Product Name

  • Name

    (3,4-Diaminophenyl)phenylmethanone

  • EINECS 254-273-8
  • CAS No. 39070-63-8
  • Article Data12
  • CAS DataBase
  • Density 1.233 g/cm3
  • Solubility 410 mg/L (20 ºC)
  • Melting Point 115-117 °C(lit.)
  • Formula C13H12N2O
  • Boiling Point 440.7 °C at 760 mmHg
  • Molecular Weight 212.251
  • Flash Point 220.3 °C
  • Transport Information
  • Appearance yellow to ochre-yellow powder
  • Safety 26-36-37/39
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 39070-63-8 ((3,4-Diaminophenyl)phenylmethanone)
  • Hazard Symbols IrritantXi
  • Synonyms (3,4-Diaminophenyl)phenylmethanone;2-Amino-4-benzoylaniline;3,4-Benzophenonediamine;3,4-Diaminobenzophenone;4-Benzoyl-1,2-benzenediamine;4-Benzoyl-1,2-phenylenediamine;4-Benzoyl-o-phenylenediamine;p-Benzoyl-o-phenylenediamine;
  • PSA 69.11000
  • LogP 3.24440

Synthetic route

2-nitro-4-benzoylaniline
31431-19-3

2-nitro-4-benzoylaniline

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
With pyrrolidine In 5,5-dimethyl-1,3-cyclohexadiene at 20 - 60℃; for 5h; Reagent/catalyst; Temperature;98.9%
With sodium sulfide for 5h; Reduction; Heating;90%
(i) Fe, aq. NH4Cl, (ii) aq. HCl; Multistep reaction;
With tin(ll) chloride In ethanol Heating;
With sulfur; sodium hydroxide In methanol at 78 - 80℃;
3,4-dinitrobenzophenone
33609-48-2

3,4-dinitrobenzophenone

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
With hydrogen; nickel In tetrahydrofuran at 30 - 40℃;
With palladium 10% on activated carbon; hydrogen In methanol at 20℃; for 24h;
N-(4-benzoylphenyl)acetamide
4834-61-1

N-(4-benzoylphenyl)acetamide

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 95 percent / fuming HNO3
2: aq. NaOH / methanol / Heating
3: 90 percent / aq. Na2S / 5 h / Heating
View Scheme
4-acetamido-3-nitrobenzophenone
53502-23-1

4-acetamido-3-nitrobenzophenone

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aq. NaOH / methanol / Heating
2: 90 percent / aq. Na2S / 5 h / Heating
View Scheme
N-phenyl methyl carbamate
2603-10-3

N-phenyl methyl carbamate

phloroglucinoldicarboxylic acid ester

phloroglucinoldicarboxylic acid ester

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 98 percent / AlCl3 / 1,2-dichloro-ethane / 5 h / 0 - 5 °C
2: 96 percent / fuming HNO3 / 0.75 h / 0 - 25 °C
3: 94 percent / aq. NaOH / methanol / 3 h / Heating
4: 90 percent / aq. Na2S / 5 h / Heating
View Scheme
Methyl N-(4-benzoylphenyl)carbamate
134919-56-5

Methyl N-(4-benzoylphenyl)carbamate

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 96 percent / fuming HNO3 / 0.75 h / 0 - 25 °C
2: 94 percent / aq. NaOH / methanol / 3 h / Heating
3: 90 percent / aq. Na2S / 5 h / Heating
View Scheme
Methyl N-(4-benzoyl-2-nitrophenyl)carbamate
136023-33-1

Methyl N-(4-benzoyl-2-nitrophenyl)carbamate

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 94 percent / aq. NaOH / methanol / 3 h / Heating
2: 90 percent / aq. Na2S / 5 h / Heating
View Scheme
Benzotrichlorid
98-07-7

Benzotrichlorid

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 98 percent / AlCl3 / 1,2-dichloro-ethane / 5 h / 0 - 5 °C
2: 96 percent / fuming HNO3 / 0.75 h / 0 - 25 °C
3: 94 percent / aq. NaOH / methanol / 3 h / Heating
4: 90 percent / aq. Na2S / 5 h / Heating
View Scheme
3,4-dinitrobenzoic acid
528-45-0

3,4-dinitrobenzoic acid

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1.) SOCl2, 2.) AlCl3 / 1.) reflux, 10 min, 2.) room temp., 24 h, then 40-50 deg C, 0.5 h
2: H2 / Raney nickel / tetrahydrofuran / 30 - 40 °C
View Scheme
Multi-step reaction with 3 steps
1: thionyl chloride / N,N-dimethyl-formamide / 0 °C
2: aluminum (III) chloride / dichloromethane / 3 h / Reflux; Inert atmosphere
3: palladium 10% on activated carbon; hydrogen / methanol / 24 h / 20 °C
View Scheme
3,4-Dinitrotoluene
610-39-9

3,4-Dinitrotoluene

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 75 percent / CrO3, aq. H2SO4 / 1.) 35 deg C, 0.5 h, 2.) 45-55 deg C, 4 h
2: 1.) SOCl2, 2.) AlCl3 / 1.) reflux, 10 min, 2.) room temp., 24 h, then 40-50 deg C, 0.5 h
3: H2 / Raney nickel / tetrahydrofuran / 30 - 40 °C
View Scheme
4-methyl-2-nitro-1-nitrosobenzene
6971-33-1

4-methyl-2-nitro-1-nitrosobenzene

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 8 g / aq. HNO3 / 0.08 h
2: 75 percent / CrO3, aq. H2SO4 / 1.) 35 deg C, 0.5 h, 2.) 45-55 deg C, 4 h
3: 1.) SOCl2, 2.) AlCl3 / 1.) reflux, 10 min, 2.) room temp., 24 h, then 40-50 deg C, 0.5 h
4: H2 / Raney nickel / tetrahydrofuran / 30 - 40 °C
View Scheme
4-methyl-2-nitroaniline
89-62-3

4-methyl-2-nitroaniline

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 89 percent / K2S2O8, H2SO4 / 24 h
2: 8 g / aq. HNO3 / 0.08 h
3: 75 percent / CrO3, aq. H2SO4 / 1.) 35 deg C, 0.5 h, 2.) 45-55 deg C, 4 h
4: 1.) SOCl2, 2.) AlCl3 / 1.) reflux, 10 min, 2.) room temp., 24 h, then 40-50 deg C, 0.5 h
5: H2 / Raney nickel / tetrahydrofuran / 30 - 40 °C
View Scheme
4-chloro-3-nitrobenzophenone
56107-02-9

4-chloro-3-nitrobenzophenone

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NH3
2: (i) Fe, aq. NH4Cl, (ii) aq. HCl
View Scheme
Multi-step reaction with 2 steps
1: ammonia / 130 - 135 °C / 4500.45 - 5250.53 Torr
2: sulfur; sodium hydroxide / methanol / 78 - 80 °C
View Scheme
3,4-dinitrobenzoyl chloride
24376-18-9

3,4-dinitrobenzoyl chloride

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aluminum (III) chloride / dichloromethane / 3 h / Reflux; Inert atmosphere
2: palladium 10% on activated carbon; hydrogen / methanol / 24 h / 20 °C
View Scheme
para-chlorotoluene
106-43-4

para-chlorotoluene

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: nitric acid / 70 °C
2: nitric acid / 50 °C
3: thionyl chloride / N,N-dimethyl-formamide / 75 - 80 °C
4: ammonia / 130 - 135 °C / 4500.45 - 5250.53 Torr
5: sulfur; sodium hydroxide / methanol / 78 - 80 °C
View Scheme
para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: nitric acid / 50 °C
2: thionyl chloride / N,N-dimethyl-formamide / 75 - 80 °C
3: ammonia / 130 - 135 °C / 4500.45 - 5250.53 Torr
4: sulfur; sodium hydroxide / methanol / 78 - 80 °C
View Scheme
4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: thionyl chloride / N,N-dimethyl-formamide / 75 - 80 °C
2: ammonia / 130 - 135 °C / 4500.45 - 5250.53 Torr
3: sulfur; sodium hydroxide / methanol / 78 - 80 °C
View Scheme
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

4,4'-dibromobenzil
35578-47-3

4,4'-dibromobenzil

(2,3-bis(4-bromophenyl)quinoxalin-6-yl)(phenyl)methanone
1352635-46-1

(2,3-bis(4-bromophenyl)quinoxalin-6-yl)(phenyl)methanone

Conditions
ConditionsYield
With titanium(IV) oxide In 1,2-dichloro-ethane at 25℃; for 0.5h;99%
With niobium pentachloride In ethanol at 20℃; for 0.0833333h;94%
With acetic acid Reflux;90%
With acetic acid for 8h; Reflux;80%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

dimethylglyoxal
431-03-8

dimethylglyoxal

(2,3-dimethylquinoxalin-6-yl)(phenyl)methanone
119426-73-2

(2,3-dimethylquinoxalin-6-yl)(phenyl)methanone

Conditions
ConditionsYield
In neat (no solvent) at 24.84℃;98%
With 1-methyl-3-(3-trimethoxysilylpropyl)imidazolium hydrogen sulfate immobilized on cellulose In water at 20℃; for 0.0833333h; Green chemistry;97%
With PEG-400 at 110℃; for 0.416667h; Neat (no solvent);92%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

furil
492-94-4

furil

(2,3-di(furan-2-yl)quinoxalyn-6-yl)(phenyl)methanone

(2,3-di(furan-2-yl)quinoxalyn-6-yl)(phenyl)methanone

Conditions
ConditionsYield
With gallium(III) triflate In ethanol at 20℃; for 0.166667h;98%
With H3PMo12O40 nanoparticles immobilized on imidazole functionalized core-shell Fe3O4(at)SiO2 nanoparticle In ethanol at 20℃; for 0.333333h; Green chemistry;95%
With titanium(IV) oxide In 1,2-dichloro-ethane at 25℃; for 1.25h;91%
glycolic Acid
79-14-1

glycolic Acid

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

(2-hydroxymethyl-1(3)H-benzoimidazol-5-yl)-phenyl-methanone
66353-67-1

(2-hydroxymethyl-1(3)H-benzoimidazol-5-yl)-phenyl-methanone

Conditions
ConditionsYield
With hydrogenchloride In water at 100℃; for 2h;98%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

9,10-phenanthrenequinone
84-11-7

9,10-phenanthrenequinone

11-benzoyldibenzophenazine

11-benzoyldibenzophenazine

Conditions
ConditionsYield
With tungstate sulfuric acid at 20℃; for 0.333333h; Neat (no solvent);98%
With lithium chloride In ethanol at 20℃; for 0.666667h;97%
With lead(II) chloride In ethanol at 20℃; for 0.25h;97%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

acenaphthene quinone
82-86-0

acenaphthene quinone

11-benzoyldibenzophenazine

11-benzoyldibenzophenazine

Conditions
ConditionsYield
With magnesium sulfate heptahydrate In ethanol at 20℃; for 0.166667h;98%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

4-dimethylamino-benzaldehyde
100-10-7

4-dimethylamino-benzaldehyde

[2-(4-dimethylamino-phenyl)-1H-benzoimidazol-5-yl](phenyl)methanone

[2-(4-dimethylamino-phenyl)-1H-benzoimidazol-5-yl](phenyl)methanone

Conditions
ConditionsYield
With sodium metabisulfite In ethanol; water at 20℃; for 2h;98%
5-iodovaniline
5438-36-8

5-iodovaniline

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

(2-(4-hydroxy-3-iodo-5-methoxyphenyl)-1H-benzoimidazol-5-yl)(phenyl)methanone

(2-(4-hydroxy-3-iodo-5-methoxyphenyl)-1H-benzoimidazol-5-yl)(phenyl)methanone

Conditions
ConditionsYield
With sodium metabisulfite In ethanol; water at 20℃; for 2h;98%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

benzil
134-81-6

benzil

6-benzoyl-2,3-diphenylquinoxaline
150252-47-4

6-benzoyl-2,3-diphenylquinoxaline

Conditions
ConditionsYield
With silica gel at 20 - 100℃; for 2h; Neat (no solvent);97%
With 1-methyl-3-(3-trimethoxysilylpropyl)imidazolium hydrogen sulfate immobilized on cellulose In water at 20℃; for 0.166667h; Green chemistry;97%
With gallium(III) triflate In ethanol at 20℃; for 0.333333h;95%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

4-Nitrophenyl isocyanate
100-28-7

4-Nitrophenyl isocyanate

C20H16N4O4
1315320-49-0

C20H16N4O4

Conditions
ConditionsYield
In dichloromethane at 20℃; for 24h;97%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

furoin
552-86-3

furoin

(2,3-di(furan-2-yl)quinoxalyn-6-yl)(phenyl)methanone

(2,3-di(furan-2-yl)quinoxalyn-6-yl)(phenyl)methanone

Conditions
ConditionsYield
With [P4-VP]-PdNPs In N,N-dimethyl-formamide at 120℃; for 0.0833333h; Reflux;97%
With silica sulfuric acid; PEG-400 at 120℃; for 6h;52%
carbon disulfide
75-15-0

carbon disulfide

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

(2-mercapto-1H-benzo[d]imidazol-6-yl)(phenyl)methanone
92685-57-9

(2-mercapto-1H-benzo[d]imidazol-6-yl)(phenyl)methanone

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water for 3h; Reflux;96.8%
With sodium hydroxide In ethanol Reflux;96.8%
Stage #1: carbon disulfide With potassium hydroxide In methanol Reflux;
Stage #2: 4-benzoylbenzene-1,2-diamine In methanol for 10h; Reflux;		69%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

3,3,6,6-tetrachloro-1,2-cyclohexanedione
96147-14-7

3,3,6,6-tetrachloro-1,2-cyclohexanedione

7-benzoyl-1,1,4,4-tetrachloro-1,2,3,4-tetrahydrophenazine

7-benzoyl-1,1,4,4-tetrachloro-1,2,3,4-tetrahydrophenazine

Conditions
ConditionsYield
In chloroform for 1h; Ambient temperature;96%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

4-isothiocyanato-4-methylpentan-2-one
27248-25-5

4-isothiocyanato-4-methylpentan-2-one

[4-amino-3-(4,4,6-trimethyl-2-thioxo-3,4-dihydro-2H-pyrimidin-1-yl)-phenyl]-phenyl-methanone

[4-amino-3-(4,4,6-trimethyl-2-thioxo-3,4-dihydro-2H-pyrimidin-1-yl)-phenyl]-phenyl-methanone

Conditions
ConditionsYield
In tetrahydrofuran for 48h; Ambient temperature;96%
dimethyl N-benzoyldithiocarbonimidate
24786-18-3

dimethyl N-benzoyldithiocarbonimidate

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

N-(5-benzoyl-1H-benzimidazol-2-yl)benzamide

N-(5-benzoyl-1H-benzimidazol-2-yl)benzamide

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 150℃; for 9h;96%
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

N, N'-di-(tert-butoxycarbonyl)-3,4-diaminobenzophenone
1282523-82-3

N, N'-di-(tert-butoxycarbonyl)-3,4-diaminobenzophenone

Conditions
ConditionsYield
With guanidine hydrochloride In ethanol at 35 - 40℃; for 3.5h;96%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

1,3-Dichloroacetone
534-07-6

1,3-Dichloroacetone

2,2-bis(chloromethyl)-5-benzoyl-2,3-dihydro-1H-benzo[d]imidazole
1093377-34-4

2,2-bis(chloromethyl)-5-benzoyl-2,3-dihydro-1H-benzo[d]imidazole

Conditions
ConditionsYield
at 60℃; for 0.25h; Neat (no solvent); grinding;96%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

benzaldehyde
100-52-7

benzaldehyde

phenyl (2-phenyl-1H-benzo[d]imidazol-5-yl)methanone
129545-20-6

phenyl (2-phenyl-1H-benzo[d]imidazol-5-yl)methanone

Conditions
ConditionsYield
With vanadium(IV)-salen complex nanoparticles immobilized onto silica In ethanol at 20℃; for 6h;95%
With ammonium acetate In ethanol at 75℃; for 7.5h;92%
With air In ethanol at 20℃; for 5.5h;90%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

5-Benzoylbenzotriazole
107508-46-3

5-Benzoylbenzotriazole

Conditions
ConditionsYield
With acetic acid; sodium nitrite In water at 20℃; for 12h;95%
With acetic acid In water at 70 - 80℃; for 0.466667h;87%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

acenaphthene quinone
82-86-0

acenaphthene quinone

9-benzoylacenaphtho<1,2-b>quinoxaline

9-benzoylacenaphtho<1,2-b>quinoxaline

Conditions
ConditionsYield
With niobium pentachloride In ethanol at 20℃; for 0.0666667h;95%
With lithium chloride In ethanol at 20℃; for 0.75h;95%
With lead(II) chloride In ethanol at 20℃; for 0.333333h;95%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

2-hydroxy-2-phenylacetophenone
119-53-9

2-hydroxy-2-phenylacetophenone

6-benzoyl-2,3-diphenylquinoxaline
150252-47-4

6-benzoyl-2,3-diphenylquinoxaline

Conditions
ConditionsYield
With [P4-VP]-PdNPs In N,N-dimethyl-formamide at 120℃; for 0.116667h; Reflux;95%
With potassium permanganate; copper(II) sulfate In ethanol for 2.5h; Reflux;87%
With potassium fluoride on basic alumina at 80℃; for 7h;79%
With silica sulfuric acid; PEG-400 at 120℃; for 6h;51%
With oxygen In ethanol at 70℃; for 6h; Schlenk technique; Sealed tube; Green chemistry;
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

2,2-dihydroxy-1-phenyl-ethanone
1075-06-5

2,2-dihydroxy-1-phenyl-ethanone

[2-(4-phenyl)quinoxalin-6-yl](phenyl)methanone
1338368-84-5

[2-(4-phenyl)quinoxalin-6-yl](phenyl)methanone

Conditions
ConditionsYield
With lithium chloride In ethanol at 20℃; for 0.666667h;95%
With lead(II) chloride In ethanol at 20℃; for 0.333333h; Reagent/catalyst;95%
With titanium(IV) oxide In 1,2-dichloro-ethane at 25℃; for 1.16667h;90%
Trimethyl orthoacetate
1445-45-0

Trimethyl orthoacetate

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

5-benzoyl-2-methyl benzimidazole
97375-60-5

5-benzoyl-2-methyl benzimidazole

Conditions
ConditionsYield
With silica choride at 80℃; for 0.3h;95%
With iron(II,III) oxide at 80℃; for 0.166667h;88%
With tungstate sulfuric acid In neat (no solvent) at 80℃; for 0.583333h; Green chemistry;85%
2,2-dihydroxy-1-(3-methoxyphenyl)ethanone
1201806-19-0

2,2-dihydroxy-1-(3-methoxyphenyl)ethanone

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

3-(3-methoxyphenyl)-7-benzoylquinoxaline

3-(3-methoxyphenyl)-7-benzoylquinoxaline

Conditions
ConditionsYield
With lead(II) chloride In ethanol at 20℃; for 0.333333h; Reagent/catalyst;95%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

O-methyl-N-(methoxycarbonyl)-isourea
40943-37-1

O-methyl-N-(methoxycarbonyl)-isourea

mebendazole
31431-39-7

mebendazole

Conditions
ConditionsYield
With acetic acid In toluene95%
With hydrogenchloride In chloroform Cooling with ice; Reflux;
Cyclohexyl isocyanide
931-53-3

Cyclohexyl isocyanide

trimethylsilylazide
4648-54-8

trimethylsilylazide

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

cyclohexanone
108-94-1

cyclohexanone

{4a'-(1-cyclohexyl-1H-tetrazol-5-yl)-1',2',3',4',4a',5',10',11a'-octahydrospiro[cyclohexane-1,11'-dibenzo[b,e][1,4]diazepine]-7'-yl}(phenyl)methanone
1374754-04-7

{4a'-(1-cyclohexyl-1H-tetrazol-5-yl)-1',2',3',4',4a',5',10',11a'-octahydrospiro[cyclohexane-1,11'-dibenzo[b,e][1,4]diazepine]-7'-yl}(phenyl)methanone

Conditions
ConditionsYield
With NiO39PW11(5-)*5C8H15N2(1+)*3H2O In methanol at 20℃; for 4h;95%
...Expand
m-bromobenzoic aldehyde
3132-99-8

m-bromobenzoic aldehyde

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

(2-(3-bromophenyl)-1H-benzo[d]imidazol-6-yl)(phenyl)methanone

(2-(3-bromophenyl)-1H-benzo[d]imidazol-6-yl)(phenyl)methanone

Conditions
ConditionsYield
With nickel diacetate In chloroform at 60℃; Microwave irradiation; Green chemistry;95%
4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

1,2-bis(4-methoxyphenyl)-1,2-ethanedione
1226-42-2

1,2-bis(4-methoxyphenyl)-1,2-ethanedione

(2,3-bis(4-methoxyphenyl)quinoxalin-6-yl)(phenyl)methanone

(2,3-bis(4-methoxyphenyl)quinoxalin-6-yl)(phenyl)methanone

Conditions
ConditionsYield
With titanium(IV) oxide In 1,2-dichloro-ethane at 25℃; for 1.5h;94%
With zirconium triflate In ethanol; water at 20℃; for 0.333333h; Green chemistry;94%
With H3PMo12O40 nanoparticles immobilized on imidazole functionalized core-shell Fe3O4(at)SiO2 nanoparticle In ethanol at 20℃; for 0.333333h; Green chemistry;93%
2,2'-Pyridil
492-73-9

2,2'-Pyridil

4-benzoylbenzene-1,2-diamine
39070-63-8

4-benzoylbenzene-1,2-diamine

phenyl(2,3-di(pyridin-2-yl)quinoxalin-6-yl)methanone
246518-07-0

phenyl(2,3-di(pyridin-2-yl)quinoxalin-6-yl)methanone

Conditions
ConditionsYield
With PEG-400 at 110℃; for 1h; Neat (no solvent);94%
With polyethylene glycol-400 at 120℃; for 0.0833333h; Microwave irradiation;91%
In glycerol at 90℃; for 0.133333h; Microwave irradiation; Green chemistry;86%

3,4-DIAMINOBENZOPHENONE Chemical Properties

IUPAC Name: (3,4-Diaminophenyl)phenylmethanone
The MF of (3,4-Diaminophenyl)phenylmethanone (39070-63-8) is C13H12N2O.

                                  
The MW of (3,4-Diaminophenyl)phenylmethanone (39070-63-8) is 212.25.
Synonyms of (3,4-Diaminophenyl)phenylmethanone (39070-63-8): (3,4-Diaminophenyl)(phenyl)methanon ; 2-Amino-4-benzoylaniline ; Methanone, (3,4-diaminophenyl)phenyl- ; (3,4-Diaminophenyl)phenylmethanone ; 3,4-Diaminobenzophenone
Product Categories: FINE Chemical & INTERMEDIATES;Aromatic Benzophenones Form: yellow to ochre-yellow powder
Index of Refraction: 1.673 
EINECS: 254-273-8
Density: 1.233 g/ml 
Flash Point: 220.3 °C
Boiling Point: 440.7 °C
Melting Point: 115-117 °C
Water Solubility: 410 mg/L (20 ºC)
BRN: 2212487

3,4-DIAMINOBENZOPHENONE Uses

  (3,4-Diaminophenyl)phenylmethanone (39070-63-8) is used as pharmaceutical intermediates, for the production of anthelmintic mebendazole.

3,4-DIAMINOBENZOPHENONE Production

It is derived from O-Dichlorobenzene and Benzoyl chloride by the reaction of amine.

3,4-DIAMINOBENZOPHENONE Safety Profile

Safety information of (3,4-Diaminophenyl)phenylmethanone (39070-63-8):
Hazard Codes  Xi
Risk Statements 
36/37/38  Irritating to eyes, respiratory system and skin
Safety Statements 
26  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39  Wear suitable protective clothing, gloves and eye/face protection
WGK Germany  3
F  9-23
HS Code  29223900

Related Products

Hot Products

Post buying leads

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View