Product Name

  • Name

    3-Picolyl chloride hydrochloride

  • EINECS 230-150-4
  • CAS No. 6959-48-4
  • Article Data6
  • CAS DataBase
  • Density
  • Solubility >=10 g/100 mL at 19 °C in water
  • Melting Point 137-143 °C
  • Formula C6H6ClN.HCl
  • Boiling Point 210 °C at 760 mmHg
  • Molecular Weight 164.034
  • Flash Point 100.5 °C
  • Transport Information UN 2811
  • Appearance White to pale brown solid
  • Safety 26-36-53-45
  • Risk Codes 22-36/37/38-45-20/21/22
  • Molecular Structure Molecular Structure of 6959-48-4 (3-Picolyl chloride hydrochloride)
  • Hazard Symbols HarmfulXn, CorrosiveC, ToxicT
  • Synonyms Pyridine,3-(chloromethyl)-, hydrochloride (8CI,9CI);(Pyridin-3-yl)methyl chloridehydrochloride;3-(Chloromethyl)pyridine hydrochloride;3-(Chloromethyl)pyridinemonohydrochloride;3-Picolyl chloride hydrochloride;3-Pyridylmethyl chloridehydrochloride;
  • PSA 12.89000
  • LogP 2.62240

Synthetic route

3-Methylpyridine
108-99-6

3-Methylpyridine

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

Conditions
ConditionsYield
Stage #1: 3-Methylpyridine With hydrogenchloride at 0℃; under 760.051 Torr; for 9h; Large scale;
Stage #2: With chlorine at 110 - 125℃; for 8h; Temperature; Large scale;		93.26%
Multi-step reaction with 4 steps
1: potassium permanganate / water / 0.5 h / 80 - 90 °C
2: sulfuric acid
3: aluminum (III) chloride; sodium tetrahydroborate / tetrahydrofuran; toluene / 0 - 5 °C
4: thionyl chloride
View Scheme
3-hydroxymethylpyridin
100-55-0

3-hydroxymethylpyridin

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

Conditions
ConditionsYield
With thionyl chloride at 60℃; for 16h;86%
With thionyl chloride In chloroform at 0℃; Reflux;63.6%
With thionyl chloride26.9 mg
With thionyl chloride In methanol26.2 g
With thionyl chloride In dichloromethane at 0 - 60℃; for 1.25h;
3-pyridinecarboxaldehyde
500-22-1

3-pyridinecarboxaldehyde

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium tetrahydroborate; methanol / 8 h / 0 - 20 °C
2: thionyl chloride / chloroform / 0 °C / Reflux
View Scheme
nicotinic acid
59-67-6

nicotinic acid

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: sulfuric acid
2: aluminum (III) chloride; sodium tetrahydroborate / tetrahydrofuran; toluene / 0 - 5 °C
3: thionyl chloride
View Scheme
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

triphenylphosphine
603-35-0

triphenylphosphine

Triphenyl-3-pyridylmethylphosphonium chloride hydrochlorides
79296-92-7

Triphenyl-3-pyridylmethylphosphonium chloride hydrochlorides

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 140℃; for 20h;100%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

methyl 4-oxo-3-piperidinecarboxylate hydrochloride
71486-53-8

methyl 4-oxo-3-piperidinecarboxylate hydrochloride

methyl 4-oxo-1-(pyridin-3-ylmethyl)piperidine-3-carboxylate
1225498-23-6

methyl 4-oxo-1-(pyridin-3-ylmethyl)piperidine-3-carboxylate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; sodium iodide In acetonitrile at 80℃; for 1h;100%
With N-ethyl-N,N-diisopropylamine; sodium iodide In acetonitrile at 80℃; for 1h;
sodium methylate
124-41-4

sodium methylate

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

3-(methoxymethyl)pyridine
58418-62-5

3-(methoxymethyl)pyridine

Conditions
ConditionsYield
In methanol at 20℃; for 72h;99%
In dimethyl sulfoxide at 20℃; for 24h;64%
2-(4-but-2-ynyloxy-phenylsulfonyl)-propionic acid ethyl ester
287392-70-5

2-(4-but-2-ynyloxy-phenylsulfonyl)-propionic acid ethyl ester

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

2-(4-buty-2-nyloxy-phenylsulfonyl)-2-methyl-3-pyridin-3-yl propionic acid ethyl ester

2-(4-buty-2-nyloxy-phenylsulfonyl)-2-methyl-3-pyridin-3-yl propionic acid ethyl ester

Conditions
ConditionsYield
98%
sodium ethanolate
141-52-6

sodium ethanolate

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

3-(ethoxymethyl)pyridine
58418-63-6

3-(ethoxymethyl)pyridine

Conditions
ConditionsYield
In dimethyl sulfoxide at 20℃;98%
In dimethyl sulfoxide at 20℃;98%
(S)-1-tert-butoxycarbonyl-2-tert-butylcarboxamide-4-benzyloxycarbonyl-piperazine

(S)-1-tert-butoxycarbonyl-2-tert-butylcarboxamide-4-benzyloxycarbonyl-piperazine

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

4-pyridin-3-ylmethyl-piperazine-2-carboxylic acid tert-butylamide

4-pyridin-3-ylmethyl-piperazine-2-carboxylic acid tert-butylamide

Conditions
ConditionsYield
Stage #1: (S)-1-tert-butoxycarbonyl-2-tert-butylcarboxamide-4-benzyloxycarbonyl-piperazine With cyclohexa-1,4-diene; hydrogen; palladium on activated charcoal In ethyl acetate at 23℃; for 1h;
Stage #2: 3-chloromethylpyridinium chloride With triethylamine In N,N-dimethyl-formamide at 23℃; for 22h;
Stage #3: With triethylsilane; trifluoroacetic acid In dichloromethane at 23℃; for 20h; Further stages.;		97%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

diethylamine
109-89-7

diethylamine

3-(N,N-diethylaminomethyl)pyridine
2055-14-3

3-(N,N-diethylaminomethyl)pyridine

Conditions
ConditionsYield
In acetonitrile at -10 - 20℃; for 96h; Cooling with ice;97%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

3-Picolyl chloride
3099-31-8

3-Picolyl chloride

Conditions
ConditionsYield
With sodium hydrogencarbonate In water96%
With potassium hydroxide In benzene at 0℃; for 0.0166667h;
With sodium hydroxide In diethyl ether; water
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

thiourea
17356-08-0

thiourea

S-(3-picolyl)isothiourea dihydrochloride
82081-34-3, 82081-66-1

S-(3-picolyl)isothiourea dihydrochloride

Conditions
ConditionsYield
In ethanol for 3h; Heating;95%
In methanol for 10h; Ambient temperature;93%
In ethanol Heating;
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

N-[(4-methoxyphenyl)sulfonyl]-D-valine tert-butyl ester
161315-62-4

N-[(4-methoxyphenyl)sulfonyl]-D-valine tert-butyl ester

tert-butyl 2-{[(4-methoxyphenyl)sulfonyl](3-pyridinylmethyl)amino}-3-methylbutanoate

tert-butyl 2-{[(4-methoxyphenyl)sulfonyl](3-pyridinylmethyl)amino}-3-methylbutanoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide for 48h; Ambient temperature;95%
3,5-dichlorothiophenol
17231-94-6

3,5-dichlorothiophenol

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

3-(3,5-dichloro-phenylsulfanylmethyl)-pyridine
915413-26-2

3-(3,5-dichloro-phenylsulfanylmethyl)-pyridine

Conditions
ConditionsYield
With sodium hydroxide In ethanol at 20℃;95%
With sodium hydroxide In ethanol; water at 20℃;95%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

3-(3,5-dichloro-phenylsulfanylmethyl)-pyridine

3-(3,5-dichloro-phenylsulfanylmethyl)-pyridine

Conditions
ConditionsYield
Stage #1: 3,5-dichlorothiophenol With sodium hydroxide In ethanol for 0.166667h;
Stage #2: 3-chloromethylpyridinium chloride In ethanol; water at 20℃;		95%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

meta-hydroxyacetanilide
621-42-1

meta-hydroxyacetanilide

3-(3'-pyridylmethoxy)acetanilide

3-(3'-pyridylmethoxy)acetanilide

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20 - 80℃; for 48h;95%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

3,3'-(2,7-dioxaoctane)-dipyridine
851761-78-9

3,3'-(2,7-dioxaoctane)-dipyridine

Conditions
ConditionsYield
Stage #1: Butane-1,4-diol With sodium t-butanolate In N,N-dimethyl-formamide at 0 - 20℃; for 1h;
Stage #2: 3-chloromethylpyridinium chloride With sodium t-butanolate In N,N-dimethyl-formamide at -16 - 0℃;
Stage #3: With water In dichloromethane Product distribution / selectivity;		94.9%
Stage #1: Butane-1,4-diol With potassium tert-butylate In N,N-dimethyl-formamide at 0 - 20℃; for 1 - 2h;
Stage #2: 3-chloromethylpyridinium chloride With potassium tert-butylate In N,N-dimethyl-formamide at -16 - 5℃;
Stage #3: With water In dichloromethane Product distribution / selectivity;		89.9%
Stage #1: C10H15NO2 With potassium tert-butylate In N,N-dimethyl-formamide at 0℃;
Stage #2: 3-chloromethylpyridinium chloride With potassium tert-butylate In N,N-dimethyl-formamide at 5 - 6℃;
Stage #3: With water In dichloromethane Product distribution / selectivity;
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

thiourea
17356-08-0

thiourea

C7H10N3S(1+)*Cl(1-)

C7H10N3S(1+)*Cl(1-)

Conditions
ConditionsYield
In ethanol for 4h; Heating;94%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

(2R,3R,4S,5R,6R)-2-(5-Azido-pentyloxymethyl)-4,5-bis-benzyloxy-6-methoxy-tetrahydro-pyran-3-ol
543697-42-3

(2R,3R,4S,5R,6R)-2-(5-Azido-pentyloxymethyl)-4,5-bis-benzyloxy-6-methoxy-tetrahydro-pyran-3-ol

3-[(2R,3R,4S,5R,6R)-2-(5-Azido-pentyloxymethyl)-4,5-bis-benzyloxy-6-methoxy-tetrahydro-pyran-3-yloxymethyl]-pyridine
543697-44-5

3-[(2R,3R,4S,5R,6R)-2-(5-Azido-pentyloxymethyl)-4,5-bis-benzyloxy-6-methoxy-tetrahydro-pyran-3-yloxymethyl]-pyridine

Conditions
ConditionsYield
Stage #1: (2R,3R,4S,5R,6R)-2-(5-Azido-pentyloxymethyl)-4,5-bis-benzyloxy-6-methoxy-tetrahydro-pyran-3-ol With sodium hydride In N,N-dimethyl-formamide at 0℃;
Stage #2: 3-chloromethylpyridinium chloride With tetra-(n-butyl)ammonium iodide In N,N-dimethyl-formamide at 0℃;		94%
cobalt(II) chloride hexahydrate

cobalt(II) chloride hexahydrate

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

Co(2+)*4Cl(1-)*2C6H6ClN*2H(1+)

Co(2+)*4Cl(1-)*2C6H6ClN*2H(1+)

Conditions
ConditionsYield
With hydrogenchloride In ethanol94%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

(Z)-5-(4-ethoxybenzylidene)thiazolidine-2,4-dione

(Z)-5-(4-ethoxybenzylidene)thiazolidine-2,4-dione

(Z)-5-(4-ethoxybenzylidene)-3-(pyridin-3-ylmethyl)thiazolidine-2,4-dione
1438409-41-6

(Z)-5-(4-ethoxybenzylidene)-3-(pyridin-3-ylmethyl)thiazolidine-2,4-dione

Conditions
ConditionsYield
Stage #1: (Z)-5-(4-ethoxybenzylidene)thiazolidine-2,4-dione With potassium carbonate; sodium iodide In N,N-dimethyl-formamide at 0℃; for 0.333333h;
Stage #2: 3-chloromethylpyridinium chloride In N,N-dimethyl-formamide at 20℃;		93.1%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

methyl 2(R)-[(4-methoxyphenyl)sulfonyl amino]-3-methylbutanoate
161315-46-4

methyl 2(R)-[(4-methoxyphenyl)sulfonyl amino]-3-methylbutanoate

methyl 2(R)-[[(4-methoxyphenyl)sulfonyl](3-picolyl)amino]-3-methylbutanoate
477908-17-1

methyl 2(R)-[[(4-methoxyphenyl)sulfonyl](3-picolyl)amino]-3-methylbutanoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃;93%
tert-butyl (R)-N-(4-methoxyphenylsulfonyl)-γ-fluoro-α-aminobutanoate
1408282-72-3

tert-butyl (R)-N-(4-methoxyphenylsulfonyl)-γ-fluoro-α-aminobutanoate

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

tert-butyl (R)-N-(4-methoxyphenylsulfonyl)-N-(3-pyridylmethyl)-2-amino-4-fluorobutanoate
1408282-83-6

tert-butyl (R)-N-(4-methoxyphenylsulfonyl)-N-(3-pyridylmethyl)-2-amino-4-fluorobutanoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 48h;93%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

phosphonic acid diethyl ester
762-04-9

phosphonic acid diethyl ester

diethyl (pyridin-3-ylmethyl)phosphonate
2682-86-2

diethyl (pyridin-3-ylmethyl)phosphonate

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; N-ethyl-N,N-diisopropylamine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In tetrahydrofuran for 4h; Reflux; Inert atmosphere;92%
homoalylic alcohol
627-27-0

homoalylic alcohol

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

3-NC5H4CH2O(CH2)2CHCH2
1364571-64-1

3-NC5H4CH2O(CH2)2CHCH2

Conditions
ConditionsYield
Stage #1: homoalylic alcohol With sodium at 80℃; Inert atmosphere;
Stage #2: 3-chloromethylpyridinium chloride at 80℃; for 12h; Inert atmosphere;		92%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

aniline
62-53-3

aniline

N,N-bis(-pyridin-2ylmethyl)benzenamine
301668-92-8

N,N-bis(-pyridin-2ylmethyl)benzenamine

Conditions
ConditionsYield
With potassium carbonate at 50℃; for 12h;92%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

Diethyl methylmalonate
609-08-5

Diethyl methylmalonate

diethyl 2-(1-(pyridin-3-yl)propan-2-yl)malonate
1101217-82-6

diethyl 2-(1-(pyridin-3-yl)propan-2-yl)malonate

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 8h;91.2%
N-{2-hydroxy-3-(4-methylpiperazin-1-yl)propyl}cis-cyclohex-4-ene-1,2-dicarboximide

N-{2-hydroxy-3-(4-methylpiperazin-1-yl)propyl}cis-cyclohex-4-ene-1,2-dicarboximide

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

maleic acid
110-16-7

maleic acid

N-{3-(4-Methylpiperazin-1-yl)-2-nicotinyloxypropyl}cis-cyclohex-4-ene-1,2-dicarboximide dimaleate

N-{3-(4-Methylpiperazin-1-yl)-2-nicotinyloxypropyl}cis-cyclohex-4-ene-1,2-dicarboximide dimaleate

Conditions
ConditionsYield
With triethylamine In ethanol; water; 1,2-dichloro-ethane91%
...Expand
tert-butyl (R)-N-(4-methoxyphenylsulfonyl)aminobutanoate
1408282-64-3

tert-butyl (R)-N-(4-methoxyphenylsulfonyl)aminobutanoate

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

tert-butyl (R)-N-(4-methoxyphenylsulfonyl)-N-(3-pyridylmethyl)-2-aminobutanoate
1408282-77-8

tert-butyl (R)-N-(4-methoxyphenylsulfonyl)-N-(3-pyridylmethyl)-2-aminobutanoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 48h;91%
bisphenol M
13595-25-0

bisphenol M

3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

1,3-di(2-(4-(3-pyridylmethoxy)phenyl)prop-2-yl)benzene
1020725-73-8

1,3-di(2-(4-(3-pyridylmethoxy)phenyl)prop-2-yl)benzene

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydroxide In benzene at 80℃; for 48h;90.4%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

7-Chloro-4-(3,5-dimethylpyrazol-1-yl)imidazo<4,5-d>pyridazine-2-thiol
85732-80-5

7-Chloro-4-(3,5-dimethylpyrazol-1-yl)imidazo<4,5-d>pyridazine-2-thiol

7-Chloro-4-(3,5-dimethylpyrazol-1-yl)-2-(3-picolylthio)imidazo<4,5-d>pyridazine
85732-89-4

7-Chloro-4-(3,5-dimethylpyrazol-1-yl)-2-(3-picolylthio)imidazo<4,5-d>pyridazine

Conditions
ConditionsYield
With potassium hydroxide at 45℃; for 5h;90%
3-chloromethylpyridinium chloride
6959-48-4

3-chloromethylpyridinium chloride

1H-[1,2,4]triazole-3-thiol
3179-31-5

1H-[1,2,4]triazole-3-thiol

3-(3-pyridylmethylsulfanyl)-1H-1,2,4-triazole

3-(3-pyridylmethylsulfanyl)-1H-1,2,4-triazole

Conditions
ConditionsYield
Stage #1: 1H-[1,2,4]triazole-3-thiol With sodium In methanol; N,N-dimethyl-formamide at 20℃; for 0.166667h;
Stage #2: 3-chloromethylpyridinium chloride In methanol; N,N-dimethyl-formamide at 20℃;		90%

3-Picolyl chloride hydrochloride Chemical Properties

IUPAC:3-(chloromethyl)pyridine
CAS:6959-48-4
The Molecular formula of 3-(chloromethyl)-pyridinhydrochloride(6959-48-4):C6H7Cl2N
The Molecular Weight of 3-(chloromethyl)-pyridinhydrochloride(6959-48-4):164.03
Synonyms:3-(chloromethyl)-pyridinhydrochloride;3-chloromethyl-pyridinhydrochloride;3-pyridylmethylchloridehydrochloride;nci-c03838;3-(CHLOROMETHYL)PYRIDINE HYDROCHLORIDE;3-(CHLOROMETHYL)-PYRIDINIUM CHLORIDE;3-PICOLYL CHLORIDE HYDROCHLORIDE;3-Picolyl chloride HCl (65% in water)
EINECS:230-150-4
Melting Point:137-143oC(lit.)
Boiling Point:210oC at 760 mmHg
Flash Point:62oC
Water Solubility:>=10 g/100 mL at 19oC
Appearance:white to yellow powder
Vapour Pressure:0.285 mmHg at 25oC
Product Categories:blocks;Pyridines;Pyridine;Heterocycles;Pyridines, Pyrimidines, Purines and Pteredines;Pyridinium Compounds
Mol File:6959-48-4.mol

3-Picolyl chloride hydrochloride Uses

3-(chloromethyl)-pyridinhydrochloride(6959-48-4) is used as an important pharmaceutical intermediate and research chemical.

3-Picolyl chloride hydrochloride Toxicity Data With Reference

1.   

mmo-sat 333 µg/plate

   IARCCD    IARC Scientific Publications. 27 (1980),283.
2.   

mma-sat 33,300 ng/plate

   ENMUDM    Environmental Mutagenesis. 7 (Suppl 5)(1985),1.
3.   

mma-esc 1 mg/plate

   ENMUDM    Environmental Mutagenesis. 7 (Suppl 5)(1985),1.
4.   

otr-rat:emb 640 ng/plate

   JJATDK    JAT, Journal of Applied Toxicology. 1 (1981),190.
5.   

orl-rat LD50:316 mg/kg

   NCILB*    Progress Report for Contract No. NIH-NCI-E-C-72-3252, Submitted to the National Cancer Institute by Litton Bionetics, Inc. (Bethesda, MD) NIH-NCI-E-C-72-3252 .
6.   

orl-mus LD50:316 mg/kg

   NCILB*    Progress Report for Contract No. NIH-NCI-E-C-72-3252, Submitted to the National Cancer Institute by Litton Bionetics, Inc. (Bethesda, MD) NIH-NCI-E-C-72-3252 .

3-Picolyl chloride hydrochloride Consensus Reports

NCI Carcinogenesis Bioassay (gavage); Clear Evidence: mouse, rat NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-95 ,1978. . EPA Genetic Toxicology Program.

3-Picolyl chloride hydrochloride Safety Profile

Suspected carcinogen with experimental carcinogenic data. Poison by ingestion. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx and Cl−.

Safty informations about 3-(chloromethyl)-pyridinhydrochloride(6959-48-4):
Hazard Codes:Xn,C,T
Risk Statements:22-36/37/38-45-20/21/22
 22(Harmful if swallowed)
 36/37/38(Irritating to eyes, respiratory system and skin)
 45(May cause cancer)
 20/21/22(Harmful by inhalation, in contact with skin and if swallowed)
Safety Statements:26-36-53-45
 26(In case of contact with eyes, rinse immediately with plenty of water and seek medical advice)
 36(Wear suitable protective clothing)
 53(Avoid exposure - obtain special instruction before use)
 45(In case of accident or if you feel unwell, seek medical advice immediately (show label where possible))
RIDADR:2811
WGK Germany:3
RTECS:US7000000
F:3-10
HazardClass:8

3-Picolyl chloride hydrochloride Specification

Handling and Storage:
Storage:Store in a cool, dry place. Keep containers tightly closed. Store protected from moisture.
Handling:Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use only in a chemical fume hood. Do not breathe dust.

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