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inquiryWholesale factory price Platinum tetrachloride CAS 13454-96-1 Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed additiv
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inquiryPlatinum tetrachloride 13454-96-1 Platinum tetrachloride Basic information Product Name: Platinum tetrachloride Synonyms: PLATINIC CHLORIDE;PLATINUM TETRACHLORIDE;PLATINUM CHLORID
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inquiryAbout Product Details Items Specifications Test Results Appearance White to white crystalline powde
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inquiryProduct Name: Platinum tetrachloride CAS: 13454-96-1 MF: Cl4Pt MW: 336.89 EINECS: 236-645-1 Platinum tetrachloride Structure Platinum tetrachloride Chemical Properties Melting point 370 °C (dec.)(lit.) density 4.303 g/mL
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inquiryLocated in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an
Conditions | Yield |
---|---|
In neat (no solvent) heating for some days to 150°C;; | |
In neat (no solvent) some days (150°C); platinum wire;; | |
In neat (no solvent) heating for some days to 150°C;; |
Conditions | Yield |
---|---|
With tris-(2-chloro-ethyl)-amine In not given byproducts: NH3, N2; Pt is dissolved in a mixture of HCl and HN3;; | |
With HN3 In not given byproducts: NH3, N2; Pt is dissolved in a mixture of HCl and HN3;; |
Conditions | Yield |
---|---|
In neat (no solvent) at 1700°C;; | |
In neat (no solvent) High Pressure; Pt metal reacted with Cl2 under pressure 50 atm in thick-wall quartz tube at 200°C for 5 d; XRD, IR, elem. anal.; | |
In neat (no solvent) at 1700°C;; |
chlorine
platinum
A
platinum trichloride
B
platinum(IV) chloride
Conditions | Yield |
---|---|
In neat (no solvent) platinum black is heated in a Cl2 stream to 360°C, fast cooling;; | |
In neat (no solvent) platinum black is heated in a Cl2 stream to 360°C, fast cooling;; |
potassium tetrachloroplatinate(II)
platinum(IV) chloride
Conditions | Yield |
---|---|
With CoW12O40(5-) In water Kinetics; byproducts: CoW12O40(6-); oxidation of Pt(II) by Co(III)W12O40(5-) in H2O at 25.0°C; mechanism discussed; not isolated, detected by UV spectroscopy; |
platinum tetraiodide
B
iodine
C
Iodine monochloride
D
platinum(IV) chloride
Conditions | Yield |
---|---|
With chlorine In water composition of product depends on amount of Cl2; | |
With Cl2 In water composition of product depends on amount of Cl2; |
Conditions | Yield |
---|---|
With chlorine in cold Cl2 flow; | |
With Cl2 in cold Cl2 flow; |
platinum(IV) chloride
Conditions | Yield |
---|---|
byproducts: H2O; heating in vacuum at 215°C over KOH; | |
at 215°C in vacuum over KOH; | |
byproducts: H2O; heating in vacuum at 215°C over KOH; | |
at 215°C in vacuum over KOH; |
platinum(IV) chloride
Conditions | Yield |
---|---|
With chlorine in Cl2 flow at 300°C; | 0% |
With Cl2 in Cl2 flow at 300°C; | 0% |
Conditions | Yield |
---|---|
at 300°C; | 0% |
at 300°C; | 0% |
PtCl2I2
Iodine monochloride
A
iodine
B
platinum(IV) chloride
platinum(IV) chloride
Conditions | Yield |
---|---|
In neat (no solvent) heating (270 or 350°C, 24 h); |
Conditions | Yield |
---|---|
byproducts: Cl2; glow; | |
byproducts: Cl2; glow; |
Conditions | Yield |
---|---|
With water | |
With ethanol boiling; | |
With methanol |
platinum(IV) chloride
Conditions | Yield |
---|---|
In methanol byproducts: MgCl2; | |
In ethanol byproducts: MgCl2; | |
In methanol byproducts: MgCl2; | |
In ethanol byproducts: MgCl2; |
platinum(IV) chloride
Conditions | Yield |
---|---|
With ethanol byproducts: CaCl2; | |
With methanol byproducts: CaCl2; | |
With ethanol byproducts: CaCl2; | |
With methanol byproducts: CaCl2; |
Conditions | Yield |
---|---|
In water partial decompn. in H2O soln.; | |
With ethanol | |
In water partial decompn. in H2O soln.; | |
With ethanol |
Conditions | Yield |
---|---|
in a sealed tube; | |
in a sealed tube; |
selenium
arsenic trichloride
platinum
platinum(IV) chloride
Conditions | Yield |
---|---|
With chlorine heating in Cl2 flow for 0.5 h, then in a sealed tube at 250°C for more h; after selection of AsCl3 heating 1 h at 360°C in Cl2 flow; at 100°C in vacuum from AsCl3; at 200°C from SeCl4; | |
With Cl2 heating in Cl2 flow for 0.5 h, then in a sealed tube at 250°C for more h; after selection of AsCl3 heating 1 h at 360°C in Cl2 flow; at 100°C in vacuum from AsCl3; at 200°C from SeCl4; |
platinum(IV) chloride
Conditions | Yield |
---|---|
With chlorine In neat (no solvent) byproducts: HCl, N2; loss of 12.23 wt.-% on heating at 360°C in stream of Cl2 for 5 hours;; | |
With Cl2 In neat (no solvent) byproducts: HCl, N2; loss of 12.23 wt.-% on heating at 360°C in stream of Cl2 for 5 hours;; |
platinum(IV) chloride
Conditions | Yield |
---|---|
platinum In water byproducts: HCl; hydrolysis; establishment of equil. in darkness: 0.01-0.005 M aq. K2(PtCl6) soln. at 20°C within 200 days, no remarkable decompn. of 0.0025 M or more diluted soln. within 0.5 years; catalyst: Pt black; autocatalysis by hydrolysis product;; | |
In water byproducts: HCl; Irradiation (UV/VIS); hydrolysis, equil. reaction; establishment of equil. of 0.0025 M ore more diluted aq. K2(PtCl6) soln. within 2 days; reaction rate depends on intensity of light and autocatalysis of hydrolysis product;; | |
platinum In water byproducts: HCl; hydrolysis; establishment of equil. in darkness: 0.01-0.005 M aq. K2(PtCl6) soln. at 20°C within 200 days, no remarkable decompn. of 0.0025 M or more diluted soln. within 0.5 years; catalyst: Pt black; autocatalysis by hydrolysis product;; | |
In water byproducts: HCl; Irradiation (UV/VIS); hydrolysis, equil. reaction; establishment of equil. of 0.0025 M ore more diluted aq. K2(PtCl6) soln. within 2 days; reaction rate depends on intensity of light and autocatalysis of hydrolysis product;; |
platinum(IV) chloride
Conditions | Yield |
---|---|
With H2SO4 In not given in concd. soln.; | |
With sulfuric acid In not given in concd. soln.; |
platinum(IV) chloride
Conditions | Yield |
---|---|
With potassium hydroxide; chlorine byproducts: H2O; drying in vacuum over KOH for more d; then heating for 5 h in vacuum at 170°C over KOH; | |
at higher temp.; | |
decompn. at 110°C; |
A
platinum(IV) chloride
B
platinum
Conditions | Yield |
---|---|
at 150°C for 24 h; formation of PtCl2is poor; | |
at 150°C for 24 h; formation of PtCl2is poor; |
A
platinum(IV) chloride
Conditions | Yield |
---|---|
heating in dry air at 200°C for 4.5 h; | |
With hydrogenchloride in HCl flow, between 170 and 200°C; at 165°C only PtCl4 formed; | |
With HCl in HCl flow, between 170 and 200°C; at 165°C only PtCl4 formed; | |
heating in dry air at 200°C for 4.5 h; |
Conditions | Yield |
---|---|
In neat (no solvent, solid phase) Pt compd. heated in corundum crucible in a quartz tube under Cl2 stream up to 513 K for 2-3 h; | |
In neat (no solvent, solid phase) H2PtCl6*6H2O in chlorine decomposed at 493 K for 8-10 h according to G. Brauer, Handbuch der Preparativen Anorganischen Chemie, Ferdinand Enke Verlag, Stuttgart, 1956; elem. anal.; |
platinum(IV) chloride
Conditions | Yield |
---|---|
In ethanol byproducts: NaCl; partial decompn. of Na2(PtCl6) on boiling ethanolic soln. by presence of ether;; | |
In ethanol byproducts: NaCl; decompn. on boiling in ethanol;; | |
In ethanol byproducts: NaCl; partial decompn. of Na2(PtCl6) on boiling ethanolic soln. by presence of ether;; | |
In ethanol byproducts: NaCl; decompn. on boiling in ethanol;; |
platinum trichloride
platinum(IV) chloride
Conditions | Yield |
---|---|
With chlorine in Cl2 (1 atm) at 364°C it is an equilibrium; | |
With Cl2 in Cl2 (1 atm) at 364°C it is an equilibrium; |
Conditions | Yield |
---|---|
In water reduction with Mg in neutral or acidic soln.; | 100% |
In water reduction with Mg in neutral or acidic soln.; | 100% |
In water reaction in neutral and acid solutions complete;; |
closo-1-Sn-2-(SiMe3)-3-(SiMe3)-2,3-C2B4H4
platinum(IV) chloride
1,2-bis(trimethylsilyl)-1,2-dicarba-closo-hexaborane(6)
Conditions | Yield |
---|---|
In benzene byproducts: SnCl2, Pt; Sn-compd. soln. poured in react. flask with PtCl4 (vac., -23°C); warming (room temp.); monitoring by (11)B-NMR; volatiles fractionation, trap at -45°C collection of B-compd.; elem. anal.; residue in react. flask dissoln. (THF), soln. filtration, THF removal from filtrate, residue drying (80°C, vac.) gave solid SnCl2; | 98% |
In hexane Sn-compd. soln. poured in react. flask with PtCl4 (vac., -23°C); warming (room temp.); monitoring by (11)B-NMR; volatiles fractionation, trap at -45°C collection of B-compd.; elem. anal.; residue in react. flask dissoln. (THF), soln. filtration, THF removal from filtrate, residue drying (80°C, vac.) gave solid SnCl2; | 98% |
In chloroform byproducts: SnCl2, Pt; Sn-compd. soln. poured in react. flask with PtCl4 (vac., -23°C); warming (room temp.); monitoring by (11)B-NMR; volatiles fractionation, trap at -45°C collection of B-compd.; elem. anal.; residue in react. flask dissoln. (THF), soln. filtration, THF removal from filtrate, residue drying (80°C, vac.) gave solid SnCl2; | 98% |
1-n-butyl-4-methylpyridinium chloride
platinum(IV) chloride
Conditions | Yield |
---|---|
In acetonitrile for 3h; Schlenk technique; Reflux; | 98% |
platinum(IV) chloride
Conditions | Yield |
---|---|
In acetonitrile for 3h; Schlenk technique; Reflux; | 96% |
platinum(IV) chloride
1-butyl-3-methylimidazolium chloride
Conditions | Yield |
---|---|
In acetonitrile for 3h; Schlenk technique; Reflux; | 95% |
Conditions | Yield |
---|---|
Stage #1: Piroxicam With sodium hydroxide In ethanol Stage #2: platinum(IV) chloride In ethanol for 3h; Reflux; | 95% |
Conditions | Yield |
---|---|
pH=2; | 90% |
bis(dimethylamine)chlor(methyl)boronium chloride
platinum(IV) chloride
Conditions | Yield |
---|---|
With hydrogenchloride In diethyl ether | 89.3% |
With HCl In diethyl ether | 89.3% |
4-hydroxy-N’-((5-nitrofuran-2-yl)methylene)benzohydrazide
water
platinum(IV) chloride
Conditions | Yield |
---|---|
Stage #1: 4-hydroxy-N’-((5-nitrofuran-2-yl)methylene)benzohydrazide; platinum(IV) chloride In methanol at 20℃; for 24h; Stage #2: water | 88% |
platinum(IV) chloride
2-cyano-2-(p-tolylhydrazono)thioacetamide
Conditions | Yield |
---|---|
In acetone at 20℃; for 24h; | 87.67% |
platinum(IV) chloride
Conditions | Yield |
---|---|
In thionyl chloride (N2); stirred at room temp. for 12 h; evapd., treated with toluene, filtered, dried (vac.); elem. anal.; | 83% |
platinum(IV) chloride
Conditions | Yield |
---|---|
In ethanol; acetone for 2h; | 82% |
Homophthalic acid
platinum(IV) chloride
1,10-phenanthroline hydrate
1,10-phenanthroline platinum(IV) homophthalate
Conditions | Yield |
---|---|
With KOH In water byproducts: HCl; soln. of PtCl4 in distd. H2O was mixed homogeneously with soln. of homophthalic acid in ethanol and refluxed for 1h, pH raised to 6.0 by addn. of ethanolic KOH, soln. of 1,10-phenanthroline in ethanol was added, heated at 70 °C for 1h, cooled;; formed ppt. was filtered, washed several times successively with distd. H2O and ethanol, dried in a vacuum desiccator over silica gel; elem. anal.;; | 81% |
Conditions | Yield |
---|---|
With ammonium hydroxide In 1,4-dioxane; water byproducts: HCl; the complex was prepd. by mixing a hot aq. soln. of the metal chloride (2.5 mmol) with hot dioxane soln. of the ligand (5 mmol); the react. mixt. was then refluxed; aq. ammonia soln. (1:10) was slowly added with stirring (pH 5.0-5.5); the ppt. was filtered, washed with hot dioxane and diethyl ether and dried over anhyd. CaCl2; elem. anal.; | 80% |
platinum(IV) chloride
Conditions | Yield |
---|---|
In neat (no solvent) under N2 using Schlenk techniques; heating at 150°C for 1 h; cooling to room temp.; washed (dry benzene); recrystd. (acetonitrile/benzene); elem.anal.; | 80% |
2-Mercaptopyridine
platinum(IV) chloride
cis-1,2-bis-(diphenylphosphino)ethene
cis-[Pt(η1-S-pyridine-2-thiolato)2(1,2-bis(diphenylphosphino)ethene)]
Conditions | Yield |
---|---|
With Et3N In ethanol; benzene byproducts: Et3N*HCl; pyridine-2-thione in benzene with Et3N was added dropwise to soln. of PtCl4 in ethanol under stirring, solid ligand was added, stirred for 24 h; filtered, evapd. slowly, elem. anal.; | 80% |
2-Mercaptopyridine
platinum(IV) chloride
1,2-bis-(diphenylphosphino)ethane
cis-[Pt(η1-S-pyridine-2-thiolato)2(1,2-bis(diphenylphosphino)ethane)]
Conditions | Yield |
---|---|
With Et3N In ethanol; benzene byproducts: Et3N*HCl; pyridine-2-thione in benzene with Et3N was added dropwise to soln. of PtCl4 in ethanol under stirring, solid ligand was added, stirred for 24 h; filtered, evapd. slowly, elem. anal.; | 80% |
water
platinum(IV) chloride
1-(p-anisyl)-5-aminoimidazole-4-carboxamide
Conditions | Yield |
---|---|
In ethanol; water mixed hot 1:1 EtOH-water soln. of metal salt with EtOH soln. of ligand in stoich. amts., refluxed; filtered, washed with EtOH and Et2O, dried in desiccator over anhyd. CaCl2, elem. anal.; | 80% |
Conditions | Yield |
---|---|
In ethanol for 1.5h; Reflux; | 80% |
platinum(IV) chloride
Conditions | Yield |
---|---|
With n-butyllithium In tetrahydrofuran byproducts: LiCl; dropwise addn. of n-butyllithium soln. (n-hexane) to triazene soln. (THF)with stirring excluding light and moisture, 15°C; after 30 min addn. of PtCl4; stirring, room temp., 12h; evapn.; dissoln. in hexamethyldisiloxane of 40°C; filtration; crystn. at 4°C within 2 d; | 79.5% |
3-(2-(3-chlorophenyl)hydrazono)pentane-2,4-dione
platinum(IV) chloride
Conditions | Yield |
---|---|
In acetone at 20℃; for 24h; | 78.6% |
2-Mercaptopyridine
(diphenylphosphinomethyl)diphenylphosphine selenide
platinum(IV) chloride
cis-[Pt(η1-S-pyridine-2-thiolato)2(dppmPSe)]
Conditions | Yield |
---|---|
With Et3N In ethanol; benzene byproducts: Et3N*HCl; pyridine-2-thione in benzene with Et3N was added dropwise to soln. of PtCl4 in ethanol under stirring, solid ligand was added, stirred for 24 h; filtered, evapd. slowly, elem. anal.; | 78% |
2-Mercaptopyridine
platinum(IV) chloride
1,4-di(diphenylphosphino)-butane
cis-[Pt(η1-S-pyridine-2-thiolato)2(1,4-bis(diphenylphosphino)butane)]
Conditions | Yield |
---|---|
With Et3N In ethanol; benzene byproducts: Et3N*HCl; pyridine-2-thione in benzene with Et3N was added dropwise to soln. of PtCl4 in ethanol under stirring, solid ligand was added, stirred for 24 h; filtered, evapd. slowly, elem. anal.; | 78% |
Conditions | Yield |
---|---|
In ethanol at 60 - 70℃; | 78% |
Conditions | Yield |
---|---|
In neat (no solvent) heating mixt. of LiCl, HgCl2 and PtCl4 (molar ratio 1:2:3) under steam at 425°C overnight; treated with warm aqua regia; | 77% |
[2,2]bipyridinyl
Homophthalic acid
platinum(IV) chloride
2,2'-bipyridine platinum(IV) homophthalate
Conditions | Yield |
---|---|
With KOH In water byproducts: HCl; soln. of PtCl4 in distd. H2O was mixed homogeneously with soln. of homophthalic acid in ethanol and refluxed for 1h, pH raised to 6.0 by addn. of ethanolic KOH, soln. of 2,2'-bipyridine in ethanol was added, heated at 70 °C for 1h, cooled;; formed ppt. was filtered, washed several times successively with distd. H2O and ethanol, dried in a vacuum desiccator over silica gel; elem. anal.;; | 76% |
1-vinylimidazole
platinum(IV) chloride
Conditions | Yield |
---|---|
In water refluxed for 3 h; distd., cooled, poured into ice, ppt. is washed with ethanol and ether,dried in vac.; | 75% |
In ethanol refluxed for 3 h; distd., cooled, poured into ice, ppt. is filtd., dried in vac.; | 65% |
In acetone the azole is added to a soln. of PtCl4 in acetone with intense stirring(ratio PtCl4:azole 1:8); the ppt. is recrystd. from methanol, dried in vac., elem. anal.; | 25% |
2-Mercaptopyridine
1,3-bis-(diphenylphosphino)propane
platinum(IV) chloride
cis-[Pt(η1-S-pyridine-2-thiolato)2(1,3-bis(diphenylphosphino)propane)]
Conditions | Yield |
---|---|
With Et3N In ethanol; benzene byproducts: Et3N*HCl; pyridine-2-thione in benzene with Et3N was added dropwise to soln. of PtCl4 in ethanol under stirring, solid ligand was added, stirred for 24 h; filtered, evapd. slowly, elem. anal.; | 75% |
2-Mercaptopyridine
(diphenylphosphinomethyl)diphenylphosphine sulphide
platinum(IV) chloride
cis-[Pt(η1-S-pyridine-2-thiolato)2(dppmPS)]
Conditions | Yield |
---|---|
With Et3N In ethanol; benzene byproducts: Et3N*HCl; pyridine-2-thione in benzene with Et3N was added dropwise to soln. of PtCl4 in ethanol under stirring, solid ligand was added, stirred for 24 h; filtered, evapd. slowly, elem. anal.; | 75% |
water
platinum(IV) chloride
1-(p-tolyl)-5-aminoimidazole-4-carboxamide
Conditions | Yield |
---|---|
In ethanol; water mixed hot 1:1 EtOH-water soln. of metal salt with EtOH soln. of ligand in stoich. amts., refluxed; filtered, washed with EtOH and Et2O, dried in desiccator over anhyd. CaCl2, elem. anal.; | 73% |
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