For the first time, poly (o-anisidine-co-metanilic acid) (PASM) was deposited on mild steel substrate by electrochemical polymerization of o-anisidine and metanilic acid monomers in aqueous solution of 0.1 M H2SO4. The electrochemical polymerization of o-anisidine takes place in the presence of ...
In order to investigate the effect of a strongly hydrophilic substituent group on the anticorrosion properties of polyaniline (PANI) coatings, sulfonic acid groups (SO3H) were introduced into the polyaniline molecular structure by the copolymerization of aniline (ANI) and 3-aminobenzenesulfonic ...
Nanostructured poly(aniline-co-metanilic acid) is prepared using the chemical oxidative polymerization of aniline (Ani) and metanilic acid (Maa). The copolymerization of poly(aniline-co-metanilic acid) with various molar feed ratios of Ani/Maa is conducted to attain highly porous nanowire copoly...
The hydroformylation of norbornene catalysed by [Pt(C2H4)(dppb)]/CH3SO3H (dppb = 1,4-bis(diphenylphosphino)butane) occurs under standard oxo conditions giving the exo-norbornanecarboxaldehyde exclusively. The deuteroformylation of this olefin shows that the addition of H and CHO groups is cis. A...
A kinetic investigation of the selective hydrogenation of 2,5-norbornadiene to norbornene catalyzed by [Rh(NBD)(PPh3)2]BF4 (1) has been carried out in dichloromethane at room temperature. The reaction is independent of the substrate concentration, while it is first order in catalyst and hydrogen...
Co(acac)x-Dppe-EtyAl2Cl6-y (x =2, 3; y=3,4) system promotes the codimerization of 2,5-norbornadiene (1) with ethylene to give a mixture of 3-vinylnortricyclene (2), 5-vinyl-2-norbornene (3) and deltacyclane (4). A maximum turnover (C9/Co) of 46.3 for the codimers is achieved with the cobalt syst...
Mitochondria from iris (Iris hollandica cv. Ideal) bulbs (circumference 7–8 cm) that have been treated with ethylene to evoke early flowering show an induction of alternative respiratory capacity and a rise in state 3 respiration. Mitochondria from untreated control bulbs have no alternative re...
Complex OsHCl(CO)(PiPr3)2 catalyzes the ring-opening metathesis polymerization (ROMP) of norbornene and 2,5-norbornadiene to give poly(norbornene) and poly(norbornadiene), respectively. In both cases the resulting polymers have a high cis (74–95%) content. The stereoregularity or tacticity of t...
The production of C7Hn2+ (with n = 6, 8) dications from 2,5-norbornadiene (NBD) and their reactivity toward Xe and N2 are studied using multipole-based tandem mass spectrometry techniques coupled with ionization either by collisions with energetic electrons or with tunable VUV photons coming fro...
Producing impurity-doped diamond films is a critical task for modern electronic applications. In this study, the effects of phosphorus in the gas phase on the morphological features of polycrystalline diamond films were investigated. The diamond films were prepared on n-type Si(100) substrates b...
The reaction of substitution of carbon monoxide by P(OMe)3 in the complex (μ-η2PhC(S) = C(S)Ph)Fe2(CO)6 1 under thermal activation afforded two colored compounds: a binuclear disubstituted complex (μ-PhC(S) = C(S)Ph)Fe2(CO)4 [P(OMe)3]2 2 and a mononuclear iron disubstituted complex (η2PhC(S)...
Infrared and Raman data were used to assign the vibrational spectrum of trimethyl phosphite. The assignment was aided by comparison of the infrared and Raman data for trimethyl phosphite with the known infrared and Raman data and assignments for phosphorous triflouride and trimethyl phosphate.Th...
Trimethyl phosphite (TMP) is an organophosphorus alkylating agent used primarily in the synthesis of organophosphate compounds. To evaluate teratogenic potential, TMP was administered by gavage to pregnant rats at rates of 16, 49, or 164 mg/kg/day, on gestation Days 6 through 15. Acetyl salicyli...
The oxidation of triphenylphosphine to the corresponding oxide in pyridine is faster in the presence of FeIII compounds, especially FeCl3. Even greater effects are seen for the oxidation of trimethyl phosphite.
The purpose of this paper is to investigate compositions on the interface between LiCoO2 and electrolyte when trimethyl phosphite TMP(i) is used as an additive in 1 M LiPF6/EC + DEC electrolyte system and the thermal stability of the electrolyte as well as Li0.5CoO2 mixed with the electrolyte. T...
Safety concerns of lithium ion batteries have been the key problems in their practical applications. Trimethyl phosphite (TMP(i)) and trimethyl phosphate (TMP(a)) were used as the electrolyte additives to improve the safety and electrochemical performance of lithium cells. Gallvanostatic cell cy...
In the present work we have studied the structure and the acidic properties of HZSM-5 zeolite modified with trimethyl phosphite. The modifications were carried out by using a chemical vapour deposition method as well as impregnation from n-octane solution. Both modification techniques resulted i...
Lithium-rich layered oxide cathode is a promising high-capacity cathode material for high-energy lithium-ion batteries. However, to achieve its high capacity, the development of high-voltage electrolytes is essential. In this work, trimethyl phosphite (TMP) is investigated as an electrolyte addi...
Triethylamine (TEA), a high-molecular amine, has a terrible desorption rate on oxide surfaces, and it remains a challenge to develop a rapid response sensor to detect it. Herein, Cr-doped α-MoO3 nanorods have been prepared through a grinding and subsequent annealing route. The microstructure of...
Microalgae have become increasingly attractive as feedstocks for biodiesel production since they have many advantages over traditional raw materials, such as strong carbon fixation ability, high growth rate, not competing with arable land etc. In this study, different concentrations of triethyla...
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