zinc(II) nitrate
Conditions | Yield |
---|---|
at 20 - 800℃; | 69.8% |
zinc
A
zinc(II) nitrate
Conditions | Yield |
---|---|
In water aq. soln. of Al(NO3)3*9H2O treated with Zn, stirred overnight; filtered, evapd., washed with isopropanol; monitored by XRD; | A n/a B 55.2% |
Conditions | Yield |
---|---|
In nitric acid prepn. by treating of metal carbonate with 70% HNO3 at room temp.; washed (petroleum ether); recrystd. (H2O); dried over fused CaCl2 in desiccator; |
Conditions | Yield |
---|---|
In water formation from Zn(NO2)2 in aq. soln. with O2 or O2 containing gases under pressure above 150°C;; | |
In water formation from Zn(NO2)2 in aq. soln. with O2 or O2 containing gases under pressure above 150°C;; |
zinc(II) nitrate
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: basic zinc nitrates; on dehydration on monohydrate on heating or at room temp. in vacuum, insol. basic zinc nitrates are formed;; | 0% |
In neat (no solvent) byproducts: basic zinc nitrates; on dehydration on monohydrate on heating or at room temp. in vacuum, insol. basic zinc nitrates are formed;; | 0% |
Conditions | Yield |
---|---|
In nitric acid aq. HNO3; oxide dissoln. soln. evapn. to dryness; residue dissoln. in water, soln. evapn. (excess acid removal); | |
In water | |
In water |
Conditions | Yield |
---|---|
In further solvent(s) byproducts: NH3, H2O; on dissolving of ZnO in molten ammonium nitrate;; | |
byproducts: NH3; H2O; |
Conditions | Yield |
---|---|
In water Irradiation (UV/VIS); addition of solid ZnO to a solution of AgNO3 in H2O; sun light (day light) irradiation;; |
Conditions | Yield |
---|---|
byproducts: Ag, O2; Irradiation (UV/VIS); irradiated ZnO is reacting with AgNO3;; |
Conditions | Yield |
---|---|
on react. of N2O5 in a closed apparatus;; small amt. of ZnO and Zn(NO2)2;; | |
on react. of N2O5 in a closed apparatus;; small amt. of ZnO and Zn(NO2)2;; |
Conditions | Yield |
---|---|
In nitric acid on solvolysis of anhydrous zinc picrate with abs. HNO3; | 0% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In neat (no solvent) heating to 130 to 135°C in a atmosphere of water-free HNO3;; | |
In neat (no solvent) heating to 130 to 135°C in a atmosphere of water-free HNO3;; |
nitric acid
zinc(II) nitrate
Conditions | Yield |
---|---|
With zinc(II) chloride no reaction at low temp.; | 0% |
With zinc(II) chloride | |
With ZnCl2 | |
With ZnCl2 no reaction at low temp.; | 0% |
Conditions | Yield |
---|---|
In water addn. of 0.1 n-HNO3 at 25 °C; formation of HNO2 postulated; no NH4OH found;; | |
In water |
Conditions | Yield |
---|---|
In water byproducts: nitrous gases; dild. HNO3; hydroxylamine nitrate as intermediate reacts with Zn to form Zn-ammoniumhydroxide which reacts with H2O to give Zn(OH)2 and NH3;; | |
In water |
Conditions | Yield |
---|---|
dissolving in HNO3;; | |
dissolving in HNO3;; |
zinc
A
zinc(II) nitrate
B
nitrogen
C
ammonia
D
water
Conditions | Yield |
---|---|
10-20°C above the melting-point; |
Conditions | Yield |
---|---|
byproducts: NH3, N2, H2O; vigorous react. of Zn with molten NH4NO3;; |
dinitrogen tetraoxide
zinc
A
zinc(II) nitrate
B
dinitrogen trioxide
Conditions | Yield |
---|---|
In sulfolane byproducts: NO; React. of Zn powder with excess of N2O4 in sulfolane.; Distn. of NO, N2O3 and of excess N2O4 in vac.; |
Conditions | Yield |
---|---|
With zinc sulfide byproducts: H2S; NH3; H2O; |
Conditions | Yield |
---|---|
In water byproducts: KAg(CN)2; react. of an aq. soln. of Zn(CN)2*2KCN with AgNO3;; | |
In water byproducts: KAg(CN)2; react. of an aq. soln. of Zn(CN)2*2KCN with AgNO3;; |
Conditions | Yield |
---|---|
With H2O decompn.;; | |
With water decompn.;; |
zinc(II) nitrate
Conditions | Yield |
---|---|
With 3 A molecular sieve In N,N-dimethyl-formamide Zn(NO3)2*99H2O dissolved in DMF, treated with 3A Molecular Sieves undervac.; |
zinc(II) nitrate
Conditions | Yield |
---|---|
With air In neat (no solvent) in a stream of dry air at 105°C;; | |
With air In neat (no solvent) in a stream of dry air at 105°C;; | 0% |
With air In neat (no solvent) in a stream of dry air at 105°C;; | |
With air In neat (no solvent) in a stream of dry air at 105°C;; | 0% |
21-(4-nitrobenzyl)-5,10,15,20-tetrakis(4-sulfonatophenyl)-23H-porphyrinatozinc(II)
nitric acid
zinc(II) nitrate
Conditions | Yield |
---|---|
In water Kinetics; 25°C, 0.1 M NaNO3, organic byproduct: 21-(4-nitrobenzyl)- 5,10,15,20-tetrakis(4-sulfonatophenyl)-23H-porphyrin; variation of HNO3 concn. and temperature; UV-monitoring; |
zinc(II) nitrate
Conditions | Yield |
---|---|
With O2 In water on react. of O2 on aq. Zn(NO2)2 under pressure above 150°C, formation of nitrate;; | |
With oxygen In water on react. of O2 on aq. Zn(NO2)2 under pressure above 150°C, formation of nitrate;; |
Conditions | Yield |
---|---|
In water byproducts: Ag2O, NaNO3; | |
In water byproducts: Ag2O, NaNO3; |
Conditions | Yield |
---|---|
With nitrous gases In water on introduction of nitrous gases into an aq. suspension of Zn(OH)2, formation of nitrite beside nitrate;; | |
With nitrous gases In water on introduction of nitrous gases into an aq. suspension of Zn(OH)2, formation of nitrite beside nitrate;; |
Conditions | Yield |
---|---|
In sodium hydroxide High Pressure; 2 M Zn(NO3)2 neutralized with 2 M NaOH to pH 11; heated with microwave treatment (100°C, 15 psi, 2 min); solid sepd. (centrifugation), washed (deionized H2O, EtOH), dried; XRD; | 100% |
In sodium hydroxide Sonication; 2 M Zn(NO3)2 neutralized with 2 M NaOH to pH 12; heated with microwave treatment (100°C, 15 or 30 min); solid sepd. (centrifugation), washed (deionized H2O, EtOH), dried; XRD; | 99.7% |
In sodium hydroxide High Pressure; 2 M Zn(NO3)2 neutralized with 2 M NaOH to pH 12; heated with microwave treatment (100°C, 15 psi, 2 min); solid sepd. (centrifugation), washed (deionized H2O, EtOH), dried; XRD; | 98.3% |
Conditions | Yield |
---|---|
With 1,2-ethanediol In water byproducts: C2H2O4(2-); by thermal decompn. of complex combination isolated in heat by oxidn. inaq. soln. of 1,2-ethanediol to C2H2O4(2-) by Ni(II), Zn(II), Fe(III) ni trates; heated at 500-900°C for 3 h; detd. by XRD; | 100% |
zinc(II) nitrate
phosphoric acid
water
1,2-diaminocyclohexane
Conditions | Yield |
---|---|
In water hydrothermal conditions, 180°C; | 100% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In methanol; dichloromethane room temp.; | 100% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In methanol reflux (5 days); washing (MeOH, water, acetone), filtn., drying (room temp.); | 100% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In methanol reflux (5 days); washing (MeOH, water, acetone), filtn., drying (room temp.); | 100% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In methanol reflux (5 days); washing (MeOH, water, acetone), filtn., drying (room temp.); | 100% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In methanol reflux (5 days); washing (MeOH, water, acetone), filtn., drying (room temp.); | 100% |
zinc(II) nitrate
2,6-bis[(bis(2-pyridylmethyl)amino)methyl]-4-fluorophenol
Conditions | Yield |
---|---|
In methanol at 20℃; for 0.75h; | 100% |
Conditions | Yield |
---|---|
In methanol; water for 0.5h; | 100% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In methanol; dichloromethane Inert atmosphere; | 100% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In methanol; dichloromethane at 20℃; Inert atmosphere; | 100% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In methanol; dichloromethane at 20℃; Inert atmosphere; | 100% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In methanol; dichloromethane at 20℃; for 1h; Inert atmosphere; | 100% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In methanol; dichloromethane Inert atmosphere; | 100% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In methanol; dichloromethane Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
In methanol; water for 0.5h; | 100% |
zinc(II) nitrate
9,10-bis[(2,2′-dipicolylamino)methyl]anthracene
Conditions | Yield |
---|---|
In methanol; dichloromethane at 20℃; for 1h; | 100% |
Conditions | Yield |
---|---|
In water shaking, keeping at 50°C overnight; filtration, drying; | 99.4% |
zinc(II) nitrate
zinc(II) thiocyanate
Conditions | Yield |
---|---|
With KSCN In ethanol KSCN reacted with metal nitrate in EtOH; | 99% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In water pptn. on addn. of metal nitrate to Pt-complex (contg. NaCl as impurity); elem. anal.; | 99% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In water pptn. on addn. of metal nitrate to Pt-complex (contg. NaCl as impurity); elem. anal.; | 99% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In water pptn. on addn. of metal nitrate to Pt-complex (contg. NaCl as impurity); elem. anal.; | 99% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In water pptn. on addn. of metal nitrate to Pt-complex (contg. NaCl as impurity); elem. anal.; | 99% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In water pptn. on addn. of metal nitrate to Pt-complex (contg. NaCl as impurity); elem. anal.; | 99% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In methanol; dichloromethane to a soln. of cluster (CH2Cl2) added a satrd. soln. of metal salt (methanol), stirred for 5 min; diethyl ether vap. diffused overnight; elem. anal.; | 99% |
zinc(II) nitrate
Conditions | Yield |
---|---|
In dichloromethane; acetonitrile Zn-contg. compd. (0.05 mmol) was added to a soln. of Fe-contg. compd. (0.05 mmol) in CH3CN/CH2Cl2 (1:5, resp.); the soln. became immediately orange; stirring for 4 h at room temp.; the solvent was evapd. to dryness; | 99% |
Molecule structure of Zinc nitrate hexahydrate (CAS NO.10196-18-6):
IUPAC Name: Zinc dinitrate hexahydrate
Molecular Weight: 297.51048 g/mol
Molecular Formula: H12N2O12Zn
Density: 2.065 g/mL at 25 °C(lit.)
Melting Point: 36 °C(lit.)
Water Solubility: 1800 G/L (20 °C)
H-Bond Donor: 6
H-Bond Acceptor: 12
Exact Mass: 295.96817
MonoIsotopic Mass: 295.96817
Topological Polar Surface Area: 138
Heavy Atom Count: 15
Canonical SMILES: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.[Zn+2]
InChI: InChI=1S/2NO3.6H2O.Zn/c2*2-1(3)4;;;;;;;/h;;6*1H2;/q2*-1;;;;;;;+2
InChIKey: JGPSMWXKRPZZRG-UHFFFAOYSA-N
EINECS: 231-943-8
Product Categories: Essential Chemicals; Reagent Grade; Routine Reagents
Zinc nitrate hexahydrate (CAS NO.10196-18-6) is mainly used for machines and bicycle parts galvanized, preparation of steel phosphating agent. It is also used as a mordant in dyeing. And it's used as analytical reagent, but also for the pharmaceutical industry.
The following is the reaction fomular of preparation of Zinc nitrate hexahydrate .
ZnO +2 HNO3 → Zn (NO3) 2 + H2O
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intraperitoneal | 110mg/kg (110mg/kg) | SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION SKIN AND APPENDAGES (SKIN): HAIR: OTHER | Veterinary and Human Toxicology. Vol. 30, Pg. 224, 1988. |
mouse | LD50 | oral | 926mg/kg (926mg/kg) | SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION SKIN AND APPENDAGES (SKIN): HAIR: OTHER | Veterinary and Human Toxicology. Vol. 30, Pg. 224, 1988. |
rat | LD50 | intraperitoneal | 133mg/kg (133mg/kg) | SENSE ORGANS AND SPECIAL SENSES: MIOSIS (PUPILLARY CONSTRICTION): EYE VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION | Veterinary and Human Toxicology. Vol. 30, Pg. 224, 1988. |
rat | LD50 | oral | 1190mg/kg (1190mg/kg) | "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 10, 1972. |
Zinc and its compounds are on the Community Right-To-Know List.
Hazard Codes: O, Xn
Risk Statements: 8-22-36/37/38-38
R8 :Contact with combustible material may cause fire.
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
R38:Irritating to skin.
Safety Statements: 17-26-24/25
S17:Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24/25:Avoid contact with skin and eyes.
RIDADR: UN 1514 5.1/PG 2
WGK Germany: 3
RTECS: ZH4775000
HazardClass: 5.1
PackingGroup: II
Moderately toxic by ingestion. A severe skin and eye irritant. Can react violently with carbon; copper; metal sulfides; organic matter; phosphorus; sulfur. When heated to decomposition it emits toxic fumes of NOx and ZnO. See also ZINC COMPOUNDS and NITRATES.
Zinc nitrate hexahydrate (CAS NO.10196-18-6) is also named as CCRIS 8894 ; Dusicnan zinecnaty ; Dusicnan zinecnaty [Czech] ; Nitric acid, zinc salt, hexahydrate ; Zinc(II) nitrate, hexahydrate (1:2:6) . Zinc nitrate hexahydrate (CAS NO.10196-18-6) is white crystal. It is soluble in water and ethanol .
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