Product Name

This product is a nationally controlled contraband, and the Lookchem platform doesn't provide relevant sales information.
  • Name

    1,5-Dinitronaphthalene

  • EINECS 210-095-2
  • CAS No. 605-71-0
  • Article Data55
  • CAS DataBase
  • Density 1.58
  • Solubility 0.1 g/100ml AUTOIGNITION
  • Hazard Symbols
  • Synonyms 1,5-Dinitronaphthalene;NSC 20593
  • PSA 91.64000
  • LogP 3.70260

Synthetic route

1,5-diaminonaphthalene
2243-62-1

1,5-diaminonaphthalene

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With trifluoroacetyl peroxide In dichloromethane at -5 - 5℃; for 4h;85%
naphthalene
91-20-3

naphthalene

A

1-Nitronaphthalene
86-57-7

1-Nitronaphthalene

B

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

C

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With nitric acid at 64.84℃; for 3h; Catalytic behavior; Reagent/catalyst;A 78.5%
B 10.6%
C 6.2%
With nitric acid In acetic acid at 64.84℃; for 3h; Catalytic behavior; Solvent;A 22.5%
B 42.5%
C 32.6%
With phosphotungstic acid; nitric acid at 64.84℃; for 3h; Catalytic behavior; Reagent/catalyst;A 31.5%
B 36.7%
C 28.5%
With nitric acid In dichloromethane for 12h; Reflux; regioselective reaction;
naphthalene
91-20-3

naphthalene

A

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

B

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With nitric acid at 64.84℃; for 3h; Catalytic behavior; Reagent/catalyst;A 49.2%
B 48.5%
With nitric acid
With nitric acid Erwaermen des Reaktionsgemischs mit konz. Schwefelsaeure;
naphthalene
91-20-3

naphthalene

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With sulfuric acid; nitric acid
With Nitrogen dioxide at 100℃;
naphthalene
91-20-3

naphthalene

A

2,4-dinitronaphthalene
606-37-1

2,4-dinitronaphthalene

B

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With sulfuric acid; nitric acid at -60 - -50℃;
1-Nitronaphthalene
86-57-7

1-Nitronaphthalene

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With nitric acid
With sulfuric acid; nitric acid Erwaermen des Reaktionsprodukts auf 80-90grad;
With sulfuric acid; nitric acid
With sulfuric acid; nitric acid Erwaermen des Reaktionsprodukts auf 80-90grad;
1-Nitronaphthalene
86-57-7

1-Nitronaphthalene

A

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

B

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With nitric acid
With sulfuric acid; nitric acid at 0℃; Trennung der beiden Isomere durch Umkrystallisieren aus Pyridin;
With sulfuric acid; nitric acid at 0℃;
5-nitro-[1]naphthylamine
3272-91-1

5-nitro-[1]naphthylamine

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With hydrogenchloride Diazotization.Versetzen der neutralisierten Diazoniumsalz-Loesung mit Na3 und Behandlung des gebildeten Diazonium-hexanitrocobaltats(III) mit NaNO2,Cu2O und CuSO4;
2-amino-1,5-dinitronaphthalene
139765-92-7

2-amino-1,5-dinitronaphthalene

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
ueber die Diazonium-Verbindung;
C11H9N2O5(1-)*Na(1+)

C11H9N2O5(1-)*Na(1+)

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With (decomposition) In methanol; dimethyl sulfoxide at 24.9℃; Equilibrium constant; Rate constant;
naphthalene
91-20-3

naphthalene

A

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

B

1,7-dinitronaphthalene
24824-25-7

1,7-dinitronaphthalene

C

1,6-dinitronaphthalene
607-46-5

1,6-dinitronaphthalene

D

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With cupric nitrate trihydrate supported on K 10 montmorillonite clay; nitric acid; acetic anhydride In tetrachloromethane for 3h; Ambient temperature; Yield given. Yields of byproduct given;
naphthalene
91-20-3

naphthalene

A

1-Nitronaphthalene
86-57-7

1-Nitronaphthalene

B

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

C

2,4-dinitronaphthalene
606-37-1

2,4-dinitronaphthalene

D

2-nitronaphthalene
581-89-5

2-nitronaphthalene

E

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With Nitrogen dioxide; ozone In dichloromethane at -25℃; for 0.0833333h; Product distribution; Mechanism; other methylnaphthalenes; also with HNO3/Ac2O system and with methanesulfonic acid; var. temp. and reaction times;
5-nitro-naphthalene-carboxylic acid-(1)

5-nitro-naphthalene-carboxylic acid-(1)

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With nitric acid
naphthalene
91-20-3

naphthalene

nitric acid
7697-37-2

nitric acid

A

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

B

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

naphthalene
91-20-3

naphthalene

NO2

NO2

A

1-Nitronaphthalene
86-57-7

1-Nitronaphthalene

B

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

C

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

naphthalene
91-20-3

naphthalene

HNO3+H2SO4

HNO3+H2SO4

A

1-Nitronaphthalene
86-57-7

1-Nitronaphthalene

B

2,4-dinitronaphthalene
606-37-1

2,4-dinitronaphthalene

C

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
at -60 - -50℃;
1-Nitronaphthalene
86-57-7

1-Nitronaphthalene

sulfuric acid
7664-93-9

sulfuric acid

nitric acid
7697-37-2

nitric acid

A

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

B

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
Product distribution;
1-Nitronaphthalene
86-57-7

1-Nitronaphthalene

HNO3+H2SO4

HNO3+H2SO4

A

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

B

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

1-Nitronaphthalene
86-57-7

1-Nitronaphthalene

sulfuric acid
7664-93-9

sulfuric acid

KNO3

KNO3

A

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

B

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
at 0℃;
5-nitro-1-naphthoic acid
1975-44-6

5-nitro-1-naphthoic acid

nitric acid
7697-37-2

nitric acid

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

5-nitro-1-naphthoic acid
1975-44-6

5-nitro-1-naphthoic acid

nitric acid
7697-37-2

nitric acid

A

4,5-dinitro-[1]naphthoic acid
99972-07-3

4,5-dinitro-[1]naphthoic acid

B

5,8-dinitro-[1]naphthoic acid

5,8-dinitro-[1]naphthoic acid

C

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

D

5.x-dinitro-naphthoic acid-(1)

5.x-dinitro-naphthoic acid-(1)

sulfuric acid
7664-93-9

sulfuric acid

4,8-dinitro-[1]naphthoic acid methyl ester

4,8-dinitro-[1]naphthoic acid methyl ester

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

3-nitro-benzenesulfonic acid-(1,5-dinitro-[2]naphthylamide)
858500-11-5

3-nitro-benzenesulfonic acid-(1,5-dinitro-[2]naphthylamide)

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: H2SO4 / 50 °C
2: ueber die Diazonium-Verbindung
View Scheme
2-amino-5-nitronaphthalene
607-44-3

2-amino-5-nitronaphthalene

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: pyridine
2: acetic acid; HNO3
3: H2SO4 / 50 °C
4: ueber die Diazonium-Verbindung
View Scheme
3-nitro-benzenesulfonic acid-(5-nitro-[2]naphthylamide)
858501-23-2

3-nitro-benzenesulfonic acid-(5-nitro-[2]naphthylamide)

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: acetic acid; HNO3
2: H2SO4 / 50 °C
3: ueber die Diazonium-Verbindung
View Scheme
naphthalene
91-20-3

naphthalene

nitric acid
7697-37-2

nitric acid

A

1-Nitronaphthalene
86-57-7

1-Nitronaphthalene

B

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

C

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

naphthalene
91-20-3

naphthalene

A

1-Nitronaphthalene
86-57-7

1-Nitronaphthalene

B

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

C

2-nitronaphthalene
581-89-5

2-nitronaphthalene

D

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With nitric acid In dichloromethane for 12h; Reflux; regioselective reaction;
With nitric acid In acetonitrile for 12h; Reflux; regioselective reaction;
With nitric acid In hexane for 2.3h; Reflux; regioselective reaction;
With nitric acid In nitrobenzene at 90℃; for 24h; Solvent; Temperature; Time; regioselective reaction;
1-Nitronaphthalene
86-57-7

1-Nitronaphthalene

A

1,8-dinitronaphthalene
602-38-0

1,8-dinitronaphthalene

B

2,4-dinitronaphthalene
606-37-1

2,4-dinitronaphthalene

C

1,4-dinitronaphthalene
6921-26-2

1,4-dinitronaphthalene

D

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

Conditions
ConditionsYield
With nickel(II) acetate tetrahydrate; Nitrogen dioxide In acetonitrile at 100℃; for 3h; Temperature; Time; Reagent/catalyst; Sealed tube; regioselective reaction;
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

1,5-diaminonaphthalene
2243-62-1

1,5-diaminonaphthalene

Conditions
ConditionsYield
With sodium tetrahydroborate; diphenyl ditelluride In ethanol; benzene at 55℃; for 15h;92%
With iodophosphorus; water
With sulfuric acid; acetic acid elektrolytische Reduktion an Bleikathoden;
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

benzyl alcohol
100-51-6

benzyl alcohol

5-(benzyloxy)-1-nitronaphthalin
128923-94-4

5-(benzyloxy)-1-nitronaphthalin

Conditions
ConditionsYield
With potassium hydroxide; tetrabutylammomium bromide In various solvent(s) 1) 4 h, room temperature, 2) 1 h, 50 deg C;92%
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

1,4,5-trinitronaphthalene
2243-95-0

1,4,5-trinitronaphthalene

Conditions
ConditionsYield
With sulfuric acid; nitric acid for 3h; cooling;91%
With sulfuric acid; nitric acid
With sulfuric acid; nitric acid
Nitrierung;
With sulfuric acid; nitric acid
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

1,4,5,8-tetranitronaphthalene
4793-98-0

1,4,5,8-tetranitronaphthalene

Conditions
ConditionsYield
With sulfuric acid; potassium nitrate at 20 - 50℃; for 3h;85%
chloromethyl tert-butyl sulfone
24824-96-2

chloromethyl tert-butyl sulfone

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

2-(tert-Butylsulfonylmethyl)-1,5-dinitronaphthalene
108451-12-3

2-(tert-Butylsulfonylmethyl)-1,5-dinitronaphthalene

Conditions
ConditionsYield
With sodium hydroxide In dimethyl sulfoxide at 18 - 22℃; for 0.75h;83%
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

4.8-dinitro-1-hydroxy-naphthalene
80651-01-0

4.8-dinitro-1-hydroxy-naphthalene

Conditions
ConditionsYield
With potassium hydroxide; Cumene hydroperoxide In water; dimethyl sulfoxide at 20℃; for 10h; Oxidation;83%
trans-4-methoxy-3-buten-2-one
51731-17-0

trans-4-methoxy-3-buten-2-one

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

(E)-1-((1S*,2R*)-1,5-dinitro-1,2-dihydronaphthalen-2-yl)-4-methoxybut-3-en-2-one

(E)-1-((1S*,2R*)-1,5-dinitro-1,2-dihydronaphthalen-2-yl)-4-methoxybut-3-en-2-one

Conditions
ConditionsYield
Stage #1: trans-4-methoxy-3-buten-2-one With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: With N,N,N,N,N,N-hexamethylphosphoric triamide In tetrahydrofuran; hexane at -78℃; for 0.0833333h; Inert atmosphere;
Stage #3: 1,5-dinitronaphthalene In tetrahydrofuran; hexane at -78℃; for 4h; Reagent/catalyst; Inert atmosphere;
82%
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

A

4.8-dinitro-1-hydroxy-naphthalene
80651-01-0

4.8-dinitro-1-hydroxy-naphthalene

B

1.5-dinitro-2-hydroxy-naphthalene
80651-00-9

1.5-dinitro-2-hydroxy-naphthalene

Conditions
ConditionsYield
With tert.-butylhydroperoxide; potassium tert-butylate In ammonia at -33℃;A 5%
B 81%
With tert.-butylhydroperoxide; sodium hydroxide In ammonia at -33℃;A 61%
B 22%
With sodium hydroxide; Cumene hydroperoxide In dimethyl sulfoxide at 20℃; for 2h; Product distribution; Further Variations:; Reagents; Solvents; Oxidation;A 30%
B 5%
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

3,4,7,8-tetrachloro-1,5-dinitronaphthalene

3,4,7,8-tetrachloro-1,5-dinitronaphthalene

Conditions
ConditionsYield
With chlorosulfonic acid; iodine; chlorine81%
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

5-nitro-[1]naphthylamine
3272-91-1

5-nitro-[1]naphthylamine

Conditions
ConditionsYield
With hydrazine hydrate at 90℃; for 16h;80%
With sodium sulfide; sodium hydrogencarbonate In methanol; water at 70℃; for 0.0833333h; Reflux;71%
With sodiumsulfide nonahydrate; water In ethanol at 65℃;60%
Ethyl isocyanoacetate
2999-46-4

Ethyl isocyanoacetate

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

6-Nitro-2H-benzo[e]isoindole-3-carboxylic acid ethyl ester

6-Nitro-2H-benzo[e]isoindole-3-carboxylic acid ethyl ester

Conditions
ConditionsYield
With tert-butylimino-tri(pyrrolidino)phosphorane In tetrahydrofuran for 16h; Cyclization; Condensation; Heating;78%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran Heating;44%
cyclohexenone
930-68-7

cyclohexenone

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

(S)-6-((1R,2S)-1,5-dinitro-1,2-dihydronaphthalen-2-yl)cyclohex-2-enone

(S)-6-((1R,2S)-1,5-dinitro-1,2-dihydronaphthalen-2-yl)cyclohex-2-enone

Conditions
ConditionsYield
Stage #1: cyclohexenone With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: With N,N,N,N,N,N-hexamethylphosphoric triamide In tetrahydrofuran; hexane at -78℃; for 0.0833333h; Inert atmosphere;
Stage #3: 1,5-dinitronaphthalene In tetrahydrofuran; hexane at -78℃; for 14h; Inert atmosphere;
72%
N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine
93102-05-7

N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

(3aS*,9bS*)-2-benzyl-6,9b-dinitro-2,3,3a,9b-tetrahydro-1H-benzo[e]isoindole

(3aS*,9bS*)-2-benzyl-6,9b-dinitro-2,3,3a,9b-tetrahydro-1H-benzo[e]isoindole

Conditions
ConditionsYield
Stage #1: N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine; 1,5-dinitronaphthalene With trifluoroacetic acid In dichloromethane at 20℃; for 5.5h; Inert atmosphere;
Stage #2: With sodium hydrogencarbonate In dichloromethane Saturated solution; diastereoselective reaction;
66%
With trifluoroacetic acid In dichloromethane at 0 - 20℃; for 5.5h; Inert atmosphere;66%
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

5-amino-8-hydroxy-[1,4]naphthoquinone
68217-36-7

5-amino-8-hydroxy-[1,4]naphthoquinone

Conditions
ConditionsYield
With sulfuric acid; sulfur trioxide; sulfur 1.) 1 h, 2.) 50 deg C, 10 min, 3.) room temp., 18 h;65%
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

A

dimethyl 1,5-naphthalenedicarbamate
63896-10-6

dimethyl 1,5-naphthalenedicarbamate

B

(5-Amino-naphthalen-1-yl)-carbamic acid methyl ester

(5-Amino-naphthalen-1-yl)-carbamic acid methyl ester

Conditions
ConditionsYield
With [2,2]bipyridinyl; dodecacarbonyl-triangulo-triruthenium; montmorillonitebipyridynylpalladium(II) acetate (Pd-clay) In benzene at 180℃; under 53200 Torr; for 24h;A 64%
B 12%
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

phenylboronic acid
98-80-6

phenylboronic acid

1-nitro-5-phenylnaphthalene

1-nitro-5-phenylnaphthalene

Conditions
ConditionsYield
With bis(acetylacetonato)palladium(II); 18-crown-6 ether; tripotassium phosphate "n" hydrate; dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine In 1,4-dioxane at 130℃; for 3h; Suzuki-Miyaura Coupling; Inert atmosphere; Glovebox;61%
propylamine
107-10-8

propylamine

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

1,5-dinitro-N-propylnaphthalen-2-amine
1137661-34-7

1,5-dinitro-N-propylnaphthalen-2-amine

Conditions
ConditionsYield
With bis(pyridine)silver(I) permanganate In tetrahydrofuran at -15 - -12℃; for 2h;60%
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

N-butylamine
109-73-9

N-butylamine

N-butyl-1,5-dinitronaphthalen-2-amine
1137661-37-0

N-butyl-1,5-dinitronaphthalen-2-amine

Conditions
ConditionsYield
With bis(pyridine)silver(I) permanganate In tetrahydrofuran at -15 - -12℃; for 2h;60%
acetic anhydride
108-24-7

acetic anhydride

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

A

5-nitronapthyl-1-acetate
93201-38-8

5-nitronapthyl-1-acetate

B

acetic acid 4,8-dinitro-naphthalen-1-yl ester

acetic acid 4,8-dinitro-naphthalen-1-yl ester

Conditions
ConditionsYield
Stage #1: 1,5-dinitronaphthalene With perhydrodibenzo-18-crown-6 In benzene for 2h;
Stage #2: acetic anhydride
A 59.7%
B 24.4%
ethylamine
75-04-7

ethylamine

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

N-ethyl-1,5-dinitronaphthalen-2-amine
1137661-32-5

N-ethyl-1,5-dinitronaphthalen-2-amine

Conditions
ConditionsYield
With bis(pyridine)silver(I) permanganate In tetrahydrofuran at -15 - -12℃; for 2h;59%
N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine
93102-05-7

N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

(3aS*, 3bS*, 6aS*, 10bR*)-2,5-dibenzyl-6a,10-dinitro-1,2,3,3a,3b,4,5,6,6a,10-bdecahydrobenzo[e]pyrrolo[3,4-g]isoindole

(3aS*, 3bS*, 6aS*, 10bR*)-2,5-dibenzyl-6a,10-dinitro-1,2,3,3a,3b,4,5,6,6a,10-bdecahydrobenzo[e]pyrrolo[3,4-g]isoindole

Conditions
ConditionsYield
Stage #1: N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine; 1,5-dinitronaphthalene With trifluoroacetic acid In dichloromethane at 20℃; for 26h; Inert atmosphere;
Stage #2: With sodium hydrogencarbonate In dichloromethane Saturated solution; diastereoselective reaction;
57%
With trifluoroacetic acid In dichloromethane at 0 - 20℃; for 26h; Inert atmosphere;57%
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

A

5-nitro-[1]naphthylamine
3272-91-1

5-nitro-[1]naphthylamine

B

1,5-diaminonaphthalene
2243-62-1

1,5-diaminonaphthalene

Conditions
ConditionsYield
With sodium sulfide; ammonium hydroxide at 80℃;A 54%
B 34%
With sodium sulfide; ammonium chloride In water at 80 - 85℃; for 4h;A 54%
B 34%
With nickel; hydrazine hydrate In ethanol; 1,2-dichloro-ethane at 50 - 60℃; for 8h;A 20.33%
B 47.26%
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

5,8-Dihydroxy-1,4-naphthoquinone
475-38-7

5,8-Dihydroxy-1,4-naphthoquinone

Conditions
ConditionsYield
With sulfuric acid; sulfur for 1h; Ambient temperature;50%
With sulfuric acid; sulfur at 40℃;
danishefsky's diene
54125-02-9

danishefsky's diene

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

2-hydroxy-8-nitrophenanthrene

2-hydroxy-8-nitrophenanthrene

Conditions
ConditionsYield
In benzene at 150℃; for 72h;48%
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

1-amino-4-nitronaphthalene
776-34-1

1-amino-4-nitronaphthalene

Conditions
ConditionsYield
With potassium hydroxide; hydroxylamine hydrochloride In methanol at 50℃; for 2h;46%
1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

6-Nitro-2H-benzo[e]isoindole-3-carboxylic acid ethyl ester

6-Nitro-2H-benzo[e]isoindole-3-carboxylic acid ethyl ester

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran for 12h; Ambient temperature;43%
potassium methanolate
865-33-8

potassium methanolate

1,5-dinitronaphthalene
605-71-0

1,5-dinitronaphthalene

A

1-Methoxy-4,8-dinitronaphthalene
13772-70-8

1-Methoxy-4,8-dinitronaphthalene

B

1,7-Dimethoxy-4,8-dinitronaphthalene
1153-59-9

1,7-Dimethoxy-4,8-dinitronaphthalene

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 14h; Substitution; Methoxylation;A 18%
B 30%

1,5-Dinitronaphthalene Chemical Properties

Chemical Name: 1,5-Dinitronaphthalene
IUPAC NAME: 1,5-Dinitronaphthalene
CAS No.: 605-71-0
EINECS: 210-095-2
RTECS: QJ4551000
RTECS Class: Mutagen
Molecular Formula: C10H6N2O4
Molecular Weight: 218.17 g/mol
Melting Point: 214 °C
Density: 1.481 g/cm3
Flash Point: 200.3 °C
Boiling Point: 389.8 °C at 760 mmHg
Following is the structure of 1,5-Dinitronaphthalene (CAS No.605-71-0):


Product Categories about 1,5-Dinitronaphthalene (CAS No.605-71-0) are Intermediates of Dyes and Pigments ; Naphthalene derivatives ; Nitro Compounds ; Nitrogen Compounds ; Organic Building Blocks
The chemical synonymous of 1,5-Dinitronaphthalene (CAS No.605-71-0) are 1,5-Dinitro-Naphthalen ; Naphthalene,1,5-Dinitro- ; 1,5-Dinitronaphthalene ; Labotest-Bb Lt00436936 ; 1,5-Dinitroaphthalene ; 1,5-Dinitronaphthalene98% ; 1,5-Dinitronaphthalene,Tech.90% ; 1,5-Dinitro Naphtalene

1,5-Dinitronaphthalene Toxicity Data With Reference

1.    

mmo-sat 50 µg/plate

    MUREAV    Mutation Research. 91 (1981),321.
2.    

uns-bac-esc 5 µg/tube

    EMMUEG    Environmental and Molecular Mutagenesis. 18 (1991),41.
3.    

pic-esc 15,500 ng/well

    MUREAV    Mutation Research. 260 (1991),349.

1,5-Dinitronaphthalene Safety Profile

A suspected carcinogen. Mutation data reported. Mixtures with sulfur or sulfuric acid (used in commercial reactions) may explode if heated to 120°C. Initiation temperature depends on the quality of the dinitronaphthalene. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS of AROMATIC HYDROCARBONS.
Hazard Codes: IrritantXi HarmfulXn
Risk Statements about 1,5-Dinitronaphthalene (CAS No.605-71-0):
R41:Risk of serious damage to the eyes. 
R43:May cause sensitization by skin contact. 
R68:Possible risk of irreversible effects. 
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements about 1,5-Dinitronaphthalene (CAS No.605-71-0):
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S29:Do not empty into drains. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
Attention:
1. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
2. Handling: Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation.

1,5-Dinitronaphthalene Standards and Recommendations

DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View