A new method for synthesis of graphene-protected iron silicides has been tested, which consists in formation of graphene on Ni(111) followed by two-step intercalation of the system with Fe and Si. Characterization of the samples was performed in situ by low-energy electron diffraction, angular-r...
Silicon/iron silicide/three-dimensional (3D) carbon nanocomposite anodes with tunable pore structures have been prepared by a simple and environmentally benign method, which can be used to control not only the internal porosity of agglomerated anode particles, but also the density of their 3D ne...
We have investigated thermoelectric properties of oxygen-included iron-silicide thin films prepared by facing target sputtering for applying them to thermoelectric devices. The highest Seebeck coefficient of 17.84 μV/K are obtained. It is the first attempt to investigate thermoelectric properti...
The effect of local environment on the formation of magnetic moments on Fe atoms in iron silicides is studied by combination of ab initio and model calculations. The suggested model includes all Fe d- and Si p-orbitals, intra-atomic Coulomb interactions, inter-atomic Fe-Fe exchange and hopping o...
Single-walled carbon nanotubes (SWNTs) are synthesized from iron silicide (FeSi) catalyst by the chemical vapor deposition (CVD). During the growth process, Fe atoms migrate onto the FeSi surface and form active Fe nanoparticles, catalyzing the growth of SWNTs. The produced SWNTs demonstrate a n...
The effect of the tensile stress applied during ion beam synthesis of thin silicide films on magnetic properties is studied. The magneto-optical Kerr effect revealed the existence of both magnetically anisotropic and isotropic regions in the synthesized thin film. In the isotropic regions, the i...
The magnetic properties of the nine title compounds were studied by magnetic susceptibility measurements with a SQUID magnetometer between 2 and 300 K. At temperatures above 100 K, all compounds with the exception of the cerium and samarium compounds show Curie-Weiss behaviour. The effective mag...
Gallium antimonide (GaSb) which is a narrow band gap compound semiconductor has received attention because of its potential applications in optoelectronic devices. In the present work, p-type GaSb wafers of 〈1 0 0〉 orientation were irradiated with 70 MeV 56Fe ions at fluences varying from 1 ×...
Surface modifications caused by a swift heavy ion irradiation on crystalline p-type gallium antimonide crystal have been reported. Single crystal, 1 0 0〉 orientations and ∼500 μm thick p-type GaSb samples with carrier concentration of 3.30 × 1017 cm−3 were irradiated at 100 MeV Fe7+ ions. We...
Lanthanum gallium manganese antimonide La12Ga3.5Mn0.5Sb23.5 is the first quaternary rare-earth antimonide containing a p-block metal and a transition metal. It has been synthesized by reaction of the elements and its structure has been determined by single-crystal X-ray diffraction methods (orth...
Polycrystalline samples of the ZrCuSiAs type antimonide oxides REZnSbO and REMnSbO (RE = Ce, Pr) were prepared from RESb precursors and MnO, respectively ZnO via a ceramic route. X-ray photoelectron spectroscopy (XPS) studies are used to investigate the charge assignments. For comparison the CeO...
Single crystal gallium antimonide substrate was implanted with 200 keV iron ions with different ion fluences varying from 1 × 1014 to 1 × 1016 cm− 2. Optical and structural properties have been investigated using the micro-Raman, Fourier transform infrared and grazing-angle X-ray diffraction m...
The newly synthesized alkali metal iron antimonides with a filled skutterudite structure NaFe4Sb12 and KFe4Sb12 together with the known BaFe4Sb12 have been investigated by means of specific heat and AC susceptibility measurements. The alkali metal samples exhibit ferromagnetism below 85 K and al...
The Λ-S electronic states with respect to the lowest four dissociation limits of BeSb are investigated theoretically on the icMRCI + Q level employing basis set of quintuple-ζ quality. The geometrical parameters, potential energy curves, vibrational energy levels, spectroscopic constants for t...
The effect of 100 MeV irradiation of iron ions in p-type gallium antimonide for ion fluences varying from 1 × 1011 to 5 × 1013 cm−2 was investigated using Raman scattering, Fourier transform infrared and X-ray diffraction measurements. Raman spectra showed a strong peak at 232.82 cm−1 (LO) and...
A surface functionalization system targeted for iron-based materials is developed by combining two biodegradable components, iron oxide nanostructured arrays and polycaprolactone (PCL) coatings. Iron oxide nanoporous and nanotubular arrays are superior surface functionalization matrices, while t...
This study aims to investigate how the photocatalytic efficiency of zinc oxide can be improved by introducing doping species into its crystal lattice. New materials based on zinc oxide doped with iron, have been synthesized using different methods, characterized and tested toward the abatement o...
The analysis of the tribological behavior of a steel ball on pure titanium has been carried out under alternative motion on both, a coarse grained Ti surface and its nanostructured derivative obtained by surface mechanical attrition treatment (SMAT). Along the duration of the tribology test, var...
The effectiveness of the current UK iron oxide powder suspension formulation, ‘C-IOPS-09’ (Triton X-100 based), for fingermark or latent fingerprint visualization is shown to be affected by variations between batches of the recommended iron oxide powder from Fisher Scientific (I/1100/53). When...
The structure and the properties of the oxide films formed on titanium by means of plasma electrolytic oxidizing at direct current density of 1 – 5 A·dm−2 have been studied. Composition of citrate-pyrophosphate electrolytes with addition of iron triad metals’ sulfates were proposed for the fo...
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