Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:131-58-8
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inquiryhigh quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
Cas:131-58-8
Min.Order:1 Gram
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inquiryAs a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis
Cas:131-58-8
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:131-58-8
Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryProduct Description Product website: http://www.finerchem.com Product Name 2-Methylbenzophenone CAS No. 131-58-8
Cas:131-58-8
Min.Order:1 Metric Ton
FOB Price: $12.0
Type:Lab/Research institutions
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:131-58-8
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryOur Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con
Cas:131-58-8
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inquiryAppearance:colorless liquid Storage:Room Temperature Package:200kg/Drum Application:2-Methylbenzophenone, is used as an important raw material and intermediate in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. Transportation:Expre
Cas:131-58-8
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:131-58-8
Min.Order:1 Kilogram
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inquiry2-Methylbenzophenone CAS:131-58-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interm
Cas:131-58-8
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:131-58-8
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryHebei Mojin Biotechnology Co., Ltd, Our company is a professional chemical raw materials and chemical reagents research and development production enterprises. We have several production line,So we can control the lowest price. We also have several
Cas:131-58-8
Min.Order:25 Gram
FOB Price: $90.0 / 100.0
Type:Trading Company
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Cas:131-58-8
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inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Appearance:CLEAR COLORLESS TO PALE YELLO Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common produc
Cas:131-58-8
Min.Order:100 Metric Ton
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Type:Lab/Research institutions
inquiry1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie
Cas:131-58-8
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:131-58-8
Min.Order:0 Metric Ton
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff
Cas:131-58-8
Min.Order:100 Gram
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Type:Other
inquiryMassive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Cas:131-58-8
Min.Order:1 Gram
FOB Price: $1.0
Type:Lab/Research institutions
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:131-58-8
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiry(2-methlyphenyl)phenyl-methanoneAppearance:white powder Storage:sealed, keep in the ventilated, dry Package:according to customers' requirements Application:health care Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB or CIF or
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h
Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O
Cas:131-58-8
Min.Order:1 Kilogram
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inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:131-58-8
Min.Order:1 Kilogram
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inquiryCAS:131-58-8 EINECS:205-032-0 MW:196.24 MF:C14H12O Melting point:-18 °C Boiling point:125-127 °C0.3 mm Hg(lit.) Appearance:colorless or light yellow liquid Package:200kg/Steel drum Transportation:by sea Port:Shanghai
factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:131-58-8
Min.Order:1 Kilogram
FOB Price: $18.0 / 20.0
Type:Trading Company
inquiryProduct name: 2-Methylbenzophenone CAS No.:131-58-8 Molecule Formula:C14H12O Molecule Weight:196.24 Purity: 99.0% Package: 200kg/drum Description:Clear colorless to pale yellow liquid Manufacture Standards:Enterprise Standard
Cas:131-58-8
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:131-58-8
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryConditions | Yield |
---|---|
With di-tert-butyl peroxide In N,N-dimethyl-formamide at 100℃; for 4.5h; | 99% |
With cesium hydroxide; air In toluene at 110℃; for 24h; | 97% |
With pyridinium chlorochromate In dichloromethane at 20℃; for 1h; | 94% |
Conditions | Yield |
---|---|
With bis(tricyclohexylphosphine)nickel(II) dichloride In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 25 - 100℃; for 20h; Schlenk technique; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With oxygen at 110℃; for 8h; Schlenk technique; Green chemistry; | 98% |
With oxygen at 110℃; for 8h; Sealed tube; | 97.5% |
With di-tert-butyl peroxide; iron(II) chloride In decane; acetonitrile at 20℃; for 8h; Inert atmosphere; Schlenk technique; | 92% |
With tert.-butylhydroperoxide; 2.9-dimethyl-1,10-phenanthroline; gold(I) chloride In water; tert-butyl alcohol at 90℃; for 18h; | 89% |
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at -78 - 20℃; for 2.83333h; Inert atmosphere; | 67% |
Conditions | Yield |
---|---|
Stage #1: o-tolyl magnesium chloride With zinc(II) chloride In 1-methyl-pyrrolidin-2-one; diethyl ether at 60℃; for 0.333333h; Stage #2: benzoyl chloride; ((t-Bu)2POH)2PdCl2 In 1-methyl-pyrrolidin-2-one at 25℃; for 0.5h; Further stages.; | 98% |
ortho-methylphenyl iodide
carbon monoxide
phenylboronic acid
2-Methylbenzophenone
Conditions | Yield |
---|---|
With C57H43IP2Pd; potassium carbonate In 1,4-dioxane at 90℃; under 3750.38 Torr; for 12h; carbonylative Suzuki coupling; Autoclave; | 98% |
With potassium acetate; sodium hydrogencarbonate; iron(II) chloride at 100℃; under 760.051 Torr; for 23h; Suzuki Coupling; Schlenk technique; | 93% |
With potassium fluoride; potassium phosphate; copper; Trimethylacetic acid at 100℃; under 760.051 Torr; for 24h; Suzuki Coupling; | 93% |
Conditions | Yield |
---|---|
With dipotassium peroxodisulfate; palladium diacetate In water; dimethyl sulfoxide at 20℃; for 3h; | 98% |
Conditions | Yield |
---|---|
With (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); potassium carbonate In tetrahydrofuran at 60℃; for 15h; Suzuki-Miyaura Coupling; | 98% |
With boric acid; palladium diacetate; potassium carbonate; tricyclohexylphosphine tetrafluoroborate In tetrahydrofuran at 65℃; for 15h; Suzuki-Miyaura Coupling; Inert atmosphere; | 84.2% |
Conditions | Yield |
---|---|
With boric acid; palladium diacetate; potassium carbonate; tricyclohexylphosphine tetrafluoroborate In tetrahydrofuran at 65℃; for 15h; Suzuki-Miyaura Coupling; Inert atmosphere; | 98% |
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; potassium carbonate In tetrahydrofuran at 60℃; for 15h; Reagent/catalyst; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 97% |
With (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); potassium carbonate In tetrahydrofuran at 60℃; for 15h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 97% |
With (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); potassium carbonate In tetrahydrofuran at 60℃; for 15h; Suzuki-Miyaura Coupling; | 94% |
With C19H23IN4OPd; potassium carbonate In tetrahydrofuran at 60℃; for 15h; Reagent/catalyst; Schlenk technique; Inert atmosphere; |
2-Methylphenylboronic acid
2-Methylbenzophenone
Conditions | Yield |
---|---|
With (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); potassium carbonate In tetrahydrofuran at 60℃; for 15h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 98% |
2-Methylphenylboronic acid
2-Methylbenzophenone
Conditions | Yield |
---|---|
With (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); potassium carbonate In tetrahydrofuran at 60℃; for 15h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 98% |
2-Methylphenylboronic acid
2-Methylbenzophenone
Conditions | Yield |
---|---|
With (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); potassium carbonate In tetrahydrofuran at 60℃; for 15h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 98% |
2-Methylphenylboronic acid
2-Methylbenzophenone
Conditions | Yield |
---|---|
With (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); potassium carbonate In tetrahydrofuran at 60℃; for 15h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 98% |
iodobenzene
2-Methylphenylboronic acid
molybdenum hexacarbonyl
2-Methylbenzophenone
Conditions | Yield |
---|---|
With potassium phosphate; palladium(II) trifluoroacetate In water; acetonitrile at 50℃; for 6h; Suzuki Coupling; Inert atmosphere; Sealed tube; | 97% |
With palladium diacetate; potassium carbonate In methoxybenzene at 140℃; for 12h; Suzuki coupling; | 75% |
2-Methylphenylboronic acid
N,N-di(tert-butyloxycarbonyl) benzamide
2-Methylbenzophenone
Conditions | Yield |
---|---|
With potassium fluoride; (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II) In water; toluene at 23℃; for 15h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 97% |
2-Methylphenylboronic acid
2-Methylbenzophenone
Conditions | Yield |
---|---|
With (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); potassium carbonate In tetrahydrofuran at 60℃; for 15h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 97% |
benzoyl chloride
toluene
A
4-Methylbenzophenone
B
2-Methylbenzophenone
C
3-methyl benzophenone
Conditions | Yield |
---|---|
With rhenium(I) pentacarbonyl bromide for 2h; Product distribution; Heating; also m-ksylene and anisole, var. acid chlorides, also acetic anhydride as acylating reagent; | A 96% B n/a C n/a |
With rhenium(I) pentacarbonyl bromide for 2h; Heating; | A 96% B n/a C n/a |
With C4F9SO3H at 110℃; for 24h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; |
2-Methylphenylboronic acid
N-(methylsulfonyl)-N-phenylbenzamide
2-Methylbenzophenone
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); sodium carbonate; tricyclohexylphosphine tetrafluoroborate In 1,4-dioxane at 120℃; for 15h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; chemoselective reaction; | 96% |
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid; palladium diacetate; 2-(3,5-dimethyl-1H-pyrazol-1-yl)pyridine In water at 90℃; for 1.5h; | 95% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); potassium dihydrogenphosphate; [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In N,N-dimethyl acetamide at 25℃; for 20h; Schlenk technique; Inert atmosphere; Irradiation; chemoselective reaction; | 95% |
With dipotassium hydrogenphosphate; dibenzo[f,h]quinoxaline-2,3-dicarbonitrile; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl-formamide at 20℃; for 72h; Inert atmosphere; | 73% |
2-Methylphenylboronic acid
tert-butyl benzoyl(phenyl)carbamate
2-Methylbenzophenone
Conditions | Yield |
---|---|
With [(η3-1-tBu-indenyl)Pd(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)(Cl)]; potassium carbonate In tetrahydrofuran at 23℃; for 15h; Suzuki-Miyaura Coupling; | 95% |
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; potassium carbonate In tetrahydrofuran at 60℃; for 15h; Reagent/catalyst; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 90% |
With (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); potassium carbonate In tetrahydrofuran at 60℃; for 15h; Suzuki-Miyaura Coupling; | 89% |
o-methylphenylphenylmethanol acetate
2-Methylbenzophenone
Conditions | Yield |
---|---|
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In water; chlorobenzene at 130℃; for 3h; | 95% |
With tert.-butylnitrite; oxygen; 2,3-dicyano-5,6-dichloro-p-benzoquinone In 1,1,2,2-tetrachloroethane at 130℃; under 2250.23 Torr; for 6h; Autoclave; | 95% |
Conditions | Yield |
---|---|
With palladium diacetate; N-picolinoylcyclohexylamine; potassium hydrogencarbonate In tert-Amyl alcohol at 150℃; for 24h; | 95% |
ortho-methylphenyl iodide
chromium(0) hexacarbonyl
phenylboronic acid
2-Methylbenzophenone
Conditions | Yield |
---|---|
With sodium t-butanolate In N,N-dimethyl acetamide at 80℃; for 0.666667h; Suzuki Coupling; | 95% |
Conditions | Yield |
---|---|
With C35H35ClFeN3O2PPd; sodium hydrogencarbonate In water; toluene at 50℃; Inert atmosphere; | 94% |
With [Pd(η(5)-C5H5)Fe(η(5)-C5H3-C(CH3)=N-C6H4-4-CH3)Cl(P(C6H5)3)]; potassium carbonate In toluene at 60℃; for 12h; Inert atmosphere; | 84% |
With sodium carbonate; palladium dichloride In acetone at 20℃; | 80% |
Conditions | Yield |
---|---|
With 18-crown-6 ether; potassium tert-butylate; oxygen In N,N-dimethyl-formamide at 0 - 20℃; for 3h; Inert atmosphere; | 93% |
With tert.-butylnitrite; oxygen; acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone In 1,1,2,2-tetrachloroethane at 130℃; for 12h; Autoclave; | 89% |
With oxygen; sodium t-butanolate In dimethyl sulfoxide at 50℃; for 5h; Sealed tube; | 89% |
N-benzoyl-N-methyl-4-methylbenzenesulfonamide
bis(2-methylphenyl)borinic acid
2-Methylbenzophenone
Conditions | Yield |
---|---|
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; potassium carbonate In tetrahydrofuran at 65℃; for 12h; Suzuki Coupling; Inert atmosphere; Schlenk technique; | 93% |
(E)-1-methyl-2-styryl-benzene
2-Methylbenzophenone
Conditions | Yield |
---|---|
With sodium periodate; tetraethylammonium iodide In water; acetonitrile at 105℃; for 12h; Sealed tube; | 92% |
benzoic acid phenyl ester
2-Methylphenylboronic acid
2-Methylbenzophenone
Conditions | Yield |
---|---|
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; water; potassium carbonate In tetrahydrofuran at 23℃; for 18h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; | 92% |
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; potassium carbonate In tetrahydrofuran at 80℃; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 88% |
With C40H52ClN2Pd; potassium hydroxide In tetrahydrofuran; water at 20℃; for 6h; Suzuki-Miyaura Coupling; Glovebox; | 86% |
With potassium phosphate; (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); water In tetrahydrofuran at 90℃; for 2h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube; Schlenk technique; | 76% |
With [(η3-1-tBu-indenyl)Pd(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)(Cl)]; potassium carbonate In tetrahydrofuran at 23℃; for 15h; Suzuki-Miyaura Coupling; | 72% |
Conditions | Yield |
---|---|
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; potassium carbonate In tetrahydrofuran at 110℃; for 15h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 91% |
With (bis(tricyclohexyl)phosphine)palladium(II) dichloride; potassium carbonate; tricyclohexylphosphine In 1,4-dioxane at 110℃; for 12h; Suzuki Coupling; Inert atmosphere; Schlenk technique; | 63% |
Conditions | Yield |
---|---|
With boric acid; palladium diacetate; potassium carbonate; dicyclohexylphenylphosphine In tetrahydrofuran at 65℃; for 15h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 91% |
With bis-triphenylphosphine-palladium(II) chloride; potassium phosphate In toluene at 65℃; for 4h; Suzuki Coupling; Inert atmosphere; | 82% |
Conditions | Yield |
---|---|
With [(OC-6-13)-RuCl2[P(p-CH3C6H5)3]2(en)]; potassium tert-butylate; hydrogen In isopropyl alcohol at 35℃; under 6080.41 Torr; for 18h; Catalytic hydrogenation; | 100% |
With silatrane; potassium tert-butylate In tetrahydrofuran; N,N-dimethyl-formamide at 20℃; for 0.5h; | 99% |
With C16H33Cl2CoN5P2; hydrogen; sodium t-butanolate In tert-Amyl alcohol at 20℃; under 15001.5 Torr; for 24h; Autoclave; | 97% |
2-Methylbenzophenone
(R)-o-methylbenzhydrol
Conditions | Yield |
---|---|
With C38H38IrN4S2(1+)*F6P(1-); ammonium formate; 3-methyl-5-p-methoxyphenyl-1-hydropyrazole In tetrahydrofuran; water at 40℃; for 24h; enantioselective reaction; | 99% |
With potassium phosphate buffer; D-glucose; ketoreductase enzyme 121; glucose dehydrogenase; NADP cofactor In tetrahydrofuran; water at 30℃; for 24h; pH=7.0; | 95% |
With hydrogen; C34H63ClIrNP2; lithium tert-butoxide In hexane; toluene at 20℃; under 38002.6 Torr; for 48h; Autoclave; enantioselective reaction; | 85% |
Conditions | Yield |
---|---|
With C32H39BrMnN2O2P; potassium tert-butylate; hydrogen In methanol at 20℃; under 22502.3 Torr; for 16h; Glovebox; Autoclave; enantioselective reaction; | 99% |
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; f-amphox; hydrogen; sodium t-butanolate In toluene Catalytic behavior; enantioselective reaction; | 99% |
With formic acid; ((R,R)-Ts-DENEB)RuCl; triethylamine at 60℃; for 18h; Reagent/catalyst; Inert atmosphere; enantioselective reaction; | 98% |
Conditions | Yield |
---|---|
With potassium hexamethylsilazane In toluene at 20℃; for 0.25h; Inert atmosphere; | 99% |
2-Methylbenzophenone
Conditions | Yield |
---|---|
With tetrakis(tetrabutylammonium)decatungstate(VI); 2,4,6-Triisopropylthiophenol; water-d2 In acetonitrile Irradiation; | 99% |
Conditions | Yield |
---|---|
With C84H110N10Zn2 In neat (no solvent) at 20℃; for 12h; Sealed tube; Inert atmosphere; Schlenk technique; Glovebox; | 99% |
2-Methylbenzophenone
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
Conditions | Yield |
---|---|
With C84H110N10Zn2 In neat (no solvent) at 20℃; for 6h; Sealed tube; Inert atmosphere; Schlenk technique; Glovebox; | 99% |
Conditions | Yield |
---|---|
With (S,E)-3-methyl-N-phenyl-2-((pyridin-2-ylmethylene)amino)butanamide-UiO-Fe metal-organic framework In tetrahydrofuran at 25℃; for 2h; Reagent/catalyst; Inert atmosphere; Glovebox; enantioselective reaction; | 99% |
2-Methylbenzophenone
A
(R)-o-methylbenzhydrol
B
2-methyl-(S)-benzhydrol
Conditions | Yield |
---|---|
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; C43H53FeN2O2PS; hydrogen; lithium tert-butoxide In isopropyl alcohol at 25 - 30℃; under 22801.5 Torr; for 12h; Autoclave; enantioselective reaction; | A 98% B n/a |
With (mer-[(S,S)-1,5-dimethyl-2,4-bis(4-phenyl-1,3-oxazolin-2-yl)benzene(1-)]Ru(CO)Cl)2(ZnCl2); hydrogen; sodium methylate; (-)-(S)-1-Anthracen-9-ylethanol In isopropyl alcohol at 40℃; under 22801.5 Torr; for 24h; Inert atmosphere; Autoclave; optical yield given as %ee; enantioselective reaction; | A 97% B n/a |
With (mer-[(S,S)-1,5-dimethyl-2,4-bis(4-phenyl-1,3-oxazolin-2-yl)benzene(1-)]Ru(CO)Cl)2(ZnCl2); hydrogen; sodium methylate In isopropyl alcohol at 40℃; under 22801.5 Torr; for 24h; Inert atmosphere; Autoclave; optical yield given as %ee; enantioselective reaction; | A n/a B 68% |
Conditions | Yield |
---|---|
In dimethyl sulfoxide at 25℃; for 1.58333h; UV-irradiation; Inert atmosphere; | 98% |
In dimethyl sulfoxide at 20℃; under 760.051 Torr; for 2h; Solvent; UV-irradiation; Schlenk technique; | 89% |
In dimethyl sulfoxide at 20℃; Schlenk technique; UV-irradiation; | 86% |
Togni's reagent II
2-Methylbenzophenone
Conditions | Yield |
---|---|
In dimethyl sulfoxide at 20℃; for 1h; Reagent/catalyst; Solvent; Schlenk technique; Inert atmosphere; Irradiation; | 98% |
Conditions | Yield |
---|---|
In toluene at 25℃; for 0.25h; Solvent; Inert atmosphere; UV-irradiation; | 98% |
Conditions | Yield |
---|---|
In toluene at 25℃; for 0.35h; Inert atmosphere; UV-irradiation; | 98% |
Conditions | Yield |
---|---|
In toluene at 25℃; for 0.527667h; Inert atmosphere; UV-irradiation; | 98% |
Conditions | Yield |
---|---|
In toluene at 25℃; for 0.75h; Inert atmosphere; UV-irradiation; | 98% |
Conditions | Yield |
---|---|
In toluene at 25℃; for 1h; Inert atmosphere; UV-irradiation; Flow reactor; diastereoselective reaction; | 98% |
Conditions | Yield |
---|---|
In toluene at 25℃; for 0.583333h; Concentration; Solvent; Time; Inert atmosphere; UV-irradiation; Flow reactor; diastereoselective reaction; | 98% |
Conditions | Yield |
---|---|
In toluene at 25℃; for 1h; Inert atmosphere; UV-irradiation; Flow reactor; diastereoselective reaction; | 98% |
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