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Min.Order:10 Gram
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Min.Order:1 Kilogram
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We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
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Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
FandaChem , a China-based chemical company, specialize in exporting 4-(Methylthio)benzoic acid cas 13205-48-6 (Fandachem), Please contact us by email freely. Appearance:white crystalline powder Storage:Store in dry, dark an
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Min.Order:1 Kilogram
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inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
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inquiryBest quality with low priceAppearance:light yellow to beige crystalline powder Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai
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inquiryKnown for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Prompt reaction, good quality and best service make us reliable and outstanding in this industry.Appearance:Light yellow to beige cryst
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inquiry4-(Methylthio)benzaldehyde
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; sodium hydroxide; (CTA)2SO4 at 20℃; for 20h; | 98% |
With sodium hydroxide In water at 20 - 75℃; for 20h; | 85% |
With perchloric acid; mercury(II) diacetate; N-bromoacetamide In acetic acid at 24.9℃; Kinetics; Mechanism; Thermodynamic data; other temperatures, ΔG(excit.), ΔH(excit.), ΔS(excit.); |
4-(methylthio)benzyl alcohol
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With diethylene glycol dimethyl ether at 70℃; for 0.5h; Sonication; | 95% |
With [Rh(1,3,4,5-tetramethylimidazole-2-ylidene)(trop2NH)][trifluoromethanesulfonate]; potassium tert-butylate; dinitrogen monoxide In tetrahydrofuran; toluene at 50℃; under 750.075 Torr; Schlenk technique; | 90% |
With oxygen at 120℃; for 11h; Green chemistry; | 87% |
4-iodothioanisole
diphenylmethylsilanecarboxylic acid
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With potassium trimethylsilonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; bis(dibenzylideneacetone)-palladium(0) In toluene at 40℃; for 0.333333h; | 95% |
1-(Bis-tert-butylperoxy-methyl)-4-methylsulfanyl-benzene
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With copper(II) sulfate; ascorbic acid In tetrahydrofuran; water for 8h; Ambient temperature; | 88% |
methyl 4-(methylsulfanyl)dithiobenzoate
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With sodium hydroxide; dihydrogen peroxide In methanol; water at 20℃; for 0.0833333h; | 86% |
Conditions | Yield |
---|---|
Stage #1: (4-bromophenyl)thioanisole With n-butyllithium In diethyl ether; hexane at 0℃; for 2h; Stage #2: carbon dioxide In diethyl ether; hexane at -78 - 20℃; for 24h; Further stages.; | 85% |
With [2,2]bipyridinyl; lithium chloride; cobalt(II) iodide; zinc In N,N-dimethyl-formamide; acetonitrile at 40℃; under 760.051 Torr; for 14h; Sealed tube; | 69% |
With diethylzinc; palladium diacetate; tert-butyl XPhos In hexanes; N,N-dimethyl acetamide at 40℃; under 7600.51 Torr; Automated synthesizer; | 65% |
4-mercaptobenzoic acid
carbonic acid dimethyl ester
A
4-(methylthio)benzoic acid
B
methyl 4-(methylthio)benzoate
Conditions | Yield |
---|---|
With NaY faujasite at 150℃; for 26h; | A 85% B n/a |
carbon dioxide
(4-thiomethoxyphenyl)boronic acid
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I); potassium methanolate In N,N-dimethyl acetamide at 70℃; for 24h; Schlenk technique; Sealed tube; | 85% |
Conditions | Yield |
---|---|
With formic acid; 1,3-bis-(diphenylphosphino)propane; nickel(II) acetate tetrahydrate; acetic anhydride In tetrahydrofuran at 100℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube; | 81% |
dimethyl{4-(methylthio)phenyl}sulfonium triflate
carbon dioxide
A
4-(methylthio)benzoic acid
B
(dimethyl)(phenyl)sulfonium trifluoromethanesulfonate
Conditions | Yield |
---|---|
With 2.9-dimethyl-1,10-phenanthroline; neocuproine; zinc In dimethyl sulfoxide at 20℃; under 760.051 Torr; for 16h; | A 73% B 5% |
4-(methylthio)benzyl alcohol
A
4-(methylthio)benzoic acid
B
4-(methylsulfinyl)benzoic acid
C
4-methylsulfonylbenzoic acid
Conditions | Yield |
---|---|
With chromium(VI) oxide; sulfuric acid In water; acetone for 0.05h; Ambient temperature; | A 72% B 14% C 14% |
carbon dioxide
4,4,5,5-tetramethyl-2-(4-methylsulfanylphenyl)-[1,3,2]-dioxaborolane
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With copper(l) iodide; cesium fluoride; sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride at 120℃; for 24h; Sealed tube; | 71% |
methanol
carbon monoxide
(4-bromophenyl)thioanisole
A
4-(methylthio)benzoic acid
B
methyl 4-(methylthio)benzoate
Conditions | Yield |
---|---|
With tert-Amyl alcohol; sodium hydride; cobalt(II) acetate In tetrahydrofuran at 40℃; under 760 Torr; for 71h; Irradiation; | A 11.5% B 70.5% |
carbon monoxide
(4-bromophenyl)thioanisole
A
4-(methylthio)benzoic acid
B
methyl 4-(methylthio)benzoate
Conditions | Yield |
---|---|
With methanol; tert-Amyl alcohol; sodium hydride; cobalt(II) acetate In tetrahydrofuran at 40℃; under 760 Torr; for 71h; Irradiation; | A 11.5% B 70.5% |
carbon dioxide
4-chlorophenyl methyl sulfide
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
Stage #1: 4-chlorophenyl methyl sulfide With bis(cyclopentadienyl)titanium dichloride; butyl magnesium bromide In tetrahydrofuran at 40℃; for 6h; Inert atmosphere; Schlenk technique; Stage #2: carbon dioxide In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; Schlenk technique; | 61% |
2-[4-(methylsulfanyl)phenyl]acetonitrile
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; copper diacetate In neat (no solvent) at 80℃; for 5h; Green chemistry; | 60% |
tert-butylisonitrile
(4-thiomethoxyphenyl)boronic acid
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
Stage #1: tert-butylisonitrile; (4-thiomethoxyphenyl)boronic acid With copper diacetate; palladium diacetate In N,N-dimethyl-formamide at 100℃; for 24h; Molecular sieve; Sealed tube; Stage #2: With water In N,N-dimethyl-formamide Molecular sieve; Sealed tube; | 57% |
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol for 12h; Williamson Ether Synthesis; Reflux; | 55% |
n-butyllithium
diethyl ether
(4-bromophenyl)thioanisole
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
at 20℃; anschliessende Umsetzung mit CO2; |
4-methylthiobenzophenone
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With sodium amide; toluene Zersetzen des Reaktionsprodukts mit Wasser und Verseifen mit verd. Natronlauge; |
diethyl ether
(4-bromophenyl)thioanisole
methyllithium
A
methyl-phenyl-thioether
B
4-methylphenyl methylsulfide
C
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
anschliessendes Behandeln mit festem CO2; |
(4-bromophenyl)thioanisole
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With n-butyllithium; diethyl ether Eintragen der Reaktionsloesung in festes Kohlendioxid; |
p-cyanophenyl methyl sulfide
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With potassium hydroxide |
Conditions | Yield |
---|---|
With alkali | |
With potassium hydroxide In ethanol for 6h; Reflux; |
Conditions | Yield |
---|---|
(i) aq. HCl, NaNO2, (ii) potassium ethyl xanthate, (iii) /BRN= 635994/, aq. KOH; Multistep reaction; |
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With toluene In acetonitrile at 20℃; Kinetics; Further Variations:; Reaction partners; Reagents; hydrogen-atom abstraction; |
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
In acetonitrile at 20℃; Quantum yield; photolysis; UV-irradiation; |
4-(methylthio)benzoic acid
4-(methylthio)benzoyl chloride
Conditions | Yield |
---|---|
With oxalyl dichloride In dichloromethane; N,N-dimethyl-formamide at 0℃; | 100% |
With phosphorus trichloride In acetonitrile at 60℃; for 6h; Inert atmosphere; | 95% |
With thionyl chloride |
4-(methylthio)benzoic acid
4-(methylsulfinyl)benzoic acid
Conditions | Yield |
---|---|
With ferric(III) bromide; nitric acid In acetonitrile at 20℃; for 2.5h; chemoselective reaction; | 100% |
With water; bromine; oxygen; sodium nitrite In acetonitrile at 25℃; for 5h; | 96% |
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; water; oxygen; sodium nitrite In acetonitrile at 100℃; under 7500.75 Torr; for 3h; Autoclave; chemoselective reaction; | 91% |
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide | 98% |
4-(methylthio)benzoic acid
descarboethoxyloratadine
[4-(8-Chloro-5,6-dihydro-benzo[5,6]cyclohepta[1,2-b]pyridin-11-ylidene)-piperidin-1-yl]-(4-methylsulfanyl-phenyl)-methanone
Conditions | Yield |
---|---|
With 4-methyl-morpholine; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 4℃; for 0.5h; | 97% |
4-(methylthio)benzoic acid
carbonic acid dimethyl ester
methyl 4-(methylthio)benzoate
Conditions | Yield |
---|---|
With potassium carbonate In dimethyl sulfoxide at 90℃; for 16h; Inert atmosphere; Green chemistry; | 97% |
Conditions | Yield |
---|---|
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In N,N-dimethyl-formamide at 20℃; for 12h; | 97% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 3h; Inert atmosphere; | 95.1% |
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide | 94% |
4-(methylthio)benzoic acid
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With 4,4'-dimethoxyphenyl disulfide; iridium(lll) bis[2-(2,4-difluorophenyl)-5-methylpyridine-N,C20]-4,40-di-tert-butyl-2,20-bipyridine hexafluorophosphate; triphenylphosphine In toluene for 24h; Irradiation; | 94% |
With 2,6-dimethylpyridine; nickel(II) bromide trihydrate; phenylsilane; 4,4'-di-tert-butyl-2,2'-bipyridine; zinc; dimethyl dicarbonate In ethyl acetate at 60℃; for 24h; Schlenk technique; Inert atmosphere; | 72 %Chromat. |
4-(methylthio)benzoic acid
diethylamine
N,N-diethyl-4-(methylthio)benzamide
Conditions | Yield |
---|---|
Stage #1: 4-(methylthio)benzoic acid With thionyl chloride In dichloromethane at 20℃; for 1h; Stage #2: diethylamine With triethylamine In dichloromethane at 20℃; | 93% |
4-(methylthio)benzoic acid
4-methylsulfonylbenzoic acid
Conditions | Yield |
---|---|
With sodium hydroxide; Oxone<*>; sodium hydrogencarbonate In water; acetone for 1h; Ambient temperature; | 92.6% |
With [Ti(η5-C5H4SiMe2OPh7Si7O11-κ2O2)Cl]; dihydrogen peroxide In methanol; water at 50℃; for 3h; chemoselective reaction; | 85% |
With dihydrogen peroxide; acetic acid | |
With chromium(VI) oxide; acetic acid |
4-(methylthio)benzoic acid
4-(methylthio)benzyl alcohol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; for 4h; Inert atmosphere; | 90.89% |
With lithium aluminium tetrahydride; diethyl ether | |
With diborane In tetrahydrofuran at 0℃; for 1.5h; |
Conditions | Yield |
---|---|
With sulfuric acid In water for 22h; Reflux; | 90% |
With hydrogenchloride |
morpholine
4-(methylthio)benzoic acid
(4-(methylthio)phenyl)(morpholino)methanone
Conditions | Yield |
---|---|
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In N,N-dimethyl-formamide at 20℃; for 12h; | 90% |
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In N,N-dimethyl-formamide at 20℃; for 12h; | 90% |
With 1-ethyl-3-(3-dimethylamino-propyl)-carbodiimide hydrochloride In tetrahydrofuran for 2h; |
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide | 87% |
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide | 87% |
Conditions | Yield |
---|---|
In tetrahydrofuran; water (N2); std. Schlenk technique; Zn compd. (2 equiv.) was added to suspn. of acid (3 equiv.) in THF at -78°C; after 4 h H2O (0.5 equiv.) wasadded; stirred for 20 h; recrystd. (THF, -20°C); elem. anal.; | 87% |
4-(methylthio)benzoic acid
4-amino-3-mercapto-1,2,4-triazin-5(4H)-one
C11H8N4OS2
Conditions | Yield |
---|---|
With trichlorophosphate Reflux; | 87% |
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 30℃; for 20h; Inert atmosphere; | 86.6% |
N-(4-piperidin-4-yl-3-trifluoromethyl-benzoyl)-N'-(carbobenzyloxy)-guanidine
4-(methylthio)benzoic acid
N-{4-[1-(4-methylsulfanyl-benzoyl)-piperidin-4-yl]-3-trifluoromethyl-benzoyl}-N'-(carbobenzyloxy)-guanidine
Conditions | Yield |
---|---|
Stage #1: 4-(methylthio)benzoic acid With 1,1'-carbonyldiimidazole In N,N-dimethyl-formamide for 1.5h; Stage #2: N-(4-piperidin-4-yl-3-trifluoromethyl-benzoyl)-N'-(carbobenzyloxy)-guanidine With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃; | 85% |
Conditions | Yield |
---|---|
With 4-methyl-morpholine; (benzotriazo-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate In N,N-dimethyl-formamide | 85% |
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