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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2',6'-Dihydroxyacetophenone supplier in China

Cas:699-83-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2',6'-dihydroxyacetophenone

Cas:699-83-2

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

2',6'-Dihydroxyacetophenone CAS 699-83-2 1-(2,6-dihydroxyphenyl)ethanone CAS no 699-83-2 2-Acetylresorcinol 2',6'-Dihydroxyacetophenone CAS 699-83-2 1-(2,6-dihydroxyphenyl)ethanone IN Stock CAS 699-83-2 2',6'-Dihydroxyac

2',6'-Dihydroxyacetophenone CAS 699-83-2 1-(2,6-dihydroxyphenyl)ethanone CAS no 699-83-2 2-Acetylresorcinol

Cas:699-83-2

Min.Order:5 Kiloliter

FOB Price: $3.5 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

2',6'-Dihydroxyacetophenone 699-83-2

Cas:699-83-2

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

2',6'-Dihydroxyacetophenone 699-83-2

Cas:699-83-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 699-83-2 with fast shipping

Cas:699-83-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

2',6'-Dihydroxyacetophenone cas699-83-2

Cas:699-83-2

Min.Order:1 Kilogram

FOB Price: $7.0 / 9.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name 2',6'-Dihydroxyacetophenone Synonyms 1-(2,6-Dihydroxyphenyl)ethan-1-one; 2-Acetyl-1,3-dihydroxybenzene; 2-Acetylresorcinol CAS No. 699-83-2 EINEC

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2',6'-Dihydroxyacetophenone 699-83-2

Cas:699-83-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Pharmaceutical Intermediate,2',6'-Dihydroxyacetophenone CAS:699-83-2

Cas:699-83-2

Min.Order:1 Kilogram

FOB Price: $42.5 / 48.6

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

2',6'-Dihydroxyacetophenone CAS:699-83-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality

2',6'-Dihydroxyacetophenone CAS:699-83-2

Cas:699-83-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:699-83-2

Cas:699-83-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:1 Kilogram

FOB Price: $40.0 / 60.0

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:0

Negotiable

Type:Manufacturers

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HANWAYS CHEMPHARM CO.,LIMITED

We have two GMP facilities in Hubei Province and cooperative factories in Zhejiang Province We are concentrating on the R&D and technical service of APIs and pharmaceutical intermediates Appearance:white powder Storage:room temperature Pa

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

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Taizhou Crene Biotechnology co.ltd

Our company provides one-stop services of research - development - production for a variety of special prouducts. Not only do we make effective use of our strong technological strength, but also establish of cooperative relations with several well-

2',6'-Dihydroxyacetophenone 699-83-2

Cas:699-83-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2',6'-DIHYDROXYACETOPHENONE

Cas:699-83-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

Factory 2',6'-Dihydroxyacetophenone in stock CAS No.699-83-2Appearance:powder Storage:dry and cool place Package:according to customers' requirements Application:API ,Used as pharmaceutical intermediates Transportation:By air(EMS or EUB or FedEx or

Factory 2',6'-Dihydroxyacetophenone in stock CAS No.699-83-2

Cas:699-83-2

Min.Order:1 Gram

Negotiable

Type:Other

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 2',6'-Dihydroxyacetophenone CAS No.:699-83-2 Molecule Formula:C8H8O3 Molecule Weight:152.15 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard

Best Quality 2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, in

Enke 2',6'-Dihydroxyacetophenone

Cas:699-83-2

Min.Order:1 Kilogram

FOB Price: $300.0 / 400.0

Type:Lab/Research institutions

inquiry

Synthetic route

2,6-diacetoxyacetophenone
144152-28-3

2,6-diacetoxyacetophenone

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
With water; sodium acetate In ethanol for 5h; Reflux;92%
Resorcinol diacetate
108-58-7

Resorcinol diacetate

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
With hydrogen fluoride supported on silica gel In neat (no solvent) at 55℃; for 4h; Green chemistry;60%
With Fluoro Flash In neat (no solvent) at 80℃; for 4h; Catalytic behavior; Fries Phenol Ester Rearrangement; Green chemistry;
4,5-dihydroxy-2H-benzopyran-2-one
30992-74-6

4,5-dihydroxy-2H-benzopyran-2-one

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
With potassium hydroxide
8-acetyl-7-hydroxy-4-methyl-2H-chromen-2-one
2555-29-5

8-acetyl-7-hydroxy-4-methyl-2H-chromen-2-one

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
With sodium hydroxide
2,6-dimethoxyacetophenone
2040-04-2

2,6-dimethoxyacetophenone

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
With aluminium trichloride; chlorobenzene auf Siedetemperatur;
With aluminium trichloride; toluene at 120℃;
3-acetyl-2,4-dihydroxy-benzoic acid methyl ester
62970-17-6

3-acetyl-2,4-dihydroxy-benzoic acid methyl ester

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
With sodium hydroxide
2-acetyl-2-chloro-1,3-cyclohexanedione
52956-20-4

2-acetyl-2-chloro-1,3-cyclohexanedione

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
With hydrogenchloride In N,N-dimethyl-formamide
(i) HCl, DMF, (ii) aq. HCl; Multistep reaction;
With hydrogenchloride In d7-N,N-dimethylformamide at 120 - 130℃; for 0.333333h; Yield given;
acetic anhydride
108-24-7

acetic anhydride

ethyl acetoacetate
141-97-9

ethyl acetoacetate

recorcinol
108-46-3

recorcinol

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
Multistep reaction;
2-acetyl-1,3-cyclohexanedione enol
37514-00-4

2-acetyl-1,3-cyclohexanedione enol

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
With mercury(II) diacetate; sodium acetate In acetic acid
aluminium trichloride
7446-70-0

aluminium trichloride

2,6-dimethoxyacetophenone
2040-04-2

2,6-dimethoxyacetophenone

chlorobenzene
108-90-7

chlorobenzene

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

aluminium trichloride
7446-70-0

aluminium trichloride

2,6-dimethoxyacetophenone
2040-04-2

2,6-dimethoxyacetophenone

toluene
108-88-3

toluene

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

2,6-dimethoxybenzonitrile
16932-49-3

2,6-dimethoxybenzonitrile

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: toluene; diethyl ether / Erhitzen des vom Aether befreiten Reaktionsgemisches auf Siedetemperatur,anshcliessendes Behandeln mit Eis und wss.HCl und Erwaermen der erhaltenen wss.Loesung
2: AlCl3; chlorobenzene / auf Siedetemperatur
View Scheme
Multi-step reaction with 2 steps
1: toluene; diethyl ether / Erhitzen des vom Aether befreiten Reaktionsgemisches auf Siedetemperatur,anshcliessendes Behandeln mit Eis und wss.HCl und Erwaermen der erhaltenen wss.Loesung
2: AlCl3; toluene / 120 °C
View Scheme
NSC 251156
1795-39-7

NSC 251156

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aluminium chloride / 215 °C
2: aqueous KOH
View Scheme
recorcinol
108-46-3

recorcinol

phenoldiazonium chloride-(4)

phenoldiazonium chloride-(4)

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 250 °C
2: aluminium chloride / 215 °C
3: aqueous KOH
View Scheme
recorcinol
108-46-3

recorcinol

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

acetyl chloride
75-36-5

acetyl chloride

1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

recorcinol
108-46-3

recorcinol

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
With hydrogenchloride; aluminium trichloride
2-acetyl-1,3-cyclohexanedione
4056-73-9

2-acetyl-1,3-cyclohexanedione

hydrogen sulfide
7783-06-4

hydrogen sulfide

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
In toluene0.91 g (59 mole %)
tetraethylene glycol dimethyl ether

tetraethylene glycol dimethyl ether

2-acetyl-1,3-cyclohexanedione
4056-73-9

2-acetyl-1,3-cyclohexanedione

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
In isopropyl alcohol
acetyl chloride
75-36-5

acetyl chloride

recorcinol
108-46-3

recorcinol

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

Conditions
ConditionsYield
With aluminum (III) chloride In dichloromethane at 0 - 20℃; for 12h; Inert atmosphere;
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

1,3-chlorobromopropane
109-70-6

1,3-chlorobromopropane

2-(3-chlorophenoxy)-6-hydroxyacetophenone
105277-74-5

2-(3-chlorophenoxy)-6-hydroxyacetophenone

Conditions
ConditionsYield
With potassium carbonate In acetone for 24h; Heating;100%
With potassium carbonate In N,N-dimethyl-formamide at 70℃; for 4h;46%
With potassium carbonate In acetone
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

3-methyl-4-hydroxyindazole
149071-05-6

3-methyl-4-hydroxyindazole

Conditions
ConditionsYield
With hydrazine hydrate In ethylene glycol at 20 - 160℃; for 2.5h;100%
With hydrazine hydrate In ethylene glycol at 160℃; for 2h; Cyclization;68%
With hydrazine In ethylene glycol at 20 - 160℃; for 2.33333h;68%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

benzyl chloride
100-44-7

benzyl chloride

1-[2',6'-bis(phenylmethoxy)phenyl]ethanone
3886-19-9

1-[2',6'-bis(phenylmethoxy)phenyl]ethanone

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 65 - 100℃; for 18h;99%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

o-chlorobenzoyl chloride
609-65-4

o-chlorobenzoyl chloride

2',6'-bis(2-chlorobenzoyloxy)acetophenone
920006-37-7

2',6'-bis(2-chlorobenzoyloxy)acetophenone

Conditions
ConditionsYield
With pyridine; dmap at 20℃; for 2h;99%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

C14H24O3Si2
1146968-51-5

C14H24O3Si2

Conditions
ConditionsYield
Stage #1: 2,6-dihydroxylacetophenone With lithium diisopropyl amide In tetrahydrofuran
Stage #2: chloro-trimethyl-silane In tetrahydrofuran
99%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

methyl iodide
74-88-4

methyl iodide

2'-hydroxy-6'-methoxyacetophenone
703-23-1

2'-hydroxy-6'-methoxyacetophenone

Conditions
ConditionsYield
With potassium carbonate In acetone for 4h; Heating;98%
With potassium carbonate In acetone for 8h; Reflux;97%
With potassium carbonate In acetone at 55℃; for 8h;95%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

4-nitro-benzoyl chloride
122-04-3

4-nitro-benzoyl chloride

2',6'-bis(4-nitrobenzoyloxy)acetophenone
26505-98-6

2',6'-bis(4-nitrobenzoyloxy)acetophenone

Conditions
ConditionsYield
With pyridine at 20℃; for 12h;98%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

2′-hydroxy-6′-methoxymethoxyacetophenone
78646-28-3

2′-hydroxy-6′-methoxymethoxyacetophenone

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In dichloromethane for 4.5h;97.8%
With N-ethyl-N,N-diisopropylamine In dichloromethane for 0.5h;95%
With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃;92.8%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

dimethyl sulfate
77-78-1

dimethyl sulfate

2'-hydroxy-6'-methoxyacetophenone
703-23-1

2'-hydroxy-6'-methoxyacetophenone

Conditions
ConditionsYield
Stage #1: 2,6-dihydroxylacetophenone With potassium carbonate In acetone for 0.166667h;
Stage #2: dimethyl sulfate In acetone for 6h; Reflux;
96%
With potassium carbonate In acetone for 2h; Inert atmosphere; Reflux;96%
With potassium carbonate In acetone for 0.333333h; Reflux;95%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

2,6-bis(tert-butyldimethylsilyloxy)acetophenone
466635-70-1

2,6-bis(tert-butyldimethylsilyloxy)acetophenone

Conditions
ConditionsYield
With 1H-imidazole In N,N-dimethyl-formamide at 60℃; for 20h;96%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

6-methylheptan-2-one
928-68-7

6-methylheptan-2-one

5-hydroxy-2-methyl-2-(4-methylpentyl)chroman-4-one

5-hydroxy-2-methyl-2-(4-methylpentyl)chroman-4-one

Conditions
ConditionsYield
Stage #1: 6-methylheptan-2-one With pyrrolidine; butyric acid In dimethyl sulfoxide for 0.25h; Kabe Chromanone Synthesis;
Stage #2: 2,6-dihydroxylacetophenone In dimethyl sulfoxide at 20℃; for 3h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Kabe Chromanone Synthesis;
95%
With pyrrolidine In toluene Dean-Stark; Reflux;
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

4-methoxy-benzoyl chloride
100-07-2

4-methoxy-benzoyl chloride

2',6'-bis(4-methoxybenzoyloxy)acetophenone
58124-15-5

2',6'-bis(4-methoxybenzoyloxy)acetophenone

Conditions
ConditionsYield
With pyridine at 20℃; for 12h;94%
With pyridine
With pyridine for 2h;
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

pivaloyl chloride
3282-30-2

pivaloyl chloride

2-acetyl-1,3-phenylene bis(2,2-dimethylpropanoate)

2-acetyl-1,3-phenylene bis(2,2-dimethylpropanoate)

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 0 - 23℃; for 3h; Inert atmosphere;94%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide
572-09-8

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

2',6'-dihydroxyacetophenone 2'-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside)
23141-00-6

2',6'-dihydroxyacetophenone 2'-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside)

Conditions
ConditionsYield
With benzyltri(n-butyl)ammonium chloride; potassium carbonate In chloroform at 20℃; for 24h; glycosylation;93%
With benzyltri(n-butyl)ammonium chloride; potassium carbonate In chloroform; water at 20℃; for 27h;9%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

methyl chloroformate
79-22-1

methyl chloroformate

Carbonic acid 2-acetyl-3-methoxycarbonyloxy-phenyl ester methyl ester

Carbonic acid 2-acetyl-3-methoxycarbonyloxy-phenyl ester methyl ester

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran 0 deg C to room temp., 0.5 to 1 h;92%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

4-chloro-benzoyl chloride
122-01-0

4-chloro-benzoyl chloride

2',6'-bis(4-chlorobenzoyloxy)acetophenone
502916-43-0

2',6'-bis(4-chlorobenzoyloxy)acetophenone

Conditions
ConditionsYield
With pyridine at 20℃; for 12h;92%
With pyridine for 2h;
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

trans-p-methylcinnamic acid
1866-39-3

trans-p-methylcinnamic acid

2',6'-di(4-methylcinnamoyloxy)acetophenone

2',6'-di(4-methylcinnamoyloxy)acetophenone

Conditions
ConditionsYield
With 4-pyrrolidin-1-ylpyridine; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 0.5h;92%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

1-(2-((tert-butyldimethylsilyl)oxy)-6-hydroxyphenyl)ethanone
1193107-75-3

1-(2-((tert-butyldimethylsilyl)oxy)-6-hydroxyphenyl)ethanone

Conditions
ConditionsYield
With 1H-imidazole In N,N-dimethyl-formamide at 0 - 20℃; for 13h; Inert atmosphere;92%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

formic acid ethyl ester
109-94-4

formic acid ethyl ester

5-hydroxy-4H-1-benzopyran-4-one
3952-69-0

5-hydroxy-4H-1-benzopyran-4-one

Conditions
ConditionsYield
Stage #1: 2,6-dihydroxylacetophenone; formic acid ethyl ester With sodium ethanolate at 0 - 20℃; for 18h; Schlenk technique; Inert atmosphere;
Stage #2: With hydrogenchloride In methanol; water at 0 - 20℃; for 24h;
92%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

3-chloro-2.6-dihydroxyacetophenone
87953-93-3

3-chloro-2.6-dihydroxyacetophenone

Conditions
ConditionsYield
With sulfuryl dichloride In acetic acid for 2h; Heating;90.5%
With N-chloro-succinimide; acetic acid at 50℃; for 2h;81.5%
With thionyl chloride In acetic acid
With thionyl chloride In acetic acid
With N-chloro-succinimide; acetic acid at 50℃; for 2h;
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

2-ethylbenzene-1,3-diol
4074-50-4

2-ethylbenzene-1,3-diol

Conditions
ConditionsYield
With hydrogenchloride; sodium cyanoborohydride In methanol90%
With triethylsilane In trifluoroacetic acid at 20℃; for 3h; Inert atmosphere;81%
With triethylsilane; trifluoroacetic acid for 3h;78%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

t-butyl lithioacetate
150942-98-6

t-butyl lithioacetate

2,5-Dihydroxy-2-methyl-chroman-4-one

2,5-Dihydroxy-2-methyl-chroman-4-one

Conditions
ConditionsYield
In toluene at 100℃; for 2h;90%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

benzylamine
100-46-9

benzylamine

2,6-Dihydroxyphenylethylidenebenzylamine
82488-60-6

2,6-Dihydroxyphenylethylidenebenzylamine

Conditions
ConditionsYield
In toluene Heating; or ZnCl2, 1) 30 min, 160 deg C, 2) 5 min, 180 deg C;90%
In toluene Heating;90%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

trans-2,4-dichlorocinnamic acid
1201-99-6, 20595-45-3, 20595-46-4

trans-2,4-dichlorocinnamic acid

2',6'-di(2,4-dichlorocinnamoyloxy)acetophenone

2',6'-di(2,4-dichlorocinnamoyloxy)acetophenone

Conditions
ConditionsYield
With 4-pyrrolidin-1-ylpyridine; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 0.5h;90%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

ethyl bromoacetate
105-36-2

ethyl bromoacetate

ethyl 2-(2-acetyl-3-hydroxyphenoxy)acetate
6769-65-9

ethyl 2-(2-acetyl-3-hydroxyphenoxy)acetate

Conditions
ConditionsYield
With potassium carbonate In acetone at 60℃; for 2h;89%
With potassium carbonate In N,N-dimethyl-formamide for 3h; Ambient temperature;80%
With potassium carbonate In acetone for 3h; Reflux;61%
With potassium carbonate; acetone
With potassium carbonate In acetone at 60℃; for 15h;
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

benzyl bromide
100-39-0

benzyl bromide

1-[2',6'-bis(phenylmethoxy)phenyl]ethanone
3886-19-9

1-[2',6'-bis(phenylmethoxy)phenyl]ethanone

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 2.5h;89%
With potassium carbonate; sodium iodide In acetone for 18h; Heating;46%
With sodium iodide; potassium carbonate In acetone
With potassium carbonate In dimethyl sulfoxide at 20℃;
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

benzyl chloride
100-44-7

benzyl chloride

1-[2-(benzyloxy)-6-hydroxyphenyl]ethanone
4047-24-9

1-[2-(benzyloxy)-6-hydroxyphenyl]ethanone

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 0 - 70℃; Inert atmosphere;89%
With potassium carbonate In N,N-dimethyl-formamide for 24h;78%
With potassium hydroxide; potassium carbonate In butanone for 6h; Heating;68%
With potassium carbonate In N,N-dimethyl-formamide
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

trans-2-chlorocinnamic acid
704-96-1

trans-2-chlorocinnamic acid

2'-(2-chlorocinnamoyloxy)-6'-hydroxyacetophenone

2'-(2-chlorocinnamoyloxy)-6'-hydroxyacetophenone

Conditions
ConditionsYield
With 4-pyrrolidin-1-ylpyridine; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 0.5h;89%
2,6-dihydroxylacetophenone
699-83-2

2,6-dihydroxylacetophenone

1-dodecylbromide
143-15-7

1-dodecylbromide

1-(2-(dodecyloxy)-6-hydroxyphenyl)ethanone
1393845-50-5

1-(2-(dodecyloxy)-6-hydroxyphenyl)ethanone

Conditions
ConditionsYield
With potassium carbonate; sodium iodide In acetonitrile at 70 - 80℃;88%
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