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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1-(Ferrocenyl)Ethanol supplier in China

Cas:1277-49-2

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1-(Ferrocenyl)Ethanol

Cas:1277-49-2

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1-(2-Hydroxyethyl)-ferrocene

Cas:1277-49-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 1277-49-2 with best quality

Cas:1277-49-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 1-(Ferrocenyl)ethanol CAS: 1277-49-2 MF: C12H14FeO10* MW: 230.08 EINECS: 625-176-1 Mol File: 1277-49-2.mol 1-(Ferrocenyl)ethanol Structure 1-(Ferrocenyl)ethanol Chemical Properties Melting point 76-79 °C(lit.

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

1-(FERROCENYL)ETHANOL

Cas:1277-49-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

(1-hydroxyethyl)-ferrocen

Cas:1277-49-2

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:1 Kilogram

FOB Price: $65.0 / 75.0

Type:Trading Company

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

1277-49-2 CAS NO.1277-49-2

Cas:1277-49-2

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

1,1-(Ferrocenyl)ethanol Cas no.1277-49-2 98%

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

1-Hydroxyethylferrocene

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1-Hydroxyethylferrocene

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

1-(Ferrocenyl)Ethanol

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:yellow to yellow-orange crystalline powder Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

1-(Ferrocenyl)Ethanol

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

1277-49-2

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

1-(Ferrocenyl)ethanol cas 1277-49-2Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1-(Ferrocenyl)ethanol cas 1277-49-2

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1-(Ferrocenyl)ethanol

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:White powder Storage:keep sealed and keep from direct light Package:According client's requirements Application:pharmaceutica

1-(Ferrocenyl)Ethanol manufacturer

Cas:1277-49-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

acetylferrocene
1271-55-2

acetylferrocene

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; C39H45FeN2O2PS; hydrogen; sodium methylate In methanol at 40℃; for 12h; Reagent/catalyst; Solvent; Autoclave; Large scale;99%
With LiAlH4 In diethyl ether LiAlH4 (10.54 mmol) added in portion to soln. of acetylferrocene (4.38 mmol) (0°C) under N2; stirred (room temp., 3 h);; cooled to 0°C; H2O added; ether added; org. layer sepd.; aq. layer extd. with ether; combined org. layers dried over Na2SO4; filtered; concd.;97%
With potassium tert-butylate; hydrogen; tetracarbonyl(2-(diphenylphosphino)-ethylamine)chromium(0) In diethylene glycol dimethyl ether at 120℃; under 37503.8 Torr; for 14h; Autoclave;97%
ferrocenecarboxaldehyde
12093-10-6

ferrocenecarboxaldehyde

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With LiAlH4 In diethyl ether Ar-atmosphere; addn. of acetylferrocene to excess LiAlH4 (15-20°C, stirring); addn. of satd. aq. NH4Cl (cooling to 0-5°C), washing of org. layer (water), drying (Na2SO4), solvent removal;93%
acetylferrocene
1271-55-2

acetylferrocene

water
7732-18-5

water

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With samarium diiodide In tetrahydrofuran N2-atmosphere; molar ratio SmI2:ferrocene derivative:water=2.6:1:11, 25°C, 10 min; addn. of ice water, filtration over SiO2, concn.;92%
ferrocenecarboxaldehyde
12093-10-6

ferrocenecarboxaldehyde

A

vinyl ferrocene
1271-51-8

vinyl ferrocene

B

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With methylmagnesium bromide In not given Wittig reaction;;A 6%
B 90%
With CH3MgBr In not given Wittig reaction;;A 6%
B 90%
methyl magnesium iodide
917-64-6

methyl magnesium iodide

ferrocenecarboxaldehyde
12093-10-6

ferrocenecarboxaldehyde

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
In diethyl ether reflux;85.3%
lithium borohydride

lithium borohydride

acetylferrocene
1271-55-2

acetylferrocene

A

vinyl ferrocene
1271-51-8

vinyl ferrocene

B

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
In methanol lithium borohydride (5.0 equiv.) added to a soln. of the ferrocenyl ketone (1.0 equiv.) in methanol, stirred at room temp. overnight (16 h), water added; extracted with ether, dried (MgSO4), concentrated in vacuo, crude product purified by flash column chromy. on silica gel (TLC Rf 0.66 (1:3 acetone-hexane)), elem. anal.;A 2%
B 77%
vinyl ferrocene
1271-51-8

vinyl ferrocene

A

1-ethylferrocene

1-ethylferrocene

B

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

C

butane-2,3-diyldiferrocene

butane-2,3-diyldiferrocene

D

C5H5FeC5H4CH(CH3)OC2H5

C5H5FeC5H4CH(CH3)OC2H5

Conditions
ConditionsYield
In ethanol Irradiation (UV/VIS); UV-photolysis in abs. ethanol; mechanism discussed;;A 4%
B 9%
C 4%
D 58%
In ethanol Irradiation (UV/VIS); UV-photolysis in abs. ethanol, presence of H2O; mechanism discussed;;A n/a
B 0%
C n/a
D n/a
acetylferrocene
1271-55-2

acetylferrocene

(2,2'-bipyridyl)(tetrahydroborato)zinc

(2,2'-bipyridyl)(tetrahydroborato)zinc

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
In acetonitrile addn. of Zn complex to soln. of ferrocene derivative in CH3CN at room temp., strirred for 45 min at room temp., addn. of soln. of FeCl3*6H2O, stirred for 20 min; extraction with CH2Cl2, dried (MgSO4), evapn. of solvent, chromy. (silica gel / CCl4/Et2O: 5/2);50%
1-methoxyethyl ferrocene

1-methoxyethyl ferrocene

A

acetylferrocene
1271-55-2

acetylferrocene

B

vinyl ferrocene
1271-51-8

vinyl ferrocene

C

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With aluminum oxide In n-heptane ambient temp., neutral Al2O3;;A 6%
B 3%
C 44%
lithium aluminium tetrahydride
16853-85-3

lithium aluminium tetrahydride

acetylferrocene
1271-55-2

acetylferrocene

A

vinyl ferrocene
1271-51-8

vinyl ferrocene

B

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
In tetrahydrofuran room temp., 16 h;
S-(1-ferrocenylethyl)thioglycolic acid

S-(1-ferrocenylethyl)thioglycolic acid

aniline
62-53-3

aniline

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

hydrogenchloride
7647-01-0

hydrogenchloride

(C5H5)Fe(C5H4CH(CH3)OCH2COOCH3)
191876-57-0

(C5H5)Fe(C5H4CH(CH3)OCH2COOCH3)

A

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

B

α,α'-diferrocenyldiethyl ether

α,α'-diferrocenyldiethyl ether

Conditions
ConditionsYield
In diethyl ether addn. of aq. HCl (1:1) to Fe-complex soln., stirring (room temp., 24 h); TLC (SiO2); product mixt. not sepd., detd. by NMR spectroscopy;
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

acetylferrocene
1271-55-2

acetylferrocene

A

vinyl ferrocene
1271-51-8

vinyl ferrocene

B

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
In methanol room temp., 16 h;
(C5H5)Fe(C5H4CH(CH3)N(CH3)3)(1+)*I(1-)=[(C5H5)Fe(C5H4CH(CH3)N(CH3)3)]I

(C5H5)Fe(C5H4CH(CH3)N(CH3)3)(1+)*I(1-)=[(C5H5)Fe(C5H4CH(CH3)N(CH3)3)]I

A

vinyl ferrocene
1271-51-8

vinyl ferrocene

B

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
In water decompn. in H2O at 20-40°C;;A <1
B n/a
In water decompn. in H2O at 20-40°C;;A <1
B n/a
hydrogen azide

hydrogen azide

vinyl ferrocene
1271-51-8

vinyl ferrocene

A

acetylferrocene
1271-55-2

acetylferrocene

B

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

C

1-ferrocenylethyl acetate

1-ferrocenylethyl acetate

D

1-azido-ethylferrocene

1-azido-ethylferrocene

Conditions
ConditionsYield
With acetic acid In benzene
With CH3COOH In benzene
fc-CHCl(CH3)

fc-CHCl(CH3)

A

acetylferrocene
1271-55-2

acetylferrocene

B

vinyl ferrocene
1271-51-8

vinyl ferrocene

C

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With water In water reaction with Na at -78°C or with Mg at -10°C, hydrolysis at ambient temp.; yield of products depends on conditions;;
fc-CHCl(CH3)

fc-CHCl(CH3)

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With water; sodium carbonate In water -78°C;;
{C5H5FeC5H4CHCH3}(1+)*BF4(1-)={C5H5FeC5H4CHCH3}BF4

{C5H5FeC5H4CHCH3}(1+)*BF4(1-)={C5H5FeC5H4CHCH3}BF4

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With hydroxide In water alkaline hydrolysis;;
With OH(1-) In water alkaline hydrolysis;;
C5H5FeC5H4C(CH3)N2

C5H5FeC5H4C(CH3)N2

A

acetylferrocene
1271-55-2

acetylferrocene

B

vinyl ferrocene
1271-51-8

vinyl ferrocene

C

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

D

1,2-diferrocenyl-1-methyl cyclopropane

1,2-diferrocenyl-1-methyl cyclopropane

E

(C10H9FeCH(CH3)N)2

(C10H9FeCH(CH3)N)2

Conditions
ConditionsYield
In benzene
In benzene
In benzene
(C5H5)Fe(C5H4CH(CH3)N(CH3)3)(1+)*I(1-)=[(C5H5)Fe(C5H4CH(CH3)N(CH3)3)]I

(C5H5)Fe(C5H4CH(CH3)N(CH3)3)(1+)*I(1-)=[(C5H5)Fe(C5H4CH(CH3)N(CH3)3)]I

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With water In water
With water In tetrahydrofuran; water Kinetics; 50°C, 50 Vol.-% H2O;
With H2O In water; acetone Kinetics; 10-40 Vol.-% H2O, 50°C;
sodium dicarbonyl(cyclopentadienyl)ferrate

sodium dicarbonyl(cyclopentadienyl)ferrate

fc-CO-CH2-Fe(CO)2C5H5

fc-CO-CH2-Fe(CO)2C5H5

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
byproducts: C10H9FeCOCH3, (C5H5Fe(CO)2)2;
byproducts: C10H9FeCOCH3, (C5H5Fe(CO)2)2;
fc-CO-CH2-Fe(CO)2C5H5

fc-CO-CH2-Fe(CO)2C5H5

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride byproducts: C10H9FeCOCH3, (C5H5Fe(CO)2)2;
With LiAlH4 byproducts: C10H9FeCOCH3, (C5H5Fe(CO)2)2;
C10H9FeCH(CH3)OSO2F

C10H9FeCH(CH3)OSO2F

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With water
(+)-(R)-C10H9FeCH(CH3)-S-CS-S-CH3

(+)-(R)-C10H9FeCH(CH3)-S-CS-S-CH3

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With LiAlH4 11-28 % retention of configuration;
With LiAlH4 In diethyl ether addn. of LiAlH4 to starting complex soln. in diethyl ether at 0°C under N2, reaction for 1 h; addn. of dil. NaOH or water at 0 or 25°C;
fc-CHCH3-Zr(C5H5)2Cl

fc-CHCH3-Zr(C5H5)2Cl

A

(μ-oxo)bis[chlorobis(cyclopentadienyl)zirconium(IV)]

(μ-oxo)bis[chlorobis(cyclopentadienyl)zirconium(IV)]

B

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With water In diethyl ether; water
With H2O In diethyl ether; water
ferrocenylmethyl acetate

ferrocenylmethyl acetate

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With methanol In methanol Kinetics; methanolysis at 0°C; IR;
4-(1-ferrocenylethoxy)-3-methoxybenzaldehyde

4-(1-ferrocenylethoxy)-3-methoxybenzaldehyde

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With water In acetone byproducts: vanillin; heating in aq. acetone;>99
4-(1-ferrocenylethoxy)benzaldehyde

4-(1-ferrocenylethoxy)benzaldehyde

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With silica gel In not given byproducts: p-hydroxybenzaldehyde; hydrolysis during an attempt of purification on a SiO2 column;>99
(C6H5)CN4H(CH(CH3)(C5H4)Fe(C5H5))(1+)*BF4(1-)=[C6H5CN4H(CH(CH3)(C5H4)Fe(C5H5))]BF4
207301-27-7

(C6H5)CN4H(CH(CH3)(C5H4)Fe(C5H5))(1+)*BF4(1-)=[C6H5CN4H(CH(CH3)(C5H4)Fe(C5H5))]BF4

A

5-Phenyl-1H-tetrazole
18039-42-4

5-Phenyl-1H-tetrazole

B

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

Conditions
ConditionsYield
With sodium hydroxide In water refluxing (5-10 min), cooling to 5 to 7°C; ppt. filtration off, washing (hot pentane), Fe-compd. obtaining from pentane extracts by drying, tetrazole remaining in the solid residue;
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

α-hydroxyethylferrocene*γ-cyclodextrin

α-hydroxyethylferrocene*γ-cyclodextrin

Conditions
ConditionsYield
In water molar ratio cyclodextrin : ferrocene = 1:2, addn. of crystals of ferrocene to an aq. soln. of cyclodextrin at 60°C with stirring; washed with water and THF, recrystn. from water or aq. alcohol; elem. anal.;100%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

β-cyclodextrin decahydrate

β-cyclodextrin decahydrate

α-hydroxyethylferrocene*β-cyclodextrin*2H2O

α-hydroxyethylferrocene*β-cyclodextrin*2H2O

Conditions
ConditionsYield
In water molar ratio cyclodextrin : ferrocene = 1:2, addn. of crystals of ferrocene to an aq. soln. of cyclodextrin at 60°C with stirring; washed with water and THF, recrystn. from water or aq. alcohol; elem. anal.;100%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

mercaptoacetic acid
68-11-1

mercaptoacetic acid

S-(1-ferrocenylethyl)thioglycolic acid

S-(1-ferrocenylethyl)thioglycolic acid

Conditions
ConditionsYield
With potassium hydroxide; trifluoroacetic acid In acetone addn. of 1.1 equiv. of mercapto-acid to Fe-complex soln., cooling to 0°C, addn. of CF3COOH, standing (room temp., overnight); addn. of 5% aq. KOH, treatment with CH2Cl2, addn. of few drops H3PO4 to aq. layer, extn. into CH2Cl2, shaking of extract with H2O, drying (MgSO4), evapn., recrystn. (hexane/C6H6 or EtOAc, not specified); elem. anal.;99%
With ammonium cerium (IV) nitrate In nitromethane at 20℃; Inert atmosphere;65%
With CF3COOH or CH3COOH<=93
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

water
7732-18-5

water

1-ethylferrocene

1-ethylferrocene

Conditions
ConditionsYield
With samarium diiodide In tetrahydrofuran N2-atmosphere; molar ratio SmI2:ferrocene derivative:water=3.6:1:5.5, refluxing for 50 min; chromy. (SiO2, AcOEt/hexane=1:1); elem. anal.;99%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

acetic anhydride
108-24-7

acetic anhydride

1-ferrocenylethyl acetate

1-ferrocenylethyl acetate

Conditions
ConditionsYield
With pyridine at 20℃; Inert atmosphere;99%
With catalyst: DMAP In triethylamine acetic anhydride (196 mmol) and DMAP added to soln. of 1-ferrocenylethanol (38.5 mmol); stirred (room temp., 17 h); solvent removed; dild. with ether (200 ml) and H2O (100 ml); org. layer sepd.; dried over Na2SO4; filtered; concd.;93%
With pyridine for 24h; Darkness;76%
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 2.5h;
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

chloroformic acid ethyl ester
541-41-3

chloroformic acid ethyl ester

aniline
62-53-3

aniline

A

1-[N-phenylamino]ethylferrocene

1-[N-phenylamino]ethylferrocene

B

C5H5FeC5H4CH(CH3)OC2H5

C5H5FeC5H4CH(CH3)OC2H5

Conditions
ConditionsYield
Stage #1: 1-ferrocenylethanol With n-butyllithium In tetrahydrofuran; hexane for 0.0833333h; Inert atmosphere;
Stage #2: chloroformic acid ethyl ester In tetrahydrofuran; hexane for 0.0833333h; Inert atmosphere;
Stage #3: aniline Further stages;
A 98%
B n/a
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

vinyl ferrocene
1271-51-8

vinyl ferrocene

Conditions
ConditionsYield
With copper(II) sulfate In toluene byproducts: H2O; in boiling toluene;;97%
With potassium hydrogensulfate In benzene byproducts: H2O; in boiling benzene;;90%
In neat (no solvent) byproducts: H2O; 210°C, 20 Torr;;84%
1,2,3-Benzotriazole
95-14-7

1,2,3-Benzotriazole

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

1-N-(1-ferrocenyl-1-methyl)ethylbenzotriazole
101006-59-1, 654083-40-6, 654083-57-5

1-N-(1-ferrocenyl-1-methyl)ethylbenzotriazole

Conditions
ConditionsYield
With tetrafluoroboric acid In dichloromethane; water addn. of aq. HBF4 to a mixt. of iron complex and heterocycle in CH2Cl2, stirring for 5 min; addn. of Et2O, water, ascorbic acid, sepn., washing org. phase with coldwater, evapn. drying over CaCl2; elem. anal.;97%
With HBF4 In dichloromethane treatment of 1-ferrocenylethanol with benzotriazole in CH2Cl2 in the presence of 45% aq. HBF4 at room temp. for several minutes ((J. Organomet. Chem. 580 (1999) 26);93%
With tetrafluoroboric acid In dichloromethane 20°C;
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

N,N-Dimethyltrimethylsilylamine
2083-91-2

N,N-Dimethyltrimethylsilylamine

trimethyl(α-ferrocenylethoxy)silane

trimethyl(α-ferrocenylethoxy)silane

Conditions
ConditionsYield
byproducts: (CH3)2NH; (Ar); mixing for 3 h at 80-90°C; fractionation under deep vac.; TLC; column chromy. (silica gel); elem. anal.;96.5%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

N,N-diethyl-1,1,1-trimethylsilanamine
996-50-9

N,N-diethyl-1,1,1-trimethylsilanamine

trimethyl(α-ferrocenylethoxy)silane

trimethyl(α-ferrocenylethoxy)silane

Conditions
ConditionsYield
byproducts: (C2H5)2NH; (Ar); mixing for 3 h at 80-90°C; fractionation under deep vac.; TLC; column chromy. (silica gel); elem. anal.;96.5%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

thiophenol
108-98-5

thiophenol

(1-ferrocenylethyl) phenyl sulfide

(1-ferrocenylethyl) phenyl sulfide

Conditions
ConditionsYield
With CF3COOH or CH3COOH96%
With tetrafluoroboric acid In dichloromethane; water at 20℃; for 0.0833333h;83%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

N,N-diethyl-1,1,1-trimethylsilanamine
996-50-9

N,N-diethyl-1,1,1-trimethylsilanamine

A

vinyl ferrocene
1271-51-8

vinyl ferrocene

B

trimethyl(α-ferrocenylethoxy)silane

trimethyl(α-ferrocenylethoxy)silane

Conditions
ConditionsYield
In neat (no solvent) byproducts: (C2H5)2NH, H2O, (CH3)3SiOSi(CH3)3; under argon; equimolar amts of diethylaminotrimethylsilane and the Fe complex are heated to 80-90°C; reaction mixt. distd. under vac.; vinylferrocene recrystd. from hexane; products identified by chromy., IR, and mass spectrometry;A 4%
B 96%
In toluene byproducts: (C2H5)2NH, H2O, (CH3)3SiOSi(CH3)3; under argon; 0.131 mol of diethylaminotrimethylsilane and 0.048 mol of the Fe complex in toluene are heated for 4 h at 120-125°C while distilling off the liberated Et2NH; after cooling, the pptd. crystals of vinylferrocene are sepd.; filtrate distd. under vac.; vinylferrocene recrystd. from hexane; products identified by chromy., IR, and mass spectrometry;A 83%
B 17%
In neat (no solvent) byproducts: (C2H5)2NH, H2O, (CH3)3SiOSi(CH3)3; under argon; 0.104 mole of diethylaminotrimethylsilane and 0.02 mole of the Fe complex are heated to 60-65°C; reaction mixt. distd. under vac.; vinylferrocene recrystd. from hexane; products identified by chromy., IR, and mass spectrometry;A 25%
B 75%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

triphenylphosphine
603-35-0

triphenylphosphine

(C5H5)Fe(C5H4CH(CH3)P(C6H5)3)(1+)*ClO4(1-) = ((C5H5)Fe(C5H4CH(CH3)P(C6H5)3))ClO4

(C5H5)Fe(C5H4CH(CH3)P(C6H5)3)(1+)*ClO4(1-) = ((C5H5)Fe(C5H4CH(CH3)P(C6H5)3))ClO4

Conditions
ConditionsYield
With perchloric acid In dichloromethane byproducts: H2O; addn. of acid to soln. of Fe-complex and phosphine in CH2Cl2 with vigorous stirring, stirring (20°C, 30 min), addn. of ether, keeping (10-15 h, 5-8°C), pptn.; filtration, washing (dry ether), crystn. (EtOH) or repptn. from soln. in acetone (ether); elem. anal.;96%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

sodium benzotriazolate
15217-42-2

sodium benzotriazolate

1-N-(1-ferrocenyl-1-methyl)ethylbenzotriazole
101006-59-1, 654083-40-6, 654083-57-5

1-N-(1-ferrocenyl-1-methyl)ethylbenzotriazole

Conditions
ConditionsYield
With tetrafluoroboric acid In dichloromethane; water byproducts: NaBF4; addn. of aq. HBF4 to mixt. of sodium benzotriazolide and Fe complex in CH2Cl2 with rapid stirring; maintaining, 1 h; evapn.; addn. of ether; washing ethereal soln. (water); drying over Na2SO4; evapn.; crystn. (hexane); elem. anal.;96%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

dimethylsulfide borane complex
13292-87-0

dimethylsulfide borane complex

1-ethylferrocene

1-ethylferrocene

Conditions
ConditionsYield
In dichloromethane all manipulations under Ar atm.; to soln. of ferrocenyl compd. added equiv. amt. of soln. of B compd. in CH2Cl2, stirred at room temp. for 3.5 h; quenched with aq. NH4Cl, org. layer sepd., aq. layer extd. with CH2Cl2,combined org. extracts dried over anhyd. MgSO4, solvent removed in vac., chromy., elem. anal.;95%
hydrogenchloride
7647-01-0

hydrogenchloride

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

fc-CHCl(CH3)

fc-CHCl(CH3)

Conditions
ConditionsYield
In diethyl ether in cold abs. ether;;95%
tetrafluoroboric acid

tetrafluoroboric acid

pentetrazole
54-95-5

pentetrazole

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

C5H5FeC5H4CHCH3N4C(CH2)5(1+)*BF4(1-)=C5H5FeC5H4CHCH3N4C(CH2)5BF4

C5H5FeC5H4CHCH3N4C(CH2)5(1+)*BF4(1-)=C5H5FeC5H4CHCH3N4C(CH2)5BF4

Conditions
ConditionsYield
In dichloromethane; water aq. HBF4 was added to mixt. of corazol and Fe-complex in CH2Cl2, 15 min,Et2O was added; filtered, washed with ether, dried; elem. anal.;94%
tetrafluoroboric acid

tetrafluoroboric acid

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

1-ferrocenylmethyl-1H-1,2,3-benzotriazole
101006-58-0

1-ferrocenylmethyl-1H-1,2,3-benzotriazole

C6N3H4((CH(CH3)C5H4)Fe(C5H5))2(1+)*BF4(1-)=C6N3H4((CH(CH3)C5H4)Fe(C5H5))2BF4
151602-74-3

C6N3H4((CH(CH3)C5H4)Fe(C5H5))2(1+)*BF4(1-)=C6N3H4((CH(CH3)C5H4)Fe(C5H5))2BF4

Conditions
ConditionsYield
In dichloromethane aq. soln. of HBF4 addn. to intensively stirred soln. of Fe-compounds, stirring 3-5 min, ether addn.; ppt. filtration off, washing (water, hexane) drying (CaCl2, vacuum); elem. anal., mass spectroscopy;94%
tetrafluoroboric acid

tetrafluoroboric acid

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

hexamethylenetetramine
100-97-0

hexamethylenetetramine

1,1'-bis[α-(N-hexamethylenetetramino)ethyl]ferrocene bistetrafluoroborate

1,1'-bis[α-(N-hexamethylenetetramino)ethyl]ferrocene bistetrafluoroborate

Conditions
ConditionsYield
In dichloromethane aq. HBF4 addn. to vigorously stirred soln. of Fe-compounds, 4 min; ppt. filtration off, washing (cold water, pentane), drying (CaCl2, vacuum); elem. anal., mass spectroscopy;94%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

N-Phenyl-2-naphthylamine
135-88-6

N-Phenyl-2-naphthylamine

C5H5FeC5H4CH(CH3)N(C6H5)(C10H7)
93122-45-3

C5H5FeC5H4CH(CH3)N(C6H5)(C10H7)

Conditions
ConditionsYield
With HClO4 or HBF4 In dichloromethane byproducts: H2O; aq. HClO4 (70 %) or HBF4 (45 %) added (vigorous stirring) to the Fe-complex and the amine; soln. stirred (30 min, room temp.), addn. of ether; ether soln. washed twice (water), dried (sodium sulfate), solvent removed (vac.); elem. anal.;93%
tetrafluoroboric acid

tetrafluoroboric acid

(η-cyclopentadienyl)(η-pyrrolyl)iron

(η-cyclopentadienyl)(η-pyrrolyl)iron

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

N-(α-ferrocenylethyl)azoniaferrocene tetrafluoroborate
170468-07-2

N-(α-ferrocenylethyl)azoniaferrocene tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane aq. HBF4 addn. to vigorously stirred soln. of Fe-compounds, 5 min, diethyl ether addn., water addn.; pptn. on cooling (0°C), ppt. filtration off, washing (water, ether), drying (CaCl2, vacuum); elem. anal., mass spectroscopy;93%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

acetylene
74-86-2

acetylene

1-(vinyloxy)ethylferrocene

1-(vinyloxy)ethylferrocene

Conditions
ConditionsYield
With potassium hydroxide semihydrate In dimethyl sulfoxide at 70℃; under 9880.66 Torr; for 0.75h; Temperature; Concentration; Reagent/catalyst; Autoclave;93%
With potassium hydroxide In dimethyl sulfoxide at 70 - 80℃;93%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

C2H13B10S

C2H13B10S

1-[(m-carboran-9-yl)thio]-1-ferrocenyl ethane

1-[(m-carboran-9-yl)thio]-1-ferrocenyl ethane

Conditions
ConditionsYield
With ammonium cerium (IV) nitrate In nitromethane at 20℃; Inert atmosphere;93%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

thiophenol
108-98-5

thiophenol

1-ferrocenyl-1-phenylethane

1-ferrocenyl-1-phenylethane

Conditions
ConditionsYield
With HBF4 or HClO4 In dichloromethane byproducts: H2O; aq. HBF4 (45 %) or HClO4 (70 %) added (vigorous stirring) to the Fe-complex and PhSH; soln. stirred (60 min, 20°C), addn. of ether; ether soln. washed twice (water), dried (sodium sulfate), solvent removed (vac.), recrystn. (ethanol);92%
1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

diphenylamine
122-39-4

diphenylamine

C5H5FeC5H4CH(CH3)N(C6H5)2
93122-44-2

C5H5FeC5H4CH(CH3)N(C6H5)2

Conditions
ConditionsYield
With HBF4 or HClO4 In dichloromethane byproducts: H2O; aq. HBF4 (45 %) or HClO4 (70 %) added (vigorous stirring) to the Fe-complex and the amine; soln. stirred (30 min, room temp.), addn. of ether; ether soln. washed twice (water), dried (sodium sulfate), solvent removed (vac.); elem. anal.;92%
tetrafluoroboric acid

tetrafluoroboric acid

1-ferrocenylethanol
1277-49-2

1-ferrocenylethanol

(C5H5)Fe(C5H4CH(CH3)NC5H5)(1+)*BF4(1-) = ((C5H5)Fe(C5H4CH(CH3)NC5H5))BF4

(C5H5)Fe(C5H4CH(CH3)NC5H5)(1+)*BF4(1-) = ((C5H5)Fe(C5H4CH(CH3)NC5H5))BF4

Conditions
ConditionsYield
With pyridine In dichloromethane byproducts: H2O; addn. of acid to soln. of Fe-complex and base in CH2Cl2 with vigorous stirring, stirring (20°C, 45 min), addn. of ether, keeping (10-15 h, 5-8°C), pptn.; filtration, washing (dry ether), crystn. (EtOH) or repptn. from soln. in acetone (ether); elem. anal.;92%

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