
rat	LDLo	oral	4gm/kg (4000mg/kg)	LIVER: FATTY LIVER DEGERATION KIDNEY, URETER, AND BLADDER: OTHER CHANGES	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(7), Pg. 28, 1965.

Product Name

VINYLCYCLOHEXANE

Synthetic route

Vinylcyclohexane Specification

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