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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

3-Methylbenzyl bromide

Cas:620-13-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3-Methylbenzyl Bromide with high purity

Cas:620-13-3

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-Methylbenzyl Bromide

Cas:620-13-3

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

m-Xylyl bromide

Cas:620-13-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU-CHEM_3-Methylbenzyl bromide620-13-3

Cas:620-13-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

3-Methylbenzyl bromide 620-13-3

Cas:620-13-3

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 620-13-3 with fast shipping

Cas:620-13-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Benzene,1-(bromomethyl)-3-methyl-

Cas:620-13-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:620-13-3

Cas:620-13-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

1-(Brommethyl)-3-methylbenzol

Cas:620-13-3

Min.Order:1 Kilogram

FOB Price: $40.0 / 50.0

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

3-Methylbenzyl Bromide

Cas:620-13-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Specification : 3-Methylbenzyl bromide CAS No:89

3-Methylbenzyl bromide

Cas:620-13-3

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:clear colorless to light yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Appl

alpha-Bromo-m-xylene

Cas:620-13-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Methylbenzyl bromide

Cas:620-13-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzene,1-(bromomethyl)-3-methyl-

Cas:620-13-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

3-Methylbenzyl bromide Chemical Properties Melting point -20.49°C (estimate) Boiling point 185 °C340 mm Hg(lit.) density 1.37 g/mL at 25 °C(lit.) refractive index n20/D 1.566(lit.) Fp 180 °F form Liquid color

3-Methylbenzyl bromide

Cas:620-13-3

Min.Order:1 Gram

FOB Price: $25.0

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

3-Methylbenzyl bromide

Cas:620-13-3

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

alpha-Bromo-m-xylene

Cas:620-13-3

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

3-Methylbenzyl bromide

Cas:620-13-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 3-Methylbenzyl bromide 100g

Cas:620-13-3

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

alpha-BroMo-M-xylene

Cas:620-13-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

3-Methylbenzyl Bromide

Cas:620-13-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

α-BroMo-M-xylene

Cas:620-13-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

3-Methylbenzyl bromide

Cas:620-13-3

Min.Order:0

Negotiable

Type:Other

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

Appearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

3-Methylbenzyl bromide CAS No.620-13-3

Cas:620-13-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as pri

3-Methylbenzyl bromide

Cas:620-13-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

3-Methylbenzyl bromide cas 620-13-3Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

3-Methylbenzyl bromide cas 620-13-3

Cas:620-13-3

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:clear colorless to light yellow liquid Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

3-Methylbenzyl bromide

Cas:620-13-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:White powder Storage:keep sealed and keep from direct light Package:According client's requirements Application:pharmaceutica

3-Methylbenzyl Bromide manufacturer

Cas:620-13-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

3-Methylbenzyl bromide

Cas:620-13-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

Conditions
ConditionsYield
With N-Bromosuccinimide; trityl tetrafluoroborate In dichloromethane; benzene at 20℃; Irradiation; Inert atmosphere; chemoselective reaction;92%
With dibenzoyl peroxide In ethyl acetate for 3.5h; Reflux;75%
With hydrogen bromide; dihydrogen peroxide In water at 0℃; Incandescent lamp light;71.1%
m-tolyl aldehyde
620-23-5

m-tolyl aldehyde

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

Conditions
ConditionsYield
With bromine; trimethylamine borane In chloroform at 0 - 5℃; for 0.0333333h;92%
Multi-step reaction with 2 steps
1: sodium tetrahydroborate / methanol / 0.5 h / 20 °C
2: phosphorus tribromide / dichloromethane / 0.5 h / 0 °C
View Scheme
Multi-step reaction with 2 steps
1: sodium tetrahydroborate; methanol / 0.17 h / 0 °C
2: phosphorus tribromide / diethyl ether / 3 h / 0 - 20 °C
View Scheme
Multi-step reaction with 2 steps
1: sodium tetrahydroborate / methanol / 2 h / 0 °C
2: phosphorus tribromide / diethyl ether / 0.5 h / 0 °C
View Scheme
m-xylene
108-38-3

m-xylene

A

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

B

1,3-bis-(bromomethyl)benzene
626-15-3

1,3-bis-(bromomethyl)benzene

Conditions
ConditionsYield
With hydrogen bromide; dihydrogen peroxide In water at 20℃; Irradiation;A 73%
B 11%
With N-Bromosuccinimide for 0.15h; microwave irradiation;A 40%
B 42%
With bromine In water Irradiation;A 40 % Chromat.
B 53 % Chromat.
m-xylene
108-38-3

m-xylene

A

1-bromo-2,4-dimethylbenzene
583-70-0

1-bromo-2,4-dimethylbenzene

B

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

Conditions
ConditionsYield
With sodium bromate; sodium hydrogensulfite In cyclohexane; water at 20℃; for 4h; Bromination;A 1%
B 64%
With sodium bromate; sodium hydrogensulfite In water; acetonitrile at 20℃; for 4h; Bromination;A 57%
B n/a
With N-Bromosuccinimide at 150℃; under 2625.26 Torr; for 0.0666667h; microwave irradiation;A 1.5 % Chromat.
B 56 % Chromat.
3-methylbenzyl Co(III)(dmgH)2py
36583-13-8

3-methylbenzyl Co(III)(dmgH)2py

Bromotrichloromethane
75-62-7

Bromotrichloromethane

A

bromo Co(III)(dmgH)2py

bromo Co(III)(dmgH)2py

B

hexachloroethane
67-72-1

hexachloroethane

C

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

D

1-Methyl-3-(2,2,2-trichloro-ethyl)-benzene

1-Methyl-3-(2,2,2-trichloro-ethyl)-benzene

Conditions
ConditionsYield
In chloroform Excess of CHCl3, 55°C for 5 h;; detected by NMR spectra and GLC;;A n/a
B n/a
C 45%
D 55%
m-MeC6H4CH2Co(dmgH)2Py

m-MeC6H4CH2Co(dmgH)2Py

A

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

B

1-bromo-2-(bromomethyl)-4-methylbenzene
27561-50-8

1-bromo-2-(bromomethyl)-4-methylbenzene

Conditions
ConditionsYield
With bromine In chloroform Ambient temperature;A 50%
B 50%
m-methylbenzyl-p-methylphenyldimethylammonium bromide

m-methylbenzyl-p-methylphenyldimethylammonium bromide

A

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

B

Dimethyl-p-toluidine
99-97-8

Dimethyl-p-toluidine

Conditions
ConditionsYield
In acetone at 45℃; Rate constant; Equilibrium constant;
m-methylbenzyl-m-methylphenyldimethylammonium bromide

m-methylbenzyl-m-methylphenyldimethylammonium bromide

A

N,N-dimethyl-m-toluidine
121-72-2

N,N-dimethyl-m-toluidine

B

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

Conditions
ConditionsYield
In acetone at 45℃; Rate constant; Equilibrium constant;
m-methylbenzyl-p-bromophenyldimethylammonium bromide

m-methylbenzyl-p-bromophenyldimethylammonium bromide

A

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

B

4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

Conditions
ConditionsYield
In acetone at 45℃; Rate constant; Equilibrium constant;
m-methylbenzyl-m-chlorophenyldimethylammonium bromide

m-methylbenzyl-m-chlorophenyldimethylammonium bromide

A

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

B

3-chloro-N,N-dimethylaniline
6848-13-1

3-chloro-N,N-dimethylaniline

Conditions
ConditionsYield
In acetone at 45℃; Rate constant; Equilibrium constant;
m-xylene
108-38-3

m-xylene

1 mol tetrabromomethane

1 mol tetrabromomethane

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

Conditions
ConditionsYield
at 150 - 180℃;
bromine
7726-95-6

bromine

m-xylene
108-38-3

m-xylene

A

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

B

1,3-bis-(bromomethyl)benzene
626-15-3

1,3-bis-(bromomethyl)benzene

bromine
7726-95-6

bromine

m-xylene
108-38-3

m-xylene

A

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

B

1,3-bis-(bromomethyl)benzene
626-15-3

1,3-bis-(bromomethyl)benzene

C

ω.ω.ω'.ω'-tetrabromo-1.3-dimethyl-benzene

ω.ω.ω'.ω'-tetrabromo-1.3-dimethyl-benzene

Conditions
ConditionsYield
im Sonnenlicht;
bromine
7726-95-6

bromine

m-xylene
108-38-3

m-xylene

A

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

B

1,3-bis-(bromomethyl)benzene
626-15-3

1,3-bis-(bromomethyl)benzene

C

ω.ω.ω'-tribromo-m-xylene

ω.ω.ω'-tribromo-m-xylene

tetrachloromethane
56-23-5

tetrachloromethane

3,5-dimethylenecyclohexene
38461-17-5

3,5-dimethylenecyclohexene

bromine
7726-95-6

bromine

sodium hydrogencarbonate

sodium hydrogencarbonate

A

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

B

1,3-bis-(bromomethyl)benzene
626-15-3

1,3-bis-(bromomethyl)benzene

bromocyane
506-68-3

bromocyane

N-benzyl-N-methyl-1-(m-tolyl)methanamine
20441-10-5

N-benzyl-N-methyl-1-(m-tolyl)methanamine

A

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

B

N-benzyl-N-methyl cyanamide
34065-04-8

N-benzyl-N-methyl cyanamide

C

methyl-benzyl-bis-<3-methyl-benzyl>-ammonium bromide

methyl-benzyl-bis-<3-methyl-benzyl>-ammonium bromide

Bromotrichloromethane
75-62-7

Bromotrichloromethane

<3-MeC6H4CH2Co(dmgH)2Py>

<3-MeC6H4CH2Co(dmgH)2Py>

A

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

B

1-Methyl-3-(2,2,2-trichloro-ethyl)-benzene

1-Methyl-3-(2,2,2-trichloro-ethyl)-benzene

Conditions
ConditionsYield
With 1H-imidazole In chloroform at 70℃; for 3h; Title compound not separated from byproducts;
triethyl borate
150-46-9

triethyl borate

carbon monoxide
201230-82-2

carbon monoxide

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

ethyl m-methylphenylacetate
40061-55-0

ethyl m-methylphenylacetate

Conditions
ConditionsYield
1,5-hexadienerhodium(I)-chloride dimer at 75℃; under 760 Torr; Heating; overnight; other solvent;100%
tri-n-propyl borate
688-71-1

tri-n-propyl borate

carbon monoxide
201230-82-2

carbon monoxide

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

m-Tolyl-acetic acid propyl ester
93579-00-1

m-Tolyl-acetic acid propyl ester

Conditions
ConditionsYield
1,5-hexadienerhodium(I)-chloride dimer at 75℃; under 760 Torr; Heating; overnight; other solvent;100%
tris(trimethylsilyl) phosphite
1795-31-9

tris(trimethylsilyl) phosphite

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

bis(trimethylsilyl) 3-methylbenzylphosphonate
368454-35-7

bis(trimethylsilyl) 3-methylbenzylphosphonate

Conditions
ConditionsYield
In toluene at 95℃; for 4h; Michaelis-Arbuzov reaction;100%
In toluene at 95℃; for 4h; Michaelis-Arbuzov reaction;100 % Spectr.
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

2,3-bis(methoxycarbonyl)phenol
36669-02-0

2,3-bis(methoxycarbonyl)phenol

3-(3-methyl-benzyloxy)-phthalic acid dimethyl ester
1061605-99-9

3-(3-methyl-benzyloxy)-phthalic acid dimethyl ester

Conditions
ConditionsYield
With potassium carbonate In acetone Heating / reflux;100%
N-[4-(2-amino-4-hydroxy-phenylsulfanyl)-phenyl]-acetamide
943620-65-3

N-[4-(2-amino-4-hydroxy-phenylsulfanyl)-phenyl]-acetamide

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

N-{4-[2-amino-4-(3-methyl-benzyloxy)-phenylsulfanyl]-phenyl}-acetamide
943617-50-3

N-{4-[2-amino-4-(3-methyl-benzyloxy)-phenylsulfanyl]-phenyl}-acetamide

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 15h;100%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

4-nitro-aniline
100-01-6

4-nitro-aniline

bis(3-methylbenzyl)(4-nitrophenyl)amine
1032373-71-9

bis(3-methylbenzyl)(4-nitrophenyl)amine

Conditions
ConditionsYield
With potassium carbonate; sodium iodide In N,N-dimethyl-formamide at 100℃; for 24h; Inert atmosphere;100%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

1-hydroxy-3,6,7-tris(methoxymethoxy)-9H-xanthen-9-one
1314917-55-9

1-hydroxy-3,6,7-tris(methoxymethoxy)-9H-xanthen-9-one

C27H28O9
1314917-77-5

C27H28O9

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 6h;100%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

methyl 3-chloro-1H-indole-4-carboxylate

methyl 3-chloro-1H-indole-4-carboxylate

C18H16ClNO2

C18H16ClNO2

Conditions
ConditionsYield
With sodium hydride at 0℃; for 5h;100%
4-nitro-1H-indoIe
4769-97-5

4-nitro-1H-indoIe

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

C16H14N2O2

C16H14N2O2

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 3.15h;100%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

triphenylphosphine
603-35-0

triphenylphosphine

(3-methylbenzyl)(triphenyl)phosphonium bromide
1702-41-6

(3-methylbenzyl)(triphenyl)phosphonium bromide

Conditions
ConditionsYield
In chloroform for 2h; Heating;99%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

3,6-Diisopropyl-2-pyrazinethiol
86799-80-6

3,6-Diisopropyl-2-pyrazinethiol

2-(3-methylbenzylthio)-3,6-diisopropylpyrazine
120061-26-9

2-(3-methylbenzylthio)-3,6-diisopropylpyrazine

Conditions
ConditionsYield
With sodium carbonate99%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

(3-Hydroxy-propyl)-[2-((3-methyl-benzyl)-{6-[(3-trifluoromethyl-benzylamino)-methyl]-pyridin-2-ylmethyl}-amino)-ethyl]-carbamic acid tert-butyl ester
204196-32-7

(3-Hydroxy-propyl)-[2-((3-methyl-benzyl)-{6-[(3-trifluoromethyl-benzylamino)-methyl]-pyridin-2-ylmethyl}-amino)-ethyl]-carbamic acid tert-butyl ester

(3-Hydroxy-propyl)-{2-[(3-methyl-benzyl)-(6-{[(3-methyl-benzyl)-(3-trifluoromethyl-benzyl)-amino]-methyl}-pyridin-2-ylmethyl)-amino]-ethyl}-carbamic acid tert-butyl ester
204196-35-0

(3-Hydroxy-propyl)-{2-[(3-methyl-benzyl)-(6-{[(3-methyl-benzyl)-(3-trifluoromethyl-benzyl)-amino]-methyl}-pyridin-2-ylmethyl)-amino]-ethyl}-carbamic acid tert-butyl ester

Conditions
ConditionsYield
With potassium carbonate In acetonitrile Ambient temperature;99%
2-bromo-pyridin-3-ol
6602-32-0

2-bromo-pyridin-3-ol

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

2-bromo-3-((3-methylbenzyl)oxy)pyridine

2-bromo-3-((3-methylbenzyl)oxy)pyridine

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 60℃; for 15.5h;99%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

4-(3-methyl-5-oxo-4H-pyrazol-1-yl)-N-(pyridine-4-ylmethyl)benzamide

4-(3-methyl-5-oxo-4H-pyrazol-1-yl)-N-(pyridine-4-ylmethyl)benzamide

4-({[4-(3-methyl-5-oxo-4H-pyrazol-1-yl)phenyl]formamido}methyl)-1-[(3-methylphenyl)methyl]pyridin-1-ium bromide

4-({[4-(3-methyl-5-oxo-4H-pyrazol-1-yl)phenyl]formamido}methyl)-1-[(3-methylphenyl)methyl]pyridin-1-ium bromide

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 40 - 50℃;98.3%
methyl N-[4'-(trifluoromethoxy)biphenyl-4-yl]oxamate
1019996-87-2

methyl N-[4'-(trifluoromethoxy)biphenyl-4-yl]oxamate

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

methyl N-(3-methylbenzyl)-N-[4'-(trifluoromethoxy)biphenyl-4-yl]oxamate
1019996-90-7

methyl N-(3-methylbenzyl)-N-[4'-(trifluoromethoxy)biphenyl-4-yl]oxamate

Conditions
ConditionsYield
With potassium carbonate; 18-crown-6 ether In acetonitrile at 50℃; for 3h;98%
With 18-crown-6 ether; potassium carbonate In acetonitrile at 50℃; for 3h; Inert atmosphere;98%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

phenyltriisopropoxytitanium(IV)
16635-23-7

phenyltriisopropoxytitanium(IV)

1-methyl-3-(phenylmethyl)-benzene
620-47-3

1-methyl-3-(phenylmethyl)-benzene

Conditions
ConditionsYield
With palladium diacetate; Tri(p-tolyl)phosphine In toluene at 25℃; for 2h; Inert atmosphere;98%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

phenylacetylene
536-74-3

phenylacetylene

1-(3-methyl-benzyl)-4-phenyl-1H-[1,2,3]triazole

1-(3-methyl-benzyl)-4-phenyl-1H-[1,2,3]triazole

Conditions
ConditionsYield
With sodium azide In water at 23 - 25℃; for 24h; Inert atmosphere; Schlenk technique; Green chemistry;98%
8-chlorotheophylline
85-18-7

8-chlorotheophylline

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

8-chloro-1,3-dimethyl-7-(3-methylbenzyl)-1H-purine-2,6-(3H,7H)-dione

8-chloro-1,3-dimethyl-7-(3-methylbenzyl)-1H-purine-2,6-(3H,7H)-dione

Conditions
ConditionsYield
Stage #1: 8-chlorotheophylline With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.0833333h;
Stage #2: 1-bromomethyl-3-methyl-benzene In N,N-dimethyl-formamide at 20 - 60℃; for 2.5h;
98%
Stage #1: 8-chlorotheophylline With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.0833333h;
Stage #2: 1-bromomethyl-3-methyl-benzene In N,N-dimethyl-formamide at 20 - 60℃; for 2.5h;
98%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

7-hydroxy-2-oxo-2H-chromene-3-carboxylic acid ethyl ester
6093-71-6

7-hydroxy-2-oxo-2H-chromene-3-carboxylic acid ethyl ester

ethyl 7-((3-methylbenzyl)oxy)-2-oxo-2H-chromene-3-carboxylate

ethyl 7-((3-methylbenzyl)oxy)-2-oxo-2H-chromene-3-carboxylate

Conditions
ConditionsYield
Stage #1: 7-hydroxy-2-oxo-2H-chromene-3-carboxylic acid ethyl ester With potassium carbonate In N,N-dimethyl-formamide at 20℃;
Stage #2: 1-bromomethyl-3-methyl-benzene In N,N-dimethyl-formamide at 20℃; for 48h;
98%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

3-methylbenzyl 2-oxo-2-phenylacetate

3-methylbenzyl 2-oxo-2-phenylacetate

Conditions
ConditionsYield
With [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride; 5,10,15,20-tetraphenyl-21H,23H-porphine; bis(triphenylphosphane)copper(I) nitrate; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In acetonitrile at 80℃; for 10h; Catalytic behavior; Temperature; Solvent; Reagent/catalyst;97.7%
methanol
67-56-1

methanol

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

α-methoxy-m-xylene
7116-51-0

α-methoxy-m-xylene

Conditions
ConditionsYield
With silver(II) oxide for 0.5h; Heating;97%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

7-(tert-butoxycarbonyl)-3,7,12,18-tetraazabicyclo[12.3.1]octadeca-1(18),14,16-triene
182576-19-8

7-(tert-butoxycarbonyl)-3,7,12,18-tetraazabicyclo[12.3.1]octadeca-1(18),14,16-triene

3,12-Bis-(3-methyl-benzyl)-3,7,12,18-tetraaza-bicyclo[12.3.1]octadeca-1(18),14,16-triene-7-carboxylic acid tert-butyl ester
189182-04-5

3,12-Bis-(3-methyl-benzyl)-3,7,12,18-tetraaza-bicyclo[12.3.1]octadeca-1(18),14,16-triene-7-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
With potassium carbonate In acetonitrile Ambient temperature;97%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

(3-Hydroxy-propyl)-[2-((3-trifluoromethyl-benzyl)-{6-[(3-trifluoromethyl-benzylamino)-methyl]-pyridin-2-ylmethyl}-amino)-ethyl]-carbamic acid tert-butyl ester
204196-39-4

(3-Hydroxy-propyl)-[2-((3-trifluoromethyl-benzyl)-{6-[(3-trifluoromethyl-benzylamino)-methyl]-pyridin-2-ylmethyl}-amino)-ethyl]-carbamic acid tert-butyl ester

(3-Hydroxy-propyl)-{2-[(6-{[(3-methyl-benzyl)-(3-trifluoromethyl-benzyl)-amino]-methyl}-pyridin-2-ylmethyl)-(3-trifluoromethyl-benzyl)-amino]-ethyl}-carbamic acid tert-butyl ester
204196-42-9

(3-Hydroxy-propyl)-{2-[(6-{[(3-methyl-benzyl)-(3-trifluoromethyl-benzyl)-amino]-methyl}-pyridin-2-ylmethyl)-(3-trifluoromethyl-benzyl)-amino]-ethyl}-carbamic acid tert-butyl ester

Conditions
ConditionsYield
With potassium carbonate In acetonitrile Ambient temperature;97%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

1-(azidomethyl)-3-methylbenzene
126799-82-4

1-(azidomethyl)-3-methylbenzene

Conditions
ConditionsYield
With sodium azide In N,N-dimethyl-formamide at 20 - 80℃; for 4h;97%
With sodium azide In dimethyl sulfoxide at 20℃; for 24h;94%
With sodium azide In water; acetone at 20 - 60℃;
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

potassium phenyltrifluoborate

potassium phenyltrifluoborate

1-methyl-3-(phenylmethyl)-benzene
620-47-3

1-methyl-3-(phenylmethyl)-benzene

Conditions
ConditionsYield
With [Pd(N-(3-chloro-2-quinoxalinyl)-N'-(2,6-diisopropylphenyl)imidazolium)(PPh3)Cl2]; potassium carbonate In water at 70℃; for 3h; Catalytic behavior; Suzuki-Miyaura Coupling;97%
bis(4-hydroxyphenyl)disulfide
15015-57-3

bis(4-hydroxyphenyl)disulfide

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

C28H26O2S2

C28H26O2S2

Conditions
ConditionsYield
With potassium carbonate In acetone at 60℃; Inert atmosphere;97%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

4-n-methylphenylacetylene
766-97-2

4-n-methylphenylacetylene

1-(3-methylbenzyl)-4-(p-tolyl)-1H-1,2,3-triazole

1-(3-methylbenzyl)-4-(p-tolyl)-1H-1,2,3-triazole

Conditions
ConditionsYield
With sodium azide In methanol; water at 70℃; for 4h;97%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

6-methoxy-1-(pyridin-2-yl)-9H-pyrido[3,4-b]indole

6-methoxy-1-(pyridin-2-yl)-9H-pyrido[3,4-b]indole

1-pyridin-2-yl-6-methoxy-9-(3-methylbenzyl)-β-carboline

1-pyridin-2-yl-6-methoxy-9-(3-methylbenzyl)-β-carboline

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; silver(l) oxide In acetonitrile at 55℃;96.2%
Stage #1: 6-methoxy-1-(pyridin-2-yl)-9H-pyrido[3,4-b]indole With sodium hydride In N,N-dimethyl-formamide at 20℃; for 0.333333h;
Stage #2: 1-bromomethyl-3-methyl-benzene In N,N-dimethyl-formamide at 20℃; for 0.333333h; Temperature; Concentration;
85.8%
para-xylene
106-42-3

para-xylene

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

1,4-dimethyl-2-(3-methylbenzyl) benzene
61819-81-6

1,4-dimethyl-2-(3-methylbenzyl) benzene

Conditions
ConditionsYield
With indium(III) chloride; 4 A molecular sieve In dichloromethane at 20℃; for 16h; Friedel-Crafts alkylation;96%
1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

phenylacetylene
536-74-3

phenylacetylene

1‐(3‐methylbenzyl)‐4‐phenyl‐1H‐1,2,3‐triazole
126800-03-1

1‐(3‐methylbenzyl)‐4‐phenyl‐1H‐1,2,3‐triazole

Conditions
ConditionsYield
With sodium azide In methanol; water at 70℃; for 2h;96%
With choline azide at 75℃; for 0.416667h; Green chemistry;95%
With sodium azide In water for 0.333333h; Reflux; regioselective reaction;91%
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