3,4-Dinitrotoluene supplier

Name
3,4-DINITROTOLUENE
EINECS
CAS No. 610-39-9
Article Data29
CAS DataBase
Density 1.407g/cm³
Solubility
Melting Point 54-57 °C(lit.)
Formula C7H6 N2 O4
Boiling Point 350.8°C at 760 mmHg
Molecular Weight 182.136
Flash Point >230 °F
Transport Information
Appearance
Safety Moderately toxic by ingestion. Mutation data reported. A skin irritant. When heated to decomposition it emits toxic fumes of NO_x. See also 2,4-DINITROTOLUENE.
Risk Codes 45-23/24/25-48/22-51/53-62-68
Molecular Structure
Hazard Symbols T,N
Synonyms Toluene,3,4-dinitro- (8CI); 1-Methyl-3,4-dinitrobenzene; 3,4-DNT; 3,4-Dinitrotoluene;4-Methyl-1,2-dinitrobenzene; 5-Methyl-1,2-dinitrobenzene; NSC 52216
PSA 91.64000
LogP 2.85780

Synthetic route

: 89-62-3
4-methyl-2-nitroaniline

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
Stage #1: 4-methyl-2-nitroaniline With sulfuric acid; sodium nitrite In water for 0.333333h; cooling; Stage #2: With sodium hydrogencarbonate; sodium nitrite In water at 10 - 20℃; for 0.166667h; Further stages.;	92%
With caro's acid Oxydation mit rauchender Salpetersaeure;
Diazotization.Behandlung der Diazoniumsalz-Loesung mit NaNO2 und Kupfer(I)-kupfer(II)-sulfit;

: 99-08-1
1-methyl-3-nitrobenzene

A: 602-01-7
1-methyl-2,3-dinitrobenzene

B: 610-39-9
3,4-Dinitrotoluene

C: 619-15-8
2,5-dinitrotoluene

Conditions

Conditions	Yield
With nitronium hexafluorophosphate; sulfuric acid	A 28.4% B 60.1% C 9.9%
With nitronium hexafluorophosphate In nitromethane at 24.84℃;

...Expand

: 99-08-1
1-methyl-3-nitrobenzene

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
bei der Nitrierung;
Nitrierung;
durch Nitrierung;

: 612-45-3
4-methyl-2-nitroacetanilide

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
With dihydrogen peroxide; acetic acid

: 6971-33-1
4-methyl-2-nitro-1-nitrosobenzene

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
With dihydrogen peroxide; nitric acid; acetic acid
With nitric acid
With nitric acid
With nitric acid for 0.0833333h;	8 g

: 578-46-1
5-methyl-2-nitroaniline

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
Diazotization.Behandlung der Diazoniumsalz-Loesung mit NaNO2 und Kupfer(I)-kupfer(II)-sulfit;

: 3484-29-5
2,3-dinitro-6-methylaniline

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
With ethanol; sulfuric acid; sodium nitrite

: 70343-04-3
3,4-dinitro-6-methylaniline

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
With ethanol; sulfuric acid; sodium nitrite

: 70343-07-6
2,3-dinitro-5-methylaniline

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
With ethanol; sulfuric acid; sodium nitrite

: 2-nitro-4-methylbenzene diazonium tetrafluoroborate

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
With sodium nitrite In water at 40.1 - 56.9℃; Kinetics;

: 99-08-1
1-methyl-3-nitrobenzene

A: 610-39-9
3,4-Dinitrotoluene

B 2.3-dinitro-toluene, 2.5-dinitro-toluene: 2.3-dinitro-toluene, 2.5-dinitro-toluene

Conditions

Conditions	Yield
durch Nitrierung;

: 99-08-1
1-methyl-3-nitrobenzene

: 7697-37-2
nitric acid

A: 602-01-7
1-methyl-2,3-dinitrobenzene

B: 610-39-9
3,4-Dinitrotoluene

C: 619-15-8
2,5-dinitrotoluene

...Expand

: 99-08-1
1-methyl-3-nitrobenzene

: 7664-93-9
sulfuric acid

: 7732-18-5
water

: 7697-37-2
nitric acid

A: 602-01-7
1-methyl-2,3-dinitrobenzene

B: 610-39-9
3,4-Dinitrotoluene

C: 619-15-8
2,5-dinitrotoluene

Conditions

Conditions	Yield
at 40 - 70℃; Product distribution;

...Expand

: 99-08-1
1-methyl-3-nitrobenzene

HNO3+H2SO4: HNO3+H2SO4

A: 602-01-7
1-methyl-2,3-dinitrobenzene

B: 610-39-9
3,4-Dinitrotoluene

C: 619-15-8
2,5-dinitrotoluene

...Expand

: 99-08-1
1-methyl-3-nitrobenzene

: 7664-93-9
sulfuric acid

: 7697-37-2
nitric acid

A: 618-85-9
3,5-dinitrotoluene

B: 602-01-7
1-methyl-2,3-dinitrobenzene

C: 610-39-9
3,4-Dinitrotoluene

D: 619-15-8
2,5-dinitrotoluene

Conditions

Conditions	Yield
at 60 - 85℃;

...Expand

: 6971-33-1
4-methyl-2-nitro-1-nitrosobenzene

: 7697-37-2
nitric acid

: 610-39-9
3,4-Dinitrotoluene

: 618-85-9
3,5-dinitrotoluene

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
Multi-step reaction with 5 steps 1: alcohol; ammonium sulfide 3: concentrated sulfuric acid; nitric acid / <9 4: aqueous alcoholic sulfuric acid 5: absolute alcohol; fuming sulfuric acid; sodium nitrite View Scheme

: 2879-79-0
N-(2-methyl-5-nitrophenyl)acetamide

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: concentrated sulfuric acid; nitric acid / Erhitzen des Reaktionsprodukts mit verd.Schwefelsaeure 2: absolute alcohol; fuming sulfuric acid; sodium nitrite View Scheme
Multi-step reaction with 2 steps 1: concentrated sulfuric acid; nitric acid / Erhitzen des Reaktionsprodukts mit verd.Schwefelsaeure 2: absolute alcohol; fuming sulfuric acid; sodium nitrite View Scheme

: 618-61-1
3-methyl-5-nitro-aniline

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 2: concentrated sulfuric acid; nitric acid / <9 3: aqueous alcoholic sulfuric acid 4: absolute alcohol; fuming sulfuric acid; sodium nitrite View Scheme

: 69112-72-7
acetic acid-(3-methyl-5-nitro-anilide)

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: concentrated sulfuric acid; nitric acid / <9 2: aqueous alcoholic sulfuric acid 3: absolute alcohol; fuming sulfuric acid; sodium nitrite View Scheme

: 861297-21-4
acetic acid-(5-methyl-2,3-dinitro-anilide)

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: aqueous alcoholic sulfuric acid 2: absolute alcohol; fuming sulfuric acid; sodium nitrite View Scheme

: 537-92-8
3-Methylacetanilide

: 610-39-9
3,4-Dinitrotoluene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: sulfuric acid; acetic acid; nitric acid / und Erhitzen des Reaktionsprodukts mit wss.Schwefelsaeure 2: Diazotization.Behandlung der Diazoniumsalz-Loesung mit NaNO2 und Kupfer(I)-kupfer(II)-sulfit View Scheme

: 108-88-3
toluene

A: 121-14-2
2,4-dinitrotoluene

B: 618-85-9
3,5-dinitrotoluene

C: 606-20-2
2,6-dinitrotoluene

D: 610-39-9
3,4-Dinitrotoluene

E: 619-15-8
2,5-dinitrotoluene

Conditions

Conditions	Yield
With ferric nitrate pentahydrate; nitric acid at 100℃; for 99h;

...Expand

: 610-39-9
3,4-Dinitrotoluene

: 528-45-0
3,4-dinitrobenzoic acid

Conditions

Conditions	Yield
With oxygen; ozone; acetic acid; cobalt(II) acetate at 100℃;	97.6%
With chromium(VI) oxide; sulfuric acid 1.) 35 deg C, 0.5 h, 2.) 45-55 deg C, 4 h;	75%
With nitric acid at 140℃;

: 71-23-8
propan-1-ol

: 610-39-9
3,4-Dinitrotoluene

: 2-ethyl-6-methylbenzimidazole

Conditions

Conditions	Yield
With titanium(IV) oxide for 4h; Irradiation;	97%

: 610-39-9
3,4-Dinitrotoluene

: 496-72-0
4-methyl-1,2-diaminobenzene

Conditions

Conditions	Yield
With 5%-palladium/activated carbon; hydrogen In ethanol at 20℃; for 48h;	96.6%
With hydrogen In methanol at 50℃; under 1500.15 Torr; for 0.25h; Inert atmosphere;	88%
With 5 wt% ruthenium/carbon; hydrogen; sodium nitrite In isopropyl alcohol at 150℃; under 62256.2 Torr; for 4h; Temperature; Autoclave;

: 64-18-6
formic acid

: 610-39-9
3,4-Dinitrotoluene

: 614-97-1
5-methylbenzimidazole

Conditions

Conditions	Yield
With gold nano particles supported on rutile TiO2 In toluene at 70℃; under 750.075 Torr; for 6h; Inert atmosphere; chemoselective reaction;	96%

: 64-17-5
ethanol

: 610-39-9
3,4-Dinitrotoluene

: 1792-41-2
2,6-dimethyl-1H-benzo[d]imidazole

Conditions

Conditions	Yield
With titanium(IV) oxide for 4h; Irradiation;	95%

: 610-39-9
3,4-Dinitrotoluene

: 76213-13-3
3,4-dinitrobenzo trichloride

Conditions

Conditions	Yield
With hypochlorous anhydride In tetrachloromethane at 75℃;	89%

: 610-39-9
3,4-Dinitrotoluene

: 70384-51-9
Tris(3,6-dioxaheptyl)amine

: 108-00-9
N,N-dimethylethylenediamine

A: 138423-04-8
N,N-Dimethyl-2-(5-methyl-2-nitroanilino)ethanamine

B: 144674-99-7
N,N,N-Trimethyl-2-(5-methyl-2-nitroanilino)ethanaminium Iodide

Conditions

Conditions	Yield
In dimethyl sulfoxide	A 80% B n/a

...Expand

: 610-39-9
3,4-Dinitrotoluene

: 707-07-3
orthobenzoic acid trimethyl ester

: 2963-65-7
5-methyl-2-phenyl-1H-1,3-benzimidazole

Conditions

Conditions	Yield
With indium; acetic acid In ethyl acetate for 4h; Reflux; Inert atmosphere;	58%

: 610-39-9
3,4-Dinitrotoluene

: 578-46-1
5-methyl-2-nitroaniline

Conditions

Conditions	Yield
With formic acid; triethylamine; palladium on activated charcoal at 100℃; for 1h;	55%
With urea; tetramethylurea at 110℃;

: 1445-45-0
Trimethyl orthoacetate

: 610-39-9
3,4-Dinitrotoluene

: 1792-41-2
2,5-dimethylbenzimidazole

Conditions

Conditions	Yield
With indium; acetic acid In ethyl acetate for 4.5h; Reflux; Inert atmosphere;	53%

: 610-39-9
3,4-Dinitrotoluene

: 302-72-7
rac-Ala-OH

: 639474-96-7
D,L-N-(5-methyl-2-nitrophenyl)alanine

Conditions

Conditions	Yield
With sodium hydroxide In dimethyl sulfoxide at 150℃; for 0.5h;	49.7%

: 610-39-9
3,4-Dinitrotoluene

: 67-64-1
acetone

A: 2,2,4,7-tetramethyl-2,3-dihydro-1H-benzo[b][1,4]diazepine

B: C10H14N2

C: 2,2,4,8-tetramethyl-2,3-dihydro-1H-1,5-benzodiazepine

Conditions

Conditions	Yield
With 0.2 wt% Pt/TiO2; hydrogen at 55 - 65℃; under 5250.53 Torr; for 3.25h;	A n/a B 7% C n/a

...Expand

: 610-39-9
3,4-Dinitrotoluene

: 65542-35-0
3-nitrotoluene-4-sulfonic acid

Conditions

Conditions	Yield
With sodium sulfite In water Substitution; Heating;	4%

: 610-39-9
3,4-Dinitrotoluene

: 100-67-4
potassium phenolate

: 60287-60-7
4-methyl-1-nitro-2-phenoxybenzene

Conditions

Conditions	Yield
With phenol

: 610-39-9
3,4-Dinitrotoluene

: 124-41-4
sodium methylate

: 38512-82-2
3-methoxy-4-nitrotoluene

: 610-39-9
3,4-Dinitrotoluene

: 563-41-7
semicarbazide hydrochloride

: 1-(5-methyl-2-nitro-phenyl)-semicarbazide

Conditions

Conditions	Yield
With ethanol; sodium acetate

: 610-39-9
3,4-Dinitrotoluene

A: 5-methyl-3H-benzotriazole-1-oxide

B: 56637-42-4
5-methyl-2-nitrophenylhydrazine

Conditions

Conditions	Yield
With ethanol; hydrazine hydrate

: 610-39-9
3,4-Dinitrotoluene

: 602-29-9
2,3,4-trinitrotoluene

Conditions

Conditions	Yield
Nitrierung;

: 610-39-9
3,4-Dinitrotoluene

A: 602-29-9
2,3,4-trinitrotoluene

B: 610-25-3
2,4,5-trinitrotoluene

Conditions

Conditions	Yield
With sulfuric acid; nitric acid

: 610-39-9
3,4-Dinitrotoluene

: 610-25-3
2,4,5-trinitrotoluene

Conditions

Conditions	Yield
With sulfuric acid; nitric acid at 95℃;
Nitrierung;
With sulfuric acid; nitric acid at 80 - 90℃; for 0.5h;

: 610-39-9
3,4-Dinitrotoluene

: 52062-85-8
(5,5'-dimethyl-2,2'-dinitrophenyl)disulfide

Conditions

Conditions	Yield
With methanol; sodium sulfide; sulfur

: 610-39-9
3,4-Dinitrotoluene

: 6971-33-1
4-methyl-2-nitro-1-nitrosobenzene

Conditions

Conditions	Yield
With potassium hydroxide; hydroxylamine Behandeln mit Wasser und Ansaeuern mit Salzsaeure;

: 610-39-9
3,4-Dinitrotoluene

A: 6971-33-1
4-methyl-2-nitro-1-nitrosobenzene

B: 474318-51-9
5-methyl-2-nitronitrosobenzene

Conditions

Conditions	Yield
With methanol; hydroxylamine

: 610-39-9
3,4-Dinitrotoluene

: 89-62-3
4-methyl-2-nitroaniline

Conditions

Conditions	Yield
With methanol; ammonia at 150℃; unter Druck;

: 610-39-9
3,4-Dinitrotoluene

A: 578-46-1
5-methyl-2-nitroaniline

B: 89-62-3
4-methyl-2-nitroaniline

Conditions

Conditions	Yield
With hydrogenchloride; tin(ll) chloride at 7℃;
With methanol; ammonia at 150℃; unter Druck;

3,4-Dinitrotoluene Chemical Properties

Chemistry informtion about 3,4-Dinitrotoluene (CAS NO.610-39-9) is:
IUPAC Name: 4-Methyl-1,2-Dinitrobenzene
Synonyms: 1,2-Dinitro4-Methylbenzene ; 3,4-Dinitro-Toluen ; 3,4-Dnt ; 4-Methyl-1,2-Dinitro-Benzen ; 4-Methyl-1,2-Dinitrobenzene ; Benzene,1-Methyl-3,4-Dinitro- ; Benzene,4-Methyl-1,2-Dinitro- ; Toluene, 3,4-Dinitro-
Product Categories: Intermediates of Dyes and Pigments ; Nitro Compounds ; Nitrogen Compounds ; Organic Building Blocks
MF: C₇H₆N₂O₄
MW: 182.13
EINECS: 210-222-1
Density: 1.407 g/cm3
Melting Point: 54-57 °C(lit.)
Flash Point: 184.1 °C
Boiling Point: 350.8 °C at 760 mmHg
Vapour Pressure: 8.66E-05 mmHg at 25°C
Enthalpy of Vaporization: 57.2 kJ/mol
Following is the molecular structure of 3,4-Dinitrotoluene (CAS NO.610-39-9) is:

3,4-Dinitrotoluene Production

Raw materials is 3-Nitrotoluene .

3,4-Dinitrotoluene Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	oral	747mg/kg (747mg/kg)	behavioral: somnolence (general depressed activity)	National Technical Information Service. Vol. AD-A080-146,
rat	LD50	oral	807mg/kg (807mg/kg)		National Technical Information Service. Vol. AD-A080-146,

3,4-Dinitrotoluene Consensus Reports

Reported in EPA TSCA Inventory.

3,4-Dinitrotoluene Safety Profile

Moderately toxic by ingestion. Mutation data reported. A skin irritant. When heated to decomposition it emits toxic fumes of NO_x. See also 2,4-DINITROTOLUENE.
Hazard Codes:
Toxic T
Dangerous N
Risk Statements:
R45:May cause cancer.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R48/22:Harmful: danger of serious damage to health by prolonged exposure if swallowed.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R62:Risk of impaired fertility.
R68:Possible risk of irreversible effects.
Safety Statements:
S53:Avoid exposure - obtain special instructions before use.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 3454 6.1/PG 2
WGK Germany: 3
RTECS: XT2100000
HazardClass: 6.1
PackingGroup: II

3,4-Dinitrotoluene Standards and Recommendations

OSHA PEL: TWA 1.5 mg/m³ (skin)
NIOSH REL: (Dinitrotoluene) Reduce to lowest level

3,4-Dinitrotoluene Specification

3,4-Dinitrotoluene (CAS NO.610-39-9) is a yellow to red solid or heated liquid with a slight odor. Solidifies in cool water. Solid and liquid sink in water . It may explode when exposed to heat or flame [USCG, 1999]. Inhalation, ingestion or skin absorption: Headache, weakness, nausea or dizziness, cyanosis, drowsiness, shortness of breath and collapse. Eyes and skins: Can burn eyes and skin.

Product Name

3,4-DINITROTOLUENE

Synthetic route

3,4-Dinitrotoluene Chemical Properties

3,4-Dinitrotoluene Production

3,4-Dinitrotoluene Toxicity Data With Reference

3,4-Dinitrotoluene Consensus Reports

3,4-Dinitrotoluene Safety Profile

3,4-Dinitrotoluene Standards and Recommendations

3,4-Dinitrotoluene Specification

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