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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesis.

High purity and quality 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:100 Gram

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages for 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Cas 14647-23-5 Guaranteed purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Red to orange powder Storage:Refrige

High quality 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Cas 14647-23-5 with best price

Cas:14647-23-5

Min.Order:100 Gram

FOB Price: $3.0 / 3.5

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Henan Allgreen Chemical Co.,Ltd

high purity Storage:Sealed, dry, microtherm , avoid light and smell. Package:meet customer's demand Application:organic synthesis Transportation:by sea or by air Port:shanghai

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:1 Kilogram

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply [1,2-Bis(Diphenylphosphino)Ethane]Dichloronickel

Cas:14647-23-5

Min.Order:1

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Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 14647-23-5 [1,2-Bis(diphenylphosphino)ethane]dichloronickel Manufacturer

Cas:14647-23-5

Min.Order:1 Gram

FOB Price: $0.1

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis 1. Beijing High-Tech Enterprises 2. Strong R&D Team 3. 8 years of experiences in R & D of high-tech Catalyst; 4. 5000 production techniques, 69 items of national patents, and 360 kinds of prod

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:0 Metric Ton

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,2-Bis-(diphenylphosphino)-ethane nickel chloride

Cas:14647-23-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

1,2-Bis(diphenylphosphino)ethan nickel(II) chloride

Cas:14647-23-5

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.

TIANFU CHEM 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:100 Gram

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Hot CAS 14647-23-5 with best quality

Cas:14647-23-5

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Synonyms 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride;1,2-Bis(diphenylphosphino)ethane nickel(II) chlori CAS:

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride 14647-23-5

Cas:14647-23-5

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:Yellowish to off-white powder Storage:Store in sealed contai

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride CAS no. 14647-23-5

Cas:14647-23-5

Min.Order:100 Gram

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Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride 14647-23-5

Cas:14647-23-5

Min.Order:1 Kilogram

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Metal catalyst, 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride CAS:14647-23-5

Cas:14647-23-5

Min.Order:1 Kilogram

FOB Price: $24.0 / 28.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride CAS:14647-23-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializ

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride CAS:14647-23-5

Cas:14647-23-5

Min.Order:1 Gram

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Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:1 Kilogram

FOB Price: $10.0 / 100.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:0

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:0

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:4 Kilogram

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:100 Gram

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Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride/High quality/Best price

Cas:14647-23-5

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

1,2-Bis(diphenylphosphino)ethane nickel(II) chlorideAppearance:white powder Storage:Keep away of light, cool place Package:according to customers' requirements Application:pharmaceutical intermediates Transportation:By air(EMS or EUB or FedEx or TNT

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:1 Gram

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Type:Other

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Siwei Development Group Ltd.

Product name: 1,2-Bis(Diphenylphosphinoethane)Nickel(II)Chloride CAS No.:14647-23-5 Molecule Formula:C26H24Cl2NiP2 Molecule Weight:528.02 Purity: 98.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise St

High Quality 1,2-Bis(Diphenylphosphinoethane)Nickel(II)Chloride in stock

Cas:14647-23-5

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

[1,2-Bis(diphenylphosphino)ethane]dichloronickel

Cas:14647-23-5

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Chemical Properties Melting point 263-265 °C(lit.) storage temp. Refrigerator form crystal color orange Water Solubility insoluble CAS DataBase Reference 14647-2

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:200 Kilogram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:0

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Type:Other

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Cas:14647-23-5

Min.Order:0

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Type:Manufacturers

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Synthetic route

(1,2-bis(diphenylphosphino)ethane)Ni(C2H4CO2)

(1,2-bis(diphenylphosphino)ethane)Ni(C2H4CO2)

chlorine
7782-50-5

chlorine

A

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

B

3-chloropropanoic anhydride
20495-99-2

3-chloropropanoic anhydride

C

[(1,2-bis(diphenylphosphino)ethaneO2)3Ni][NiCl4]

[(1,2-bis(diphenylphosphino)ethaneO2)3Ni][NiCl4]

Conditions
ConditionsYield
In dichloromethane at -196.16℃; for 14h; Glovebox; Sealed tube;A 100%
B 96%
C 75%
nickel(II) chloride hexahydrate

nickel(II) chloride hexahydrate

1,2-bis-(diphenylphosphino)ethane
1663-45-2

1,2-bis-(diphenylphosphino)ethane

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

Conditions
ConditionsYield
In ethanol at 80℃; for 0.5h; Sealed tube; Inert atmosphere;98%
In methanol; isopropyl alcohol for 0.5h;93%
In methanol; isopropyl alcohol equimolar amounts; stirring for 30 min;; filtration; recrystn. from hot acetone; elem. anal.;;>75
nickel(II) chloride dihydrate

nickel(II) chloride dihydrate

1,2-bis-(diphenylphosphino)ethane
1663-45-2

1,2-bis-(diphenylphosphino)ethane

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

Conditions
ConditionsYield
With acetic acid In water for 10h; Heating;95%
dimethylnickel{1,2-bis(diphenylphosphino)ethane}
31387-22-1

dimethylnickel{1,2-bis(diphenylphosphino)ethane}

propionyl chloride
79-03-8

propionyl chloride

A

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

B

methane
34557-54-5

methane

C

ethane
74-84-0

ethane

D

ethene
74-85-1

ethene

E

acetone
67-64-1

acetone

Conditions
ConditionsYield
In toluene toluene and EtCOCl added to Ni complex at -196°C, after evacuation stirred at room temp. for 24 h; ppt. collected by filtration, crystd. from THF-Et2O; GLC anal.;A 88%
B 51%
C 8%
D 15%
E 21%
NiCl3(bis(diphenylphosphino)ethane)

NiCl3(bis(diphenylphosphino)ethane)

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

Conditions
ConditionsYield
In acetonitrile at 25℃; under 20 Torr; Solvent; Photolysis;87%
2,3,4,5-tetraphenylnickelole-bis(1,2-diphenylphosphino)ethane

2,3,4,5-tetraphenylnickelole-bis(1,2-diphenylphosphino)ethane

diphenyl acetylene
501-65-5

diphenyl acetylene

A

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

B

hexaphenylbenzene
992-04-1

hexaphenylbenzene

Conditions
ConditionsYield
With hydrogenchloride In toluene under anhyd. and O2-free N2; refluxed (18 h); 6 N HCl added; ppt. filtered off; org. filtrate washed (aq. NaHCO3); dried (anhyd. MgSO4); evapd.;A n/a
B 60%
dimethylnickel{1,2-bis(diphenylphosphino)ethane}
31387-22-1

dimethylnickel{1,2-bis(diphenylphosphino)ethane}

A

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

B

ethane
74-84-0

ethane

C

NiPh(Cl)(1,2-bis(diphenylphosphino)ethane)
88544-62-1

NiPh(Cl)(1,2-bis(diphenylphosphino)ethane)

D

NiCl(Me)(1,2-bis(diphenylphosphino)ethane)
88544-61-0

NiCl(Me)(1,2-bis(diphenylphosphino)ethane)

E

toluene
108-88-3

toluene

Conditions
ConditionsYield
With chlorobenzene In neat (no solvent) mixt. of educt and PhCl stirred at room temp. for 5 d; hexane added, ppt. dissolved in THF, solid recovered by addn. of hexane; GLC, NMR anal.;A n/a
B 14%
C n/a
D 55%
E 50%
(1,2-dimethoxyethane)dichloronickel(II)
29046-78-4

(1,2-dimethoxyethane)dichloronickel(II)

1,2-bis-(diphenylphosphino)ethane
1663-45-2

1,2-bis-(diphenylphosphino)ethane

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

Conditions
ConditionsYield
In dichloromethane at 20℃; Schlenk technique; Inert atmosphere;54%
In dichloromethane at 20℃; for 0.5h; Inert atmosphere; Glovebox;219 mg
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

1,2-bis-(diphenylphosphino)ethane
1663-45-2

1,2-bis-(diphenylphosphino)ethane

A

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

B

(DPPE)NiCl(sulfonyl-O,O'-Me)

(DPPE)NiCl(sulfonyl-O,O'-Me)

C

1,5-dicyclooctadiene
5259-72-3, 10060-40-9, 111-78-4

1,5-dicyclooctadiene

Conditions
ConditionsYield
In tetrahydrofuran inert atmosphere; addn. of DPPE to soln. of Ni(COD)2 in THF, cooling (-78°C), addn. of sulfonyl chloride, stirring (room temp.); filtn., pptn. on addn. of hexane, washing, drying; elem. anal.;A 38%
B 18%
C n/a
1,2-bis-(diphenylphosphino)ethane
1663-45-2

1,2-bis-(diphenylphosphino)ethane

nickel dichloride

nickel dichloride

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

Conditions
ConditionsYield
In not given
In N,N-dimethyl-formamide NiCl2 was reacted with dppe in DMF;
In ethanol in refluxing EtOHfor 15 min;
(DPPE)Ni(cycloocta-1,5-diene)
96055-24-2

(DPPE)Ni(cycloocta-1,5-diene)

dimethylamino sulfonyl chloride
13360-57-1

dimethylamino sulfonyl chloride

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

1,2-bis(diphenylphosphinoyl)ethane
4141-50-8

1,2-bis(diphenylphosphinoyl)ethane

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: oxalyl dichloride / dichloromethane / 1 h / 20 °C / Schlenk technique; Inert atmosphere; Sealed tube
2: hexachlorodisilane / dichloromethane-d2 / 0.08 h / 20 °C / Inert atmosphere; Schlenk technique; Glovebox
3: dichloromethane / 0.5 h / 20 °C / Inert atmosphere; Glovebox
View Scheme
C26H24Cl2P2(2+)*2Cl(1-)

C26H24Cl2P2(2+)*2Cl(1-)

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: hexachlorodisilane / dichloromethane-d2 / 0.08 h / 20 °C / Inert atmosphere; Schlenk technique; Glovebox
2: dichloromethane / 0.5 h / 20 °C / Inert atmosphere; Glovebox
View Scheme
methyllithium lithium bromide

methyllithium lithium bromide

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

(μ-PhPH)2Fe2(CO)6

(μ-PhPH)2Fe2(CO)6

{μ-(Ph2PCH2CH2PPh2)Ni(PhP)2}Fe2(CO)6

{μ-(Ph2PCH2CH2PPh2)Ni(PhP)2}Fe2(CO)6

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether; acetone (N2); to soln. of Fe- and LiMe/LiBr-complex in Et2O and THF added Ni complex at -78°C, then degassed acetone; mixt. was warmed up to room temp., after 1 h removed solvents in vac., leaving black solid.; chromy. (silicic acid/CH2Cl2); solvent removed, recrystn. from CH2Cl2/pentane; elem. anal.;99%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

C2H3N*2ClO4(1-)*C36H44N8Ni3S4(2+)

C2H3N*2ClO4(1-)*C36H44N8Ni3S4(2+)

2ClO4(1-)*2H2O*C44H46N4Ni2P2S2(2+)

2ClO4(1-)*2H2O*C44H46N4Ni2P2S2(2+)

Conditions
ConditionsYield
Stage #1: 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; C2H3N*2ClO4(1-)*C36H44N8Ni3S4(2+) In acetonitrile at 20℃; for 0.5h; Inert atmosphere;
Stage #2: With 1,2-bis-(diphenylphosphino)ethane In acetonitrile for 24h; Inert atmosphere;
Stage #3: With sodium perchlorate In acetonitrile for 1h; Inert atmosphere;
95%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

diethyl ether
60-29-7

diethyl ether

C32H32Br4N8Ni3S4(2+)*2ClO4(1-)*2.5H2O

C32H32Br4N8Ni3S4(2+)*2ClO4(1-)*2.5H2O

2ClO4(1-)*0.75C4H10O*C42H40Br2N4Ni2P2S2(2+)

2ClO4(1-)*0.75C4H10O*C42H40Br2N4Ni2P2S2(2+)

Conditions
ConditionsYield
Stage #1: 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; C32H32Br4N8Ni3S4(2+)*2ClO4(1-)*2.5H2O In acetonitrile at 20℃; for 0.5h; Inert atmosphere;
Stage #2: With 1,2-bis-(diphenylphosphino)ethane In acetonitrile for 24h; Inert atmosphere;
Stage #3: diethyl ether Further stages;
95%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

(μ-dithio)bis(tricarbonyliron)

(μ-dithio)bis(tricarbonyliron)

lithium triethylborohydride
22560-16-3

lithium triethylborohydride

{μ-(diphos)NiS2}Fe2(CO)6
116888-32-5

{μ-(diphos)NiS2}Fe2(CO)6

Conditions
ConditionsYield
In tetrahydrofuran; acetone under N2, to the stirred soln. of 2.91 mmol Fe compd. in THF cooled to -78°C was added LiEt3BH in THF in small portions, to this was added (diphos)NiCl2 and acetone, stirred for 6 h at -78°C, then warmed to room temp. over 1 h; solvent. evapd. in vac., chromy. (silicic acid-CH2Cl2), recrystd. from CH2Cl2;93%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

(μ-dithio)bis(tricarbonyliron)
14243-23-3

(μ-dithio)bis(tricarbonyliron)

{μ-(diphos)NiS2}Fe2(CO)6
116888-32-5

{μ-(diphos)NiS2}Fe2(CO)6

Conditions
ConditionsYield
With lithium triethylborohydride In tetrahydrofuran (N2); (a) 1-2 equiv of LiB(C2H5)3H/THF added slowly to Fe complex soln., (b) treated with Ni complex in THF/acetone;93%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

[Sn((CH2S5C3)2)(CH3)2]
470664-68-7

[Sn((CH2S5C3)2)(CH3)2]

[Ni(2-thioxo-1,3-dithiol-4,5-dithiolato)(bis(diphenylphosphino)ethane)]
96042-52-3

[Ni(2-thioxo-1,3-dithiol-4,5-dithiolato)(bis(diphenylphosphino)ethane)]

Conditions
ConditionsYield
In acetone byproducts: cyclo-[S(CS)S2C2SCH2CH2SC2S2(CS)S]; Ni complex added to suspn. of Sn complex in acetone, stirred for 12 h; solvent removed in vacuo, chromy. (silica, hexane/acetone (2/1));93%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

cadmium(II) diethyldithiocarbamate
14239-68-0

cadmium(II) diethyldithiocarbamate

dichloromethane
75-09-2

dichloromethane

(N,N-diethyldithiocarbamato)[1,2-bis(diphenylphosphino)ethane]nickel(II) tetrachlorocadmate*0.5(dichloromethane)

(N,N-diethyldithiocarbamato)[1,2-bis(diphenylphosphino)ethane]nickel(II) tetrachlorocadmate*0.5(dichloromethane)

Conditions
ConditionsYield
In acetonitrile refluxed for 1 h; filtered, evapd. to dryness (vac.), repptd. (dichloromethane/diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac.); elem. anal.;93%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

bis(N,N-diethyldithiocarbamato)zinc(II)
14324-55-1

bis(N,N-diethyldithiocarbamato)zinc(II)

(N,N-diethyldithiocarbamato)[1,2-bis(diphenylphosphino)ethane]nickel(II) tetrachlorozincate

(N,N-diethyldithiocarbamato)[1,2-bis(diphenylphosphino)ethane]nickel(II) tetrachlorozincate

Conditions
ConditionsYield
In acetonitrile refluxed for 1 h; filtered, evapd. to dryness (vac.), repptd. (dichloromethane/diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac.); elem. anal.;93%
pentachlorothiophenol
133-49-3

pentachlorothiophenol

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

C38H24Cl10NiP2S2

C38H24Cl10NiP2S2

Conditions
ConditionsYield
Stage #1: pentachlorothiophenol With methyllithium In tetrahydrofuran; diethyl ether at 0 - 20℃; Inert atmosphere; Schlenk technique;
Stage #2: 1,2-bis(diphenylphosphino)ethane nickel(II) chloride In tetrahydrofuran; diethyl ether for 2h; Inert atmosphere; Schlenk technique;
93%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

disodium maleonitriledithiolato

disodium maleonitriledithiolato

(bis(1,2-diphenylphosphino)ethane)(maleonitriledithiolato)nickel(II)
81097-96-3

(bis(1,2-diphenylphosphino)ethane)(maleonitriledithiolato)nickel(II)

Conditions
ConditionsYield
In acetone byproducts: NaCl; mixing equimolar amts. at 0°C, stirring and warming to room temp.(overnight); centrifugation, evapn. (vac.), chromy. (SiO2, CHCl3), crystn. on slow evapn.;92.4%
In acetone byproducts: NaCl; acetone was added to a mixture of solid complex and salt, stirred for 30 min; filtration, pptn. by slow addition of water, filtration, washin a ppt. with diethyl ether, recrystn. (dichloromethane/diethyl ether); elem. anal.;
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

silver diethyldithiocarbamate
38351-46-1

silver diethyldithiocarbamate

(N,N-diethyldithiocarbamato)[1,2-bis(diphenylphosphino)ethane]nickel(II) chloride

(N,N-diethyldithiocarbamato)[1,2-bis(diphenylphosphino)ethane]nickel(II) chloride

(N,N-diethyldithiocarbamato)[1,2-bis(diphenylphosphino)ethane]nickel(II) dichloroargenate

(N,N-diethyldithiocarbamato)[1,2-bis(diphenylphosphino)ethane]nickel(II) dichloroargenate

Conditions
ConditionsYield
In acetonitrile byproducts: AgCl; refluxed for 1 h; filtered (celite), evapd. to dryness (vac.), repptd. (dichloromethane/diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac.); elem.anal.;A n/a
B 92%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

thallium(I) bis(3-tert-butylmercaptoimidazolyl)dihydroborate

thallium(I) bis(3-tert-butylmercaptoimidazolyl)dihydroborate

[(1,2-bis(diphenylphosphino)ethane)Ni(.kappa(3)-S,S,H-bis(3-tert-butylmercaptoimidazolyl)dihydroborate)]Cl

[(1,2-bis(diphenylphosphino)ethane)Ni(.kappa(3)-S,S,H-bis(3-tert-butylmercaptoimidazolyl)dihydroborate)]Cl

Conditions
ConditionsYield
In dichloromethane byproducts: TlCl; 1 equiv. of Tl-compd. suspn. in CH2Cl2 was added to Ni-compd. soln. in CH2Cl2, stirring for 15 min; soln. was filtered, concd. in vac., pentane was added, solid was filtered off, dried in vac. for 3 h, elem. anal.;92%
hexamethylcyclotrisilathiane
3574-04-7

hexamethylcyclotrisilathiane

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

methyllithium
917-54-4

methyllithium

Ni(SSiMe3)2(1,2-diphenylphosphino)ethane)
379262-18-7

Ni(SSiMe3)2(1,2-diphenylphosphino)ethane)

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether under inert atm. soln. (Me2SiS)3 in Et2O was treated with soln. MeLi in Et2O, stirred at 0°C for 5 min, and added to suspn. NiCl2(dppe) in THF and stirred at 0°C for 10 min, THF was added and stirred at0°C for 15 min; soln. was evapd., residue was extd. with toluene and centrifuged, soln. was concd., hexane was added, ppt. was filtered and washed with hexane; elem. anal.;92%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

(CH3C5H4)2TiS4P2(C6H4OCH3)2
90432-13-6

(CH3C5H4)2TiS4P2(C6H4OCH3)2

A

dichlorobis(η5-methylcyclopentadienyl)titanium(IV)
1282-40-2

dichlorobis(η5-methylcyclopentadienyl)titanium(IV)

NiS3P(C6H4OCH3)(P(C6H5)2(CH2)2P(C6H5)2)
90413-02-8

NiS3P(C6H4OCH3)(P(C6H5)2(CH2)2P(C6H5)2)

Conditions
ConditionsYield
In tetrahydrofuran byproducts: (C6H4OCH3PS)3; The soln. of reagents in THF was stirred for 20 h (N2 atm.);; evapd., recrystd. by dilution of CH2Cl2 soln. with methanol; elem. anal.;;A n/a
B 91%
3-thiapentan-1,5-dithiol
3570-55-6

3-thiapentan-1,5-dithiol

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

[(η5-pentamethylcyclopentadienyl)iron(acetonitrile)3]PF6
86991-88-0

[(η5-pentamethylcyclopentadienyl)iron(acetonitrile)3]PF6

2Li(1+)*SCH2CH2SCH2CH2S(2-)=LiSCH2CH2SCH2CH2SLi

2Li(1+)*SCH2CH2SCH2CH2S(2-)=LiSCH2CH2SCH2CH2SLi

C40H47FeNiP2S3(1+)*F6P(1-)

C40H47FeNiP2S3(1+)*F6P(1-)

Conditions
ConditionsYield
Stage #1: 3-thiapentan-1,5-dithiol; 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; 2Li(1+)*SCH2CH2SCH2CH2S(2-)=LiSCH2CH2SCH2CH2SLi With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: [(η5-pentamethylcyclopentadienyl)iron(acetonitrile)3]PF6 In tetrahydrofuran; hexane Inert atmosphere; Schlenk technique;
90%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

3,5-dichlorothiophenol
17231-94-6

3,5-dichlorothiophenol

C38H30Cl4NiP2S2

C38H30Cl4NiP2S2

Conditions
ConditionsYield
Stage #1: 3,5-dichlorothiophenol With methyllithium In tetrahydrofuran; diethyl ether at 0 - 20℃; Inert atmosphere; Schlenk technique;
Stage #2: 1,2-bis(diphenylphosphino)ethane nickel(II) chloride In tetrahydrofuran; diethyl ether for 2h; Inert atmosphere; Schlenk technique;
90%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

tris(N,N-diethyldithiocarbamato)manganese(III)
15740-71-3

tris(N,N-diethyldithiocarbamato)manganese(III)

dichloromethane
75-09-2

dichloromethane

(N,N-diethyldithiocarbamato)[1,2-bis(diphenylphosphino)ethane]nickel(II) tetrachloromanganate(II)*dichloromethane

(N,N-diethyldithiocarbamato)[1,2-bis(diphenylphosphino)ethane]nickel(II) tetrachloromanganate(II)*dichloromethane

Conditions
ConditionsYield
In acetonitrile byproducts: tetraethylthiuram disulfide; refluxed for 1 h; filtered, evapd. to dryness (vac.), repptd. (dichloromethane/diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac.); elem. anal.;89%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

[NEt4][Fe(N(CH2CH2S)3)(NO)]

[NEt4][Fe(N(CH2CH2S)3)(NO)]

acetonitrile
75-05-8

acetonitrile

[(Fe(N(CH2CH2S)3)(NO)-S,S')NiCl(dppe)]*CH3CN

[(Fe(N(CH2CH2S)3)(NO)-S,S')NiCl(dppe)]*CH3CN

Conditions
ConditionsYield
In acetonitrile under N2 atm. to stirred suspn. (NiCl2(dppe)) in MeCN was added soln. (NEt4)(Fe(N(CH2CH2S)3)(NO)) in MeCN; after standing overnight, ppt. was filtered and dried; elem. anal.;88%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

C9H13NO2S3

C9H13NO2S3

Ni[(SCH2)2NTs](dppe)

Ni[(SCH2)2NTs](dppe)

Conditions
ConditionsYield
With sodium ethanolate In ethanol; dichloromethane for 3h;88%
carbon disulfide
75-15-0

carbon disulfide

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

(2-cyanophenyl)acetonitrile
3759-28-2

(2-cyanophenyl)acetonitrile

[Ni(1,2-bis(diphenylphosphino)ethane)(2-cyanobenzylcyanidedithiolate)]

[Ni(1,2-bis(diphenylphosphino)ethane)(2-cyanobenzylcyanidedithiolate)]

Conditions
ConditionsYield
Stage #1: (2-cyanophenyl)acetonitrile With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: carbon disulfide In tetrahydrofuran for 2h; Inert atmosphere;
Stage #3: 1,2-bis(diphenylphosphino)ethane nickel(II) chloride In tetrahydrofuran; dichloromethane at 20℃; for 24h; Inert atmosphere;
88%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

[(η5-pentamethylcyclopentadienyl)iron(acetonitrile)3]PF6
86991-88-0

[(η5-pentamethylcyclopentadienyl)iron(acetonitrile)3]PF6

(LiSCH2CH2)2O·2THF

(LiSCH2CH2)2O·2THF

bis(2-mercaptoethyl)ether
2150-02-9

bis(2-mercaptoethyl)ether

C40H47FeNiOP2S2(1+)*F6P(1-)

C40H47FeNiOP2S2(1+)*F6P(1-)

Conditions
ConditionsYield
Stage #1: 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; (LiSCH2CH2)2O·2THF; bis(2-mercaptoethyl)ether With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: [(η5-pentamethylcyclopentadienyl)iron(acetonitrile)3]PF6 In tetrahydrofuran; hexane Inert atmosphere; Schlenk technique;
88%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

sodium trimethylsilanethiolate
87495-22-5

sodium trimethylsilanethiolate

Ni(dppe)(SSiMe3)2
379262-18-7

Ni(dppe)(SSiMe3)2

Conditions
ConditionsYield
In tetrahydrofuran (N2); standard air-sensitive technique; NaSSiMe3 (2.2 equiv.) was added to stirred suspn. of Ni complex in THF; suspn. was stirred for 20 min; solvent removed (vac.); extd. (ether); filtered through Celite; hexane added; crystd. (-30°C); elem. anal.;87%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

2-mesityl isocyanide
57116-96-8

2-mesityl isocyanide

[Ni(1,2-bis(diphenylphosphino)ethane)(mesityl isocyanide)3](PF6)2

[Ni(1,2-bis(diphenylphosphino)ethane)(mesityl isocyanide)3](PF6)2

Conditions
ConditionsYield
In dichloromethane; acetone addn. of mixt. of 3 equiv. of isocyanide and excess NH4PF6 (in CH2Cl2/Me2CO=1:1) to Ni-complex soln. (in CH2Cl2/Me2CO=3:1), stirring for 2 h; solvent removal, extn. into CH2Cl2; elem. anal.;87%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

1,4,7-trithiacyclononane
6573-11-1

1,4,7-trithiacyclononane

A

{Ni((SC2H4)3)2}(2+)*2PF6(1-)={Ni((SC2H4)3)2}{PF6}2

{Ni((SC2H4)3)2}(2+)*2PF6(1-)={Ni((SC2H4)3)2}{PF6}2

{Ni(C6H5)2PCH2CH2P(C6H5)2((SC2H4)3)}(2+)*2PF6(1-)={Ni(C6H5)2PCH2CH2P(C6H5)2((SC2H4)3)}{PF6}2

{Ni(C6H5)2PCH2CH2P(C6H5)2((SC2H4)3)}(2+)*2PF6(1-)={Ni(C6H5)2PCH2CH2P(C6H5)2((SC2H4)3)}{PF6}2

Conditions
ConditionsYield
In methanol react. of Ni complex with cyclononane (1 molar equivalent) in refluxing methanol; addn. of NH4PF6, refluxing, pptn.; fractional recrystn. from CH3CN-diethyl ether (removal of (Ni((9)aneS3)2)(PF6)); elem. anal.;A n/a
B 86%
thallium(I) hexafluorophosphate

thallium(I) hexafluorophosphate

1,2-bis(diphenylphosphino)ethane nickel(II) chloride
14647-23-5

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

1,4,7-trithiacyclononane
6573-11-1

1,4,7-trithiacyclononane

{Ni(C6H5)2PCH2CH2P(C6H5)2((SC2H4)3)}(2+)*2PF6(1-)={Ni(C6H5)2PCH2CH2P(C6H5)2((SC2H4)3)}{PF6}2

{Ni(C6H5)2PCH2CH2P(C6H5)2((SC2H4)3)}(2+)*2PF6(1-)={Ni(C6H5)2PCH2CH2P(C6H5)2((SC2H4)3)}{PF6}2

Conditions
ConditionsYield
In nitromethane react. of Ni complex with cyclononane (1 molar equivalent) in nitromethane at 293K in the presence of TlPF6 (2 molar equivalents);; filtration; addn. of diethyl ether, crystn.; elem. anal.;86%

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