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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

4-nitrophenylsulfur pentafluoride

Cas:2613-27-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1-nitro-4-(pentafluorosulphanyl)benzene

Cas:2613-27-6

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Nitrophenylsulfurpentafluoride

Cas:2613-27-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can be

4-NITROPHENYLSULFUR PENTAFLUORIDE CAS:2613-27-6

Cas:2613-27-6

Min.Order:1 Kilogram

FOB Price: $30.0 / 40.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 2613-27-6 with best quality

Cas:2613-27-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Sulfur,pentafluoro(4-nitrophenyl)-, (OC-6-21)-

Cas:2613-27-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Sulfur,pentafluoro(4-nitrophenyl)-, (OC-6-21)-

Cas:2613-27-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

4-NITROPHENYLSULFUR PENTAFLUORIDE,2613-27-6

Cas:2613-27-6

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Sulfur,pentafluoro(4-nitrophenyl)-, (OC-6-21)-

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Sulfur,pentafluoro(4-nitrophenyl)-, (OC-6-21)-

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

4-NITROPHENYLSULFUR PENTAFLUORIDE,2613-27-6

Cas:2613-27-6

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-NITROPHENYLSULFUR PENTAFLUORIDE,2613-27-6

Cas:2613-27-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-NITROPHENYLSULFUR PENTAFLUORIDE

Cas:2613-27-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-NITROPHENYLSULFUR PENTAFLUORIDE,2613-27-6

Cas:2613-27-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2613-27-6 CAS NO.2613-27-6

Cas:2613-27-6

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

4-Nitrophenylsulfur pentafluoride

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

4-NITROPHENYLSULFUR PENTAFLUORIDE,2613-27-6

Cas:2613-27-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

4-Nitrophenylsulfur Pentafluoride

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4-Nitrophenylsulfur Pentafluoride

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages? High purity, all above 98.5%, no impurities after dissolution? We will test each batch to ensure quality? OEM and private brand services designed for free? Various cap colors available? We can also provide MT1 peptide powder2.

4-NITROPHENYLSULFUR PENTAFLUORIDE

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Sulfur,pentafluoro(4-nitrophenyl)-, (OC-6-21)-

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

4-NITROPHENYLSULFUR PENTAFLUORIDE,2613-27-6

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

4-NITROPHENYLSULFUR PENTAFLUORIDE,2613-27-6 Application:4-NITROPHENYLSULFUR PENTAFLUORIDE,2613-27-6

4-NITROPHENYLSULFUR PENTAFLUORIDE,2613-27-6

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Other

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as primary and sec

4-Nitrophenylsulfur pentafluoride

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

2613-27-6

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

4-Nitrobenzenesulphur pentafluoride

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

4-NITROPHENYLSULFUR PENTAFLUORIDE

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. is focused on customization, research and development and production of APIs and advanced intermediates, which can effectively compensate for the deficiencies of traditional CRO and CMO. Priority of high-tech barri

4-NITROPHENYLSULFUR PENTAFLUORIDE

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

2613-27-6 Application:intermediate

4-Nitrophenylsulfur Pentafluoride

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Newgreat Chemical Co., Ltd

Wuhan Xinweiye Chemical Co., Ltd. is mainly engaged in the process development and production of customized synthesis and pharmaceutical intermediates. We have professional researchers in organic synthesis, analytical chemistry and production process

4-NITROPHENYLSULFUR PENTAFLUORIDE,2613-27-6

Cas:2613-27-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

4-nitrophenyltetrafluoro-λ6-sulfanyl chloride

4-nitrophenyltetrafluoro-λ6-sulfanyl chloride

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

Conditions
ConditionsYield
With hydrogen fluoride; mercury(II) oxide at -30 - 20℃; Inert atmosphere; Sealed tube;81%
With iodine pentafluoride In neat (no solvent) at 65℃; for 14h; Glovebox; Inert atmosphere;75%
With silver carbonate at 70℃; Inert atmosphere; Glovebox;66%
With zinc(II) fluoride at 150℃; for 72h; Inert atmosphere;36%
With silver tetrafluoroborate In dichloromethane at 20℃; for 14h; Inert atmosphere;189.9 mg
di(p-nitrophenyl) disulfide
100-32-3

di(p-nitrophenyl) disulfide

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

Conditions
ConditionsYield
With potassium fluoride; bis(fluoroxy)methane at -20 - -15℃;63%
With silver(II) fluoride In various solvent(s) at 20 - 130℃;50%
With fluorine In acetonitrile at -5℃; for 1h; Inert atmosphere;45%
4-nitrophenylsulphur trifluoride
1526-28-9

4-nitrophenylsulphur trifluoride

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

Conditions
ConditionsYield
With fluorine In acetonitrile at 20℃;60%
With fluorine Ambient temperature;44%
With bis(fluoroxy)methane In acetonitrile at -20 - 20℃;
With fluorine; cesium fluoride In acetonitrile at -30 - -25℃;
With potassium fluoride; bis(fluoroxy)methane In acetonitrile at -15℃;
para-nitrobenzenethiol
1849-36-1

para-nitrobenzenethiol

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

Conditions
ConditionsYield
In acetonitrile28%
Multi-step reaction with 3 steps
1.1: sodium hydroxide / water / 0.5 h / Inert atmosphere
1.2: 14 h / 20 °C / Inert atmosphere
2.1: potassium fluoride; chlorine / acetonitrile / 20 °C / Inert atmosphere; Glovebox; Cooling with ice
3.1: iodine pentafluoride / neat (no solvent) / 14 h / 65 °C / Glovebox; Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1.1: sodium hydroxide / water / 0.5 h / Inert atmosphere
1.2: 12 h / 20 °C / Inert atmosphere
2.1: potassium fluoride; chlorine / acetonitrile / 20 °C / Inert atmosphere; Glovebox; Cooling with ice
3.1: silver carbonate / 70 °C / Inert atmosphere; Glovebox
View Scheme
4-nitrobenzenesulfenyl chloride
937-32-6

4-nitrobenzenesulfenyl chloride

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

Conditions
ConditionsYield
Stage #1: 4-nitrobenzenesulfenyl chloride With bis(fluoroxy)methane In acetonitrile at -20 - -15℃;
Stage #2: With cesium fluoride In acetonitrile
Stage #1: 4-nitrobenzenesulfenyl chloride With bis(fluoroxy)methane In acetonitrile at -20 - -15℃;
Stage #2: With fluorine; cesium fluoride In acetonitrile at -30 - -25℃;
Multi-step reaction with 2 steps
1: potassium fluoride; chlorine / acetonitrile / 5 - 11 °C
2: zinc(II) fluoride / 72 h / 150 °C / Inert atmosphere
View Scheme
di(p-nitrophenyl) disulfide
100-32-3

di(p-nitrophenyl) disulfide

A

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

B

4-nitrophenylsulphur trifluoride
1526-28-9

4-nitrophenylsulphur trifluoride

Conditions
ConditionsYield
With fluorine In acetonitrile at -35 - -25℃;
di(p-nitrophenyl) disulfide
100-32-3

di(p-nitrophenyl) disulfide

A

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

B

4-nitrobenzenesulfonyl fluoride
349-96-2

4-nitrobenzenesulfonyl fluoride

Conditions
ConditionsYield
With silver(II) fluoride; copper at 60 - 125℃; for 8h; Sealed tube;A 6.73 g
B n/a
4-Fluoronitrobenzene
350-46-9

4-Fluoronitrobenzene

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: sodium sulfide / N,N-dimethyl-formamide / 4 h / 20 °C / Inert atmosphere
2.1: sodium hydroxide / water / 0.5 h / Inert atmosphere
2.2: 12 h / 20 °C / Inert atmosphere
3.1: potassium fluoride; chlorine / acetonitrile / 20 °C / Inert atmosphere; Glovebox; Cooling with ice
4.1: silver carbonate / 70 °C / Inert atmosphere; Glovebox
View Scheme
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

4-(pentafluorosulfanyl)aniline
2993-24-0

4-(pentafluorosulfanyl)aniline

Conditions
ConditionsYield
With hydrogenchloride; iron In ethanol; water at 0 - 20℃; for 1h;100%
With hydrogen; nickel In ethanol99%
Stage #1: 1-nitro-4-(pentafluorosulfanyl)benzene With hydrogenchloride; tin(ll) chloride In water at 45 - 100℃; for 3.5h;
Stage #2: With sodium hydroxide In dichloromethane; water at 0℃;
99%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

benzyl alcohol
100-51-6

benzyl alcohol

(4-(benzyloxy)phenyl)pentafluoro-λ6-sulfane
1126968-88-4

(4-(benzyloxy)phenyl)pentafluoro-λ6-sulfane

Conditions
ConditionsYield
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 1h; Inert atmosphere;96%
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 1h;96%
meta-bromotoluene
591-17-3

meta-bromotoluene

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

3,3''-dimethyl-2'-nitro-[1,1':3',1''-terphenyl]-5'-yl sulfurpentafluoride

3,3''-dimethyl-2'-nitro-[1,1':3',1''-terphenyl]-5'-yl sulfurpentafluoride

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); 2,2-dimethylbutyric acid; potassium carbonate; tricyclohexylphosphine tetrafluoroborate In toluene at 130℃; for 15h; Schlenk technique; Inert atmosphere; Sealed tube;95%
3-methoxyphenyl bromide
2398-37-0

3-methoxyphenyl bromide

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

3,3''-dimethoxy-2'-nitro-[1,1':3',1''-terphenyl]-5'-yl sulfurpentafluoride

3,3''-dimethoxy-2'-nitro-[1,1':3',1''-terphenyl]-5'-yl sulfurpentafluoride

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); 2,2-dimethylbutyric acid; potassium carbonate; tricyclohexylphosphine tetrafluoroborate In toluene at 130℃; for 15h; Schlenk technique; Inert atmosphere; Sealed tube;92%
tert-Butyl chloroacetate
107-59-5

tert-Butyl chloroacetate

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

tert-butyl [2-nitro-5-(pentafluoro-λ6-sulfanyl)phenyl]acetate
1309569-24-1

tert-butyl [2-nitro-5-(pentafluoro-λ6-sulfanyl)phenyl]acetate

Conditions
ConditionsYield
With potassium tert-butylate In N,N-dimethyl-formamide at -30℃; for 0.166667h;91%
With potassium tert-butylate In N,N-dimethyl-formamide at -30℃; for 0.166667h; Vicarious Nucleophilic Substitution;80%
With potassium tert-butylate In N,N-dimethyl-formamide at -30℃; Inert atmosphere;38%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

2-nitro-5-(pentafluorosulfanyl)phenol
1329120-21-9

2-nitro-5-(pentafluorosulfanyl)phenol

Conditions
ConditionsYield
With Cumene hydroperoxide; potassium tert-butylate; methylamine In tetrahydrofuran at -78 - -50℃; for 0.5h;91%
With Cumene hydroperoxide; potassium tert-butylate; methylamine In tetrahydrofuran at -50℃; for 0.25h;90%
With Cumene hydroperoxide; potassium tert-butylate; ammonia In tetrahydrofuran at -50℃; for 0.25h;76%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

sodium methylate
124-41-4

sodium methylate

1-methoxy-4-(pentafluorosulfanyl)-benzene

1-methoxy-4-(pentafluorosulfanyl)-benzene

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; for 1h;87%
In N,N-dimethyl-formamide at 20℃; for 1h; Inert atmosphere;83%
In N,N-dimethyl-formamide at 20℃; for 1h;83%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

chloromethyl phenyl sulfone
7205-98-3

chloromethyl phenyl sulfone

pentafluoro(4-nitro-3-((phenylsulfonyl)methyl)phenyl)-λ6-sulfane
1309569-14-9

pentafluoro(4-nitro-3-((phenylsulfonyl)methyl)phenyl)-λ6-sulfane

Conditions
ConditionsYield
With potassium tert-butylate In N,N-dimethyl-formamide at -40℃; for 0.166667h; Vicarious Nucleophilic Substitution;87%
With potassium tert-butylate In N,N-dimethyl-formamide at -30℃; for 0.5h; Inert atmosphere;86%
With potassium tert-butylate In N,N-dimethyl-formamide at -30℃; for 0.5h;86%
With potassium tert-butylate In N,N-dimethyl-formamide at -40℃; for 0.5h;84%
With potassium tert-butylate In N,N-dimethyl-formamide at -40℃; for 0.5h;84%
bromobenzene
108-86-1

bromobenzene

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

A

2'-nitro-[1,1':3',1''-terphenyl]-5'-yl sulfurpentafluoride

2'-nitro-[1,1':3',1''-terphenyl]-5'-yl sulfurpentafluoride

B

6-nitro-[1,1'-biphenyl]-3-yl sulfurpentafluoride

6-nitro-[1,1'-biphenyl]-3-yl sulfurpentafluoride

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); 2,2-dimethylbutyric acid; potassium carbonate; tricyclohexylphosphine tetrafluoroborate In toluene at 130℃; for 15h; Reagent/catalyst; Temperature; Schlenk technique; Inert atmosphere; Sealed tube;A 87%
B 4%
With bis(η3-allyl-μ-chloropalladium(II)); 2,2-dimethylbutyric acid; caesium carbonate; tricyclohexylphosphine tetrafluoroborate In toluene at 130℃; for 12h; Reagent/catalyst; Temperature; Schlenk technique; Inert atmosphere; Sealed tube;A 18 %Spectr.
B 41 %Spectr.
Ethyl 4-bromobenzoate
5798-75-4

Ethyl 4-bromobenzoate

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

A

diethyl 5'-(pentafluorothio)-2'-nitro-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate

diethyl 5'-(pentafluorothio)-2'-nitro-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate

B

C15H12F5NO4S

C15H12F5NO4S

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); 2,2-dimethylbutyric acid; potassium carbonate; tricyclohexylphosphine tetrafluoroborate In toluene at 130℃; for 15h; Schlenk technique; Inert atmosphere; Sealed tube;A 86%
B 5%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

2-bromo-4-(pentafluoro-λ6-sulfanyl)aniline
159727-25-0

2-bromo-4-(pentafluoro-λ6-sulfanyl)aniline

Conditions
ConditionsYield
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In dichloromethane at 3 - 20℃; for 2h;85%
Multi-step reaction with 2 steps
1: 99 percent / H2 / Raney nickel / ethanol
2: NBS / acetonitrile / 0 °C
View Scheme
diethyl chloromethylphosphonate
3167-63-3

diethyl chloromethylphosphonate

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

diethyl 2-nitro-5-(pentafluorosulfanyl)benzylphosphonate
1309569-28-5

diethyl 2-nitro-5-(pentafluorosulfanyl)benzylphosphonate

Conditions
ConditionsYield
With potassium tert-butylate In N,N-dimethyl-formamide at -60℃; for 0.166667h;84%
With potassium tert-butylate In N,N-dimethyl-formamide at -60℃; for 0.5h; Vicarious Nucleophilic Substitution;77%
Stage #1: diethyl chloromethylphosphonate; 1-nitro-4-(pentafluorosulfanyl)benzene With potassium tert-butylate In N,N-dimethyl-formamide at -60℃; for 0.166667h;
Stage #2: With water Acidic conditions;
octanol
111-87-5

octanol

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

1-(n-octyloxy)-4-(pentafluorosulfanyl)benzene
1272542-14-9

1-(n-octyloxy)-4-(pentafluorosulfanyl)benzene

Conditions
ConditionsYield
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 0.3h; Inert atmosphere;83%
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 0.333333h;83%
dichloroacetic acid methyl ester
116-54-1

dichloroacetic acid methyl ester

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

C9H7ClF5NO4S
1309569-25-2

C9H7ClF5NO4S

Conditions
ConditionsYield
With potassium tert-butylate In N,N-dimethyl-formamide at -30℃; for 0.166667h;83%
4-biphenylacetonitrile
31603-77-7

4-biphenylacetonitrile

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

3-(biphenyl-4-yl)-5-(pentafluorosulfanyl)benzo[c]isoxazole
1440512-00-4

3-(biphenyl-4-yl)-5-(pentafluorosulfanyl)benzo[c]isoxazole

Conditions
ConditionsYield
With sodium hydroxide In ethanol at 20℃; for 1h;83%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

2-nitro-5-(pentafluorosulfanyl)aniline
1379803-65-2

2-nitro-5-(pentafluorosulfanyl)aniline

Conditions
ConditionsYield
With potassium tert-butylate; N,N,N-trimethylhydrazinium iodide In dimethyl sulfoxide at 20℃; for 0.0833333h;82%
With potassium tert-butylate; N,N,N-trimethylhydrazinium iodide In dimethyl sulfoxide82%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

4-Ethynylaniline
14235-81-5

4-Ethynylaniline

N-(4-ethynylphenyl)-2-nitro-5-(pentafluorosulfanyl)aniline

N-(4-ethynylphenyl)-2-nitro-5-(pentafluorosulfanyl)aniline

Conditions
ConditionsYield
Stage #1: 4-Ethynylaniline With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.0166667h; Inert atmosphere;
Stage #2: 1-nitro-4-(pentafluorosulfanyl)benzene In tetrahydrofuran; hexane at -120 - -110℃; for 0.166667h; Inert atmosphere;
Stage #3: With potassium permanganate; ammonia In tetrahydrofuran; hexane at -110℃; for 0.0833333h; Inert atmosphere;
78%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

chloroacetic acid ethyl ester
105-39-5

chloroacetic acid ethyl ester

C10H10F5NO4S
1309569-23-0

C10H10F5NO4S

Conditions
ConditionsYield
With potassium tert-butylate In N,N-dimethyl-formamide at -30℃; for 0.166667h;76%
With potassium tert-butylate In N,N-dimethyl-formamide at -30℃; for 0.166667h;76%
chloroform
67-66-3

chloroform

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

2-(dichloromethyl)-1-nitro-4-(pentafluorosulfanyl)benzene
1309569-30-9

2-(dichloromethyl)-1-nitro-4-(pentafluorosulfanyl)benzene

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran; chloroform; N,N-dimethyl-formamide at -78℃; for 0.5h; Inert atmosphere;75%
With potassium tert-butylate In tetrahydrofuran; N,N-dimethyl-formamide at -70℃; for 0.0333333h;74%
2-bromonaphthalene
580-13-2

2-bromonaphthalene

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

A

diethyl 5'-(pentafluorothio)-2'-nitro-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate

diethyl 5'-(pentafluorothio)-2'-nitro-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate

B

C16H10F5NO2S

C16H10F5NO2S

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); 2,2-dimethylbutyric acid; potassium carbonate; tricyclohexylphosphine tetrafluoroborate In toluene at 130℃; for 15h; Schlenk technique; Inert atmosphere; Sealed tube;A 75%
B 17%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

sodium ethanolate
141-52-6

sodium ethanolate

1-ethoxy-4-(pentafluorosulfanyl)benzene
1272542-12-7

1-ethoxy-4-(pentafluorosulfanyl)benzene

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; for 1h; Inert atmosphere;74%
In N,N-dimethyl-formamide at 20℃; for 1h;74%
Bromoform
75-25-2

Bromoform

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

C7H4Br2F5NO2S
1309569-31-0

C7H4Br2F5NO2S

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran; N,N-dimethyl-formamide at -70℃; for 0.0333333h;74%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

phenoxyacetonitrile
3598-14-9

phenoxyacetonitrile

2-(2-nitro-5-(pentafluorosulfanyl)phenyl)acetonitrile
1309569-29-6

2-(2-nitro-5-(pentafluorosulfanyl)phenyl)acetonitrile

Conditions
ConditionsYield
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 0.166667h;74%
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 0.166667h;74%
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 0.5h; Vicarious Nucleophilic Substitution;41%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

aniline
62-53-3

aniline

2-nitro-5-(pentafluorosulfanyl)-N-phenylaniline

2-nitro-5-(pentafluorosulfanyl)-N-phenylaniline

Conditions
ConditionsYield
Stage #1: aniline With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.0166667h; Inert atmosphere;
Stage #2: 1-nitro-4-(pentafluorosulfanyl)benzene In tetrahydrofuran; hexane at -120 - -110℃; for 0.166667h; Inert atmosphere;
Stage #3: With potassium permanganate; ammonia In tetrahydrofuran; hexane at -110℃; for 0.0833333h; Reagent/catalyst; Temperature; Solvent; Inert atmosphere;
73%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

p-toluidine
106-49-0

p-toluidine

2-nitro-5-(pentafluorosulfanyl)-N-p-tolylaniline

2-nitro-5-(pentafluorosulfanyl)-N-p-tolylaniline

Conditions
ConditionsYield
Stage #1: p-toluidine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.0166667h; Inert atmosphere;
Stage #2: 1-nitro-4-(pentafluorosulfanyl)benzene In tetrahydrofuran; hexane at -120 - -110℃; for 0.166667h; Inert atmosphere;
Stage #3: With potassium permanganate; ammonia In tetrahydrofuran; hexane at -110℃; for 0.0833333h; Inert atmosphere;
73%
1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

4-chloro-aniline
106-47-8

4-chloro-aniline

N-(4-chlorophenyl)-2-nitro-5-(pentafluorosulfanyl)aniline

N-(4-chlorophenyl)-2-nitro-5-(pentafluorosulfanyl)aniline

Conditions
ConditionsYield
Stage #1: 4-chloro-aniline With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.0166667h; Inert atmosphere;
Stage #2: 1-nitro-4-(pentafluorosulfanyl)benzene In tetrahydrofuran; hexane at -120 - -110℃; for 0.166667h; Inert atmosphere;
Stage #3: With potassium permanganate; ammonia In tetrahydrofuran; hexane at -110℃; for 0.0833333h; Inert atmosphere;
72%
propan-1-ol
71-23-8

propan-1-ol

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

1-(n-propoxy)-4-(pentafluorosulfanyl)benzene
1272542-13-8

1-(n-propoxy)-4-(pentafluorosulfanyl)benzene

Conditions
ConditionsYield
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 0.5h; Inert atmosphere;71%
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 0.5h;71%
para-bromotoluene
106-38-7

para-bromotoluene

1-nitro-4-(pentafluorosulfanyl)benzene
2613-27-6

1-nitro-4-(pentafluorosulfanyl)benzene

4,4''-dimethyl-2'-nitro-[1,1':3',1''-terphenyl]-5'-yl sulfurpentafluoride

4,4''-dimethyl-2'-nitro-[1,1':3',1''-terphenyl]-5'-yl sulfurpentafluoride

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); 2,2-dimethylbutyric acid; potassium carbonate; tricyclohexylphosphine tetrafluoroborate In toluene at 130℃; for 15h; Schlenk technique; Inert atmosphere; Sealed tube;71%

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