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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Hydroxycyclohexanone Manufacturer/High quality/Best price/In stock

Cas:13482-22-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-Hydroxycyclohexanone

Cas:13482-22-9

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Hydroxycyclohexanone

Cas:13482-22-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. High quality and competitive price: 1) Standard: BP/USP/EP/ enterprise standard 2) All purity ≥99% 3) We are manufacturers and can provide high quality products at factory prices. 2. Fast and safe delivery 1) The package c

4-HYDROXYCYCLOHEXANONE CAS:13482-22-9

Cas:13482-22-9

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

4-HYDROXYCYCLOHEXANONE 13482-22-9

Cas:13482-22-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 13482-22-9 with competitive price

Cas:13482-22-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Cyclohexanone,4-hydroxy- 13482-22-9

Cas:13482-22-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

4-HYDROXYCYCLOHEXANONE CAS:13482-22-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic in

4-HYDROXYCYCLOHEXANONE CAS:13482-22-9

Cas:13482-22-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Cyclohexanone,4-hydroxy-

Cas:13482-22-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

4-hydroxy-cyclohexanone CAS13482-22-9

Cas:13482-22-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Cyclohexanone,4-hydroxy-

Cas:13482-22-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-hydroxy-cyclohexanone

Cas:13482-22-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Hydroxycyclohexanone

Cas:13482-22-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-HYDROXYCYCLOHEXANONE

Cas:13482-22-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

4-Hydroxycyclohexanone

Cas:13482-22-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

4-hydroxy-cyclohexanone

Cas:13482-22-9

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

4-HYDROXYCYCLOHEXANONE

Cas:13482-22-9

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

4-HYDROXYCYCLOHEXANONE

Cas:13482-22-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

4-HYDROXYCYCLOHEXANONECAS13482-22-9

Cas:13482-22-9

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Trading Company

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Buy Top Quality4-HYDROXYCYCLOHEXANONE

Cas:13482-22-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Product Name:4-HYDROXYCYCLOHEXANONE CAS No:13482-22

4-HYDROXYCYCLOHEXANONE

Cas:13482-22-9

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-hydroxy-cyclohexanone

Cas:13482-22-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

4-Hydroxycyclohexanone

Cas:13482-22-9

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-HYDROXYCYCLOHEXANONE

Cas:13482-22-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-HYDROXYCYCLOHEXANONE

Cas:13482-22-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

4-hydroxy-cyclohexanone

Cas:13482-22-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, in

Enke 4-Hydroxycyclohexanone

Cas:13482-22-9

Min.Order:1 Kilogram

FOB Price: $300.0 / 400.0

Type:Lab/Research institutions

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

4-Hydroxy-cyclohexanone

Cas:13482-22-9

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

4-hydroxy-cyclohexanone

Cas:13482-22-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

4-Hydroxycyclohexanone cas no. 13482-22-9 98%

Cas:13482-22-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2,3-dioxabicyclo[2.2.2]octane
280-53-5

2,3-dioxabicyclo[2.2.2]octane

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 72h; Kornblum-DeLaMare rearrangement;100%
Multi-step reaction with 3 steps
1: 49 percent / n-BuLi / diethyl ether / -78 °C
2: 47 percent / CH2Cl2 / 1 h / 0 - 20 °C
3: 75 percent / potassium t-butoxide / tetrahydrofuran / 0.25 h
View Scheme
4,4-ethylenedioxycyclohexan-1-ol
22428-87-1

4,4-ethylenedioxycyclohexan-1-ol

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With water; toluene-4-sulfonic acid for 2h; Heating;99%
With hydrogenchloride In water; acetone at 20℃; for 28h;99%
With ammonium cerium(IV) nitrate; water In acetonitrile at 60℃; for 0.416667h; pH=8; Hydrolysis;92%
4-methoxy-phenol
150-76-5

4-methoxy-phenol

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With potassium hydroxide; samarium diiodide In tetrahydrofuran; water for 0.116667h; Ambient temperature;97%
1,4-Cyclohexanedione
637-88-7

1,4-Cyclohexanedione

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With [(1S,2S)-N-(p-toluensulfonyl)-1,2-diphenylethanediamine](p-cymene)ruthenium (I); formic acid; triethylamine In acetonitrile at 20℃;96%
With Candida parapsilosis ATCC 7330 whole cells In ethanol; water at 25℃; for 8h; pH=6.8; Microbiological reaction; regioselective reaction;63%
With sodium tetrahydroborate In methanol at -20℃;60%
With keto reductases from Lactobacillus kefir; nicotinamide adenine dinucleotide phosphate; isopropyl alcohol In aq. phosphate buffer at 30℃; for 12h; pH=7; Reagent/catalyst; pH-value; Enzymatic reaction;
1,4-Cyclohexanediol
556-48-9

1,4-Cyclohexanediol

A

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

B

1,4-Cyclohexanedione
637-88-7

1,4-Cyclohexanedione

Conditions
ConditionsYield
With sodium bromate; sodium hydrogensulfite In water; acetonitrile at 20℃; for 6h; Oxidation;A 1%
B 93%
With sodium bromate; sodium hydrogensulfite In water; acetonitrile at 20℃; for 2h; Oxidation;A 78%
B 10%
With 2O34W9Zn(12-)*W(6+)*3Zn(2+)*2H2O; dihydrogen peroxide In water; acetonitrile at 135℃; under 2250.23 Torr; for 0.25h; Microwave irradiation;A n/a
B 58%
1,4-Cyclohexanediol
556-48-9

1,4-Cyclohexanediol

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With sodium bromate; ammonium cerium(IV) nitrate In water; acetonitrile92%
With sodium bromate; ammonium cerium (IV) nitrate In water; acetonitrile for 2.5h; Reflux;91%
With calcium hypochlorite; potassium bromide In water; acetic acid at 0℃; for 3h;88%
3-(1-phenyl-vinyl)-1,2,5-trioxa-spiro[5.5]undecan-9-ol
868696-17-7

3-(1-phenyl-vinyl)-1,2,5-trioxa-spiro[5.5]undecan-9-ol

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With N-benzyl-trimethylammonium hydroxide In tetrahydrofuran at 20℃; for 1h;86%
3,3-dimethyl-9-(tetrahydro-pyran-2-yloxy)-1,5-dioxa-spiro[5.5]undecane

3,3-dimethyl-9-(tetrahydro-pyran-2-yloxy)-1,5-dioxa-spiro[5.5]undecane

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With methanol; Montmorillonite K-10 clay at 20℃; Methanolytic deprotection;85%
4-hydroxy-1-methoxy-1-cyclohexene
69125-55-9

4-hydroxy-1-methoxy-1-cyclohexene

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With hydrogenchloride at 50℃; for 0.75h;82%
succinic acid methyl ester 3-(1-phenylvinyl)-1,2,5-trioxaspiro[5.5]undec-9-yl ester
872891-56-0

succinic acid methyl ester 3-(1-phenylvinyl)-1,2,5-trioxaspiro[5.5]undec-9-yl ester

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With N-benzyl-trimethylammonium hydroxide In tetrahydrofuran at 20℃; for 1h;82%
hydroquinone
123-31-9

hydroquinone

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With sodium formate; sodium hydroxide In water at 120℃; pH=12;82%
With 5% palladium on Al2O3; hydrogen In 1,2-dichloro-ethane at 60℃; under 3750.38 Torr; for 24h; chemoselective reaction;50%
With hydrogen; palladium In water at 80℃; under 750.075 Torr; for 6h; Sealed;
C11H24NO2(1+)*CF3O3S(1-)

C11H24NO2(1+)*CF3O3S(1-)

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran for 0.25h;75%
1,4-bis(trimethylsilyloxy)cyclohex-1-ene
6838-67-1

1,4-bis(trimethylsilyloxy)cyclohex-1-ene

A

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

B

4-(trimethylsiloxy)cyclohexanone
23510-94-3

4-(trimethylsiloxy)cyclohexanone

Conditions
ConditionsYield
With methanol; biphenyl; 1-Cyanonaphthalene In acetonitrile Product distribution; Mechanism; Ambient temperature; Irradiation; var. temp., no irradiation; 1-(trimethylsiloxy)cyclohexene;A n/a
B 63%
cyclohexanedione monoethylene ketal
4746-97-8

cyclohexanedione monoethylene ketal

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
Stage #1: cyclohexanedione monoethylene ketal With methanol; sodium tetrahydroborate at 0 - 20℃; for 2h;
Stage #2: With hydrogenchloride; water In tetrahydrofuran at 20℃; for 18h;
62%
Multi-step reaction with 2 steps
1: 98 percent / sodium borohydride / methanol / 1 h
2: 78 percent / HCl
View Scheme
Multi-step reaction with 2 steps
1: NaBH4 / ethanol / 3 h / 20 °C
2: ceric ammonium nitrate / acetonitrile; H2O / 0.5 h / 70 °C
View Scheme
cis-(3R)-4-benzoyl-3-methyl-1-oxa-4-azaspiro[4.5]decane-8-ol
387819-51-4

cis-(3R)-4-benzoyl-3-methyl-1-oxa-4-azaspiro[4.5]decane-8-ol

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
mildly acidic conditions;59%
2,3-dioxabicyclo<2.2.2>octane
280-53-5

2,3-dioxabicyclo<2.2.2>octane

A

ethene
74-85-1

ethene

B

butanedial
638-37-9

butanedial

C

cis-1,4-cyclohexanediol
931-71-5

cis-1,4-cyclohexanediol

D

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With tris(triphenylphosphine)ruthenium(II) chloride In dichloromethane at 50℃; for 2h; Product distribution; ruthenium(II) catalyzed reaction of 1,4-endoperoxide;A 43%
B 19%
C 17%
D 11%
With tris(triphenylphosphine)ruthenium(II) chloride In dichloromethane at 50℃; for 2h; Title compound not separated from byproducts;A 43 % Chromat.
B 19 % Spectr.
C 17 % Chromat.
D 11 % Chromat.
2,3-dioxabicyclo<2.2.2>octane
280-53-5

2,3-dioxabicyclo<2.2.2>octane

A

butanedial
638-37-9

butanedial

B

cis-1,4-cyclohexanediol
931-71-5

cis-1,4-cyclohexanediol

C

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

D

1,4-Cyclohexanedione
637-88-7

1,4-Cyclohexanedione

Conditions
ConditionsYield
With cobalt(II) 5,10,15,20-tetraphenylporphyrin In chloroform at 60℃; for 11h; Further byproducts given;A 21%
B 28%
C 17%
D 5%
4-(1-oxoethyl)-1-cyclohexanone
5034-21-9

4-(1-oxoethyl)-1-cyclohexanone

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With sulfuric acid; water
With sodium hydroxide; water
2,3-dioxabicyclo<2.2.2>octane
280-53-5

2,3-dioxabicyclo<2.2.2>octane

A

cis-1,4-cyclohexanediol
931-71-5

cis-1,4-cyclohexanediol

B

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

C

1,4-Cyclohexanedione
637-88-7

1,4-Cyclohexanedione

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In dichloromethane at 60℃; for 5h; Product distribution; other reagent;A 39 % Chromat.
B 44 % Chromat.
C 4 % Chromat.
(1S,4R)-Cyclohex-2-ene-1,4-diol
53762-85-9

(1S,4R)-Cyclohex-2-ene-1,4-diol

A

4-hydroxy-2-cyclohexenone
30182-12-8

4-hydroxy-2-cyclohexenone

B

1,4-Cyclohexanediol
556-48-9

1,4-Cyclohexanediol

C

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
ruthenium In tetrahydrofuran at 65℃; for 15h; Yield given. Yields of byproduct given;
ruthenium In tetrahydrofuran at 60℃; for 15h; Yield given. Yields of byproduct given;
1,4-Cyclohexanedione
637-88-7

1,4-Cyclohexanedione

A

1,4-Cyclohexanediol
556-48-9

1,4-Cyclohexanediol

B

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With hydrogen; silica gel; nickel In isopropyl alcohol at 100℃; under 4650.4 Torr; Product distribution; Kinetics; various catalyst, var. temp., var. of hydrogen pressure, var. of substrate concentr.;A n/a
B 87 % Chromat.
With hydrogen; palladium/alumina at 130℃; under 22502.3 Torr; Conversion of starting material;
With Zr -F-100 In isopropyl alcohol at 82℃; for 6h; Reagent/catalyst;
With nicotinamide adenine dinucleotide phosphate; isopropyl alcohol In aq. phosphate buffer at 30℃; for 12h; pH=7; Enzymatic reaction;
1,4-Cyclohexanedione
637-88-7

1,4-Cyclohexanedione

A

1,4-Cyclohexanediol
556-48-9

1,4-Cyclohexanediol

B

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

C

cyclohexanone
108-94-1

cyclohexanone

D

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen; palladium In tert-butyl alcohol at 30℃; Product distribution; further catalyst;
With hydrogen; palladium In tert-butyl alcohol at 30℃; Yield given. Yields of byproduct given;
(8-hydroxy-1-oxa-4-aza-spiro[4.5]dec-4-yl)-phenyl-methanone
252857-23-1

(8-hydroxy-1-oxa-4-aza-spiro[4.5]dec-4-yl)-phenyl-methanone

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With IR 120 (H(+)-form In acetonitrile Hydrolysis; Title compound not separated from byproducts;
4-benzoyloxy-cyclohexanone-(1)

4-benzoyloxy-cyclohexanone-(1)

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With methanol; sodium methylate
cyclohexanol
108-93-0

cyclohexanol

A

hexanedial
1072-21-5

hexanedial

B

3-hydroxycyclohexanone
823-19-8

3-hydroxycyclohexanone

C

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

D

cyclohexanone
108-94-1

cyclohexanone

Conditions
ConditionsYield
With air; methyl nitrite; nitrogen(II) oxide at 24.85℃; under 760 Torr; Kinetics; Product distribution;
cis-6-phenylthio-4-hydroxy-2-cyclohexenone

cis-6-phenylthio-4-hydroxy-2-cyclohexenone

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
With ethanol; Raney nickel W-2 at 20℃; for 1h;
cyclohexanol
108-93-0

cyclohexanol

A

cyclohexane-1,4-diol
6995-79-5

cyclohexane-1,4-diol

B

cis-1,4-cyclohexanediol
931-71-5

cis-1,4-cyclohexanediol

C

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

D

trans-4-hydroxycyclohexyl hydroperoxide

trans-4-hydroxycyclohexyl hydroperoxide

Conditions
ConditionsYield
With oxygen at 129.85℃; Kinetics; Product distribution;
3-(1-Phenyl-vinyl)-1,2,5-trioxaspiro[5.5]undec-9-one
678967-25-4

3-(1-Phenyl-vinyl)-1,2,5-trioxaspiro[5.5]undec-9-one

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 96 percent / NaBH4 / methanol / 0.5 h / 0 °C
2: 86 percent / Triton B / tetrahydrofuran / 1 h / 20 °C
View Scheme
(1R,1S)-2,3-dioxabicyclo[2.2.2]oct-5-ene
6671-70-1

(1R,1S)-2,3-dioxabicyclo[2.2.2]oct-5-ene

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 48 percent / n-BuLi / diethyl ether / -78 °C
2: 83 percent / H2 / Pd/C / ethyl acetate / 7 h
3: 47 percent / CH2Cl2 / 1 h / 0 - 20 °C
4: 75 percent / potassium t-butoxide / tetrahydrofuran / 0.25 h
View Scheme
1-(6-bromo-2-pyridyl)-1-methyl-hydrazine
1260240-66-1

1-(6-bromo-2-pyridyl)-1-methyl-hydrazine

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

C12H16BrN3O
1342811-31-7

C12H16BrN3O

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 1h;100%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

4-(tert-butyldimethylsilyloxy)cyclohexanone
55145-45-4

4-(tert-butyldimethylsilyloxy)cyclohexanone

Conditions
ConditionsYield
With 1H-imidazole99%
With 1H-imidazole In dichloromethane for 1h; Ambient temperature;98%
With 1H-imidazole 1.) CH2Cl2, 0 deg C, 15 min, 2.) CH2Cl2, RT, overnight; Yield given. Multistep reaction;
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

4-oxocyclohexyl methanesulfonate
78847-53-7

4-oxocyclohexyl methanesulfonate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 16h; Inert atmosphere;98%
With triethylamine In dichloromethane at 0℃; for 0.5h; Yield given;
With triethylamine In dichloromethane at 0 - 20℃;
3-Phenylpropenol
104-54-1

3-Phenylpropenol

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

2-cinnamyl-4-hydroxycyclohexan-1-one

2-cinnamyl-4-hydroxycyclohexan-1-one

Conditions
ConditionsYield
Stage #1: 3-Phenylpropenol With 1,1'-bis-(diphenylphosphino)ferrocene; bis(η3-allyl-μ-chloropalladium(II)) In methanol at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: 4-hydroxycyclohexanone With pyrrolidine In methanol for 12h; Inert atmosphere;
98%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

4-Phenylbutyric acid
1821-12-1

4-Phenylbutyric acid

4-oxocyclohexanoyl 4-phenylbutanoate

4-oxocyclohexanoyl 4-phenylbutanoate

Conditions
ConditionsYield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0℃; Steglich Esterification;97%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

(S,S)-hydrobenzoin
2325-10-2

(S,S)-hydrobenzoin

(2S,3S)-2,3-Diphenyl-1,4-dioxa-spiro[4.5]decan-8-ol
573702-90-6

(2S,3S)-2,3-Diphenyl-1,4-dioxa-spiro[4.5]decan-8-ol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 3.5h; Heating;96%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Cyclopropylamine
765-30-0

Cyclopropylamine

4-(cyclopropylamino)cyclohexanol
1346555-34-7

4-(cyclopropylamino)cyclohexanol

Conditions
ConditionsYield
Stage #1: 4-hydroxycyclohexanone; Cyclopropylamine With sodium tris(acetoxy)borohydride; acetic acid In 1,2-dichloro-ethane at 20℃; for 13h;
Stage #2: With sodium hydroxide In water; 1,2-dichloro-ethane
96%
methanol
67-56-1

methanol

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

4,4-dimethoxycyclohexanol
112906-44-2

4,4-dimethoxycyclohexanol

Conditions
ConditionsYield
Stage #1: methanol; 4-hydroxycyclohexanone With trimethyl orthoformate; toluene-4-sulfonic acid at 20℃; for 0.166667h; Heating / reflux;
Stage #2: With sodium hydrogencarbonate In methanol; water at 0℃; pH=7;
95%
at 0 - 20℃; for 1h; Inert atmosphere; Molecular sieve;10.95 g
3,4-dihydro-2H-pyran
110-87-2

3,4-dihydro-2H-pyran

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone
60739-53-9

4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone

Conditions
ConditionsYield
With toluene-4-sulfonic acid In dichloromethane for 1.5h; ice-bath;94%
With trichlorophosphate
With toluene-4-sulfonic acid for 0.666667h; Ambient temperature;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

1,4-bis(trimethylsilyloxy)cyclohex-1-ene
6838-67-1

1,4-bis(trimethylsilyloxy)cyclohex-1-ene

Conditions
ConditionsYield
With triethylamine; sodium iodide In acetonitrile at -30 - 20℃; Inert atmosphere;92%
With triethylamine In N,N-dimethyl-formamide for 4.5h; Heating;68%
Stage #1: 4-hydroxycyclohexanone With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 1h; Metallation;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78 - 20℃; for 1h; silylation;
allyl propyl ether
1471-03-0

allyl propyl ether

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

2-allyl-4-hydroxycyclohexanone
1579255-30-3

2-allyl-4-hydroxycyclohexanone

Conditions
ConditionsYield
With pyrrolidine; 1,1'-bis-(diphenylphosphino)ferrocene; bis(η3-allyl-μ-chloropalladium(II)) In methanol at 20℃; for 12h; Inert atmosphere; regioselective reaction;92%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

acetyl chloride
75-36-5

acetyl chloride

4-acetoxycyclohexanone
41043-88-3

4-acetoxycyclohexanone

Conditions
ConditionsYield
With pyridine at 0 - 20℃; for 12.5h; Inert atmosphere;91%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

chloroacetyl chloride
79-04-9

chloroacetyl chloride

4-oxo-cyclohexyl chloroacetate
1361557-20-1

4-oxo-cyclohexyl chloroacetate

Conditions
ConditionsYield
With pyridine at 0 - 20℃; for 12.5h; Inert atmosphere;91%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

acryloyl chloride
814-68-6

acryloyl chloride

C9H12O3

C9H12O3

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 4h;90.6%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

3,3-dimethyl-1,5-dioxaspiro<5.5>undecan-9-ol
69825-15-6

3,3-dimethyl-1,5-dioxaspiro<5.5>undecan-9-ol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 4.6h; Heating;90%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

4-methoxy-benzoyl chloride
100-07-2

4-methoxy-benzoyl chloride

4-oxocyclohexyl 4-methoxybenzoate

4-oxocyclohexyl 4-methoxybenzoate

Conditions
ConditionsYield
With triethylamine for 24h; Ambient temperature;90%
With pyridine In dichloromethane at 45℃; for 4h; Inert atmosphere; Schlenk technique;
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

aniline
62-53-3

aniline

C12H17NO

C12H17NO

Conditions
ConditionsYield
With sodium tris(acetoxy)borohydride; acetic acid In dichloromethane at 20℃; Borch Reduction; Inert atmosphere;90%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

Trichloroacetyl chloride
76-02-8

Trichloroacetyl chloride

4-oxo-cyclohexyl trichloroacetate
57307-54-7

4-oxo-cyclohexyl trichloroacetate

Conditions
ConditionsYield
With pyridine at 0 - 20℃; for 12.5h; Inert atmosphere;89%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

4,4-diethoxycyclohexanone
60612-00-2

4,4-diethoxycyclohexanone

Conditions
ConditionsYield
With toluene-4-sulfonic acid In ethanol at 20℃;89%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

benzaldehyde
100-52-7

benzaldehyde

(2E,6E)‑2,6‑bis(benzylidene)‑4‑hydroxycyclohexan-1-one

(2E,6E)‑2,6‑bis(benzylidene)‑4‑hydroxycyclohexan-1-one

Conditions
ConditionsYield
With potassium hydroxide In methanol; water at 20℃; Claisen-Schmidt Condensation;88%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

1,4-Cyclohexanedione
637-88-7

1,4-Cyclohexanedione

Conditions
ConditionsYield
With pyridinium chlorochromate In dichloromethane for 2h; Ambient temperature;87%
tribromoacetyl chloride
34718-47-3

tribromoacetyl chloride

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

4-oxo-cyclohexyl tribromoacetate
1361557-28-9

4-oxo-cyclohexyl tribromoacetate

Conditions
ConditionsYield
With pyridine at 0 - 20℃; for 12.5h; Inert atmosphere;87%
4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

butyryl chloride
141-75-3

butyryl chloride

4-oxo-cyclohexyl butanoate

4-oxo-cyclohexyl butanoate

Conditions
ConditionsYield
With pyridine at 0 - 20℃; for 12.5h; Inert atmosphere;87%
(E)-3-phenylpropenal
14371-10-9

(E)-3-phenylpropenal

4-hydroxycyclohexanone
13482-22-9

4-hydroxycyclohexanone

(2E,6E)‑2,6‑bis(cinnamylidene)‑4‑hydroxycyclohexanone

(2E,6E)‑2,6‑bis(cinnamylidene)‑4‑hydroxycyclohexanone

Conditions
ConditionsYield
With potassium hydroxide In methanol; water at 20℃; Claisen-Schmidt Condensation;87%
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