As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch
Cas:3446-89-7
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:3446-89-7
Min.Order:0 Metric Ton
Negotiable
Type:Manufacturers
inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards. 2. Now we have established long-term stab
Cas:3446-89-7
Min.Order:1 Kilogram
FOB Price: $1.0
Type:Other
inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:3446-89-7
Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryHenan Tianfu Chemical Co., Ltd. is located in Zhengzhou High-tech Development Zone with import and export license. We passed ISO 9001:2008 in 2009, and won "High-tech Enterprise" by provincial government in 2013.The objective of the com
Cas:3446-89-7
Min.Order:1 Gram
FOB Price: $1000.0
Type:Lab/Research institutions
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:3446-89-7
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
Cas:3446-89-7
Min.Order:1 Kilogram
FOB Price: $1.0 / 10.0
Type:Trading Company
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:3446-89-7
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese
Cas:3446-89-7
Min.Order:1 Kilogram
FOB Price: $88.0 / 100.0
Type:Trading Company
inquiry4-(Methylthio)benzaldehyde CAS:3446-89-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic
Cas:3446-89-7
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:3446-89-7
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s
Cas:3446-89-7
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:3446-89-7
Min.Order:0 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryPacking: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:3446-89-7
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:3446-89-7
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryProduct Name: 4-(Methylthio)benzaldehyde Synonyms: 4-(methylthio)-benzaldehyd;p-Methylmercaptobenzaldehyde;METHYLMERCAPTOBENZALDEHYDE(4-);4-ALDEHYDE THIOANISOLE;4-METHYLMERCAPTOBENZALDEHYDE;(4-METHYLTHIOCYCLOHEXYL)METHANOL;4-(METHYLTHIO)BENZAL
Cas:3446-89-7
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:3446-89-7
Min.Order:1 Kilogram
FOB Price: $18.0 / 20.0
Type:Trading Company
inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:3446-89-7
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiry1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:3446-89-7
Min.Order:1 Metric Ton
FOB Price: $1.5
Type:Trading Company
inquiryAppearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea
We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Cas:3446-89-7
Min.Order:1 Metric Ton
FOB Price: $1.0
Type:Trading Company
inquiryStock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai
Cas:3446-89-7
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
Cas:3446-89-7
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates
Q1: Are you a manufacturer Answer: Yes, we are factory founded on 2012.Q2: How to contact with us Click "contact supplier" And then send us message the product you interest in, you will get reply within 12 hours.Q3:Which kind of payment terms do you
Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea
Cas:3446-89-7
Min.Order:1 bottle
Negotiable
Type:Lab/Research institutions
inquiryConditions | Yield |
---|---|
With cobalt(II) nitrate hexahydrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; manganese (II) nitrate tetrahydrate; oxygen; acetic acid at 40℃; under 760.051 Torr; for 0.75h; | 100% |
With N,N,N',N'-tetramethylguanidine In dichloromethane at 20℃; for 1h; | 99% |
With hydrogenchloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium nitrite In dichloromethane; water at 20℃; under 760.051 Torr; for 11h; in air; | 99% |
p-methylsulfinylbenzaldehyde
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With indium; tungsten(VI) chloride In tetrahydrofuran at 20℃; for 0.0833333h; | 95% |
With niobium pentachloride; sodium iodide In acetonitrile at 20℃; for 0.0833333h; | 95% |
With iododioxobis(triphenylphosphine)rhenium(V); phenylsilane In tetrahydrofuran at 20℃; for 2.25h; chemoselective reaction; | 92% |
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With H6P2W18O62 In toluene at 100℃; for 0.0833333h; | 95% |
4-(methylthio)benzoic acid
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With 4,4'-dimethoxyphenyl disulfide; iridium(lll) bis[2-(2,4-difluorophenyl)-5-methylpyridine-N,C20]-4,40-di-tert-butyl-2,20-bipyridine hexafluorophosphate; triphenylphosphine In toluene for 24h; Irradiation; | 94% |
With 2,6-dimethylpyridine; nickel(II) bromide trihydrate; phenylsilane; 4,4'-di-tert-butyl-2,2'-bipyridine; zinc; dimethyl dicarbonate In ethyl acetate at 60℃; for 24h; Schlenk technique; Inert atmosphere; | 72 %Chromat. |
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With 1,3,5-trichloro-2,4,6-triazine; dimethyl sulfoxide In dichloromethane at 20℃; for 1h; | 93% |
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane; copper(l) iodide at 130℃; for 12h; Sealed tube; Inert atmosphere; | 92% |
With copper(l) iodide; zinc(II) fluoride at 150℃; for 36h; Sealed tube; Under air; | 85% |
With copper(l) iodide; zinc diacetate at 135℃; for 36h; regioselective reaction; | 70% |
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With iodosylbenzene In dichloromethane at 20℃; for 0.333333h; | 90% |
methyl-phenyl-thioether
N,N-dimethyl-formamide
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With trichlorophosphate at -5 - 45℃; for 7h; | 89.2% |
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With 1,2,3-trimethoxybenzene; oxalyl dichloride In dichloromethane at 0℃; for 0.00166667h; Inert atmosphere; chemoselective reaction; | 89% |
carbon monoxide
(4-bromophenyl)thioanisole
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With N,N,N,N,-tetramethylethylenediamine; hydrogen; palladium diacetate; propyl di-tert-butylphosphinite In toluene at 100℃; under 3750.38 Torr; for 20h; Inert atmosphere; | 88% |
4-(methylthio)benzyl bromide
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With benzo[c]cinnoline In N,N-dimethyl-formamide at 80℃; Kornblum Aldehyd Synthesis; | 87% |
Conditions | Yield |
---|---|
With copper(l) iodide; oxygen In dimethyl sulfoxide at 120℃; for 25h; chemoselective reaction; | 85% |
Conditions | Yield |
---|---|
With [Rh(1,3,4,5-tetramethylimidazole-2-ylidene)(trop2NH)][trifluoromethanesulfonate]; potassium tert-butylate; dinitrogen monoxide In tetrahydrofuran; water; toluene at 50℃; under 750.075 Torr; Schlenk technique; Molecular sieve; Overall yield = 88 %; Overall yield = 165 mg; | A 3% B 85% |
4-(Methylthio)-N-methylbenzenemethanamine
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene In dichloromethane at 0 - 20℃; for 0.333333h; Inert atmosphere; Green chemistry; | 85% |
4-(methylthio)benzyl alcohol
A
(4-(methylsulfinyl)phenyl)methanol
B
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical In neat (no solvent) at 70℃; for 6h; Irradiation; Green chemistry; | A 15% B 85% |
(4-thiomethoxyphenyl)boronic acid
Glyoxilic acid
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With 1,2,3,4-tetrahydroisoquinoline In acetonitrile at 20℃; Green chemistry; | 77% |
1-(azidomethyl)-4-methylsulfanylbenzene
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
Stage #1: 1-(azidomethyl)-4-methylsulfanylbenzene With sodium hydride In dimethyl sulfoxide; mineral oil at 20℃; for 4h; Inert atmosphere; Stage #2: With water In dimethyl sulfoxide; mineral oil for 0.25h; Inert atmosphere; | 75% |
3-oxobenzo[d]isothiazole-2(3H)-carbaldehyde 1,1-dioxide
4-(methylthio)phenyl trifluoromethanesulfonate
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With triethylsilane; 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium carbonate In acetonitrile at 80℃; for 16h; Inert atmosphere; Sealed tube; | 73% |
Conditions | Yield |
---|---|
With triethylsilane; dichloro bis(acetonitrile) palladium(II); sodium carbonate; 1,4-di(diphenylphosphino)-butane In N,N-dimethyl-formamide at 20 - 100℃; under 15001.5 Torr; for 20h; Inert atmosphere; Autoclave; | 69% |
Conditions | Yield |
---|---|
With iron(III) chloride hexahydrate In 1,4-dioxane; water at 80 - 100℃; for 18h; | 66% |
(E)-4-(methylthio)benzaldehyde oxime
B
p-methylsulfinylbenzaldehyde
C
4-(methylsulfonyl)benzaldehyde oxime
D
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With dihydrogen peroxide; bis(acetylacetonato)dioxidomolybdenum(VI) In acetone at 20℃; Product distribution; Further Variations:; Catalysts; Solvents; | A 5% B 3% C 3% D 60% |
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In water at 189℃; for 48h; | 60% |
4-(methylthio)benzyl alcohol
A
p-methylsulfinylbenzaldehyde
B
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical In n-heptane at 80℃; under 760.051 Torr; for 24h; | A 21% B 59% |
With polystyrene-supported hypervalent iodine(V) reagent In 1,2-dichloro-ethane at 85℃; for 1h; | |
With N-(2-iodylphenyl)glutarylamide supported on amonomethylpolystyrene resin In 1,2-dichloro-ethane at 85℃; for 1h; | A 7 %Spectr. B 85 %Spectr. |
2-nitropropane
4-(methylthio)benzyl bromide
B
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride In tetrahydrofuran Hass-Bender/Henry reaction; | A 57% B n/a |
4-(methylthio)benzyl bromide
A
4-(methylthio)benzyl alcohol
B
1-bromomethyl-4-methanesulfinylbenzene
C
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With dihydrogen peroxide at 70℃; for 1h; | A n/a B 52% C n/a |
Conditions | Yield |
---|---|
With 9-(benzoyl(cyclohexyl)carbamoyl)-10-phenylacridinium perchlorate In water; acetonitrile at 20℃; for 18h; Irradiation; Green chemistry; chemoselective reaction; | 49% |
4-(methylthio)benzyl alcohol
A
p-methylsulfinylbenzaldehyde
B
(4-(methylsulfinyl)phenyl)methanol
C
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With 1-iodyl-2-butoxybenzene In acetonitrile for 15h; Heating; | A 16% B 46% C 32% |
With 4-(2-iodylphenoxy)butanoylaminomethylated polystyrene In 1,2-dichloro-ethane for 3h; Heating; |
p-methylsulfinylbenzaldehyde
B
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With DL-dithiothreitol; methionine sulfoxide reductase A from Pseudomonas alcaliphila In aq. phosphate buffer at 30℃; for 1h; pH=8; Resolution of racemate; Enzymatic reaction; enantioselective reaction; | A 43% B n/a |
With recombinant methionine sulfoxide reductase A from Pseudomonas monteilii; diothiothreitol In aq. phosphate buffer at 30℃; for 4h; pH=8; Sealed tube; Resolution of racemate; Green chemistry; Enzymatic reaction; enantioselective reaction; | A n/a B n/a |
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide; trichlorophosphate | |
Multi-step reaction with 2 steps 1: acetic acid 2: hexamethylenetetramine; acetic acid / Erhitzen des Reaktionsprodukts mit H2O View Scheme |
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; sodium hydroxide at 70℃; for 2h; | 100% |
With oxone In tetrahydrofuran; water at 20℃; for 24h; | 94% |
With sodium perborate In acetic acid at 45 - 50℃; | 90% |
With oxygen at 100℃; for 20h; Reagent/catalyst; Schlenk technique; chemoselective reaction; | 87% |
4-(Methylthio)benzaldehyde
4-(methylthio)benzamide
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; sodium hydroxide; (CTA)2SO4 at 50℃; for 2h; | 100% |
With nitromethane; trifluoromethylsulfonic anhydride; acetic acid In formic acid at 80 - 120℃; | 57% |
Multi-step reaction with 2 steps 1: hydroxylamine hydrochloride; pyridine / methanol / 24 h / 20 °C 2: [RuCl2(η2-C6H6){P(NMe2)3}]; water / 3 h / 100 °C / Inert atmosphere; Sealed tube View Scheme |
4-(Methylthio)benzaldehyde
trimethyl orthoformate
1-(1,1-dimethoxy-methyl)-4-methylsulfanyl-benzene
Conditions | Yield |
---|---|
With potassium tert-butylate; toluene-4-sulfonic acid In methanol at 20℃; for 1.5h; Inert atmosphere; | 100% |
With toluene-4-sulfonic acid In methanol for 1.5h; Ambient temperature; | 83% |
With toluene-4-sulfonic acid In methanol at 20℃; for 1h; |
Conditions | Yield |
---|---|
With hydrogen; phosphotungstic acid 44-hydrate; [Fe(C5H4P(i-Pr)2)2Rh(C8H12)]BF4 In water; isopropyl alcohol at 20℃; under 5171.62 Torr; for 16h; | 100% |
With isopropyl alcohol; hydrotalcite at 81.84℃; for 3h; Kinetics; Further Variations:; Temperatures; Reagents; | 100% |
Stage #1: 4-(Methylthio)benzaldehyde With chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II); phenylsilane at 80℃; for 0.666667h; Stage #2: With tetrabutyl ammonium fluoride at 20℃; for 0.5h; Reagent/catalyst; Temperature; Time; Solvent; chemoselective reaction; | 98% |
ethyl acetoacetate
urea
4-(Methylthio)benzaldehyde
ethyl 6-methyl-4-[4-(methylsulfanyl)phenyl]-2-oxo-1,2,3,4-tetrahydro-5-pyrimidinecarboxylate
Conditions | Yield |
---|---|
With copper(II) bis(trifluoromethanesulfonate) In ethanol at 100℃; for 1h; Biginelli reaction; Microwave irradiation; Inert atmosphere; | 100% |
Wells-Dawson heteropolyacid catalyst at 80℃; for 1.5h; Biginelli reaction; | 92% |
With 25,26,27,28-terahydroxycalix[4]arene-5,11,7,23-tetrasulfonic acid In ethanol for 8h; Biginelli reaction; Reflux; | 92% |
4-(Methylthio)benzaldehyde
1-t-Butoxycarbonylpiperazine
Conditions | Yield |
---|---|
Stage #1: 4-(Methylthio)benzaldehyde; 1-t-Butoxycarbonylpiperazine In methanol for 0.5h; Stage #2: With borohydride; polymer-supported In methanol for 24h; | 100% |
Conditions | Yield |
---|---|
With sodium hydroxide In water; isopropyl alcohol at 0 - 20℃; for 5h; | 100% |
With sodium hydroxide In water; isopropyl alcohol at 0 - 20℃; | 100% |
1,1′-(9-ethyl-9H-carbazole-3,6-diyl)diethanone
4-(Methylthio)benzaldehyde
C34H29NO2S2
Conditions | Yield |
---|---|
With sodium hydroxide In water; tert-butyl alcohol at 0 - 20℃; for 5h; | 100% |
With sodium hydroxide In water; tert-butyl alcohol at 0 - 20℃; | 100% |
ethyl acetoacetate
1,3-cylohexanedione
4-(Methylthio)benzaldehyde
2-Methyl-4-(4-methylsulfanyl-phenyl)-5-oxo-1,4, 5,6,7,8-hexahydro-quinoline-3-carboxylic acid ethyl ester
Conditions | Yield |
---|---|
With Cu(OTf)2; ammonium acetate In ethanol at 100℃; for 0.25h; Hantzsch reaction; Microwave irradiation; | 100% |
Conditions | Yield |
---|---|
With copper(II) choride dihydrate; ammonium acetate In ethanol for 4h; Reflux; | 100% |
With 1,1,1,3',3',3'-hexafluoro-propanol; ammonium acetate at 55℃; for 1.5h; | 84% |
Conditions | Yield |
---|---|
With sodium acetate In ethanol; water at 20℃; | 100% |
4-(Methylthio)benzaldehyde
p-methylsulfinylbenzaldehyde
Conditions | Yield |
---|---|
With phthaloyl peroxide In dichloromethane at 25℃; for 8h; Schlenk technique; chemoselective reaction; | 99% |
Stage #1: 4-(Methylthio)benzaldehyde With aluminum (III) chloride In methanol; dichloromethane at 20℃; for 0.0166667h; Stage #2: With [bis(acetoxy)iodo]benzene In methanol; dichloromethane at 20℃; for 12h; | 99% |
With nitric acid; phosphorus pentoxide; silica gel In water for 0.0833333h; | 97% |
4-(Methylthio)benzaldehyde
γ-aminopropyl-2-methyl-6-phenyl-1,3-dioxa-6-aza-2-silacyclooctane
Conditions | Yield |
---|---|
With potassium carbonate In benzene at 20℃; for 6h; | 99% |
Methyltriphenylphosphonium bromide
4-(Methylthio)benzaldehyde
4-methythiostyrene
Conditions | Yield |
---|---|
With sodium hydride In tetrahydrofuran at 20℃; Wittig reaction; | 99% |
With sodium hydride In tetrahydrofuran at 0 - 20℃; Inert atmosphere; | 99% |
Stage #1: Methyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran; hexane at 0 - 20℃; for 2h; Wittig Olefination; Inert atmosphere; Stage #2: 4-(Methylthio)benzaldehyde In tetrahydrofuran; hexane at 0 - 20℃; for 16h; Wittig Olefination; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
With sodium metabisulfite In N,N-dimethyl-formamide at 80℃; for 0.1h; Microwave irradiation; | 99% |
Stage #1: 4-(Methylthio)benzaldehyde In N,N-dimethyl-formamide at 240℃; under 7500.75 Torr; for 0.0833333h; Microwave irradiation; Stage #2: 1,2-diamino-benzene In N,N-dimethyl-formamide at 240℃; under 7500.75 Torr; for 0.0833333h; Microwave irradiation; |
Conditions | Yield |
---|---|
With sodium hydroxide In water at 20℃; Aldol Condensation; | 99% |
4-methoxy-aniline
phosphonic acid diethyl ester
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) In neat (no solvent) at 80℃; for 0.166667h; chemoselective reaction; | 99% |
4-(Methylthio)benzaldehyde
4-(methylthio)benzoic acid
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; sodium hydroxide; (CTA)2SO4 at 20℃; for 20h; | 98% |
With sodium hydroxide In water at 20 - 75℃; for 20h; | 85% |
With perchloric acid; mercury(II) diacetate; N-bromoacetamide In acetic acid at 24.9℃; Kinetics; Mechanism; Thermodynamic data; other temperatures, ΔG(excit.), ΔH(excit.), ΔS(excit.); |
Conditions | Yield |
---|---|
With sodium hydroxide; 3-chloro-benzenecarboperoxoic acid at 1 - 3℃; for 2h; | 98% |
With Oxone In neat (no solvent) for 1.5h; Milling; Green chemistry; chemoselective reaction; | 97% |
With C2MoO9(2-)*H2O*2C19H42N(1+); dihydrogen peroxide In water at 20℃; for 0.0166667h; chemoselective reaction; | 97% |
Bromoform
4-(Methylthio)benzaldehyde
2-hydroxy-2-(4-methylthiophenyl)ethanoic acid
Conditions | Yield |
---|---|
With sodium hydroxide; lithium bromide In 1,4-dioxane | 98% |
With potassium hydroxide; lithium bromide In 1,4-dioxane; water 1.) 0 deg C, 18 h, 2.) 23 deg C, 24 h; | 7.6 g |
4-(Methylthio)benzaldehyde
4-(methylthio)benzaldehyde oxime
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride; sodium hydroxide In ethanol at 80℃; for 4h; Inert atmosphere; | 98% |
With sodium hydroxide; hydroxylamine hydrochloride In ethanol; water at 0℃; | 46% |
With hydroxylamine hydrochloride; sodium carbonate In ethanol; water for 24h; |
N-methylhydroxyamine hydrochloride
4-(Methylthio)benzaldehyde
N-[4-(methylthio)benzylidene]methylamine N-oxide
Conditions | Yield |
---|---|
With sodium sulfate; sodium carbonate at 20℃; for 0.0833333h; Neat (no solvent); | 98% |
With sodium hydrogencarbonate In dichloromethane at 20℃; | 82% |
With sodium acetate In ethanol at 50 - 60℃; for 3h; | 78% |
piperidine
(4-methoxyphenyl)zinc(II) bromide
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With copper(l) iodide In acetonitrile at 20℃; for 3h; | 98% |
Conditions | Yield |
---|---|
With triethylamine In chloroform at 20℃; for 16h; | 98% |
hydrogen cyanide
4-(Methylthio)benzaldehyde
2-hydroxy-2-(4-(methylthio)phenyl)acetonitrile
Conditions | Yield |
---|---|
With Prunus communis L. (R)-hydroxynitrile lyase In various solvent(s) at 20℃; for 12h; | 98% |
With hydroxynitrile lyase isozyme 5 from Prunus communis In tert-butyl methyl ether at 25℃; for 4h; pH=5; pH-value; Temperature; Reagent/catalyst; Solvent; Enzymatic reaction; | 94% |
With hydroxynitrile lyase PcHNL5, L343F mutant at 10℃; for 12h; pH=2.5; Reagent/catalyst; Enzymatic reaction; enantioselective reaction; | n/a |
4-chloro-aniline
4-(Methylthio)benzaldehyde
4-chloro-N-[4-methylsulfanylbenzylidene]aniline
Conditions | Yield |
---|---|
98% | |
In methanol for 4h; Reflux; | 88% |
With acetic acid In ethanol at 78℃; for 10h; |
2-hydroxy-2-phenylacetophenone
4-(Methylthio)benzaldehyde
2-(4-(methylthio)phenyl)-4,5-diphenyl-1H-imidazole
Conditions | Yield |
---|---|
With P2O5/SiO2; ammonium acetate at 100℃; for 2h; | 98% |
With triphenyl(propyl-3-sulphonyl)phosphonium toluenesulfonate; ammonium acetate at 100℃; for 2h; neat (no solvent); | 98% |
With 1-methyl-2-oxopyrrolidinium hydrogen sulfate; ammonium acetate at 100℃; for 2.5h; Neat (no solvent); | 95% |
With ammonium acetate at 130℃; for 1.33333h; Neat (no solvent); | 90% |
4-(Methylthio)benzaldehyde
N-phenyl-1,2-benzenediamine
2-[4-(methylthio)phenyl]-1-phenyl-1H-benzo[d]imidazole
Conditions | Yield |
---|---|
With sodium metabisulfite In N,N-dimethyl-formamide at 100℃; for 0.1h; Microwave irradiation; | 98% |
1,3-cylohexanedione
2,4-diamino-6-hydroxypyrimidine
4-(Methylthio)benzaldehyde
Conditions | Yield |
---|---|
With zirconium(IV) oxide In ethylene glycol at 120℃; for 0.133333h; Green chemistry; | 98% |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View