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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

4-(Methylthio)benzoic acid

Cas:13205-48-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price in China. If you are looking for the product’s supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product specifica

4-(Methylthio)benzoic acid

Cas:13205-48-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-(Methylthio)-benzoic acid

Cas:13205-48-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--13205-48-6--4-(METHYLTHIO)BENZOIC ACID in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business

TIANFUCHEM--13205-48-6--4-(METHYLTHIO)BENZOIC ACID in stock

Cas:13205-48-6

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 13205-48-6 with best quality

Cas:13205-48-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoic acid,4-(methylthio)- 13205-48-6

Cas:13205-48-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzoic acid,4-(methylthio)-

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

4-(methylthio)benzoic acid CAS NO.13205-48-6

Cas:13205-48-6

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-(Methylthio)benzoic Acid

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

4-Methylthio benzoic acid

Cas:13205-48-6

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Methylthio benzoic acid

Cas:13205-48-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Pyridinecarboxylicacid, 3-methoxy-, methyl ester

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-(METHYLTHIO)BENZOIC ACID

Cas:13205-48-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply 4-(methylthio)benzoic acid

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Other

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-Methylthio benzoic acid

Cas:13205-48-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-Methylthio benzoic acid

Cas:13205-48-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

4-(methylthio)benzoic acid CAS NO.13205-48-6 CAS NO.13205-48-6

Cas:13205-48-6

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

4-Methylthio benzoic acid

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

4-Methylthio benzoic acid

Cas:13205-48-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

4-METHYLTHIO BENZOIC ACID cas no. 13205-48-6 98%

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

4-(methylthio)benzoic acid

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

4-(Methylthio)benzoic acid

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 4-(Methylthio)Benzoic Acid 5g

Cas:13205-48-6

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4-(METHYLTHIO)BENZOIC ACID

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

4-(Methylthio)Benzoic Acid

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Fandachem Co.,Ltd

FandaChem , a China-based chemical company, specialize in exporting 4-(Methylthio)benzoic acid cas 13205-48-6 (Fandachem), Please contact us by email freely. Appearance:white crystalline powder Storage:Store in dry, dark an

4-(Methylthio)benzoic acid cas 13205-48-6 (Fandachem)

Cas:13205-48-6

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

4-(Methylthio)benzoic acid

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:light yellow to beige crystalline powder Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

4-(methylthio)benzoic acid

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

4-(METHYLTHIO)BENZOIC ACID

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Prompt reaction, good quality and best service make us reliable and outstanding in this industry.Appearance:Light yellow to beige cryst

4-Methylthio benzoic acid manufacture

Cas:13205-48-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

4-(Methylthio)benzaldehyde
3446-89-7

4-(Methylthio)benzaldehyde

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; sodium hydroxide; (CTA)2SO4 at 20℃; for 20h;98%
With sodium hydroxide In water at 20 - 75℃; for 20h;85%
With perchloric acid; mercury(II) diacetate; N-bromoacetamide In acetic acid at 24.9℃; Kinetics; Mechanism; Thermodynamic data; other temperatures, ΔG(excit.), ΔH(excit.), ΔS(excit.);
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With diethylene glycol dimethyl ether at 70℃; for 0.5h; Sonication;95%
With [Rh(1,3,4,5-tetramethylimidazole-2-ylidene)(trop2NH)][trifluoromethanesulfonate]; potassium tert-butylate; dinitrogen monoxide In tetrahydrofuran; toluene at 50℃; under 750.075 Torr; Schlenk technique;90%
With oxygen at 120℃; for 11h; Green chemistry;87%
4-iodothioanisole
35371-03-0

4-iodothioanisole

diphenylmethylsilanecarboxylic acid
18414-58-9

diphenylmethylsilanecarboxylic acid

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With potassium trimethylsilonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; bis(dibenzylideneacetone)-palladium(0) In toluene at 40℃; for 0.333333h;95%
1-(Bis-tert-butylperoxy-methyl)-4-methylsulfanyl-benzene
106914-57-2

1-(Bis-tert-butylperoxy-methyl)-4-methylsulfanyl-benzene

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With copper(II) sulfate; ascorbic acid In tetrahydrofuran; water for 8h; Ambient temperature;88%
methyl 4-(methylsulfanyl)dithiobenzoate
5969-48-2

methyl 4-(methylsulfanyl)dithiobenzoate

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With sodium hydroxide; dihydrogen peroxide In methanol; water at 20℃; for 0.0833333h;86%
carbon dioxide
124-38-9

carbon dioxide

(4-bromophenyl)thioanisole
104-95-0

(4-bromophenyl)thioanisole

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
Stage #1: (4-bromophenyl)thioanisole With n-butyllithium In diethyl ether; hexane at 0℃; for 2h;
Stage #2: carbon dioxide In diethyl ether; hexane at -78 - 20℃; for 24h; Further stages.;
85%
With [2,2]bipyridinyl; lithium chloride; cobalt(II) iodide; zinc In N,N-dimethyl-formamide; acetonitrile at 40℃; under 760.051 Torr; for 14h; Sealed tube;69%
With diethylzinc; palladium diacetate; tert-butyl XPhos In hexanes; N,N-dimethyl acetamide at 40℃; under 7600.51 Torr; Automated synthesizer;65%
4-mercaptobenzoic acid
1074-36-8

4-mercaptobenzoic acid

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

A

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

B

methyl 4-(methylthio)benzoate
3795-79-7

methyl 4-(methylthio)benzoate

Conditions
ConditionsYield
With NaY faujasite at 150℃; for 26h;A 85%
B n/a
carbon dioxide
124-38-9

carbon dioxide

(4-thiomethoxyphenyl)boronic acid
98546-51-1

(4-thiomethoxyphenyl)boronic acid

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I); potassium methanolate In N,N-dimethyl acetamide at 70℃; for 24h; Schlenk technique; Sealed tube;85%
4-iodothioanisole
35371-03-0

4-iodothioanisole

H2O*CHLiO2

H2O*CHLiO2

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With formic acid; 1,3-bis-(diphenylphosphino)propane; nickel(II) acetate tetrahydrate; acetic anhydride In tetrahydrofuran at 100℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube;81%
dimethyl{4-(methylthio)phenyl}sulfonium triflate
870081-83-7

dimethyl{4-(methylthio)phenyl}sulfonium triflate

carbon dioxide
124-38-9

carbon dioxide

A

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

B

(dimethyl)(phenyl)sulfonium trifluoromethanesulfonate
85980-21-8

(dimethyl)(phenyl)sulfonium trifluoromethanesulfonate

Conditions
ConditionsYield
With 2.9-dimethyl-1,10-phenanthroline; neocuproine; zinc In dimethyl sulfoxide at 20℃; under 760.051 Torr; for 16h;A 73%
B 5%
4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

A

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

B

4-(methylsulfinyl)benzoic acid
33963-58-5

4-(methylsulfinyl)benzoic acid

C

4-methylsulfonylbenzoic acid
4052-30-6

4-methylsulfonylbenzoic acid

Conditions
ConditionsYield
With chromium(VI) oxide; sulfuric acid In water; acetone for 0.05h; Ambient temperature;A 72%
B 14%
C 14%
carbon dioxide
124-38-9

carbon dioxide

4,4,5,5-tetramethyl-2-(4-methylsulfanylphenyl)-[1,3,2]-dioxaborolane
190788-58-0

4,4,5,5-tetramethyl-2-(4-methylsulfanylphenyl)-[1,3,2]-dioxaborolane

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With copper(l) iodide; cesium fluoride; sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride at 120℃; for 24h; Sealed tube;71%
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

(4-bromophenyl)thioanisole
104-95-0

(4-bromophenyl)thioanisole

A

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

B

methyl 4-(methylthio)benzoate
3795-79-7

methyl 4-(methylthio)benzoate

Conditions
ConditionsYield
With tert-Amyl alcohol; sodium hydride; cobalt(II) acetate In tetrahydrofuran at 40℃; under 760 Torr; for 71h; Irradiation;A 11.5%
B 70.5%
carbon monoxide
201230-82-2

carbon monoxide

(4-bromophenyl)thioanisole
104-95-0

(4-bromophenyl)thioanisole

A

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

B

methyl 4-(methylthio)benzoate
3795-79-7

methyl 4-(methylthio)benzoate

Conditions
ConditionsYield
With methanol; tert-Amyl alcohol; sodium hydride; cobalt(II) acetate In tetrahydrofuran at 40℃; under 760 Torr; for 71h; Irradiation;A 11.5%
B 70.5%
carbon dioxide
124-38-9

carbon dioxide

4-chlorophenyl methyl sulfide
123-09-1

4-chlorophenyl methyl sulfide

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
Stage #1: 4-chlorophenyl methyl sulfide With bis(cyclopentadienyl)titanium dichloride; butyl magnesium bromide In tetrahydrofuran at 40℃; for 6h; Inert atmosphere; Schlenk technique;
Stage #2: carbon dioxide In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; Schlenk technique;
61%
2-[4-(methylsulfanyl)phenyl]acetonitrile
38746-92-8

2-[4-(methylsulfanyl)phenyl]acetonitrile

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper diacetate In neat (no solvent) at 80℃; for 5h; Green chemistry;60%
tert-butylisonitrile
119072-55-8, 7188-38-7

tert-butylisonitrile

(4-thiomethoxyphenyl)boronic acid
98546-51-1

(4-thiomethoxyphenyl)boronic acid

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
Stage #1: tert-butylisonitrile; (4-thiomethoxyphenyl)boronic acid With copper diacetate; palladium diacetate In N,N-dimethyl-formamide at 100℃; for 24h; Molecular sieve; Sealed tube;
Stage #2: With water In N,N-dimethyl-formamide Molecular sieve; Sealed tube;
57%
methyl bromide
74-83-9

methyl bromide

4-mercaptobenzoic acid
1074-36-8

4-mercaptobenzoic acid

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With potassium hydroxide In ethanol for 12h; Williamson Ether Synthesis; Reflux;55%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

diethyl ether
60-29-7

diethyl ether

(4-bromophenyl)thioanisole
104-95-0

(4-bromophenyl)thioanisole

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
at 20℃; anschliessende Umsetzung mit CO2;
4-methylthiobenzophenone
23405-48-3

4-methylthiobenzophenone

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With sodium amide; toluene Zersetzen des Reaktionsprodukts mit Wasser und Verseifen mit verd. Natronlauge;
diethyl ether
60-29-7

diethyl ether

(4-bromophenyl)thioanisole
104-95-0

(4-bromophenyl)thioanisole

methyllithium
917-54-4

methyllithium

A

methyl-phenyl-thioether
100-68-5

methyl-phenyl-thioether

B

4-methylphenyl methylsulfide
623-13-2

4-methylphenyl methylsulfide

C

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
anschliessendes Behandeln mit festem CO2;
(4-bromophenyl)thioanisole
104-95-0

(4-bromophenyl)thioanisole

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With n-butyllithium; diethyl ether Eintragen der Reaktionsloesung in festes Kohlendioxid;
p-cyanophenyl methyl sulfide
21382-98-9

p-cyanophenyl methyl sulfide

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With potassium hydroxide
4-mercaptobenzoic acid
1074-36-8

4-mercaptobenzoic acid

dimethyl sulfate
77-78-1

dimethyl sulfate

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With alkali
With potassium hydroxide In ethanol for 6h; Reflux;
4-amino-benzoic acid
150-13-0

4-amino-benzoic acid

dimethyl sulfate
77-78-1

dimethyl sulfate

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
(i) aq. HCl, NaNO2, (ii) potassium ethyl xanthate, (iii) /BRN= 635994/, aq. KOH; Multistep reaction;
p-methylthiobenzoyloxyl radical

p-methylthiobenzoyloxyl radical

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
With toluene In acetonitrile at 20℃; Kinetics; Further Variations:; Reaction partners; Reagents; hydrogen-atom abstraction;
bis(p-methylthiobenzoyl) peroxide

bis(p-methylthiobenzoyl) peroxide

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

Conditions
ConditionsYield
In acetonitrile at 20℃; Quantum yield; photolysis; UV-irradiation;
4-(Methylthio)benzaldehyde
3446-89-7

4-(Methylthio)benzaldehyde

KMnO4

KMnO4

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

4-(methylthio)benzoyl chloride
1442-06-4

4-(methylthio)benzoyl chloride

Conditions
ConditionsYield
With oxalyl dichloride In dichloromethane; N,N-dimethyl-formamide at 0℃;100%
With phosphorus trichloride In acetonitrile at 60℃; for 6h; Inert atmosphere;95%
With thionyl chloride
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

4-(methylsulfinyl)benzoic acid
33963-58-5

4-(methylsulfinyl)benzoic acid

Conditions
ConditionsYield
With ferric(III) bromide; nitric acid In acetonitrile at 20℃; for 2.5h; chemoselective reaction;100%
With water; bromine; oxygen; sodium nitrite In acetonitrile at 25℃; for 5h;96%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; water; oxygen; sodium nitrite In acetonitrile at 100℃; under 7500.75 Torr; for 3h; Autoclave; chemoselective reaction;91%
C19H29N3O4

C19H29N3O4

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

C27H35N3O5S

C27H35N3O5S

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide98%
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

descarboethoxyloratadine
100643-71-8

descarboethoxyloratadine

[4-(8-Chloro-5,6-dihydro-benzo[5,6]cyclohepta[1,2-b]pyridin-11-ylidene)-piperidin-1-yl]-(4-methylsulfanyl-phenyl)-methanone
169252-29-3

[4-(8-Chloro-5,6-dihydro-benzo[5,6]cyclohepta[1,2-b]pyridin-11-ylidene)-piperidin-1-yl]-(4-methylsulfanyl-phenyl)-methanone

Conditions
ConditionsYield
With 4-methyl-morpholine; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 4℃; for 0.5h;97%
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

methyl 4-(methylthio)benzoate
3795-79-7

methyl 4-(methylthio)benzoate

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 90℃; for 16h; Inert atmosphere; Green chemistry;97%
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

dibenzylamine
103-49-1

dibenzylamine

N,N-dibenzyl-4-(methylthio)benzamide

N,N-dibenzyl-4-(methylthio)benzamide

Conditions
ConditionsYield
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In N,N-dimethyl-formamide at 20℃; for 12h;97%
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

methyl iodide
74-88-4

methyl iodide

methyl 4-(methylthio)benzoate
3795-79-7

methyl 4-(methylthio)benzoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 3h; Inert atmosphere;95.1%
C19H29N3O4

C19H29N3O4

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

C27H35N3O5S

C27H35N3O5S

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide94%
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

4-(Methylthio)benzaldehyde
3446-89-7

4-(Methylthio)benzaldehyde

Conditions
ConditionsYield
With 4,4'-dimethoxyphenyl disulfide; iridium(lll) bis[2-(2,4-difluorophenyl)-5-methylpyridine-N,C20]-4,40-di-tert-butyl-2,20-bipyridine hexafluorophosphate; triphenylphosphine In toluene for 24h; Irradiation;94%
With 2,6-dimethylpyridine; nickel(II) bromide trihydrate; phenylsilane; 4,4'-di-tert-butyl-2,2'-bipyridine; zinc; dimethyl dicarbonate In ethyl acetate at 60℃; for 24h; Schlenk technique; Inert atmosphere;72 %Chromat.
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

diethylamine
109-89-7

diethylamine

N,N-diethyl-4-(methylthio)benzamide
1378313-78-0

N,N-diethyl-4-(methylthio)benzamide

Conditions
ConditionsYield
Stage #1: 4-(methylthio)benzoic acid With thionyl chloride In dichloromethane at 20℃; for 1h;
Stage #2: diethylamine With triethylamine In dichloromethane at 20℃;
93%
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

4-methylsulfonylbenzoic acid
4052-30-6

4-methylsulfonylbenzoic acid

Conditions
ConditionsYield
With sodium hydroxide; Oxone<*>; sodium hydrogencarbonate In water; acetone for 1h; Ambient temperature;92.6%
With [Ti(η5-C5H4SiMe2OPh7Si7O11-κ2O2)Cl]; dihydrogen peroxide In methanol; water at 50℃; for 3h; chemoselective reaction;85%
With dihydrogen peroxide; acetic acid
With chromium(VI) oxide; acetic acid
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; for 4h; Inert atmosphere;90.89%
With lithium aluminium tetrahydride; diethyl ether
With diborane In tetrahydrofuran at 0℃; for 1.5h;
methanol
67-56-1

methanol

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

methyl 4-(methylthio)benzoate
3795-79-7

methyl 4-(methylthio)benzoate

Conditions
ConditionsYield
With sulfuric acid In water for 22h; Reflux;90%
With hydrogenchloride
morpholine
110-91-8

morpholine

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

(4-(methylthio)phenyl)(morpholino)methanone
675618-10-7

(4-(methylthio)phenyl)(morpholino)methanone

Conditions
ConditionsYield
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In N,N-dimethyl-formamide at 20℃; for 12h;90%
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In N,N-dimethyl-formamide at 20℃; for 12h;90%
With 1-ethyl-3-(3-dimethylamino-propyl)-carbodiimide hydrochloride In tetrahydrofuran for 2h;
C24H27F3N4O4

C24H27F3N4O4

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

C32H33F3N4O5S

C32H33F3N4O5S

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide87%
C24H28F3N5O4

C24H28F3N5O4

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

C32H34F3N5O5S

C32H34F3N5O5S

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide87%
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

water
7732-18-5

water

diethylzinc
557-20-0

diethylzinc

[Zn4(μ4-O)(O2C-p-MeSC6H4)6]

[Zn4(μ4-O)(O2C-p-MeSC6H4)6]

Conditions
ConditionsYield
In tetrahydrofuran; water (N2); std. Schlenk technique; Zn compd. (2 equiv.) was added to suspn. of acid (3 equiv.) in THF at -78°C; after 4 h H2O (0.5 equiv.) wasadded; stirred for 20 h; recrystd. (THF, -20°C); elem. anal.;87%
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

4-amino-3-mercapto-1,2,4-triazin-5(4H)-one
23702-90-1

4-amino-3-mercapto-1,2,4-triazin-5(4H)-one

C11H8N4OS2
1403747-99-8

C11H8N4OS2

Conditions
ConditionsYield
With trichlorophosphate Reflux;87%
4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

2-methoxyindolizine

2-methoxyindolizine

(2-methoxyindolizin-3-yl)(4-(methylthio)phenyl)methanone

(2-methoxyindolizin-3-yl)(4-(methylthio)phenyl)methanone

Conditions
ConditionsYield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 30℃; for 20h; Inert atmosphere;86.6%
N-(4-piperidin-4-yl-3-trifluoromethyl-benzoyl)-N'-(carbobenzyloxy)-guanidine
1204331-51-0

N-(4-piperidin-4-yl-3-trifluoromethyl-benzoyl)-N'-(carbobenzyloxy)-guanidine

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

N-{4-[1-(4-methylsulfanyl-benzoyl)-piperidin-4-yl]-3-trifluoromethyl-benzoyl}-N'-(carbobenzyloxy)-guanidine
1204331-57-6

N-{4-[1-(4-methylsulfanyl-benzoyl)-piperidin-4-yl]-3-trifluoromethyl-benzoyl}-N'-(carbobenzyloxy)-guanidine

Conditions
ConditionsYield
Stage #1: 4-(methylthio)benzoic acid With 1,1'-carbonyldiimidazole In N,N-dimethyl-formamide for 1.5h;
Stage #2: N-(4-piperidin-4-yl-3-trifluoromethyl-benzoyl)-N'-(carbobenzyloxy)-guanidine With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃;
85%
C23H31F3N4O4
746670-24-6

C23H31F3N4O4

4-(methylthio)benzoic acid
13205-48-6

4-(methylthio)benzoic acid

C31H37F3N4O5S
746666-66-0

C31H37F3N4O5S

Conditions
ConditionsYield
With 4-methyl-morpholine; (benzotriazo-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate In N,N-dimethyl-formamide85%

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