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Wuhan BJM Pharm Inc.

We have two factories in Dezhou , Shandong and Xianning, Hubei. The factory covers an area of 48,000 square meters with the building area of 26,000 square meters. We are specialized in the manufacture of pharmaceutical intermediates and cosmetic addi

Octyl 4-methoxycinnamate CAS No: 5466-77-3 OMC Sunscreen, anti-aging and uv absorbent

Cas:5466-77-3

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

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Qingdao Jade New Material Technology CO.,Ltd

■COSMETICS ADDITIVES JADEWIN MC 80 UV ABSORBER CHEMICAL COMPONENT COMPONENT p-Methoxycinnamic acid 2-ethylhexyl ester; ETHYLHEXYL METHOXYCINNAMATE CAS 5466-77-3 Molecular C18H26O3 M.W 290.40

UV ABSORBER MC80

Cas:5466-77-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Octyl 4-methoxycinnamate

Cas:5466-77-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Octyl P-Methoxycinnamate supplier in China

Cas:5466-77-3

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name Octyl 4-methoxycinnamate CAS number 5466-77-3 Assay ≥99% Appearance Yellowish liquid Capacity 1000mt/year Application Cosmetics, plastics, r

Octyl 4-methoxycinnamate

Cas:5466-77-3

Min.Order:1 Kilogram

FOB Price: $12.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carb

Octyl 4-methoxycinnamate

Cas:5466-77-3

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

High quality Octyl 4-methoxycinnamate CAS 5466-77-3 with low price Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed ad

High quality Octyl 4-methoxycinnamate CAS 5466-77-3 with low price

Cas:5466-77-3

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Hefei TNJ chemical industry co.,ltd

ISO Best Service: 1.Sticking to such policy of quality first, customer first; 2.Honest business as number one priority, and work for meeting your demands. 3.With the newest quality, and best service. 5.The most strict management system i

Octyl 4-methoxycinnamate

Cas:5466-77-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Xi'an Quanao Biotech Co., Ltd.

We are: Focus on the research, production and sale of Plant and Animal extract, Medical intermediate, complete coverage six industries. Product grade: Medicine, Health care product, Cosmetics, Food,Feed, Biopesticide. Hot selling market: Europe,

octyl methoxycinnamate CAS 5466-77-3

Cas:5466-77-3

Min.Order:1 Kilogram

FOB Price: $60.0 / 63.5

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

2-Ethylhexyl 4-MethoxycinnaMate

Cas:5466-77-3

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Octyl P-Methoxycinnamate

Cas:5466-77-3

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Large Stock 99.0% octyl P-methoxycinnamate 5466-77-3 Producer

Cas:5466-77-3

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chengdu Lemeitian Pharmaceutical Technology Co,. Ltd

ADVANTAGE: 1. More than 3,000 Chinese medicine reference substances / standard products available from stock, issued on the same day, multiple cities can be delivered the next day 2. The products are provided with COA, HPLC, NMR, quality assurance,

2-Ethylhexyl Trans-4-Methoxycinnamate

Cas:5466-77-3

Min.Order:5 Milligram

Negotiable

Type:Manufacturers

inquiry

Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality Octyl 4-methoxycinnamate

Cas:5466-77-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

High purity CAS 5466-77-3 Octyl 4-methoxycinnamate in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business re

High purity CAS 5466-77-3 Octyl 4-methoxycinnamate in stock

Cas:5466-77-3

Min.Order:1 Gram

FOB Price: $1.0 / 10.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can be sent

Octyl 4-methoxycinnamate

Cas:5466-77-3

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Best CAS 5466-77-3 with competitive price

Cas:5466-77-3

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powder 2. Fact

Octyl 4-methoxycinnamateCAS5466-77-3

Cas:5466-77-3

Min.Order:1 Kilogram

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Octyl methoxycinnamate (INCI) or octinoxate (USAN), trade names Eusolex 2292, parsol 1789 and Uvinul MC80, is an organic compound that is an ingredient in some sunscreens and lip balms. It is an ester formed from methoxycinnamic acid and (RS)-2-e

OMC; Octyl Methoxy Cinnamate

Cas:5466-77-3

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:colourless or pale yellow liquid Storage:Room temperature Package:25kg/Barrel, 200kg/Barrel Application:Sunscreen, anti-aging agent and UV absorber Transportation:Express/Sea/Air Port:Any port in china

High Quality Octyl 4-methoxycinnamate (OMC) UV ABSORBER MC80

Cas:5466-77-3

Min.Order:25 Kilogram

Negotiable

Type:Lab/Research institutions

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Leader Biochemical Group

Octyl 4-methoxycinnamate Basic information Product Name: Octyl 4-methoxycinnamate Synonyms: 2-ETHYLHEXYL TRANS-4-METHOXYCINNAMATE;2-ETHYLHEXYL P-METHOXYCINNAMATE;2-ETHYLHEXYL 4-METHOXYCINNAMATE;4-METHOXYCINNAMI

China Biggest Factory & Manufacturer supply Octyl 4-methoxycinnamate/Octinoxate CAS 5466-77-3

Cas:5466-77-3

Min.Order:1000 Kilogram

FOB Price: $2.0 / 3.0

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Propenoic acid,3-(4-methoxyphenyl)-, 2-ethylhexyl ester 5466-77-3

Cas:5466-77-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xi'an Faithful Biotech Co., Ltd.

We are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery

Qingdao Beluga Import and Export Co., LTD

Octyl 4-methoxycinnamate CAS: 5466-77-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

Octyl 4-methoxycinnamate CAS: 5466-77-3

Cas:5466-77-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Ethylhexyl P-Methoxycinnamate

Cas:5466-77-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional chemical raw materials and chemical reagents research and development production enterprises. We have several production line,So we can control the lowest price. We also have several

Ethyl Hexyl Methoxy Cinnamate CAS 5466-77-3 Octyl 4-Methoxycinnamate

Cas:5466-77-3

Min.Order:25 Kilogram

FOB Price: $28.0 / 30.0

Type:Trading Company

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists

2-ETHYLHEXYL TRANS-4-METHOXYCINNAMATE 5466-77-3

Cas:5466-77-3

Min.Order:25 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei CuiRan Biotechnology Co., Ltd

Hubei CuiRan Biotechnology Co., Ltd is a leading company in the research, development, manufacture and marketing of High Quality Phytochemicals and Extracts(especially Active Ingredients from Traditional Chinese Medicine,Traditional Chinese Medicine)

2-Ethylhexyl Trans-4-Methoxycinnamate

Cas:5466-77-3

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Kemi-Works Chemical Co., Ltd

ProductName:Octyl4-methoxycinnamate Synonyms:octylP-methoxycinnamate,(5-Methylheptyl)3-(4-methoxyphenyl)-2-propenoate; 2-Ethylhexyl4-met… Appearance:Colorless or yellowish liquid Storage:Store in dry and cool place with good seal Package:

Octyl 4-methoxycinnamate

Cas:5466-77-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Lonwin Chemical Group Limited

Octyl 4-methoxycinnamate CAS:5466-77-3 Specification Item Specification Appearance Clear Yellow Liquid Assay 98%min Density 1.009 Boiling Point 198-200°C Welcome to c

Factory Supply Octyl 4-methoxycinnamate

Cas:5466-77-3

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Other

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Synthetic route

diazo-acetic acid-(2-ethyl-hexyl ester)

diazo-acetic acid-(2-ethyl-hexyl ester)

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With Fe(TCP)Cl; polyethylene supported arsine; polymethylhydrosiloxane In toluene at 110℃; for 20h; Wittig type reaction; Inert atmosphere; stereoselective reaction;98%
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

para-iodoanisole
696-62-8

para-iodoanisole

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With tetrabutylammomium bromide; C32H26Cl2N8O4Pd2; potassium carbonate In methanol; water for 0.416667h; Reflux;97%
With C43H54NO5P; palladium diacetate; triethylamine In water at 40℃; for 12h; Heck Reaction;95%
With tributyl-amine; chloro-[2-(9-phenyl-1,10-phenanthrolin-2-yl)phenyl]palladium In 1-methyl-pyrrolidin-2-one at 140℃; for 15h; Heck Reaction; Inert atmosphere;94%
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

4-methoxybenzenediazonium tetrafluoroborate
459-64-3

4-methoxybenzenediazonium tetrafluoroborate

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
[(1,3-dimesitylimidazol-2-ylidene)(benzoquinone)Pd(0)]2 In methanol at 50℃; for 1h; Heck reaction;96%
With calcium carbonate; Lindlar's catalyst In methanol93%
(IMes)Pd(NQ) In ethanol at 50℃; for 1h; Conversion of starting material; Heck Reaction;88%
palladium on activated carbon In dichloromethane; water; dimethyl sulfoxide80%
With xonotlite; palladium diacetate In methanol at 20℃; Reagent/catalyst;73%
2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With toluene-4-sulfonic acid Heating;94%
tert-Octylamine
107-45-9

tert-Octylamine

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

para-iodoanisole
696-62-8

para-iodoanisole

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With acetic acid; palladium on charcoal92%
palladium of charcoal

palladium of charcoal

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

para-iodoanisole
696-62-8

para-iodoanisole

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With triethylamine In water; toluene92%
2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

acetic acid methyl ester
79-20-9

acetic acid methyl ester

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

A

2-ethylhexyl acetate
103-09-3

2-ethylhexyl acetate

B

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
Stage #1: 2-Ethylhexyl alcohol; acetic acid methyl ester; 4-methoxy-benzaldehyde With sodium methylate at 20 - 100℃; under 45.0045 Torr; for 3.33333h;
Stage #2: With sulfuric acid; toluene-4-sulfonic acid In water at 100℃; for 0.25h;
A n/a
B 91.5%
Stage #1: 2-Ethylhexyl alcohol; acetic acid methyl ester; 4-methoxy-benzaldehyde With sodium methylate at 20 - 100℃; under 45.0045 Torr; for 3.33333h;
Stage #2: With sulfuric acid In water at 100 - 150℃; for 2.25h;
A n/a
B 90%
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With Hoveyda-Grubbs catalyst first generation In 1,2-dichloro-ethane at 70℃; Cross Metathesis; Schlenk technique; Inert atmosphere; Glovebox;89%
With Hoveyda-Grubbs catalyst second generation In toluene at 70℃; for 6h; Inert atmosphere; Glovebox;> 99 %Spectr.
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In 1,2-dichloro-ethane at 70℃; for 4h; Solvent; Reagent/catalyst; Inert atmosphere; Glovebox;
With 1,3-bis-(2,4,6-trimethylphenyl)-2-(imidazolidinylidene)dichloro(5-nitro-2-isopropoxyphenylmethylene)ruthenium; 2,6-di-tert-butyl-4-methyl-phenol In toluene at 70℃; for 1.5h; Catalytic behavior; Inert atmosphere; Schlenk technique;86 %Chromat.
2-ethyl-1,3-hexane diol
94-96-2

2-ethyl-1,3-hexane diol

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

ethylene glycol
107-21-1

ethylene glycol

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With sodium carbonate; triphenylphosphine; palladium diacetate In 1-bromo-4-methoxy-benzene88%
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

para-iodoanisole
696-62-8

para-iodoanisole

diethylamine
109-89-7

diethylamine

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With acetic acid; palladium on charcoal86.6%
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

1-(benzoyl)piperidine-2,6-dione

1-(benzoyl)piperidine-2,6-dione

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With lithium bromide; palladium dichloride In 1-methyl-pyrrolidin-2-one at 160℃; for 15h; Heck Reaction; Inert atmosphere; chemoselective reaction;84.8%
5-(4-methoxybenzylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione
15795-54-7

5-(4-methoxybenzylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione

2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
Stage #1: 5-(4-methoxybenzylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione; 2-Ethylhexyl alcohol With iron(III) chloride hexahydrate In nitromethane for 0.25h; Microwave irradiation;
Stage #2: With piperidine In nitromethane for 0.25h; Microwave irradiation; stereoselective reaction;
84%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine; Cy2NMe2 In 1,4-dioxane at 20℃; for 148h; Heck coupling;83%
With C21H21ClN4Pd; triethylamine In 1-methyl-pyrrolidin-2-one at 140℃; for 8h;73%
With sodium acetate; *6Ph4PCl In various solvent(s) at 130℃;71%
With tri-n-propylamine In 1-methyl-pyrrolidin-2-one at 175℃; for 24h; Heck reaction; Inert atmosphere;34%
With dimethylaminoacetic acid; bis(benzonitrile)palladium(II) dichloride
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With potassium phosphate; catacxium A; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 120℃; for 24h; Substitution; Heck reaction;82%
methanolic sodium methylate

methanolic sodium methylate

boron trifluoride dimethyl etherate
353-42-4

boron trifluoride dimethyl etherate

2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

p-Anisaldehyde dimethyl acetal
2186-92-7

p-Anisaldehyde dimethyl acetal

methyl 3-(4-methoxyphenyl)-3-methoxypropanoate
69098-08-4

methyl 3-(4-methoxyphenyl)-3-methoxypropanoate

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
75%
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

B

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; p-cresol In dichloromethane for 2h; Reflux; Inert atmosphere;A 53%
B 47%
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In 1,2-dichloro-ethane at 70℃; for 4h; Reagent/catalyst; Inert atmosphere; Glovebox;
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
40%
4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

α-hydrazino-phenylacetic acid

α-hydrazino-phenylacetic acid

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 99 percent / 4-(dimethylamino)pyridine / dimethylformamide / 25 °C
2: 94 percent / p-TsOH / Heating
View Scheme
Multi-step reaction with 2 steps
1: 97 percent / 4-(dimethylamino)pyridine; acetic acid; piperidine / dimethylformamide / 10 - 25 °C
2: 94 percent / p-TsOH / Heating
View Scheme
conc. H2 SO4

conc. H2 SO4

n-Amyl nitrite
463-04-7

n-Amyl nitrite

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

4-methoxy-aniline
104-94-9

4-methoxy-aniline

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
palladium diacetate In 2-Ethylhexyl alcohol
2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

A

sodium bromide

sodium bromide

B

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With sodium carbonate; triphenylphosphine; palladium diacetate In 1-bromo-4-methoxy-benzene
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

Aliquat 336
5137-55-3

Aliquat 336

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With sodium carbonate; triphenylphosphine; palladium diacetate
MTB ether

MTB ether

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With sodium carbonate; palladium diacetate
Estragole
140-67-0

Estragole

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) / toluene / 0.25 h / 40 °C / Inert atmosphere; Glovebox
2: Hoveyda-Grubbs catalyst second generation / toluene / 6 h / 70 °C / Inert atmosphere; Glovebox
View Scheme
Multi-step reaction with 2 steps
1: [CpRu(PN)(MeCN)]PF6 / toluene / 0.5 h / 40 °C / Inert atmosphere; Glovebox
2: Hoveyda-Grubbs catalyst second generation / toluene / 6 h / 70 °C / Inert atmosphere; Glovebox
View Scheme
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

A

4-Methoxystyrene
637-69-4

4-Methoxystyrene

B

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In 1,2-dichloro-ethane at 70℃; for 1h; Inert atmosphere; Glovebox;
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

A

4-Methoxystyrene
637-69-4

4-Methoxystyrene

C

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 70℃; for 4h; Reagent/catalyst; Inert atmosphere; Glovebox;
2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

3-(4-methoxy-phenyl)-propionic acid 2-ethyl-hexyl ester
127794-13-2

3-(4-methoxy-phenyl)-propionic acid 2-ethyl-hexyl ester

Conditions
ConditionsYield
With Triethoxysilane; water; palladium diacetate In tetrahydrofuran Ambient temperature;92%
5-methyl-1,3-benzodioxole
7145-99-5

5-methyl-1,3-benzodioxole

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

2'-ethylhexyl 3-(2-methyl-4,5-methylenedioxyphenyl)-3-(4-methoxyphenyl)propionate

2'-ethylhexyl 3-(2-methyl-4,5-methylenedioxyphenyl)-3-(4-methoxyphenyl)propionate

Conditions
ConditionsYield
With palladium diacetate; trifluoroacetic acid In dichloromethane at 20℃; for 10h; Hydroarylation;86%
With trifluoroacetic acid; palladium diacetate In dichloromethane at 20℃; for 10h; hydroarylation;85%
2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

1,4-dimethoxybezene
150-78-7

1,4-dimethoxybezene

2'-ethylhexyl 3-(2,5-dimethoxyphenyl)-3-(4-methoxyphenyl)propionate

2'-ethylhexyl 3-(2,5-dimethoxyphenyl)-3-(4-methoxyphenyl)propionate

Conditions
ConditionsYield
With palladium diacetate; trifluoroacetic acid In dichloromethane at 20℃; for 10h; Hydroarylation;83%
1,2,3-trimethoxybenzene
621-23-8

1,2,3-trimethoxybenzene

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

2'-ethylhexyl 3-(2,4,6-trimethoxyphenyl)-3-(4-methoxyphenyl)propionate

2'-ethylhexyl 3-(2,4,6-trimethoxyphenyl)-3-(4-methoxyphenyl)propionate

Conditions
ConditionsYield
With palladium diacetate; trifluoroacetic acid In dichloromethane at 20℃; for 10h; Hydroarylation;65%
2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

A

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene
1619923-81-7

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

B

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

C

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: diisobutylaluminium hydride / hexane / 2 h / 0 °C
2.1: dipyridinium dichromate; aluminum oxide / dichloromethane / 24 h / 20 °C
3.1: L-proline; acetic acid / methanol; acetonitrile / 5 h / 20 °C
3.2: 1 h / 20 °C
View Scheme
2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

A

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene
1619923-81-7

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

B

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: diisobutylaluminium hydride / hexane / 2 h / 0 °C
2.1: dipyridinium dichromate; aluminum oxide / dichloromethane / 24 h / 20 °C
3.1: L-proline; acetic acid / methanol; acetonitrile / 5 h / 20 °C
3.2: 1 h / 20 °C
View Scheme
2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

A

C24H23NO2
1619923-76-0

C24H23NO2

B

C24H23NO2

C24H23NO2

C

C24H23NO2

C24H23NO2

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: diisobutylaluminium hydride / hexane / 2 h / 0 °C
2: dipyridinium dichromate; aluminum oxide / dichloromethane / 24 h / 20 °C
3: L-proline; acetic acid / methanol; acetonitrile / 5 h / 20 °C
View Scheme

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