Product Name

  • Name

    Cyclohexanecarboxaldehyde

  • EINECS 218-057-7
  • CAS No. 2043-61-0
  • Article Data386
  • CAS DataBase
  • Density 0.992 g/cm3
  • Solubility Soluble in chloroform, ether, alcohol. Slightly soluble in water.
  • Melting Point 34-35 °C
  • Formula C7H12O
  • Boiling Point 159.5 °C at 760 mmHg
  • Molecular Weight 112.172
  • Flash Point 40.6 °C
  • Transport Information UN 1989 3/PG 3
  • Appearance Clear colorless to faintly pink liquid
  • Safety 16-26-36-37/39
  • Risk Codes 10-36/37/38-36
  • Molecular Structure Molecular Structure of 2043-61-0 (Cyclohexanecarboxaldehyde)
  • Hazard Symbols IrritantXi, FlammableF
  • Synonyms Hexahydrobenzaldehyde;Cyclohexane carboxaldehyde;1-Cyclohexylcarboaldehyde;Cyclohexane formaldehyde;Cyclohexanecarboxaldehyde (8CI)(9CI);Cyclohexanaecarboxaldehyde;Formylcyclohexane;Cyclohexylformaldehyde;Cyclohexanal;1-Formylcyclohexane;
  • PSA 17.07000
  • LogP 1.76560

Synthetic route

cyclohexylmethyl alcohol
100-49-2

cyclohexylmethyl alcohol

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; 1-(diacetoxyiodo)-4-methylbenzene In chloroform at 20℃; for 24h;100%
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; oxygen; copper(I) bromide dimethylsulfide complex In chlorobenzene at 80℃; for 8h;99%
With sodium hydrogencarbonate; sodium bromide In dichloromethane at 20℃; Electrochemical reaction;99%
Sodium; 1-oxa-spiro[2.5]octane-2-carboxylate
25957-47-5

Sodium; 1-oxa-spiro[2.5]octane-2-carboxylate

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With sulfuric acid stream of steam under a carbon dioxide atmosphere;100%
carbon monoxide
201230-82-2

carbon monoxide

cyclohexene
110-83-8

cyclohexene

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With hydrogen; (-)-(2-menthyl-4,7-dimethylindenyl)Rh(CO)2 at 120℃; under 30002.4 Torr; for 3h;100%
With hydrogen In cyclohexane at 120℃; under 45004.5 Torr; for 5h; Autoclave;99%
With hydrogen In water at 100℃; under 15001.5 Torr; for 12h; Autoclave; Green chemistry;99.5%
1-cyclohexene-1-carboxaldehyde
1192-88-7

1-cyclohexene-1-carboxaldehyde

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With hydrogen; β-cyclodextrin/Pd In water at 25℃; under 15001.2 Torr; for 2h;100%
With glucose-6-phosphate dehydrogenase; D-glucose 6-phosphate; pentaerythritol tetranitrate reductase T26S mutant; NADPH In N,N-dimethyl-formamide at 30℃; for 24h; pH=7; aq. phosphate buffer; Enzymatic reaction;84 %Chromat.
With progesterone 5β-reductase from Arabidopsis thaliana, thale cress; NADPH In aq. buffer at 30℃; for 24h; pH=7.5; Reagent/catalyst; Enzymatic reaction;
With D-glucose; glucose dehydrogenase (GDH; 10U); holo-(flavin free double bond reductase from Nicotiana tabacum); nicotinamide adenine dinucleotide phosphate In aq. phosphate buffer at 30℃; for 24h; pH=6.4; Enzymatic reaction;55 %Chromat.
cyclohexane
110-82-7

cyclohexane

carbon monoxide
201230-82-2

carbon monoxide

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With MCM-41 silicate; hydrogen; di(rhodium)tetracarbonyl dichloride at 100℃; under 21001.7 Torr; for 20h;99.4%
With Rh; benzaldehyde In benzene Mechanism; Irradiation; other d8 metal carbonyls, other aromatic ketones and aldehydes; relative quantum yields;
cyclohexanylcarbonyl chloride
2719-27-9

cyclohexanylcarbonyl chloride

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With tri-n-butyl-tin hydride; triphenylphosphine; palladium dichloride In benzene for 10h; Ambient temperature;98%
With sodium tris(tert-butoxo)aluminium hydride In tetrahydrofuran; diethylene glycol dimethyl ether at -78℃; for 3h;89%
With polymer(resin Amberlyst A-26)-supported tetracarbonylhydridoferrate anion In tetrahydrofuran for 0.75h; Heating;85%
(cyclohexyl-methoxy-methoxy)-triethyl-silane

(cyclohexyl-methoxy-methoxy)-triethyl-silane

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran at 20℃; for 2h;98%
Cyclohexancarboxaldehyde dithioethyleneacetal
70777-60-5

Cyclohexancarboxaldehyde dithioethyleneacetal

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With silica gel; copper(II) nitrate In tetrachloromethane for 0.25h; Ambient temperature;97%
With hydrogen bromide; dihydrogen peroxide In acetonitrile at 25℃; for 0.133333h;92%
With t-butyl bromide; dimethyl sulfoxide at 70 - 75℃; for 4h;86%
With trimethylsilyl iodide; dimethyl sulfoxide In tetrachloromethane at 75 - 80℃; for 6h;82%
2-cyclohexyl-1,3-dithiane
56698-00-1

2-cyclohexyl-1,3-dithiane

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With silica gel; copper(II) nitrate In tetrachloromethane for 0.416667h; Ambient temperature;97%
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In neat (no solvent) at 20℃; for 0.75h; Milling;83%
With dihydrogen peroxide; tantalum pentachloride; sodium iodide In water; ethyl acetate at 20℃; for 144h;81%
N-methoxy-N-methylcyclohexanecarboxamide
80783-98-8

N-methoxy-N-methylcyclohexanecarboxamide

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With lithium diisobutyl-tert-butoxyaluminum hydride In tetrahydrofuran; hexane at 0℃; Reagent/catalyst; Inert atmosphere; chemoselective reaction;96%
With Schwartz's reagent In tetrahydrofuran at 20℃; for 0.166667h;86%
With diisobutylaluminium hydride In tetrahydrofuran at 0℃; for 0.5h;74%
Stage #1: N-methoxy-N-methylcyclohexanecarboxamide With chloromagnesium dimethylaminoborohydride In tetrahydrofuran at 25℃; for 0.5h; Inert atmosphere;
Stage #2: With acetaldehyde; acetic acid In tetrahydrofuran; pentane for 0.5h; Inert atmosphere;
65%
2-cyclohexyl-1,3-dioxolane
4362-48-5

2-cyclohexyl-1,3-dioxolane

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With water; acetic acid at 20℃; for 0.666667h; Product distribution / selectivity;94%
With chloral hydrate In hexane at 25℃; for 3.5h; Inert atmosphere;86%
With lithium tetrafluoroborate In acetonitrile for 5h; Ambient temperature;40%
With water; β‐cyclodextrin at 20℃; for 96h;33 % Chromat.
N-(Benzylidene)cyclohexylidenemethylamine
64244-35-5

N-(Benzylidene)cyclohexylidenemethylamine

A

benzaldehyde
100-52-7

benzaldehyde

B

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With hydrogenchloride In dichloromethane for 1h; Heating;A n/a
B 94%
cyclohexanecarbaldoxime
4715-11-1

cyclohexanecarbaldoxime

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With iron(III) chloride In N,N-dimethyl-formamide at 25℃; for 0.25h; sonication;92%
With Cr-MCM-41 zeolite on silica gel for 0.1h; microwave irradiation;88%
With vanadium(III) chloride In tetrahydrofuran for 8h; Ambient temperature;77%
Yield given;
With gold(III) tribromide; dimethylglyoxal In tetrahydrofuran; water at 60℃; for 15h; pH=7;100 %Spectr.
cyclohexanecarboxylic acid Li-salt
16090-10-1

cyclohexanecarboxylic acid Li-salt

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran for 1h; Ambient temperature;92%
N′-(cyclohexylmethylene)-4-methylbenzenesulfonohydrazide
34266-29-0

N′-(cyclohexylmethylene)-4-methylbenzenesulfonohydrazide

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With silica gel; copper(II) nitrate In tetrachloromethane for 1.5h; Heating;92%
With Cr-MCM-41 zeolite on silica gel for 0.133333h; microwave irradiation;86%
Cyclohexanecarboxylic acid
98-89-5

Cyclohexanecarboxylic acid

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With thexylchloroborane-Me2SO4 In dichloromethane for 0.25h; Ambient temperature;91%
With thexylbromoborane dimethyl sulfide complex In carbon disulfide; dichloromethane at -20 - 20℃; for 1h;89%
With 9-borabicyclo[3.3.1]nonane dimer; lithium dihydrido borata-bicyclo[3.3.0]nonane In tetrahydrofuran for 1h; Ambient temperature;88%
2-cyclohexyl-1,3-benzodithiole
61666-77-1

2-cyclohexyl-1,3-benzodithiole

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With tetrafluoroboric acid; mercury(II) oxide In tetrahydrofuran for 0.166667h; Heating;90%
(2R,5S)-2-cyclohexyl-5-<(phenylsulfonyl)methyl>-1,3-dioxolan-4-one
140663-05-4

(2R,5S)-2-cyclohexyl-5-<(phenylsulfonyl)methyl>-1,3-dioxolan-4-one

A

(2R)-2-cyclohexyl-5-methylene-1,3-dioxolan-4-one
140850-05-1

(2R)-2-cyclohexyl-5-methylene-1,3-dioxolan-4-one

B

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 0℃; for 2h; Title compound not separated from byproducts;A 90%
B 10%
cyclohexanecarboxylic acid Na-salt
136-01-6

cyclohexanecarboxylic acid Na-salt

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran for 1h; Ambient temperature;90%
1-[(tert-butyl-dimethyl-silanyloxy)-cyclohexyl-methyl]-1H-imidazole

1-[(tert-butyl-dimethyl-silanyloxy)-cyclohexyl-methyl]-1H-imidazole

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With hydrogen fluoride In acetonitrile at 20℃;90%
cyclohexylmethyl trimethylsilyl ether
88773-80-2

cyclohexylmethyl trimethylsilyl ether

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate; HZSM-5 zeolite In water for 0.166667h; microwave irradiation;90%
formic acid
64-18-6

formic acid

1-iodocyclohexane
626-62-0

1-iodocyclohexane

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
Stage #1: Cyclohexyl iodide With iodine; triethylamine; triphenylphosphine In dichloromethane; toluene at 20℃; for 0.0833333h; Sealed tube; Green chemistry;
Stage #2: formic acid In dichloromethane; toluene at 70℃; for 1.5h; Sealed tube; Green chemistry;
89%
cyclohexanecarbaldehyde-semicarbazone
3183-63-9

cyclohexanecarbaldehyde-semicarbazone

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
aluminum oxide; ammonium cerium(IV) nitrate for 0.00555556h; microwave irradiation;88%
(dimethoxymethyl)cyclohexene
18231-08-8

(dimethoxymethyl)cyclohexene

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
perchloric acid In methanol; water at 25 - 30℃; for 0.166667h;88%
With water In methanol at 25 - 30℃; for 0.25h;88%
With chloral hydrate In hexane at 25℃; for 1.5h; Inert atmosphere;83%
With water; potassium carbonate; K12[Ga4(N,N'-bis(2,3-diOHbenzoyl)-1,5-diaminonaphthalene)6] at 50℃; for 6h; pH=10;
ethyl cyclohexanecarboxylate
3289-28-9

ethyl cyclohexanecarboxylate

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With diisobutylaluminium hydride In diethyl ether at -78℃;86%
With phenylsilane; cobalt(II) diacetate tetrahydrate; sodium triethylborohydride In 1,2-dimethoxyethane; toluene at 25℃; for 15h; Inert atmosphere; Schlenk technique;82%
With naphthalene In tetrahydrofuran; hexane at 0℃; for 1h;81 % Chromat.
2-cyclohexyl-2-hydroxyacetic acid
4442-94-8, 10498-47-2, 53585-93-6, 61475-31-8

2-cyclohexyl-2-hydroxyacetic acid

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With sodium hydroxide; sodium hypochlorite In diethyl ether 1.) 0 deg C -> room temperature, 2.) room temperature, 2 h;85%
cyclohexylidene(N-methylanilino)methane
76527-53-2

cyclohexylidene(N-methylanilino)methane

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran for 5h; Ambient temperature;85%
(bromomethylcyclohexane)
2550-36-9

(bromomethylcyclohexane)

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With (NH4)4[ZnMo6O18(OH)6]; oxygen In water; acetonitrile at 60℃; under 760.051 Torr; for 12h;85%
(dimethylphenylsilyl)-1-cyclohexylmethanol
75730-04-0

(dimethylphenylsilyl)-1-cyclohexylmethanol

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With chromium(VI) oxide In dimethyl sulfoxide at 25℃;83%
N-(4-Chlorobenzylidene)cyclohexylidenemethylamine
143399-68-2

N-(4-Chlorobenzylidene)cyclohexylidenemethylamine

A

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

B

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With hydrogenchloride In dichloromethane for 1h; Heating;A n/a
B 83%
aniline
62-53-3

aniline

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

N-(cyclohexylmethyl)aniline
79952-92-4

N-(cyclohexylmethyl)aniline

Conditions
ConditionsYield
With ammonium formate; palladium on activated charcoal In methanol; water at 20℃; for 0.5h;100%
With (2,6-dichlorophenyl)bis(2,3,5,6-tetrafluorophenyl)borane; hydrogen In tetrahydrofuran at 100℃; under 15201 Torr; for 6h; Sealed tube; Molecular sieve; Autoclave; Green chemistry;97%
With hydrogen In toluene at 110℃; under 7500.75 Torr; for 18h;95%
nitromethane
75-52-5

nitromethane

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
tris(bis(trimethylsilyl)amido)samarium(III) In tetrahydrofuran for 25h; Ambient temperature;100%
With potassium fluoride In isopropyl alcohol at 0 - 20℃; for 24h; Inert atmosphere;100%
With calcium oxide at 50℃; for 12h;99%
malonic acid
141-82-2

malonic acid

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

3-cyclohexylacrylic acid
4484-35-9

3-cyclohexylacrylic acid

Conditions
ConditionsYield
Stage #1: malonic acid; cyclohexanecarbaldehyde With piperidine; pyridine at 20 - 80℃; for 6h; Doebner reaction;
Stage #2: With hydrogenchloride In water Cooling with ice;
100%
With piperidine; pyridine97%
With piperidine; pyridine
cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

1-bromocyclohexanecarbaldehyde
34899-90-6

1-bromocyclohexanecarbaldehyde

Conditions
ConditionsYield
With bromine; sodium hydrogencarbonate100%
With 5,5-dibromobarbituric acid In diethyl ether for 10h; Ambient temperature;85%
With bromine In 1,4-dioxane; diethyl ether at 0℃; Inert atmosphere;58%
morpholine
110-91-8

morpholine

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

4-(cyclohexylidenemethyl)morpholine
16963-29-4

4-(cyclohexylidenemethyl)morpholine

Conditions
ConditionsYield
In benzene for 2h; Condensation; Heating;100%
In benzene for 3h; Heating;89%
lithium cyanide
2408-36-8

lithium cyanide

benzoyl chloride
98-88-4

benzoyl chloride

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

benzoic acid cyano(cyclohexyl)methyl ester
108583-50-2

benzoic acid cyano(cyclohexyl)methyl ester

Conditions
ConditionsYield
In tetrahydrofuran for 0.5h; Ambient temperature;100%
4-methoxy-aniline
104-94-9

4-methoxy-aniline

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

[2-Cyclohexyl-eth-(E)-ylidene]-(4-methoxy-phenyl)-amine
129397-33-7

[2-Cyclohexyl-eth-(E)-ylidene]-(4-methoxy-phenyl)-amine

Conditions
ConditionsYield
With magnesium sulfate In toluene100%
4-methoxy-aniline
104-94-9

4-methoxy-aniline

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Cyclohexylidenemethyl-(4-methoxy-phenyl)-amine

Cyclohexylidenemethyl-(4-methoxy-phenyl)-amine

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 2h; Heating;100%
ethane-1,2-dithiol
540-63-6

ethane-1,2-dithiol

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Cyclohexancarboxaldehyde dithioethyleneacetal
70777-60-5

Cyclohexancarboxaldehyde dithioethyleneacetal

Conditions
ConditionsYield
With zeolite HSZ-360 In dichloromethane for 15h; Ambient temperature;100%
With cobalt(II) bromide In dichloromethane for 0.05h; Ambient temperature;99%
With PPA; silica gel In 1,2-dichloro-ethane at 20℃; for 0.5h;96%
carbon monoxide
201230-82-2

carbon monoxide

2,2'-iminobis[ethanol]
111-42-2

2,2'-iminobis[ethanol]

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

2-(2-cyclohexyl-oxazolidin-3-yl)-ethanol
55135-29-0

2-(2-cyclohexyl-oxazolidin-3-yl)-ethanol

Conditions
ConditionsYield
With 1-Methylpyrrolidine; water; 3>PF6 at 140℃; under 51714.8 Torr; for 6h;100%
2-hydroxy-2-methylpropanenitrile
75-86-5

2-hydroxy-2-methylpropanenitrile

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

2-cyclohexyl-2-hydroxyacetonitrile
100007-62-3, 107485-34-7, 4354-47-6

2-cyclohexyl-2-hydroxyacetonitrile

Conditions
ConditionsYield
With titanium(IV) isopropylate for 44h; Ambient temperature;100%
With titanium(IV) isopropylate; dl-3-(2-hydroxy-1-naphthylidene)-imino-ε-caprolactam (Nap-ACL) In dichloromethane for 2.5h; Ambient temperature;99%
With ytterbium(III) isopropoxide In tetrahydrofuran for 0.5h; Ambient temperature;86%
rac-methylbenzylamine
618-36-0

rac-methylbenzylamine

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Cyclohexylidenemethyl-(1-phenyl-ethyl)-amine

Cyclohexylidenemethyl-(1-phenyl-ethyl)-amine

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 2h; Heating;100%
benzylamine
100-46-9

benzylamine

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

(E)-N-(2-cyclohexylethylidene)benzylamine
129397-34-8

(E)-N-(2-cyclohexylethylidene)benzylamine

Conditions
ConditionsYield
With magnesium sulfate In toluene100%
benzylamine
100-46-9

benzylamine

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

N-(cyclohexylmethylidene)benzylamine
130517-97-4, 79841-85-3

N-(cyclohexylmethylidene)benzylamine

Conditions
ConditionsYield
In toluene for 24h; Heating;100%
With magnesium sulfate In benzene for 1h; Ambient temperature;
In dichloromethane at 20℃; for 3h;
benzylamine
100-46-9

benzylamine

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Benzyl-cyclohexylidenemethyl-amine

Benzyl-cyclohexylidenemethyl-amine

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 2h; Heating;100%
Benzhydrylamine
91-00-9

Benzhydrylamine

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Benzhydryl-cyclohexylidenemethyl-amine

Benzhydryl-cyclohexylidenemethyl-amine

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 2h; Heating;100%
carbon tetrabromide
558-13-4

carbon tetrabromide

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

1,1-dibromo-2-cyclohexylethene
60754-49-6

1,1-dibromo-2-cyclohexylethene

Conditions
ConditionsYield
With triphenylphosphine In dichloromethane at 0℃; for 1.5h;100%
With triphenylphosphine In dichloromethane for 16h; Heating;98%
With triphenylphosphine92%
Methyl phenyl sulfone
3112-85-4

Methyl phenyl sulfone

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

1-cyclohexyl-2-(phenylsulfonyl)ethan-1-ol
86653-05-6

1-cyclohexyl-2-(phenylsulfonyl)ethan-1-ol

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran at -78℃; to r.t.;100%
Stage #1: methylphenylsulfonate With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 0.5h;
Stage #2: cyclohexanecarbaldehyde In tetrahydrofuran; hexane at -78 - 20℃; Further stages.;
(S)-1-phenyl-ethylamine
2627-86-3

(S)-1-phenyl-ethylamine

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

N-(2-cyclohexylethylidene)-(S)-α-methylbenzylamine
129397-36-0

N-(2-cyclohexylethylidene)-(S)-α-methylbenzylamine

Conditions
ConditionsYield
With magnesium sulfate In toluene100%
p,p'-dimethoxybenzhydrylamine
19293-62-0

p,p'-dimethoxybenzhydrylamine

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

[Bis-(4-methoxy-phenyl)-methyl]-[2-cyclohexyl-eth-(E)-ylidene]-amine
129397-35-9

[Bis-(4-methoxy-phenyl)-methyl]-[2-cyclohexyl-eth-(E)-ylidene]-amine

Conditions
ConditionsYield
With magnesium sulfate In benzene100%
allyltributylstanane
24850-33-7

allyltributylstanane

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

1-cyclohexyl-3-buten-1-ol
69036-26-6

1-cyclohexyl-3-buten-1-ol

Conditions
ConditionsYield
With 4-nitro-benzoic acid In acetonitrile at 25℃; for 10h;100%
With bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran for 10h; Heating;99%
bis(triphenylphosphine)platinum(II) dichloride In tetrahydrofuran for 10h; Heating;99%
(R,R)-[(E)-2-butenyl]diisopropyl tartrate boronate
99687-40-8, 106357-20-4, 106357-33-9, 99745-86-5

(R,R)-[(E)-2-butenyl]diisopropyl tartrate boronate

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

(3S,4R)-4-cyclohexyl-3-methyl-1-buten-4-ol
121155-51-9

(3S,4R)-4-cyclohexyl-3-methyl-1-buten-4-ol

Conditions
ConditionsYield
With 4 A molecular sieve In toluene at -95℃; for 4h;100%
In tetrahydrofuran at -95℃; for 4h; Molecular sieve; stereoselective reaction;100%
cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

(+/-)-1-cyclohexyl-3-(trimethylsilyl)-2-propynol
133216-88-3, 112497-25-3

(+/-)-1-cyclohexyl-3-(trimethylsilyl)-2-propynol

Conditions
ConditionsYield
With n-butyllithium Inert atmosphere;100%
With ethylmagnesium bromide In tetrahydrofuran; diethyl ether at -15 - 20℃; for 3h; Inert atmosphere;100%
Stage #1: trimethylsilylacetylene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.333333h;
Stage #2: cyclohexanecarbaldehyde In tetrahydrofuran; hexane at -78 - 24℃;
Stage #3: With water; ammonium chloride In tetrahydrofuran; hexane
92%
cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

butyric acid
107-92-6

butyric acid

2-(Cyclohexyl-hydroxy-methyl)-butyric acid
114049-45-5

2-(Cyclohexyl-hydroxy-methyl)-butyric acid

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran100%
cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

cyclohexylmethyl cyclohexanecarboxylate
2611-02-1

cyclohexylmethyl cyclohexanecarboxylate

Conditions
ConditionsYield
With [(ImDippN)Th{N(SiMe3)2}3] In benzene-d6 at 20℃; for 12h; Reagent/catalyst;100%
(η5-C5Me5)2Sm(THF)2 In toluene 1.) 0 deg C, 0.5 h, 2.) 25 deg C, 2.5 h;99%
With (2,7-dimethyl-1,8-biphenylenedioxy)-bis(diisopropoxyaluminum) In toluene at 21℃; for 0.25h; Dimerization; Tishchenko reaction;99%
cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

cyclohexylmethyl alcohol
100-49-2

cyclohexylmethyl alcohol

Conditions
ConditionsYield
With sodium tetrahydroborate In methanol at 0 - 25℃; for 2h;100%
With isopropyl alcohol; zirconium(IV) oxide for 6h; Heating;99%
With isopropyl alcohol; zirconium(IV) oxide for 6h; Rate constant; Heating;99%
triethylsilylcyanide
18301-88-7

triethylsilylcyanide

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

Cyclohexanecarboxaldehyde triethylsilyl cyanohydrin

Cyclohexanecarboxaldehyde triethylsilyl cyanohydrin

Conditions
ConditionsYield
tri-n-butyltin cyanide at 20℃; for 1h;100%

Cyclohexanecarboxaldehyde Chemical Properties

Formula : C7H12O
MW : 112.17
Boiling Point : 161 ° C
Chinese name : cyclohexane formaldehyde; Cyclohexyl - formaldehyde
English title :cyclohexanecarboxaldehyde;cxyclohexanal;
                       cyclohexanecarbaldehyde
Nature Description : colorless, transparent liquid
Refractive index : n20/D 1.452(lit.)
Fp : 105 °F
storage temp. : 2-8°C
Sensitive : Air Sensitive
MOL File: 2043-61-0.mol 
Appearance:Colorless or slight yellow liquid

Cyclohexanecarboxaldehyde Safety Profile

Hazard Codes : Xi,F
Risk Statements : 10-36/37/38
Safety Statements : 16-26-36-37/39
RIDADR : UN 1989 3/PG 3
WGK Germany : 3
PackingGroup : III
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