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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

3-Methylfuran Manufacturer/High quality/Best price/In stock

Cas:930-27-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Methylfuran

Cas:930-27-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

High Quality Best price Fast Delivery Good Service Welcome to Henan Tianfu Chemical Co., Ltd. website. Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; developm

3-Methylfuran

Cas:930-27-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

3-Methylfuran CAS:930-27-8

Cas:930-27-8

Min.Order:1 Kilogram

FOB Price: $2.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 930-27-8 with competitive price

Cas:930-27-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Furan, 3-methyl-

Cas:930-27-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Furan, 3-methyl-

Cas:930-27-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Methylfurane

Cas:930-27-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-Methylfuran

Cas:930-27-8

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality moderate price & quick delivery Appearance:clear liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:3-Methylfuran is a vo

Furan, 3-methyl-

Cas:930-27-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Wuhan Fortuna Chemical Co.,Ltd

CAS:930-27-8 MW:82.1 MF:C5H6O Boiling point:65-66 °C Density:0.92 Appearance:colorless liquid Package:200kg/Steel drum Transportation:by sea Port:Shanghai

3-Methylfuran

Cas:930-27-8

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

3-Methylfuran

Cas:930-27-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

3-Methylfuran

Cas:930-27-8

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

3-Methylfuran

Cas:930-27-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

3-Methylfuran (stabilized with HQ)

Cas:930-27-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice.pls contact with us freely for getting detailed product spec

3-Methylfuran

Cas:930-27-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

3-Methylfuran (stabilized with HQ)

Cas:930-27-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:25kg,50kg,180kg,200kg,250kg,1000kg,customization Application:Pharma;Industry;Agricultural;chemical reaserch Tran

3-Methylfuran

Cas:930-27-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use

3-Methylfuran

Cas:930-27-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

3-Methylfuran cas 930-27-8Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

3-Methylfuran cas 930-27-8

Cas:930-27-8

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

3-Methylfuran

Cas:930-27-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

930-27-8

Cas:930-27-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

3-Methylfuran

Cas:930-27-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

3-Methylfuran

Cas:930-27-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Falcon Life Sciences Pvt. Ltd

Pharma Grade Application:Pharmaceutical Intermediate

3-Methylfuran

Cas:930-27-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#930-27-8;CAT#A844425

Cas:930-27-8

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Sun-shine Bio-technology Corporation Limited

Wuhan Sun-shine Bio-technology Corporation Limited is specializing in the anticancer, antitumor,heart head blood-vessel,pharmaceutical intermediates,fine Chemicals production and customization. Company has strong ability of research and development

3-Methylfuran

Cas:930-27-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

3-Methylfuran

Cas:930-27-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EnBridge PharmTech Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:yellow to white solid Storage:keep sealed and keep from direct light Package:According client's requirements Application:fine

3-Methylfuran manufacture

Cas:930-27-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Nanjing Chemlin Chemical Co., Ltd.

Nanjing Chemlin Chemical Industry Co., Ltd was established in Aug,1999, located in the industrial park of Nanjing University of Technology, It is a private enterprises in Jiangsu Province with 1200 square meters’ R&D center. Our R&D center has a well

930-27-8

Cas:930-27-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

(2Z)-2-methylbut-2-ene-1,4-diol
40560-13-2

(2Z)-2-methylbut-2-ene-1,4-diol

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
With oxygen; palladium diacetate; copper (I) acetate at 100℃; for 15h;77%
3-methylfuran-2-carboxylic acid
4412-96-8

3-methylfuran-2-carboxylic acid

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
With quinoline; copper at 260℃;70%
With quinoline at 165 - 180℃; for 2.5h; Inert atmosphere;68%
With quinoline; copper
furan-3-carboxaldehyde
498-60-2

furan-3-carboxaldehyde

A

3-methylfuran
930-27-8

3-methylfuran

B

3-methylene-2,3-dihydrofuran
153681-93-7

3-methylene-2,3-dihydrofuran

Conditions
ConditionsYield
With potassium hydroxide; hydrazine In water; ethylene glycol at 160 - 175℃;A n/a
B 63%
2-(2-propynyloxy)-4-methylenetetrahydrofuran
86491-44-3

2-(2-propynyloxy)-4-methylenetetrahydrofuran

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
With potassium hydrogensulfate In N,N-dimethyl-formamide Heating;60%
2-methylene-4-(trimethylsilyl)but-3-yn-1-ol
190662-01-2

2-methylene-4-(trimethylsilyl)but-3-yn-1-ol

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
With silver hexafluoroantimonate; (N'-(tbutyl)-N,N-diethylcarbamimidoyl)gold(I) chloride In dichloromethane at 20℃; for 72h;50%
2-methylene-4-(trimethylsilyl)but-3-yn-1-ol
190662-01-2

2-methylene-4-(trimethylsilyl)but-3-yn-1-ol

A

3-methylfuran
930-27-8

3-methylfuran

B

2-ethynylpropenol
84100-18-5

2-ethynylpropenol

Conditions
ConditionsYield
With silver hexafluoroantimonate; (N'-(tbutyl)-N,N-diethylcarbamimidoyl)gold(I) chloride In dichloromethane at 20℃; for 8h;A 50%
B 21%
3,4-epoxy-3-methylbutanal diethyl acetal

3,4-epoxy-3-methylbutanal diethyl acetal

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
With sulfuric acid Heating;47%
4-(5-Methyl-3,6-dihydro-[1,2]oxazin-2-yl)-benzoic acid methyl ester
82698-68-8

4-(5-Methyl-3,6-dihydro-[1,2]oxazin-2-yl)-benzoic acid methyl ester

A

3-methylfuran
930-27-8

3-methylfuran

B

Methyl 4-(2-methylpyrrol-1-yl)benzoate
149323-69-3

Methyl 4-(2-methylpyrrol-1-yl)benzoate

C

4-methoxycarbonyl aniline
619-45-4

4-methoxycarbonyl aniline

Conditions
ConditionsYield
In methanol Irradiation;A n/a
B n/a
C 24%
isoprene
78-79-5

isoprene

A

3-methylfuran
930-27-8

3-methylfuran

B

2-methylpropenal
78-85-3

2-methylpropenal

C

methyl vinyl ketone
78-94-4

methyl vinyl ketone

D

1-hydroxy-3-methylbut-3-en-2-one

1-hydroxy-3-methylbut-3-en-2-one

Conditions
ConditionsYield
With air; dihydrogen peroxide for 0.5h; Product distribution; Kinetics; Further Variations:; Reagents; Oxidation; UV-irradiation;A 2.8%
B 19.1%
C 20.5%
D 3.7%
4-methyl-2-furancarboxylic acid
59304-40-4

4-methyl-2-furancarboxylic acid

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
With quinoline; copper
4-methyl-furan-2,3-dicarboxylic acid
857821-28-4

4-methyl-furan-2,3-dicarboxylic acid

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
With quinoline; copper
furan
110-00-9

furan

dimethylfluoronium ion
64710-12-9

dimethylfluoronium ion

A

2-methylfuran
534-22-5

2-methylfuran

B

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
With oxygen; trimethylamine In gas Product distribution; gas-phase methylation of furan and thiophene, pressure dependence, effect of partial pressure of NMe3, competition experiments in the presence of benzene; mechanism of methylation;
furan
110-00-9

furan

dimethylchloronium
24400-15-5

dimethylchloronium

A

2-methylfuran
534-22-5

2-methylfuran

B

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
With oxygen; trimethylamine In gas Product distribution; gas-phase methylation of furan and thiophene, pressure dependence, effect of partial pressure of NMe3, competition experiments in the presence of benzene; mechanism of methylation;
furan-3-carboxaldehyde
498-60-2

furan-3-carboxaldehyde

methyl vinyl ketone
78-94-4

methyl vinyl ketone

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
With potassium hydroxide; trifluoroacetic acid; hydrazine 1) ethylene glycol, 15 min, 2) ethylene glycol, 140 to 155 deg C; Yield given. Multistep reaction;
furan-3-carboxaldehyde
498-60-2

furan-3-carboxaldehyde

methyl vinyl ketone
78-94-4

methyl vinyl ketone

A

3-methylfuran
930-27-8

3-methylfuran

B

3-methylene-2,3-dihydrofuran
153681-93-7

3-methylene-2,3-dihydrofuran

Conditions
ConditionsYield
With potassium hydroxide; hydrazine 1) ethylene glycol, 15 min, 2) ethylene glycol, 140 to 155 deg C; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
furan-3-carboxaldehyde
498-60-2

furan-3-carboxaldehyde

methyl vinyl ketone
78-94-4

methyl vinyl ketone

A

3-methylfuran
930-27-8

3-methylfuran

B

5-(3-furyl)-2-pentanone
153681-94-8

5-(3-furyl)-2-pentanone

Conditions
ConditionsYield
With potassium hydroxide; hydrazine 1) ethylene glycol, 15 min, 2) ethylene glycol, 140 to 155 deg C, 3) CH2Cl2, 40 deg C; Yield given. Multistep reaction. Yields of byproduct given;
furan-3-carboxaldehyde
498-60-2

furan-3-carboxaldehyde

acrylonitrile
107-13-1

acrylonitrile

A

3-methylfuran
930-27-8

3-methylfuran

B

4-(3-furyl)-1-butanenitrile
153681-95-9

4-(3-furyl)-1-butanenitrile

Conditions
ConditionsYield
With potassium hydroxide; hydrazine 1) ethylene glycol, 15 min, 2) ethylene glycol, 140 to 155 deg C, CH2Cl2, 40 deg C; Yield given. Multistep reaction. Yields of byproduct given;
furan-3-carboxaldehyde
498-60-2

furan-3-carboxaldehyde

ethyl acrylate
140-88-5

ethyl acrylate

A

3-methylfuran
930-27-8

3-methylfuran

B

ethyl 4-(3-furyl)butanoate

ethyl 4-(3-furyl)butanoate

Conditions
ConditionsYield
With potassium hydroxide; hydrazine 1) ethylene glycol, 15 min, 2) ethylene glycol, 140 to 155 deg C, CH2Cl2, 40 deg C; Yield given. Multistep reaction. Yields of byproduct given;
3-tetrahydrofuranmethanol
124391-75-9, 124506-31-6, 15833-61-1

3-tetrahydrofuranmethanol

A

3-methyltetrahydrofuran
13423-15-9

3-methyltetrahydrofuran

B

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

C

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
aluminium at 310 - 330℃; for 0.5h; Yield given. Yields of byproduct given;
isoprene
78-79-5

isoprene

A

3-methylfuran
930-27-8

3-methylfuran

B

2-methyl-3,4-epoxy-1-butene
7437-61-8

2-methyl-3,4-epoxy-1-butene

C

isoprene epoxide
1838-94-4

isoprene epoxide

D

trans-3-methyl-4-nitrooxy-2-butenal

trans-3-methyl-4-nitrooxy-2-butenal

Conditions
ConditionsYield
With nitrate radical at 24.9℃; under 5.1 - 75.006 Torr; Rate constant; Product distribution; Mechanism; application to troposphere;
isoprene
78-79-5

isoprene

A

3-methylfuran
930-27-8

3-methylfuran

B

formaldehyd
50-00-0

formaldehyd

C

2-methylpropenal
78-85-3

2-methylpropenal

D

methyl vinyl ketone
78-94-4

methyl vinyl ketone

E

isoprene epoxide
1838-94-4

isoprene epoxide

F

trans-3-methyl-4-nitrooxy-2-butenal

trans-3-methyl-4-nitrooxy-2-butenal

Conditions
ConditionsYield
With nitrogen(II) oxide; nitrate radical at 24.9℃; under 5.1 - 75.006 Torr; Rate constant; Product distribution; Mechanism; application to troposphere;
(+-)-3,4-epoxy-3-methyl-butyraldehyde diethylacetal

(+-)-3,4-epoxy-3-methyl-butyraldehyde diethylacetal

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
With sulfuric acid
2-(2,2-diethoxy-ethyl)-2-methyl-oxirane
57535-94-1

2-(2,2-diethoxy-ethyl)-2-methyl-oxirane

sulfuric acid
7664-93-9

sulfuric acid

3-methylfuran
930-27-8

3-methylfuran

3-methyl-furan-carboxylic acid-(2)

3-methyl-furan-carboxylic acid-(2)

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
at 210 - 230℃; im Rohr;
furan-3-carbaldehyde hydrazone

furan-3-carbaldehyde hydrazone

3-methylfuran
930-27-8

3-methylfuran

bromoacetaldehyde dipropargyl acetal
86491-43-2

bromoacetaldehyde dipropargyl acetal

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 63 percent / bis-dimethylglyoximato(pyridine)cobalt(III), sodium borohydride, sodium hydroxide, pyridine / ethanol; diethyl ether / 3 h
2: 60 percent / potassium hydrogen sulfate / dimethylformamide / Heating
View Scheme
3-methylbut-3-enal diethyl acetal

3-methylbut-3-enal diethyl acetal

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 93 percent / m-chloroperbenzoic acid / diethyl ether / 5 h
2: 47 percent / 0.05M aq. H2SO4 / Heating
View Scheme
isoprene
78-79-5

isoprene

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: CH2Cl2 / Heating
2: methanol / Irradiation
View Scheme
methyl 3-methylfuran-2-carboxylate
6141-57-7

methyl 3-methylfuran-2-carboxylate

3-methylfuran
930-27-8

3-methylfuran

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aq. NaOH solution
2: copper; quinoline
View Scheme
Multi-step reaction with 2 steps
1.1: methanol; sodium hydroxide / water / 3.5 h / Reflux; Inert atmosphere
1.2: pH 1 / Inert atmosphere
2.1: quinoline / 2.5 h / 165 - 180 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: sodium hydroxide / water / 2 h / Reflux
2: quinoline; copper / 260 °C
View Scheme
3-methylfuran
930-27-8

3-methylfuran

diazoacetic acid ethyl ester
623-73-4

diazoacetic acid ethyl ester

(1S,5R)-4-Methyl-2-oxa-bicyclo[3.1.0]hex-3-ene-6-carboxylic acid ethyl ester

(1S,5R)-4-Methyl-2-oxa-bicyclo[3.1.0]hex-3-ene-6-carboxylic acid ethyl ester

Conditions
ConditionsYield
With dirhodium tetraacetate Cycloaddition;92%
3-methylfuran
930-27-8

3-methylfuran

3-(propa-1,2-dienyl)oxazolidin-2-one
250728-91-7

3-(propa-1,2-dienyl)oxazolidin-2-one

3-((1R,2S,5R)-6-Methyl-3-oxo-8-oxa-bicyclo[3.2.1]oct-6-en-2-yl)-oxazolidin-2-one

3-((1R,2S,5R)-6-Methyl-3-oxo-8-oxa-bicyclo[3.2.1]oct-6-en-2-yl)-oxazolidin-2-one

Conditions
ConditionsYield
With silver hexafluoroantimonate; 3,3-dimethyldioxirane; copper(II) bis(trifluoromethanesulfonate); chiral bisoxazoline derivative In dichloromethane; acetone at -78℃;91%
3-methylfuran
930-27-8

3-methylfuran

ethyl (2E)-4,4-difluorobut-2-enoate
37746-82-0, 1992-97-8

ethyl (2E)-4,4-difluorobut-2-enoate

C11H14F2O3
1353275-85-0

C11H14F2O3

Conditions
ConditionsYield
With Cl4SnC2HNOBC6H5CH(CH3)2(C6H5)2CH2C10H7 In dichloromethane at -78℃; for 8h; Diels-Alder reaction; Inert atmosphere; optical yield given as %ee; stereoselective reaction;87%
3-methylfuran
930-27-8

3-methylfuran

pentachloroacetone
1768-31-6

pentachloroacetone

2,2,4,4-tetrachloro-6-methyl-8-oxabicyclo[3.2.1]oct-6-en-3-one

2,2,4,4-tetrachloro-6-methyl-8-oxabicyclo[3.2.1]oct-6-en-3-one

Conditions
ConditionsYield
With sodium 2,2,2-trifluoroethanolate In 2,2,2-trifluoroethanol at 20℃; for 2h; Cycloaddition;86%
3-methylfuran
930-27-8

3-methylfuran

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

dimethyl 5-methyl-7-oxa-bicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate
146071-69-4

dimethyl 5-methyl-7-oxa-bicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate

Conditions
ConditionsYield
In diethyl ether at 20℃; for 264h;81%
3-methylfuran
930-27-8

3-methylfuran

1-aminotropono<4,5-d>-1,2,3-triazole
56598-81-3

1-aminotropono<4,5-d>-1,2,3-triazole

(1S,9R)-10-Methyl-12-oxa-tricyclo[7.2.1.02,8]dodeca-2(8),3,6,10-tetraen-5-one
103826-35-3

(1S,9R)-10-Methyl-12-oxa-tricyclo[7.2.1.02,8]dodeca-2(8),3,6,10-tetraen-5-one

Conditions
ConditionsYield
With lead(IV) acetate In dichloromethane at 5℃;80%
3-methylfuran
930-27-8

3-methylfuran

ethyl 4,4,4-trifluorocrotonate
25597-16-4

ethyl 4,4,4-trifluorocrotonate

A

C11H13F3O3

C11H13F3O3

B

C11H13F3O3
1353275-82-7

C11H13F3O3

Conditions
ConditionsYield
With Cl4SnC2HNOBC6H5CH(CH3)2(C6H5)2CH2C10H7 In dichloromethane at -78℃; for 8h; Diels-Alder reaction; Inert atmosphere; optical yield given as %ee; stereoselective reaction;A n/a
B 80%
3-methylfuran
930-27-8

3-methylfuran

2-bromo-1-fluoro-3,5-dimethoxybenzene
206860-47-1

2-bromo-1-fluoro-3,5-dimethoxybenzene

1,4-epoxy-2-methyl-6,8-dimethoxy-1,4-dihydronaphthalene

1,4-epoxy-2-methyl-6,8-dimethoxy-1,4-dihydronaphthalene

Conditions
ConditionsYield
With magnesium In tetrahydrofuran at 55℃; for 2h;80%
3-methylfuran
930-27-8

3-methylfuran

2-bromo-3-(4-chlorophenyl)-1-phenylprop-2-en-1-one
57038-83-2

2-bromo-3-(4-chlorophenyl)-1-phenylprop-2-en-1-one

(8-chloro-1-methylnaphtho[2,1-b]furan-4-yl)(phenyl)methanone

(8-chloro-1-methylnaphtho[2,1-b]furan-4-yl)(phenyl)methanone

Conditions
ConditionsYield
With [Ir(III){2-(2,4-difluorophenyl)-5-trifluoromethylpyridine}2(4,4'-di-tert-butyl-2,2'-dipyridyl)]PF6 In N,N-dimethyl-formamide for 12h; Inert atmosphere; Irradiation;78%
3-methylfuran
930-27-8

3-methylfuran

1,1-dimethoxy-2-<(trimethylsilyl)oxy>-2-butene

1,1-dimethoxy-2-<(trimethylsilyl)oxy>-2-butene

C10H14O3

C10H14O3

Conditions
ConditionsYield
With tert-butyl methyl ether; t-butyldimethylsiyl triflate; C38H31F6N3O3 at -78℃; for 3h; Mukaiyama Aldol Addition; enantioselective reaction;77%
3-methylfuran
930-27-8

3-methylfuran

tert-butyl (4-methoxyphenyl)(penta-1,2-dien-1-yl)carbamate

tert-butyl (4-methoxyphenyl)(penta-1,2-dien-1-yl)carbamate

tert-butyl ((1S,2R,4R,5R)-4-ethyl-7-methyl-3-oxo-8-oxabicyclo[3.2.1]oct-6-en-2-yl)(4-methoxyphenyl)carbamate

tert-butyl ((1S,2R,4R,5R)-4-ethyl-7-methyl-3-oxo-8-oxabicyclo[3.2.1]oct-6-en-2-yl)(4-methoxyphenyl)carbamate

Conditions
ConditionsYield
With 1,1,1-trifluoro-N-(4-oxido-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)methanesulfonamide; 3,3-dimethyldioxirane In ethyl acetate; toluene at -78℃; for 16h; stereoselective reaction;76%
3-methylfuran
930-27-8

3-methylfuran

C3H11B10F3O3S

C3H11B10F3O3S

C7H16B10O

C7H16B10O

Conditions
ConditionsYield
With n-butyllithium In hexane at -40℃; for 8h; Diels-Alder Cycloaddition; Inert atmosphere;75%
3-methylfuran
930-27-8

3-methylfuran

2-diazocyclohexane-1,3-dione
1460-08-8

2-diazocyclohexane-1,3-dione

3-Methyl-3a,6,7,8a-tetrahydro-5H-1,8-dioxacyclopentainden-4-one

3-Methyl-3a,6,7,8a-tetrahydro-5H-1,8-dioxacyclopentainden-4-one

Conditions
ConditionsYield
dirhodium tetraacetate In fluorobenzene for 15h; Ambient temperature;72%
3-methylfuran
930-27-8

3-methylfuran

cyclooctyne
1781-78-8

cyclooctyne

1,4,5,6,7,8,9,10-Octahydro-2-methyl-1,4-epoxybenzocycloocten
106710-62-7

1,4,5,6,7,8,9,10-Octahydro-2-methyl-1,4-epoxybenzocycloocten

Conditions
ConditionsYield
at 140℃; for 3h;68%
3-methylfuran
930-27-8

3-methylfuran

2-bromo-3-(4-bromophenyl)-1-(4-chlorophenyl)prop-2-en-1-one

2-bromo-3-(4-bromophenyl)-1-(4-chlorophenyl)prop-2-en-1-one

(8-bromo-1-methylnaphtho[2,1-b]furan-4-yl)(4-chlorophenyl)methanone

(8-bromo-1-methylnaphtho[2,1-b]furan-4-yl)(4-chlorophenyl)methanone

Conditions
ConditionsYield
With [Ir(III){2-(2,4-difluorophenyl)-5-trifluoromethylpyridine}2(4,4'-di-tert-butyl-2,2'-dipyridyl)]PF6 In N,N-dimethyl-formamide for 12h; Inert atmosphere; Irradiation;65%
3-methylfuran
930-27-8

3-methylfuran

di(1-adamantyl) ketone
38256-01-8

di(1-adamantyl) ketone

A

[2-(3-methylfuryl)]di(1-adamantyl)methanol

[2-(3-methylfuryl)]di(1-adamantyl)methanol

B

[2-(4-methylfuryl)]di(1-adamantyl)methanol

[2-(4-methylfuryl)]di(1-adamantyl)methanol

Conditions
ConditionsYield
Stage #1: 3-methylfuran With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In diethyl ether; hexane for 0.5h; Metallation; lithiation;
Stage #2: di(1-adamantyl) ketone In diethyl ether; hexane for 1h; Addition;
A 33%
B 61%
3-methylfuran
930-27-8

3-methylfuran

anthranilic acid
118-92-3

anthranilic acid

2-methyl-1,4-dihydro-1,4-epoxynaphthalene
136131-45-8

2-methyl-1,4-dihydro-1,4-epoxynaphthalene

Conditions
ConditionsYield
With isopentyl nitrite In tetrahydrofuran; dichloromethane for 1.5h; Heating;52%
3-methylfuran
930-27-8

3-methylfuran

pentacarbonyltungsten(CHCPhCHPh)
134388-61-7

pentacarbonyltungsten(CHCPhCHPh)

pentacarbonyl(6,7-η2-{3-endo-4-diphenyl-7-methyl-8-oxa-bicyclo{3.2.1}octa-2,6-diene})tungsten

pentacarbonyl(6,7-η2-{3-endo-4-diphenyl-7-methyl-8-oxa-bicyclo{3.2.1}octa-2,6-diene})tungsten

Conditions
ConditionsYield
In dichloromethane under N2: addn. of 3-methylfuran to a soln. of (CO)5WCHC(C6H5)CH(C6H5) in CH2Cl2; reaction for 22 h at -30°C; removing solvent and excess 3-methylfuran in vac.;; extraction three times with ether; removing solvent in vac.; chromy. (pentane/CH2Cl2 (5:1)); elem. anal.;;51%
3-methylfuran
930-27-8

3-methylfuran

ethyl 2-(N,N-diethylcarbamoyloxy)-3,3-difluoro-2-propenoate
327602-26-6

ethyl 2-(N,N-diethylcarbamoyloxy)-3,3-difluoro-2-propenoate

ethyl exo-2-(N,N-diethylcarbamoyloxy)-3,3-difluoro-5-methyl-7-oxabicyclo[2.2.1]hept-5-enyl-2-endo-carboxylate

ethyl exo-2-(N,N-diethylcarbamoyloxy)-3,3-difluoro-5-methyl-7-oxabicyclo[2.2.1]hept-5-enyl-2-endo-carboxylate

ethyl endo-2-(N,N-diethylcarbamoyloxy)-3,3-difluoro-5-methyl-7-oxabicyclo[2.2.1]hept-5-enyl-2-exo-carboxylate

ethyl endo-2-(N,N-diethylcarbamoyloxy)-3,3-difluoro-5-methyl-7-oxabicyclo[2.2.1]hept-5-enyl-2-exo-carboxylate

Conditions
ConditionsYield
With tin(IV) chloride In dichloromethane at 0℃; for 0.75h;A 48%
B 6%
3-methylfuran
930-27-8

3-methylfuran

methanol
67-56-1

methanol

3-methyl-2,5-dimethoxy-2,5-dihydrofuran
22048-69-7

3-methyl-2,5-dimethoxy-2,5-dihydrofuran

Conditions
ConditionsYield
With bromine; sodium carbonate In benzene at -5℃; for 2h;43%
3-methylfuran
930-27-8

3-methylfuran

Diethyl ketomalonate
609-09-6

Diethyl ketomalonate

α-hydroxy-α-(4-methylfuran-2-yl) diethyl malonate

α-hydroxy-α-(4-methylfuran-2-yl) diethyl malonate

Conditions
ConditionsYield
at 0 - 20℃;40%
3-methylfuran
930-27-8

3-methylfuran

thionicotinamide
4621-66-3

thionicotinamide

A

2-methyl-5-pyridin-3-yl-1H-pyrrole-3-carbaldehyde

2-methyl-5-pyridin-3-yl-1H-pyrrole-3-carbaldehyde

B

4-methyl-5-pyridin-3-yl-1H-pyrrole-3-carbaldehyde

4-methyl-5-pyridin-3-yl-1H-pyrrole-3-carbaldehyde

C

N-(4-methyl-5-pyridin-3-yl-2,3-dihydro-thiophen-2-yl)-formamide

N-(4-methyl-5-pyridin-3-yl-2,3-dihydro-thiophen-2-yl)-formamide

Conditions
ConditionsYield
In acetone; benzene for 20h; Irradiation;A 3%
B 6%
C 34%

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