As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch
Cas:6935-27-9
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inquiryItems Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------
Cas:6935-27-9
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inquiry2-Benzylaminopyridine CAS:6935-27-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
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Cas:6935-27-9
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
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inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Cas:6935-27-9
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
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Cas:6935-27-9
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Cas:6935-27-9
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inquiry2-benzylaminopyridine Melting point 95-97 °C (lit.) Boiling point 116-131 °C0.6 mm Hg(lit.) Flash point 182 ° C / 12mm Storage conditions Store below +30°C. BRN 134309 CAS Database 6935-27-9 (CAS DataBase Reference) EP
Cas:6935-27-9
Min.Order:100 Gram
Negotiable
Type:Lab/Research institutions
inquiryProduct Name: 2-Benzylaminopyridine Synonyms: BENZYL-PYRIDIN-2-YL-AMINE;AURORA KA-4160;ALPHA-BENZYLAMINOPYRIDINE;n-(phenylmethyl)-2-pyridinamin;N-(2-Pyridine)benzylamine;N-Benzyl-2-pyridinamine;N-Benzyl-2-pyridylamine~N-(2-Pyridyl)benzylamine;2
Cas:6935-27-9
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
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We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Cas:6935-27-9
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inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
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Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands
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Min.Order:100 Gram
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inquiryAcmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea
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inquiryhigh quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
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Conditions | Yield |
---|---|
With dichloro-[1,3-bis(4-tert-butylbenzyl)perhydrobenzimidazol-2-ylidene](p-cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube; | 100% |
With potassium tert-butylate; copper diacetate In 1,4-dioxane at 130℃; for 24h; | 99% |
With potassium tert-butylate; copper diacetate In 1,4-dioxane at 130℃; for 24h; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With sodium t-butanolate In toluene at 100 - 110℃; for 24h; Buchwald-Hartwig amination; Inert atmosphere; Sealed vial; | 99% |
With potassium phosphate In dimethyl sulfoxide at 80℃; UV-irradiation; | 95% |
With copper(l) iodide; C14H16N2O; caesium carbonate In N,N-dimethyl-formamide at 130℃; for 24h; Inert atmosphere; Sealed tube; | 93% |
Conditions | Yield |
---|---|
With cesium acetate; copper In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere; | 99% |
With copper(l) iodide; 1-tetralone oxime; potassium hydroxide In water at 25℃; for 18h; Sealed tube; Inert atmosphere; Green chemistry; | 93% |
With tetra(n-butyl)ammonium hydroxide; copper(II) sulfate In water at 80℃; for 24h; Schlenk technique; Sealed tube; Inert atmosphere; | 80% |
With tetramethyl ammoniumhydroxide; ethyl 2-oxocyclohexane carboxylate; copper(l) chloride In dimethyl sulfoxide at 80℃; for 24h; Inert atmosphere; | 72% |
N-benzylidenepyridin-2-amine
N-benzylpyridin-2-amine
Conditions | Yield |
---|---|
With Triethoxysilane; [bis(2,6-diisopropylaniline)acenaphthene]Fe(η6-toluene) at 70℃; for 18h; Schlenk technique; Inert atmosphere; Glovebox; Sealed tube; | 98% |
With (4-Ph)Triaz(NHPiPr2)2Mn(CO)2Br; potassium tert-butylate; hydrogen In tetrahydrofuran at 50℃; under 15001.5 Torr; for 4h; Glovebox; Autoclave; Sealed tube; chemoselective reaction; | 92% |
With sodium tetrahydroborate In tetrahydrofuran at 25℃; for 4h; | 40% |
With sodium tetrahydroborate In methanol for 5h; Cooling; | 19.09 g |
With [MnBr(CO)3(2-(diphenylphosphinoamino)pyridine)]; potassium tert-butylate; hydrogen In ethanol at 80℃; for 48h; Autoclave; | 50.7 mg |
methyl benzylpyridin-2-ylcarbamate
N-benzylpyridin-2-amine
Conditions | Yield |
---|---|
With water; sodium hydroxide In methanol for 3h; Reflux; | 98% |
benzyl-pyridin-2-yl-carbamic acid tert-butyl ester
N-benzylpyridin-2-amine
Conditions | Yield |
---|---|
With trifluoroacetic acid In dichloromethane; water | 97% |
With trifluoroacetic acid In dichloromethane; water at 25℃; |
Conditions | Yield |
---|---|
With dibenzylphosphoramidous acid 1,1'-binaphthyl-2,2'-diyl ester; caesium carbonate; copper(I) bromide In N,N-dimethyl-formamide at 90℃; for 36h; | 97% |
With copper(l) iodide; 1-tetralone oxime; potassium hydroxide In water at 65℃; for 18h; Sealed tube; Inert atmosphere; Green chemistry; | 95% |
With cesium acetate; copper In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere; | 92% |
N-benzyl-N-(pyridin-2-yl)hydroxylamine
N-benzylpyridin-2-amine
Conditions | Yield |
---|---|
With palladium 10% on activated carbon; hydrogen In methanol at 20℃; under 760.051 Torr; for 0.5h; Inert atmosphere; | 97% |
Conditions | Yield |
---|---|
With [RuCl(CO)(PPh3)(PNS-Me)]; potassium hydroxide In toluene at 100℃; for 12h; | 96% |
With bis(5-chlorosalicylidene)hydrazone binuclear copper(I) complex; potassium hydroxide In toluene at 100℃; for 18h; | 80% |
With aluminum (III) chloride; water In acetonitrile at 20℃; Irradiation; | 50% |
Conditions | Yield |
---|---|
With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; silver trifluoromethanesulfonate In dichloromethane at 20℃; for 2h; | 93% |
With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate In neat (no solvent) at 150℃; for 0.25h; | 92% |
With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; thiourea In toluene at 70℃; for 24h; | 91% |
2-aminopyridine
para-Chlorobenzyl alcohol
A
N-benzylpyridin-2-amine
B
N-[(4-chlorophenyl)methyl]pyridin-2-amine
Conditions | Yield |
---|---|
With potassium tert-butylate; copper diacetate In 1,4-dioxane at 130℃; for 24h; | A 8% B 90% |
With cesium hydroxide; palladium diacetate In toluene at 150℃; for 12h; | A 19% B 74% |
N-(pyridin-2-yl)benzimidamide
benzyl alcohol
A
N-benzylpyridin-2-amine
B
benzamide
Conditions | Yield |
---|---|
With potassium hydroxide In toluene at 120℃; for 15h; Schlenk technique; Glovebox; Inert atmosphere; Sealed tube; | A 82% B 94 %Chromat. |
N-benzylpyridin-2-amine
Conditions | Yield |
---|---|
With sodium hydride In N,N-dimethyl-formamide at 0 - 60℃; for 3h; Julia-Kocienski Olefination; | 80% |
2-<α-(p-tolylthio)benzylamino>pyridine
N-benzylpyridin-2-amine
Conditions | Yield |
---|---|
With sodium tetrahydroborate In 1,2-dimethoxyethane for 1h; Heating; | 75% |
N-benzylpyridin-2-amine
Conditions | Yield |
---|---|
With acetic acid; zinc at 20℃; for 29h; Reduction; | 75% |
2-aminopyridine
N-butylamine
benzyl alcohol
A
N-benzylpyridin-2-amine
B
N-benzylidenebutan-1-amine
Conditions | Yield |
---|---|
With iron(II,III) oxide; potassium tert-butylate In 1,4-dioxane at 90℃; for 168h; Inert atmosphere; | A 74% B 26% |
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine; bromo-tris(1-pyrrolidinyl)phosphonium hexafluorophosphate In dichloromethane at 25℃; for 15h; | 70% |
Conditions | Yield |
---|---|
With oxygen; lithium carbonate; copper(II) bis(trifluoromethanesulfonate) In toluene at 100℃; under 760.051 Torr; for 12h; Schlenk technique; | 62% |
With sodium hydrogencarbonate In tetrahydrofuran at 20℃; Inert atmosphere; | 56% |
benzylamine
pyridin-2-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate
N-benzylpyridin-2-amine
Conditions | Yield |
---|---|
In dimethyl sulfoxide at 100℃; for 24h; | 60% |
2-aminopyridine
benzylamine
A
N-benzylpyridin-2-amine
B
tribenzylamine
C
dibenzylamine
Conditions | Yield |
---|---|
With C4F9SO3H at 200℃; for 42h; Yields of byproduct given; | A 54% B n/a C n/a |
Conditions | Yield |
---|---|
With di-tert-butyl peroxide; copper In neat (no solvent) at 120℃; for 12h; Inert atmosphere; Schlenk technique; | 51% |
Conditions | Yield |
---|---|
With cesium acetate; copper In dimethyl sulfoxide at 110℃; for 24h; Inert atmosphere; | 50% |
In 1-methyl-pyrrolidin-2-one at 150℃; for 0.25h; Flow reactor; |
2-aminopyridine
benzyl chloride
A
N-benzylpyridin-2-amine
B
2-Benzylamino-5-benzylpyridine
Conditions | Yield |
---|---|
1) 180 to 250 deg C, 3 h, 2) 250 deg C, 0.5 h; | A 20% B 41% |
2-(Dimethylamino)pyridine
benzyl chloride
A
N-benzylpyridin-2-amine
B
N-benzyl-N-methyl-N-(2-pyridyl)amine
C
2-Benzylamino-5-benzylpyridine
D
2-(N,N-dibenzylamino)pyridine
Conditions | Yield |
---|---|
at 250℃; for 4h; | A 15% B 21% C 4.7% D 19% |
benzyl chloride
A
N-benzylpyridin-2-amine
B
2-amino-5-benzylpyridine
C
N-benzyl-N-methyl-N-(2-pyridyl)amine
D
2-(N,N-dibenzylamino)pyridine
Conditions | Yield |
---|---|
at 250℃; for 4h; Further byproducts given; | A 17% B 4.3% C 20% D 14% |
benzyl chloride
A
N-benzylpyridin-2-amine
B
N-benzyl-N-methyl-N-(2-pyridyl)amine
C
2-Benzylamino-5-benzylpyridine
D
2-(N,N-dibenzylamino)pyridine
Conditions | Yield |
---|---|
at 250℃; for 4h; Further byproducts given; | A 17% B 20% C 14% D 12% |
2-aminopyridine
benzoic acid benzyl ester
A
N-benzyl-2-pyridone
B
N-benzylpyridin-2-amine
C
benzamide
D
benzoic acid
Conditions | Yield |
---|---|
at 190 - 200℃; anschliessend Behandeln mit wss. Salzsaeure; |
2-aminopyridine
formic acid
benzaldehyde
N-benzylpyridin-2-amine
bis(1,5-cyclooctadiene)diiridium(I) dichloride
N-benzylpyridin-2-amine
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 7h; | 100% |
N-benzylpyridin-2-amine
Conditions | Yield |
---|---|
In neat (no solvent) stirring at 120°C, 16h; sublimating excess ligand; repeating heating with fresh benzylaminopyridine; collecting; washing (acetone, methanol, diethyl ether); drying (vac., 80°C); elem. anal.; | 97% |
Conditions | Yield |
---|---|
With 1,1,1,3',3',3'-hexafluoro-propanol; bis(tertbutylcarbonyloxy)iodobenzene at 25℃; for 7h; Reagent/catalyst; Solvent; | 97% |
Conditions | Yield |
---|---|
Stage #1: N-benzylpyridin-2-amine With methylmagnesium chloride In tetrahydrofuran at 20℃; for 0.166667h; Stage #2: acetyl chloride In tetrahydrofuran at 20℃; for 1h; | 94% |
N-benzylpyridin-2-amine
Conditions | Yield |
---|---|
In chlorobenzene for 3h; Reflux; | 93% |
N-benzylpyridin-2-amine
(butane-1-sulfenyl)-dipropyl-borane
(C3H7)2BN(CH2C6H5)(2-C5H4N)
Conditions | Yield |
---|---|
In dichloromethane byproducts: C4H9SH; | 92% |
In dichloromethane byproducts: C4H9SH; | 92% |
N-benzylpyridin-2-amine
benzyl(5-bromopyridin-2-yl)amine
Conditions | Yield |
---|---|
With dihydrogen peroxide; 1-butylpyridinium bromide; toluene-4-sulfonic acid In 1,2-dimethoxyethane at 80℃; for 24h; Reagent/catalyst; Schlenk technique; Inert atmosphere; Green chemistry; regioselective reaction; | 91% |
N-benzylpyridin-2-amine
bis(2,4,6-trichlorophenyl) ethylmalonate
Conditions | Yield |
---|---|
at 180℃; for 0.0833333h; Cyclization; | 86% |
at 160℃; for 0.0666667h; Condensation; | 70% |
formaldehyd
N-benzylpyridin-2-amine
diphenylphosphane
2-(N-diphenylphosphinomethyl-N-benzyl)aminopyridine
Conditions | Yield |
---|---|
With acetic acid In toluene at 70 - 80℃; for 6h; | 86% |
Conditions | Yield |
---|---|
With sulfuric acid for 24h; Ambient temperature; | 85% |
With 9,10-Dicyanoanthracene In water; acetonitrile Irradiation; | 75% |
N-benzylpyridin-2-amine
benzyl chloride
2-(N,N-dibenzylamino)pyridine
Conditions | Yield |
---|---|
With sodium amide In toluene | 83% |
N-benzylpyridin-2-amine
chlorocarbonyl-diazo-acetic acid ethyl ester
Conditions | Yield |
---|---|
83% |
N-benzylpyridin-2-amine
A
benzo[4,5]imidazo[1,2-a]pyridine
B
8-methyl-4-chloropyrido[1,2-a]benzimidazole
Conditions | Yield |
---|---|
With 1,1,1,3',3',3'-hexafluoro-propanol; bis(tertbutylcarbonyloxy)iodobenzene at 25℃; for 7h; | A 83% B 79% |
N-benzylpyridin-2-amine
(6R,8R)-(-)-2-chloro-5,6,7,8,-tetrahydro-7,7-dimethyl-[6,8-methanoquinoline]
Conditions | Yield |
---|---|
With 1,3-bis-(diphenylphosphino)propane; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate; tetrabutylammomium bromide In toluene at 100℃; Buchwald-Hartwig amination reaction; | 81% |
N-benzylpyridin-2-amine
phenylacetylene
phenyl-(2-phenylimidazo[1,2-a]pyridin-3-yl)methanone
Conditions | Yield |
---|---|
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen; lithium carbonate; copper(II) bis(trifluoromethanesulfonate) In toluene at 100℃; under 760.051 Torr; for 12h; Schlenk technique; | 81% |
N-benzylpyridin-2-amine
pivaloyl chloride
N-benzyl-N-(pyridin-2-yl)pivalamide
Conditions | Yield |
---|---|
Stage #1: N-benzylpyridin-2-amine With methylmagnesium chloride In tetrahydrofuran at 20℃; for 0.166667h; Stage #2: pivaloyl chloride In tetrahydrofuran at 20℃; for 1h; | 79% |
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