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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-(Methylthio)benzyl alcohol supplier in China

Cas:3446-90-0

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards. 2. Now we have established long-term stab

High quality P-Methylthiobenzyl Alcohol for hot sale/TAA Chemical

Cas:3446-90-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine c

4-(Methylthio)benzyl alcohol

Cas:3446-90-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-(Methylmercapto)-benzyl alcohol

Cas:3446-90-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Henan Tianfu Chemical Co., Ltd. is located in Zhengzhou High-tech Development Zone with import and export license. We passed ISO 9001:2008 in 2009, and won "High-tech Enterprise" by provincial government in 2013.The objective of the com

TIANFU-CHEM - 4-(Methylthio)benzyl alcohol

Cas:3446-90-0

Min.Order:1 Gram

FOB Price: $1000.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 3446-90-0 with best price

Cas:3446-90-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

4-(Methylthio)benzyl Alcohol 3446-90-0

Cas:3446-90-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

4-(Methylthio)benzyl alcohol CAS:3446-90-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organ

4-(Methylthio)benzyl alcohol CAS:3446-90-0

Cas:3446-90-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

4-(Methylthio)benzyl Alcohol

Cas:3446-90-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

4-Methylthiobenzyl alcohol 3446-90-0

Cas:3446-90-0

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

4-(Methylthio)benzyl Alcohol

Cas:3446-90-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Methylthio benzyl alcohol

Cas:3446-90-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply p-Methylthiobenzyl alcohol

Cas:3446-90-0

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-(Methylthio)benzyl alcohol

Cas:3446-90-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 4-(Methylthio)benzyl alcohol

Cas:3446-90-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

4-Methylthio benzyl alcohol

Cas:3446-90-0

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-Methylthio benzyl alcohol

Cas:3446-90-0

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-(Methylthio)benzyl Alcohol

Cas:3446-90-0

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-Methylthio benzyl alcohol

Cas:3446-90-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

4-Methylthio benzyl alcohol

Cas:3446-90-0

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

4-Methylthio benzyl alcohol

Cas:3446-90-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

4-Methylthio benzyl alcohol

Cas:3446-90-0

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

4-METHYLTHIO BENZYL ALCOHOL cas no. 3446-90-0 98%

Cas:3446-90-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

4-Methylthio benzyl alcohol

Cas:3446-90-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

p-Methylthiobenzyl alcohol

Cas:3446-90-0

Min.Order:0

Negotiable

Type:Other

inquiry

DB BIOTECH CO., LTD

Q1: Are you a manufacturer Answer: Yes, we are factory founded on 2012.Q2: How to contact with us Click "contact supplier" And then send us message the product you interest in, you will get reply within 12 hours.Q3:Which kind of payment terms do you

4-(Methylthio)benzyl alcohol

Cas:3446-90-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4-(Methylthio)benzyl Alcohol

Cas:3446-90-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

4-(Methylthio)benzyl alcohol

Cas:3446-90-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

4-(Methylthio)benzyl Alcohol

Cas:3446-90-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Fandachem Co.,Ltd

FandaChem , a China-based chemical company, specialize in exporting 4-(Methylthio)benzyl alcohol cas 3446-90-0 (Fandachem), Please contact us by email freely. Appearance:white crystalline powder Storage:Store in dry, dark and v

4-(Methylthio)benzyl alcohol cas 3446-90-0 (Fandachem)

Cas:3446-90-0

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Synthetic route

4-(Methylthio)benzaldehyde
3446-89-7

4-(Methylthio)benzaldehyde

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

Conditions
ConditionsYield
With hydrogen; phosphotungstic acid 44-hydrate; [Fe(C5H4P(i-Pr)2)2Rh(C8H12)]BF4 In water; isopropyl alcohol at 20℃; under 5171.62 Torr; for 16h;100%
With isopropyl alcohol; hydrotalcite at 81.84℃; for 3h; Kinetics; Further Variations:; Temperatures; Reagents;100%
Stage #1: 4-(Methylthio)benzaldehyde With chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II); phenylsilane at 80℃; for 0.666667h;
Stage #2: With tetrabutyl ammonium fluoride at 20℃; for 0.5h; Reagent/catalyst; Temperature; Time; Solvent; chemoselective reaction;
98%
4-(methylthio)benzyl acetate
102606-93-9

4-(methylthio)benzyl acetate

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

Conditions
ConditionsYield
With zirconocene dichloride; diisobutylaluminium hydride In tetrahydrofuran at -20℃; Inert atmosphere; regioselective reaction;99%
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; for 4h; Inert atmosphere;90.89%
With lithium aluminium tetrahydride; diethyl ether
With diborane In tetrahydrofuran at 0℃; for 1.5h;
p-cyanophenyl methyl sulfide
21382-98-9

p-cyanophenyl methyl sulfide

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

Conditions
ConditionsYield
With (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); water; hydrogen In 1,4-dioxane at 140℃; under 7500.75 Torr; for 69h; Autoclave;89%
methyl 4-(methylthio)benzoate
3795-79-7

methyl 4-(methylthio)benzoate

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

Conditions
ConditionsYield
With HN(CH2CH2C3H3N2Mes)2Cl2; potassium tert-butylate; hydrogen; cobalt(II) chloride In tetrahydrofuran at 100℃; under 45004.5 Torr; for 16h; Autoclave; Glovebox;85%
With lithium aluminium tetrahydride
isopropyl alcohol
67-63-0

isopropyl alcohol

4-(methylthio)-benzyl-methoxymethyl ether

4-(methylthio)-benzyl-methoxymethyl ether

A

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

B

1-isopropoxymethyl-4-methylsulfanyl-benzene

1-isopropoxymethyl-4-methylsulfanyl-benzene

Conditions
ConditionsYield
With carbon tetrabromide for 3h; Heating;A 85%
B 14%
isopropyl alcohol
67-63-0

isopropyl alcohol

4-(methylthio)-benzyl-methoxyethoxymethyl ether

4-(methylthio)-benzyl-methoxyethoxymethyl ether

A

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

B

1-isopropoxymethyl-4-methylsulfanyl-benzene

1-isopropoxymethyl-4-methylsulfanyl-benzene

Conditions
ConditionsYield
With carbon tetrabromide for 3h; Heating;A 85%
B 11%
4-(methylthio)benzyl β-(trimethylsilyl)ethoxymethyl ether

4-(methylthio)benzyl β-(trimethylsilyl)ethoxymethyl ether

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

Conditions
ConditionsYield
With carbon tetrabromide In isopropyl alcohol for 1.5h; Heating;85%
4-(methylthio)benzyl bromide
38185-19-2

4-(methylthio)benzyl bromide

A

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

B

1-bromomethyl-4-methanesulfinylbenzene
51927-46-9

1-bromomethyl-4-methanesulfinylbenzene

C

4-(Methylthio)benzaldehyde
3446-89-7

4-(Methylthio)benzaldehyde

Conditions
ConditionsYield
With dihydrogen peroxide at 70℃; for 1h;A n/a
B 52%
C n/a
4-(Methylthio)benzaldehyde
3446-89-7

4-(Methylthio)benzaldehyde

4-n-methylphenylacetylene
766-97-2

4-n-methylphenylacetylene

A

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

B

1-(4-(methylthio)phenyl)-3-(p-tolyl)prop-2-yn-1-one

1-(4-(methylthio)phenyl)-3-(p-tolyl)prop-2-yn-1-one

Conditions
ConditionsYield
With triethylamine; zinc(II) iodide In toluene at 80℃; for 12h; Schlenk technique; Inert atmosphere;A n/a
B 50%
4-(Methylthio)benzaldehyde
3446-89-7

4-(Methylthio)benzaldehyde

A

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

B

benzyl alcohol
100-51-6

benzyl alcohol

Conditions
ConditionsYield
With sodium tetrahydroborate; nickel dichloride In methanol for 18h; Ambient temperature;
C8H10OS*C5H5N*Br3H

C8H10OS*C5H5N*Br3H

A

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

B

pyridinium hydrobromide perbromide
39416-48-3

pyridinium hydrobromide perbromide

Conditions
ConditionsYield
In acetic acid at 19.9℃; Equilibrium constant; Thermodynamic data; ΔH, ΔS, ΔG, var. temp.;
(4-methylthiophenyl)methanol radical cation

(4-methylthiophenyl)methanol radical cation

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

Conditions
ConditionsYield
With bromide; dinitrogen monoxide In phosphate buffer pH=7; Equilibrium constant;
(4-methylthiophenyl)methanol radical anion

(4-methylthiophenyl)methanol radical anion

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

Conditions
ConditionsYield
With carbon dioxide; nitrogen In phosphate buffer pH=7; Equilibrium constant; Radiolysis;
With Paraquat In phosphate buffer Kinetics; Further Variations:; Reagents;
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

4-(methylthio)benzyl bromide
38185-19-2

4-(methylthio)benzyl bromide

Conditions
ConditionsYield
With carbon tetrabromide; triphenylphosphine In dichloromethane at 0 - 20℃;100%
With trimethylsilyl bromide In chloroform at 0℃; for 1h;99%
With phosphorus tribromide In diethyl ether at 20℃; Inert atmosphere; Schlenk technique;98%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

(4-(methylsulfinyl)phenyl)methanol
93183-64-3, 106732-70-1

(4-(methylsulfinyl)phenyl)methanol

Conditions
ConditionsYield
With tert.-butylhydroperoxide at 20℃; for 20h;100%
With {(Yb(PDCH2)2(PDCH))*Na(H2O)2(Na(PDCH)(H2O)2)}2[P2W18O62]*14H2O; dihydrogen peroxide In water at 85℃; for 0.833333h; Green chemistry;100%
With dichlorodioxobis(triphenylphosphineoxide)molybdenum(VI); tetrabutylammonium nitrate; copper(II) nitrate In acetonitrile at 60℃; for 10h; chemoselective reaction;99%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

4-(Methylthio)benzaldehyde
3446-89-7

4-(Methylthio)benzaldehyde

Conditions
ConditionsYield
With cobalt(II) nitrate hexahydrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; manganese (II) nitrate tetrahydrate; oxygen; acetic acid at 40℃; under 760.051 Torr; for 0.75h;100%
With N,N,N',N'-tetramethylguanidine In dichloromethane at 20℃; for 1h;99%
With hydrogenchloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium nitrite In dichloromethane; water at 20℃; under 760.051 Torr; for 11h; in air;99%
dimethylsulfide
75-18-3

dimethylsulfide

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

trifluoroacetic acid
76-05-1

trifluoroacetic acid

dimethylsulfonium trifluoroacetate
112481-55-7

dimethylsulfonium trifluoroacetate

Conditions
ConditionsYield
for 0.0833333h;100%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
Stage #1: 4-(methylthio)benzyl alcohol With triphenylphosphine dibromide 1:1 addition complex In acetonitrile at 0℃; for 0.166667h; Bromination;
Stage #2: With aluminum oxide; Oxone In chloroform for 2h; Hydrolysis; Heating;
100%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

p-methylsulfonylbenzyl alcohol
22821-77-8

p-methylsulfonylbenzyl alcohol

Conditions
ConditionsYield
With dihydrogen peroxide In acetonitrile at 40℃; for 0.333333h;99%
With 5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride; dihydrogen peroxide In ethanol at 20℃; for 0.25h;95%
With dihydrogen peroxide; molybdenium(VI) dioxodichloride In acetonitrile at 20℃; for 0.5h;93%
trimethylsilylazide
4648-54-8

trimethylsilylazide

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

4'-methylthio-1-trimethylsilyloxytoluene

4'-methylthio-1-trimethylsilyloxytoluene

Conditions
ConditionsYield
tetrabutylammomium bromide at 30℃; for 0.00333333h;99%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

4'-methylthio-1-trimethylsilyloxytoluene

4'-methylthio-1-trimethylsilyloxytoluene

Conditions
ConditionsYield
With Nafion SAC-13 at 20℃; for 0.0666667h;98%
In nitromethane at 20℃; for 0.166667h;97%
Isopropenyl acetate
108-22-5

Isopropenyl acetate

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

4-(methylthio)benzyl acetate
102606-93-9

4-(methylthio)benzyl acetate

Conditions
ConditionsYield
With platinum; 1-butyl-3-methylimidazolium Tetrafluoroborate at 20 - 60℃; for 2h; Inert atmosphere; Electrochemical reaction; Green chemistry;98%
With tetraethylammonium bicarbonate at 60℃; for 2h;98%
With 1,3-bis(2,4,6-trimethylphenyl)imidazole hydrochloride; potassium tert-butylate In benzene at 80℃; for 10h; Inert atmosphere;92%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

ethyl acetate
141-78-6

ethyl acetate

4-(methylthio)benzyl acetate
102606-93-9

4-(methylthio)benzyl acetate

Conditions
ConditionsYield
With platinum; 1-butyl-3-methylimidazolium Tetrafluoroborate at 20 - 60℃; for 2h; Inert atmosphere; Electrochemical reaction; Green chemistry;98%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

p-toluenesulfonamide
70-55-3

p-toluenesulfonamide

N-(4-methylthiobenzyl)-4-methylbenzenesulfonamide
1023247-22-4

N-(4-methylthiobenzyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With potassium carbonate at 120℃; for 15h;98%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

4-(methylthio)benzyl formate

4-(methylthio)benzyl formate

Conditions
ConditionsYield
With fluorosulfonyl fluoride; caesium carbonate at 20℃; for 12h; Sealed tube;98%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

1-(chloromethyl)-4-methylthiobenzene
874-87-3

1-(chloromethyl)-4-methylthiobenzene

Conditions
ConditionsYield
With thionyl chloride In toluene at 20℃; for 0.5h;97%
With thionyl chloride In tetrahydrofuran at 20℃; for 48h;95%
With thionyl chloride In toluene at 80℃; for 2h;93%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

Diethyl carbonate
105-58-8

Diethyl carbonate

carbonic acid ethyl ester 4-methylsulfanyl-benzyl ester

carbonic acid ethyl ester 4-methylsulfanyl-benzyl ester

Conditions
ConditionsYield
With MgLa mixed oxide at 125℃; for 5h;97%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

trityl chloride
76-83-5

trityl chloride

1-(methylsulfanyl)-4-[(trityloxy)methyl]benzene
1198081-80-9

1-(methylsulfanyl)-4-[(trityloxy)methyl]benzene

Conditions
ConditionsYield
With iron(III) chloride; 1-(n-butyl)-3-methylimidazolium triflate at 20℃; for 2h; Ionic liquid;97%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

p-methylsulfinylbenzaldehyde
37794-15-3

p-methylsulfinylbenzaldehyde

Conditions
ConditionsYield
With iodic acid In N,N-dimethyl-formamide at 60℃; for 2h; Inert atmosphere;96%
With chromium(VI) oxide; sulfuric acid at 20℃; for 1h;90%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

toluene-4-sulfonamide
70-55-3

toluene-4-sulfonamide

N-(4-(methylthio)benzyl)-4-methylbenzenesulfonamide
1023247-22-4

N-(4-(methylthio)benzyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With potassium carbonate; iron(II) chloride at 135℃; for 20h; Inert atmosphere;96%
With air; copper diacetate; potassium carbonate at 150℃; for 12h;95%
With potassium carbonate at 160℃; for 12h;95%
With copper diacetate; potassium carbonate at 150℃; for 12h;92%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

aniline
62-53-3

aniline

N-((4-methylthio)benzyl)benzenamine
723753-86-4

N-((4-methylthio)benzyl)benzenamine

Conditions
ConditionsYield
With 1,10-Phenanthroline; tungsten hexacarbonyl; potassium tert-butylate In 1,4-dioxane at 130℃; for 24h;96%
With xanth-9-one; potassium hydroxide In toluene at 150℃; for 8h; Inert atmosphere;95%
With potassium tert-butylate; C22H34Cl3CrF3N5P2 In 1,4-dioxane at 150℃; for 18h; Inert atmosphere; Sealed tube;93%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

3,4-dihydronaphthalene-1(2H)-one
529-34-0

3,4-dihydronaphthalene-1(2H)-one

(E)-2-(4-(methylthio)benzylidene)-3,4-dihydronaphthalen-1(2H)-one

(E)-2-(4-(methylthio)benzylidene)-3,4-dihydronaphthalen-1(2H)-one

Conditions
ConditionsYield
With (4-Me)Triaz(NHPiPr2)2Mn(CO)2Br; caesium carbonate In tert-Amyl alcohol at 135℃; Schlenk technique; Inert atmosphere;96%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

2-(Methylthio)aniline
2987-53-3

2-(Methylthio)aniline

C15H17NS2

C15H17NS2

Conditions
ConditionsYield
With 1,10-Phenanthroline; tungsten hexacarbonyl; potassium tert-butylate In 1,4-dioxane at 130℃; for 24h;96%
di(succinimido) carbonate
74124-79-1

di(succinimido) carbonate

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

4-methylthiobenzyl succinimidyl carbonate
127092-18-6

4-methylthiobenzyl succinimidyl carbonate

Conditions
ConditionsYield
With triethylamine In acetonitrile for 1h; Ambient temperature;95%
With triethylamine In tetrahydrofuran; acetonitrile
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

4-(methylthio)benzamide
90005-49-5

4-(methylthio)benzamide

Conditions
ConditionsYield
With tert.-butylhydroperoxide; ammonia; oxygen In water; N,N-dimethyl-formamide at 80℃; under 1520.1 Torr; for 5h; Green chemistry;95%
With Rh(trop2N)(PPh3); ammonia; methacrylic acid methyl ester In tetrahydrofuran at -20 - 25℃; for 4h; chemoselective reaction;92%
With tert.-butylhydroperoxide; ammonium hydroxide In water at 100℃; for 16h;83%
Multi-step reaction with 2 steps
1: 98 percent / 1 M aq. NaOH, (CTA)2SO4, aq. TBHP / 20 h / 20 °C
2: 100 percent / 1 M aq. NaOH, (CTA)2SO4, aq. TBHP / 2 h / 50 °C
View Scheme
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

tert-butyl(dimethyl){[4-(methylthio)benzyl]oxy}silane
1027730-39-7

tert-butyl(dimethyl){[4-(methylthio)benzyl]oxy}silane

Conditions
ConditionsYield
Stage #1: tert-butyldimethylsilyl chloride With 1H-imidazole In N,N-dimethyl-formamide for 0.333333h;
Stage #2: 4-(methylthio)benzyl alcohol In N,N-dimethyl-formamide
95%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With diethylene glycol dimethyl ether at 70℃; for 0.5h; Sonication;95%
With [Rh(1,3,4,5-tetramethylimidazole-2-ylidene)(trop2NH)][trifluoromethanesulfonate]; potassium tert-butylate; dinitrogen monoxide In tetrahydrofuran; toluene at 50℃; under 750.075 Torr; Schlenk technique;90%
With oxygen at 120℃; for 11h; Green chemistry;87%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

acetophenone
98-86-2

acetophenone

3-(4-(methylthio)phenyl)-1-phenylpropan-1-one

3-(4-(methylthio)phenyl)-1-phenylpropan-1-one

Conditions
ConditionsYield
With potassium carbonate at 135℃; for 12h;95%
With iron(III) oxide; potassium tert-butylate In toluene at 135℃; for 24h; Inert atmosphere; Sealed tube;82%
methanol
67-56-1

methanol

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

methyl 4-(methylthio)benzoate
3795-79-7

methyl 4-(methylthio)benzoate

Conditions
ConditionsYield
With Rh(trop2N)(PPh3); methacrylic acid methyl ester In tetrahydrofuran at -30 - 25℃; for 4h; chemoselective reaction;94%
With palladium 10% on activated carbon; oxygen; sodium carbonate at 120℃; under 15001.5 Torr; for 1.5h; Microwave irradiation; Green chemistry;85%
With bismuth(lll) trifluoromethanesulfonate; dichloro bis(acetonitrile) palladium(II); oxygen; potassium carbonate at 60℃; for 3h; Schlenk technique;72%
With oxygen; potassium carbonate at 60℃; under 750.075 Torr; for 24h; Schlenk technique; Green chemistry;94 %Chromat.
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

aniline
62-53-3

aniline

(4-methylsulfanylbenzylidene)phenylamine
22116-67-2

(4-methylsulfanylbenzylidene)phenylamine

Conditions
ConditionsYield
With 9-azabicyclo<3.3.1>nonane-N-oxyl; oxygen; potassium hydroxide In toluene at 80℃; for 5h; Sealed tube;94%
With 9-azabicyclo<3.3.1>nonane-N-oxyl; potassium hydroxide In toluene at 80℃; for 5h; Catalytic behavior; Sealed tube; Green chemistry;94%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

2-amino-phenol
95-55-6

2-amino-phenol

2‐(4‐(methylthio)phenyl)benzo[d]oxazole
1357378-64-3

2‐(4‐(methylthio)phenyl)benzo[d]oxazole

Conditions
ConditionsYield
Stage #1: 4-(methylthio)benzyl alcohol With oxygen at 106℃; under 3800.26 Torr; for 0.216667h; Flow reactor; Green chemistry;
Stage #2: 2-amino-phenol at 106℃; Flow reactor; Green chemistry;
Stage #3: at 106℃; for 0.666667h; Flow reactor; Green chemistry;
94%
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