1-Chloro-1,1-difluoroethane
A
2,2,2-trifluoroethanol
B
1-chloro-1-fluoroethane
Conditions | Yield |
---|---|
With aluminum(III) fluoride at 325℃; | |
With aluminum(III) fluoride at 300 - 400℃; |
Conditions | Yield |
---|---|
With sodium amalgam; ethanol | |
With water; zinc | |
With chromium(III) oxide at -28.15℃; |
Conditions | Yield |
---|---|
With ethanol; zinc | |
With ethanol; zinc |
1,2-dichloro-1-fluoroethane
A
cis-1-Chloro-2-fluoroethylene
B
trans-1-chloro-2-fluoroethylene
C
fluoroethyne
D
chloroacetylene
E
1-chloro-1-fluoroethane
F
acetylene
Conditions | Yield |
---|---|
Mechanism; Irradiation; |
1,2-dichlorofluoroethylene
A
dichloroethyne
B
cis-1-Chloro-2-fluoroethylene
C
fluoroethyne
D
chloroacetylene
E
1-chloro-1-fluoroethane
F
acetylene
Conditions | Yield |
---|---|
Product distribution; infrared multiphoton decomposition; |
chlorodifluoroacetic anhydride
methyl iodide
A
polytetrafluoroethylene
B
1-Chloro-1,1-difluoroethane
C
Vinylidene fluoride
D
1-chloro-1-fluoroethane
E
1,2-dichloro-1,1,2,2-tetrafluoroethane
F
1,1'-dichloro-2,2'-difluoroethene
Conditions | Yield |
---|---|
With mercury(I) iodide at 26.9℃; for 0.166667h; Rate constant; Thermodynamic data; Irradiation; E0, , var. pressure; |
chloroform
A
1,1,1-Trichloro-2,2,2-trifluoroethane
B
chlorotrifluoromethane
C
1-chloro-1-fluoroethane
D
1,1,2-Trichloro-1,2,2-trifluoroethane
Conditions | Yield |
---|---|
With fluorinated Co3O4 for 2h; Ambient temperature; Yields of byproduct given. Title compound not separated from byproducts; |
chloroform
A
chlorotrifluoromethane
B
trichlorofluoromethane
C
1-chloro-1-fluoroethane
Conditions | Yield |
---|---|
With fluorinated Fe3O4 for 2h; Ambient temperature; Yields of byproduct given. Title compound not separated from byproducts; |
1-Chloro-1,1-difluoroethane
A
2,2,2-trifluoroethanol
B
Vinylidene fluoride
C
1-chloro-1-fluoroethane
D
1,1-Dichloroethylene
E
acetic acid
Conditions | Yield |
---|---|
With hydrogen fluoride; fluorinated γ-alumina at 300℃; Product distribution; other temperatures; also with HCl as a reagent; |
HCFC-141b
A
2,2,2-trifluoroethanol
B
1-Chloro-1,1-difluoroethane
C
1-chloro-1-fluoroethane
D
1,1-Dichloroethylene
E
acetic acid
Conditions | Yield |
---|---|
fluorinated γ-alumina at 300℃; Product distribution; other temperatures; also with HCl or HF as reagents; |
1,1,3,3-tetrachloro-1,3-difluoro-2-propanone
acetone
A
Dichlorofluoromethane
B
HCFC-141b
C
trichlorofluoromethane
D
1-chloro-1-fluoroethane
E
1,1-Dichloroethylene
F
CFC-112a
Conditions | Yield |
---|---|
With propene; sulphur hexafluoride for 0.5h; Rate constant; Ambient temperature; Irradiation; also with acetone-d6; |
1-Chloro-1,1-difluoroethane
A
2,2,2-trifluoroethanol
B
1-chloro-1-fluoroethane
Conditions | Yield |
---|---|
at 325℃; |
1,2-dichloro-1-fluoroethane
A
cis-1,2-Dichloroethylene
B
cis-1-Chloro-2-fluoroethylene
C
trans-1-chloro-2-fluoroethylene
D
fluoroethyne
E
chloroacetylene
F
1-chloro-1-fluoroethane
Conditions | Yield |
---|---|
under 30 Torr; Product distribution; Thermodynamic data; Mechanism; Irradiation; heats of reaction, influence of pressure, additive gas pressure, pulse number, pulse energy and pulse duration; | A .491 % Chromat. B 9.28 % Chromat. C 5.86 % Chromat. D .984 % Chromat. E 1.87 % Chromat. F 3.77 % Chromat. G n/a |
Conditions | Yield |
---|---|
at 336.85 - 426.85℃; under 14 - 120 Torr; Kinetics; Activation energy; Further Variations:; Reagents; |
1,1-dichloroethane
A
1,1-difluoroethane
B
ethene
C
1-chloro-1-fluoroethane
D
1-fluoroethylene
E
chloroethylene
F
1-chloro-1-fluoroethane
G
1,1-Dichloroethylene
Conditions | Yield |
---|---|
With hydrogen fluoride at 200 - 250℃; |
-butyl vinyl ether
Chlorotrifluoroethylene
A
Vinylidene fluoride
B
1-chloro-1-fluoroethane
Conditions | Yield |
---|---|
With UmicoreM73SIPr In benzene-d6 at 60℃; for 1h; Inert atmosphere; Molecular sieve; | |
With bis[1,1-di(trifluoromethyl)ethoxy][(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum In benzene-d6 at 60℃; for 1h; Reagent/catalyst; Inert atmosphere; |
1-Chloro-1,1-difluoroethane
A
Vinylidene fluoride
B
1-chloro-1-fluoroethane
Conditions | Yield |
---|---|
With SrF2 calcined at 500 °C at 450℃; under 750.075 Torr; Temperature; Flow reactor; Inert atmosphere; |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; caesium carbonate In 1,2-dimethoxyethane at -78 - 110℃; for 18h; Sealed tube; | 98% |
methanol
1-chloro-1-fluoroethane
carbon monoxide
methyl 2-fluoroprop-2-enoate
Conditions | Yield |
---|---|
With dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II); triethylamine at 100℃; under 5250.53 Torr; for 8h; Reagent/catalyst; Autoclave; | 91.8% |
With bis(tri-t-butylphosphine)palladium(0) at 100℃; for 18h; Reagent/catalyst; Time; Autoclave; | 77.4% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; caesium carbonate In 1,2-dimethoxyethane at -78 - 110℃; for 18h; Sealed tube; | 91% |
diazoacetic acid ethyl ester
1-chloro-1-fluoroethane
2-chloro-2-fluorocyclopropanecarboxylic acid ethyl ester
Conditions | Yield |
---|---|
In dichloromethane | 86% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; caesium carbonate In 1,2-dimethoxyethane at -78 - 110℃; for 18h; | 76% |
diazoacetic acid ethyl ester
1-chloro-1-fluoroethane
(1S,2S)-2-Fluorocyclopropanecarboxylic Acid Ethyl Ester
2-chloro-2-fluorocyclopropanecarboxylic acid ethyl ester
Conditions | Yield |
---|---|
In dichloromethane | 73% |
diazoacetic acid ethyl ester
1-chloro-1-fluoroethane
(1S,2S)-2-Fluorocyclopropanecarboxylic Acid Ethyl Ester
2-chloro-2-fluorocyclopropanecarboxylic acid ethyl ester
Conditions | Yield |
---|---|
In dichloromethane | 71% |
1-chloro-1-fluoroethane
Conditions | Yield |
---|---|
With pentafluorosulfanyl bromide at 25 - 50℃; for 144h; | 51% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; caesium carbonate In 1,2-dimethoxyethane at -78 - 110℃; for 18h; Sealed tube; | 48% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; caesium carbonate In 1,2-dimethoxyethane at -78 - 110℃; for 18h; Sealed tube; | 27% |
1-chloro-1-fluoroethane
1,2-dichloro-1,2,2-trifluoro-1-iodoethane
1,2,4-trichloro-1,1,2,4-tetrafluoro-4-iodo-butane
Conditions | Yield |
---|---|
With dibenzoyl peroxide |
1-chloro-1-fluoroethane
phenyl(tribromomethyl)mercury(II)
1,1-Dibrom-2-chlor-2-fluor-cyclopropan
Hexafluoropropene oxide
1-chloro-1-fluoroethane
1,1,2-trifluoro-2-chlorocyclopropane
Conditions | Yield |
---|---|
In gas at 195℃; |
Conditions | Yield |
---|---|
under 0.5 Torr; Product distribution; Rate constant; Irradiation; effect of laser pulse energy; |
1-chloro-1-fluoroethane
(difluoroamino)chlorofluoroacetonitrile
Conditions | Yield |
---|---|
With potassium fluoride; tetrafluorohydrazine at 160℃; for 40h; |
1-chloro-1-fluoroethane
A
2,2,2-trifluoroethanol
B
1-Chloro-1,1-difluoroethane
C
Vinylidene fluoride
D
acetic acid
Conditions | Yield |
---|---|
fluorinated γ-alumina at 300℃; Product distribution; other temperatures; |
1-chloro-1-fluoroethane
A
2,2,2-trifluoroethanol
B
1-Chloro-1,1-difluoroethane
C
Vinylidene fluoride
D
1,1-Dichloroethylene
E
acetic acid
Conditions | Yield |
---|---|
With hydrogenchloride; fluorinated γ-alumina at 300℃; Product distribution; other temperatures; |
Conditions | Yield |
---|---|
With hydrogenchloride; fluorinated γ-alumina at 200℃; Product distribution; other temperatures; |
The 1-Chloro-1-fluoroethylene with the CAS number 2317-91-1 is also called Ethene,1-chloro-1-fluoro- (9CI). Its EINECS registry number is 219-027-6. The molecular formula is C2H2ClF. This chemical is highly flammable. While using this chemical, you should be very cautious.
The properties of the chemical are: (1)ACD/LogP: 1.51; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.51; (4)ACD/LogD (pH 7.4): 1.51; (5)ACD/BCF (pH 5.5): 8.29; (6)ACD/BCF (pH 7.4): 8.29; (7)ACD/KOC (pH 5.5): 158.16; (8)ACD/KOC (pH 7.4): 158.16; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 0 Å2; (13)Index of Refraction: 1.353; (14)Molar Refractivity: 15.89 cm3; (15)Molar Volume: 73.2 cm3; (16)Polarizability: 6.3×10-24cm3; (17)Surface Tension: 15.2 dyne/cm; (18)Enthalpy of Vaporization: 22.13 kJ/mol; (19)Vapour Pressure: 3720 mmHg at 25°C.
You can still convert the following datas into molecular structure:
(1)SMILES: Cl/C(F)=C
(2)InChI: InChI=1/C2H2ClF/c1-2(3)4/h1H2
(3)InChIKey: FPBWSPZHCJXUBL-UHFFFAOYAV
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