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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

Benzoylformic acid

Cas:611-73-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Benzoylformic acid Manufacturer/High quality/Best price/In stock

Cas:611-73-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Benzoyl Formoic Acid supplier in China

Cas:611-73-4

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hangzhou Think Chemical Co. Ltd

Benzoylformic acid CAS No.:611-73-4 Name Benzoylformic acid Synonyms Phenylglyoxylic acid Molecular Structure Molecular Formula C8H6O3 Molecular Weight 150.13 CAS Registry Number 611-73-4 EINECS

Benzoylformic acid CAS No.:611-73-4

Cas:611-73-4

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Benzoyl Formoic Acid

Cas:611-73-4

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Phenylglyoxylic acid

Cas:611-73-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Leader Biochemical Group

About Product Details

China Largest factory Manufacturer Supply Benzoylformic acid CAS 611-73-4

Cas:611-73-4

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 611-73-4 with competitive price

Cas:611-73-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzeneacetic acid, a-oxo- 611-73-4

Cas:611-73-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:611-73-4

Cas:611-73-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Benzoyl Formoic Acid

Cas:611-73-4

Min.Order:0

Negotiable

Type:Manufacturers

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

Phenylglyoxylic acid

Cas:611-73-4

Min.Order:1 Kilogram

FOB Price: $30.0 / 50.0

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Benzoylformic acid

Cas:611-73-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzoylformic acid

Cas:611-73-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Benzoylformic acid/High quality/Best price

Cas:611-73-4

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung, LG, Merck, Thermo Fisher Scientific and so o

611-73-4 Benzoylformic acid

Cas:611-73-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Benzoylformicacid

Cas:611-73-4

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Benzoylformic acid Chemical Properties Melting point 62-65 °C(lit.) Boiling point 84 °C0.1 mm Hg density 1.38 refractive index 1.4500 (estimate) Fp 147-151°C/12mm storage temp. Refrigerator solubility methanol:

Benzoylformic Acid

Cas:611-73-4

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

Benzoylformic Acid

Cas:611-73-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

BENZOYLFORMIC ACID cas no. 611-73-4 98%

Cas:611-73-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Benzoylformic acid

Cas:611-73-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

stable supply&competitive price Storage:Available Package:25KG Or as client requirement Application:Important pharm intermediate Transportation:By air or By sea

Benzoylformic acid

Cas:611-73-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Phenylglyoxylic acid 500g

Cas:611-73-4

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

BenzoylforMic Acid

Cas:611-73-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Benzoyl Formoic Acid

Cas:611-73-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

Benzoylformic acid

Cas:611-73-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

Benzoylformic acid

Cas:611-73-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

BenzoylforMic acid

Cas:611-73-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Benzoylformic acid

Cas:611-73-4

Min.Order:0

Negotiable

Type:Other

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

Appearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

Benzoylformic acid CAS No.611-73-4

Cas:611-73-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

methyl 2-oxo-2-phenylacetate
15206-55-0

methyl 2-oxo-2-phenylacetate

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With water; sodium hydroxide100%
With water; sodium hydroxide In dichloromethane100%
With water; sodium hydroxide at 20℃; for 2h;99.2%
tert-butyl phenylglyoxylate
7332-98-1

tert-butyl phenylglyoxylate

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With trifluoroacetic acid In dichloromethane at 20℃;100%
With trifluoroacetic acid at 0℃; for 1h;57%
With trifluoroacetic acid at 0℃; for 5h;
benzalacetophenone
94-41-7

benzalacetophenone

A

Benzoylformic acid
611-73-4

Benzoylformic acid

B

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
With methyl 3,5-bis((1H-1,2,4-triazol-1-yl)methyl)benzoate; oxygen; sodium acetate; nickel dibromide at 120℃; under 760.051 - 912.061 Torr; for 48h; chemoselective reaction;A 91%
B 99%
Multi-step reaction with 2 steps
1: sodium hydrogencarbonate; ruthenium trichloride; potassium peroxymonosulfate / acetonitrile; water; ethyl acetate / 0.3 h
2: iron(II) perchlorate hexahydrate; tetramethylammonium hydroxide pentahydrate / acetonitrile; water / 12 h / Inert atmosphere
View Scheme
Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With sodium bromate In acetonitrile for 52h; Heating;98%
With oxalyl dichloride; methyl dodecyl sulfoxide; triethylamine In dichloromethane at -60 - 20℃; Swern oxidation;96%
With oxalyl dichloride; methyl dodecyl sulfoxide; triethylamine In dichloromethane at -60 - 20℃; Swern oxidation;96%
5-hydroxy-N,N',5-triphenylimidazolidine-2,4-dione
1352131-39-5

5-hydroxy-N,N',5-triphenylimidazolidine-2,4-dione

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With water; sodium hydroxide In methanol at 20 - 50℃; for 1h;98%
2-(hydroxyimino)-2-phenylacetonitrile
825-52-5

2-(hydroxyimino)-2-phenylacetonitrile

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With sulfuric acid at 100 - 120℃; for 5h;96.6%
phenylethane 1,2-diol
93-56-1

phenylethane 1,2-diol

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; iron(III) chloride; thymidyl acetic acid In decane; acetonitrile at 80℃; for 6h;96%
With Oxone; 2-Iodobenzoic acid In water; acetonitrile at 70℃; for 6h;94%
With sodium tetrahydroborate; 1% Pd/C; water; potassium hydroxide In methanol at 20℃; for 15h; In air;91%
With potassium permanganate; acetic acid; Tris(3,6-dioxaheptyl)amine In dichloromethane for 4h; Ambient temperature;71%
aqua(2,2'-bipyridine)(2,2':6',2''-terpyridine)ruthenium(II)(2+) In phosphate buffer for 6h; pH=7.2; Electrolysis;47%
2-Bromo-1-phenylethanol
2425-28-7

2-Bromo-1-phenylethanol

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With tetramethoxytitanium; β-Propiolactone at 60℃; for 2h; Temperature;96%
Multi-step reaction with 5 steps
1.1: hydrogen bromide; dihydrogen peroxide / water / 4.5 h / 25 - 90 °C
2.1: toluene-4-sulfonic acid; benzene / water / 36 h / 85 °C
3.1: tetrabutylammomium bromide; sodium ethanolate / water / 23 h / 105 °C
4.1: oxalic acid / dichloromethane; water / 5 h / 25 °C
5.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h
5.2: 5 h / 25 - 90 °C
View Scheme
2-hydroxy-4-methyl-2-phenylmorpholin-3-one

2-hydroxy-4-methyl-2-phenylmorpholin-3-one

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With hydrogenchloride for 2h; Heating;94%
(R)-Mandelic Acid
611-71-2

(R)-Mandelic Acid

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With phosphotungstic acid; ferric nitrate at 55 - 60℃; for 0.166667h;93%
With D-lactate oxidase from Gluconobacter oxydans 621H; oxygen; catalase In aq. buffer at 30℃; pH=7.4; Reagent/catalyst; Enzymatic reaction;
With NAD at 30℃; for 48h; pH=9.5; Kinetics; Reagent/catalyst; Temperature; pH-value; Enzymatic reaction;
Na2S2O3·5H2O

Na2S2O3·5H2O

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With hydrogenchloride; sodium hypobromide; sodium thiosulfate In dichloromethane; water91%
1-phenyl-2-hydroxyethanone
582-24-1

1-phenyl-2-hydroxyethanone

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With hydrogen bromide; dihydrogen peroxide In water at 25 - 65℃; for 5h; Reagent/catalyst; Time;90.1%
With hydrogen bromide; dihydrogen peroxide In water Temperature; Reflux;79.3%
Stage #1: 1-phenyl-2-hydroxyethanone With tetrabutylammomium bromide; hydrogen bromide In water for 0.0166667h;
Stage #2: With dihydrogen peroxide In water at 25 - 90℃; for 5h;
83 %Chromat.
With hydrogen bromide; dihydrogen peroxide In water at 90℃; for 7h;
3,4-diphenyl-4-hydroxy-2-isoxazolin-5-one
80490-41-1

3,4-diphenyl-4-hydroxy-2-isoxazolin-5-one

A

benzonitrile
100-47-0

benzonitrile

B

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With triethylamine In benzene for 3h; Heating;A n/a
B 89.3%
With hydrogenchloride; sodium hydroxide; water Mechanism;
epoxide of α,β-difluoro-β-chlorostyrene
134918-42-6

epoxide of α,β-difluoro-β-chlorostyrene

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With sodium hydrogencarbonate for 0.5h;89%
acetophenone
98-86-2

acetophenone

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With pyridine; selenium(IV) oxide at 120℃; for 18h; Inert atmosphere;87%
With pyridine; selenium(IV) oxide for 3h; Reflux;87%
With pyridine; selenium(IV) oxide at 90℃; for 5h; Inert atmosphere;87%
phenylglycin
2835-06-5

phenylglycin

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With potassiuim nitrosodisulfonate In water for 60h; pH 10.0;82%
With ω-transaminase
2,2,2-Tris-benzotriazol-1-yl-1-phenyl-ethanone
130749-19-8

2,2,2-Tris-benzotriazol-1-yl-1-phenyl-ethanone

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With sulfuric acid In tetrahydrofuran at 50℃; for 48h;81%
3,5-diphenyl-4,4-dichloro-5-hydroxy-Δ2-isoxazoline
79344-05-1

3,5-diphenyl-4,4-dichloro-5-hydroxy-Δ2-isoxazoline

A

benzonitrile
100-47-0

benzonitrile

B

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With potassium hydroxide In water for 2.5h; Heating;A 75.4%
B 80%
phenylglyoxal hydrate
1074-12-0

phenylglyoxal hydrate

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
Stage #1: phenylglyoxal hydrate With silver perchlorate; sodium hydroxide In water at 20℃; Inert atmosphere;
Stage #2: With hydrogenchloride In water Inert atmosphere;
78%
bei der Einw. von gaerender Hefe;
Multi-step reaction with 2 steps
1: 26.5 percent Spectr. / Et3N, pyridine, O2, 3-Angstroem sieves / Cu(NO3)2py2 / methanol / 12 h / 25 °C / 1748 Torr
2: 68.6 percent Spectr. / Et3N, pyridine, O2, H2O / Cu(NO3)2py2 / methanol / 12 h / 25 °C / 1748 Torr
View Scheme
carbon dioxide
124-38-9

carbon dioxide

benzoic acid ethyl ester
93-89-0

benzoic acid ethyl ester

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With chloro-trimethyl-silane; magnesium In N,N-dimethyl-formamide at 20℃; Temperature; Solvent;75%
oxo-phenyl-acetaldehyde oxime
532-54-7

oxo-phenyl-acetaldehyde oxime

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With hydrogenchloride; water; sodium nitrite at 80℃; for 4h;73.5%
With acetic anhydride bei der Destillation u. Verseifen mit Salzsaeure;
carbon dioxide
124-38-9

carbon dioxide

benzaldehyde
100-52-7

benzaldehyde

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
Stage #1: carbon dioxide; benzaldehyde With potassium cyanide In N,N-dimethyl-formamide at 12℃; for 1h; Schlenk technique;
Stage #2: With titanium(IV)isopropoxide; 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 40℃; for 18h; Schlenk technique;
72%
diphenacyl sulfide
2461-80-5

diphenacyl sulfide

A

C16H10O4S
1522397-30-3

C16H10O4S

B

(3-phenylthiophene-2,5-diyl)bis(phenylmethanone)
595565-17-6

(3-phenylthiophene-2,5-diyl)bis(phenylmethanone)

C

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With selenium(IV) oxide In 1,4-dioxane for 2h; Reflux;A n/a
B 10%
C 71%
4-hydroxy-3-methyl-4-phenylisoxazoline-5-one
80490-51-3

4-hydroxy-3-methyl-4-phenylisoxazoline-5-one

A

Benzoylformic acid
611-73-4

Benzoylformic acid

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With 2,6-dichloro-benzonitrile In benzene for 0.5h; Heating;A 70%
B n/a
benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

carbon dioxide
124-38-9

carbon dioxide

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With chloro-trimethyl-silane; magnesium In N,N-dimethyl-formamide at 20℃;69%
2-nitroacetophenone
614-21-1

2-nitroacetophenone

A

Benzoylformic acid
611-73-4

Benzoylformic acid

B

benzoic acid
65-85-0

benzoic acid

C

3,4-dibenzoyl-1,2,5-oxadiazole-N-oxide
6635-54-7

3,4-dibenzoyl-1,2,5-oxadiazole-N-oxide

Conditions
ConditionsYield
With nitric acid; sodium nitrite In nitromethane; water at 60℃; for 0.5h;A 9.7%
B 4.4%
C 68.4%
With nitric acid; sodium nitrite In nitromethane; water at 60℃; for 0.5h; Product distribution; Mechanism; variation of solvents, reactants;A 9.7%
B 4.4%
C 68.4%
iodobenzene
591-50-4

iodobenzene

carbon monoxide
201230-82-2

carbon monoxide

B

Benzoylformic acid
611-73-4

Benzoylformic acid

C

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
With methyl iodide; sodium tetrahydroborate In 1,4-dioxane; water at 20℃; for 20h;A 3%
B 68%
C 5%
With methyl iodide; sodium tetrahydroborate In 1,4-dioxane; water at 20℃; for 20h;A 3%
B 64%
C 13%
With calcium hydroxide; water; dichlorobis(dimethylphenylphosphine)palladium(II) In isopropyl alcohol at 100℃; for 12h; P(CO) = 150 atm at room temperature; further catalysts, solvents and hydroxide;A 69.0 % Chromat.
B 3.8 % Chromat.
C 9.3 % Chromat.
With calcium hydroxide; water; bis(benzonitrile)palladium(II) dichloride In isopropyl alcohol at 100℃; for 12h; P(CO) = 150 atm at room temperature; further catalysts, solvents and hydroxide;A 46.0 % Chromat.
B 8.7 % Chromat.
C 25.5 % Chromat.
With sodium sulfide; CoCl2 In 1,4-dioxane; water at 20℃; for 20h; Product distribution; other reag.; other solvent;A 3 % Chromat.
B 62 % Chromat.
C 5 % Chromat.
phenylacetylene
536-74-3

phenylacetylene

A

phenylacetic acid
103-82-2

phenylacetic acid

B

Benzoylformic acid
611-73-4

Benzoylformic acid

Conditions
ConditionsYield
With dihydrogen peroxide; methyltrioxorhenium(VII) In dichloromethane for 48h;A 21%
B 68%
With dihydrogen peroxide; methyltrioxorhenium(VII) In acetone for 48h;A 65%
B 11%
2-methylsulfonyl-1-phenylethanone
3708-04-1

2-methylsulfonyl-1-phenylethanone

A

Benzoylformic acid
611-73-4

Benzoylformic acid

B

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
With ammonium cerium (IV) nitrate; oxygen In acetonitrile at 60℃;A 26%
B 65%

A

Benzoylformic acid
611-73-4

Benzoylformic acid

B

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
With oxone; 2-iodo-3,4,5,6-tetramethylbenzoic acid In water; acetonitrile at 20℃; for 3h;A 63%
B 30%
Benzoylformic acid
611-73-4

Benzoylformic acid

phenylglyoxylyl chloride
25726-04-9

phenylglyoxylyl chloride

Conditions
ConditionsYield
With Dichloromethyl methyl ether at 50℃; for 0.5h;100%
With Dichloromethyl methyl ether In dichloromethane at 15 - 20℃; for 1h; Inert atmosphere;100%
With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane95%
pyrrolidine
123-75-1

pyrrolidine

Benzoylformic acid
611-73-4

Benzoylformic acid

1-thiobenzoylpyrrolidine
15563-45-8

1-thiobenzoylpyrrolidine

Conditions
ConditionsYield
With sulfur In benzene at 80℃; for 0.166667h;100%
With sulfur In benzene for 0.166667h; Heating;100%
piperidine
110-89-4

piperidine

Benzoylformic acid
611-73-4

Benzoylformic acid

N-thiobenzoylpiperidine
15563-40-3

N-thiobenzoylpiperidine

Conditions
ConditionsYield
With sulfur In benzene at 80℃; for 0.75h;100%
With sulfur In benzene at 80℃; for 1h;
morpholine
110-91-8

morpholine

Benzoylformic acid
611-73-4

Benzoylformic acid

Thiobenzmorpholid
2032-36-2

Thiobenzmorpholid

Conditions
ConditionsYield
With sulfur In benzene at 80℃; for 0.75h;100%
1,4-pyrazine
290-37-9

1,4-pyrazine

Benzoylformic acid
611-73-4

Benzoylformic acid

phenyl(pyrazin-2-yl)methanone
3430-09-9

phenyl(pyrazin-2-yl)methanone

Conditions
ConditionsYield
With NH4S2O8; sulfuric acid; silver nitrate In dichloromethane; water at 40℃; for 2.5h;100%
Stage #1: 1,4-pyrazine; Benzoylformic acid With ammonium peroxydisulfate; sulfuric acid; silver nitrate In dichloromethane; water at 50℃; for 2h;
Stage #2: With water; sodium hydrogencarbonate In dichloromethane
91%
With ferrous(II) sulfate heptahydrate; ammonium peroxydisulfate; formic acid; dimethyl sulfoxide In dichloromethane; water at 40℃; Minisci Aromatic Substitution;74%
With ammonium peroxydisulfate; silver nitrate; trifluoroacetic acid In dichloromethane; water at 60℃; for 3h;68%
With dipotassium peroxodisulfate; silver orthophosphate In dichloromethane; water at 40℃; for 24h;26%
methyl (4-pyridyl) ketone
1122-54-9

methyl (4-pyridyl) ketone

Benzoylformic acid
611-73-4

Benzoylformic acid

1-(2-benzoylpyridin-4-yl)-ethanone
132883-96-6

1-(2-benzoylpyridin-4-yl)-ethanone

Conditions
ConditionsYield
With NH4S2O8; sulfuric acid; silver nitrate In dichloromethane; water at 40℃; for 2.5h;100%
33%
pyridine-4-carbonitrile
100-48-1

pyridine-4-carbonitrile

Benzoylformic acid
611-73-4

Benzoylformic acid

2-benzoylisonicotinonitrile

2-benzoylisonicotinonitrile

Conditions
ConditionsYield
With NH4S2O8; sulfuric acid; silver nitrate In dichloromethane; water at 40℃; for 2.5h;100%
2,3-diethynylquinoxaline
91-19-0

2,3-diethynylquinoxaline

Benzoylformic acid
611-73-4

Benzoylformic acid

phenyl(quinoxalin-2-yl)methanone
13481-33-9

phenyl(quinoxalin-2-yl)methanone

Conditions
ConditionsYield
With NH4S2O8; sulfuric acid; silver nitrate In dichloromethane; water at 40℃; for 2.5h;100%
With dipotassium peroxodisulfate In water; acetonitrile at 20 - 37℃; for 15h; Irradiation; Green chemistry; regioselective reaction;80%
With dipotassium peroxodisulfate; silver orthophosphate In dichloromethane; water at 40℃; for 24h;58%
2-furoic acid hydrazide
3326-71-4

2-furoic acid hydrazide

Benzoylformic acid
611-73-4

Benzoylformic acid

[(Furan-2-carbonyl)-hydrazono]-phenyl-acetic acid

[(Furan-2-carbonyl)-hydrazono]-phenyl-acetic acid

Conditions
ConditionsYield
100%
1,2,3,4-tetrahydroisoquinoline
91-21-4

1,2,3,4-tetrahydroisoquinoline

Benzoylformic acid
611-73-4

Benzoylformic acid

(3,4-dihydroisoquinoline-2(1H)-yl)(phenyl)methanethione
122709-96-0

(3,4-dihydroisoquinoline-2(1H)-yl)(phenyl)methanethione

Conditions
ConditionsYield
With sulfur In benzene at 80℃; for 0.25h;100%
With sulfur In benzene at 80℃; for 0.25h;
Benzoylformic acid
611-73-4

Benzoylformic acid

benzylamine
100-46-9

benzylamine

N-benzylidene benzylamine
780-25-6

N-benzylidene benzylamine

Conditions
ConditionsYield
In dichloromethane at 40℃; for 3h;100%
oxalyl dichloride
79-37-8

oxalyl dichloride

Benzoylformic acid
611-73-4

Benzoylformic acid

diallylamine
124-02-7

diallylamine

1-phenyl-2-(diallylamino)ethane-1,2-dione

1-phenyl-2-(diallylamino)ethane-1,2-dione

Conditions
ConditionsYield
Stage #1: oxalyl dichloride; Benzoylformic acid With copper diacetate; N,N-dimethyl-formamide In dichloromethane at 20℃; for 2h;
Stage #2: diallylamine With triethylamine In dichloromethane
100%
(1S,2R)-(1-methyl-2-phenyl-2-hydroxy)ethyltrimethylammonium iodide
64868-20-8

(1S,2R)-(1-methyl-2-phenyl-2-hydroxy)ethyltrimethylammonium iodide

Benzoylformic acid
611-73-4

Benzoylformic acid

[(1R,2S)-N,N-dimethylephedrinium][phenylglyoxylate]
1639366-24-7

[(1R,2S)-N,N-dimethylephedrinium][phenylglyoxylate]

Conditions
ConditionsYield
With Dowex Inert atmosphere;100%
1-acetoxy-1,2-benziodoxol-3-one
1829-26-1

1-acetoxy-1,2-benziodoxol-3-one

Benzoylformic acid
611-73-4

Benzoylformic acid

C15H9IO5

C15H9IO5

Conditions
ConditionsYield
In chloroform for 0.5h; Inert atmosphere; Reflux;100%
In chloroform for 0.5h; Inert atmosphere; Reflux;100%
2-oxo-imidazolidine-1-ethanol
3699-54-5

2-oxo-imidazolidine-1-ethanol

Benzoylformic acid
611-73-4

Benzoylformic acid

PhGA-HEI

PhGA-HEI

Conditions
ConditionsYield
In water; acetone100%
4-hydrazino-quinazoline

4-hydrazino-quinazoline

Benzoylformic acid
611-73-4

Benzoylformic acid

phenyl[(3H-quinazolin-4-ylidene)hydrazono]acetic acid

phenyl[(3H-quinazolin-4-ylidene)hydrazono]acetic acid

Conditions
ConditionsYield
In isopropyl alcohol for 1h; Heating;99.2%
Benzoylformic acid
611-73-4

Benzoylformic acid

phenylacetic acid
103-82-2

phenylacetic acid

Conditions
ConditionsYield
With chlorobenzene In methanol at 40℃; for 5h; Sealed tube; Green chemistry; chemoselective reaction;99%
With phosphonic Acid; methanesulfonic acid; sodium iodide In water at 95℃; for 48h; Inert atmosphere;94.3%
With hydrazine hydrate anschliessend Erhitzen mit KOH;
With phosphorus; hydrogen iodide at 160℃;
(-)-8-phenylmenthol
65253-04-5

(-)-8-phenylmenthol

Benzoylformic acid
611-73-4

Benzoylformic acid

Phenylglyoxylsaeure-<(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)-1-cyclohexyl>ester
88002-15-7

Phenylglyoxylsaeure-<(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)-1-cyclohexyl>ester

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene Heating;99%
With toluene-4-sulfonic acid In toluene at 130℃; for 2h; Dean-Stark;25%
With hydrogen cation
N,O-dimethylhydroxylamine*hydrochloride
6638-79-5

N,O-dimethylhydroxylamine*hydrochloride

Benzoylformic acid
611-73-4

Benzoylformic acid

N-methoxy-N-methyl-α-oxo-benzeneacetamide
141694-25-9

N-methoxy-N-methyl-α-oxo-benzeneacetamide

Conditions
ConditionsYield
With 4-methyl-morpholine; 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride In acetonitrile at 20℃; for 1.5h;99%
Stage #1: Benzoylformic acid With N-Bromosuccinimide; triphenylphosphine In dichloromethane at 0℃; for 0.25h;
Stage #2: N,O-dimethylhydroxylamine*hydrochloride With triethylamine In dichloromethane at 20℃; for 1h; chemoselective reaction;
75%
With 2-chloro-1-methyl-pyridinium iodide; triethylamine In dichloromethane for 0.75h; Heating;53%
Benzoylformic acid
611-73-4

Benzoylformic acid

(1R,2R)-1,2-diphenyl-2-(4-trifluoromethylbenzyloxy)ethanol
415919-99-2

(1R,2R)-1,2-diphenyl-2-(4-trifluoromethylbenzyloxy)ethanol

(1R,2R)-1,2-diphenyl-2-(4-trifluoromethylbenzyloxy)ethyl phenylglyoxylate
415920-05-7

(1R,2R)-1,2-diphenyl-2-(4-trifluoromethylbenzyloxy)ethyl phenylglyoxylate

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0 - 25℃;99%
(1R,2S)-2-(1,1-dimethylethoxy)-1,2-diphenylethanol
866457-05-8

(1R,2S)-2-(1,1-dimethylethoxy)-1,2-diphenylethanol

Benzoylformic acid
611-73-4

Benzoylformic acid

oxophenylacetic acid (1R,2S)-2-(1,1-dimethylethoxy)-1,2-diphenylethyl ester
866457-10-5

oxophenylacetic acid (1R,2S)-2-(1,1-dimethylethoxy)-1,2-diphenylethyl ester

Conditions
ConditionsYield
With dmap; diisopropyl-carbodiimide In dichloromethane at 20℃;99%
With dmap; diisopropyl-carbodiimide In dichloromethane at 20℃;
(1R,2S)-1-(2-methoxyethoxy)-1,2-bis-(2-methoxyphenyl)-ethanol
916525-75-2

(1R,2S)-1-(2-methoxyethoxy)-1,2-bis-(2-methoxyphenyl)-ethanol

Benzoylformic acid
611-73-4

Benzoylformic acid

oxophenylacetic acid (1R,2S)-2-(2-methoxyethoxy)-1,2-bis(2-methoxyphenyl)ethyl ester
916525-80-9

oxophenylacetic acid (1R,2S)-2-(2-methoxyethoxy)-1,2-bis(2-methoxyphenyl)ethyl ester

Conditions
ConditionsYield
With dmap; diisopropyl-carbodiimide In dichloromethane at 20℃; for 12h;99%
With dmap; diisopropyl-carbodiimide In dichloromethane at 20℃; for 12h;
diallylcarbonate
15022-08-9

diallylcarbonate

Benzoylformic acid
611-73-4

Benzoylformic acid

(E)-1-phenyl-2-buten-1-one
35660-91-4, 35845-66-0, 495-41-0

(E)-1-phenyl-2-buten-1-one

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); Tri(p-tolyl)phosphine In 1,4-dioxane at 100℃; for 12h; Inert atmosphere;99%
Benzoylformic acid
611-73-4

Benzoylformic acid

2-thiocresol
137-06-4

2-thiocresol

S-(o-tolyl) benzothioate

S-(o-tolyl) benzothioate

Conditions
ConditionsYield
With dipotassium peroxodisulfate In water; acetonitrile at 70℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;99%
With ammonium peroxydisulfate; copper(II) oxide In water; dimethyl sulfoxide at 80℃; for 12h;73%
para-thiocresol
106-45-6

para-thiocresol

Benzoylformic acid
611-73-4

Benzoylformic acid

A

di(p-tolyl) disulfide
103-19-5

di(p-tolyl) disulfide

B

S-(4-methylphenyl) thiobenzoate
10371-42-3

S-(4-methylphenyl) thiobenzoate

Conditions
ConditionsYield
With dipotassium peroxodisulfate In water; acetonitrile at 70℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;A 5.5%
B 99%
para-thiocresol
106-45-6

para-thiocresol

Benzoylformic acid
611-73-4

Benzoylformic acid

S-(4-methylphenyl) thiobenzoate
10371-42-3

S-(4-methylphenyl) thiobenzoate

Conditions
ConditionsYield
With dipotassium peroxodisulfate In water; acetonitrile at 70℃; for 24h; Reagent/catalyst; Temperature; Solvent; Inert atmosphere; Schlenk technique; Sealed tube;99%
phenylhydrazine
100-63-0

phenylhydrazine

Benzoylformic acid
611-73-4

Benzoylformic acid

phenyl-((Z)-phenylhydrazono)-acetic acid
74470-05-6

phenyl-((Z)-phenylhydrazono)-acetic acid

Conditions
ConditionsYield
With acetic acid In ethanol for 3h; Reflux;99%

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