Ethylbutylamine supplier | CasNO.13360-63-9

Name
Ethylbutylamine
EINECS 236-415-0
CAS No. 13360-63-9
Article Data38
CAS DataBase
Density 0.74
Solubility partly soluble
Melting Point -77.8oC
Formula C6H15 N
Boiling Point 108 ºC
Molecular Weight 101.192
Flash Point 18 ºC
Transport Information UN 2733
Appearance A colorless liquid with an ammonia-like odor.
Safety A poison by ingestion. When heated to decomposition it emits toxic vapors of NO_x.
Risk Codes R11;R22;R34
Molecular Structure
Hazard Symbols
Synonyms Butylamine,N-ethyl- (6CI,7CI,8CI); Butylethylamine; Ethylbutylamine; N-Butyl-N-ethylamine;N-Butylethylamine; N-Ethyl-1-butanamine; N-Ethyl-N-butylamine;N-Ethylbutanamine; N-Ethylbutylamine
PSA 12.03000
LogP 1.78690

Synthetic route

: (4-{tris[2-(perfluorohexyl)ethyl]silyl}benzyl) (butyl)(ethyl)carbamate

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
With hydrogen; palladium on activated charcoal In methanol at 20℃; for 16h;	80%

: 122-56-5
tributyl borane

: 81375-29-3
O-(p-toluenesulfonyl)-N-ethylhydroxylamine

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
In tetrahydrofuran for 2h; Ambient temperature;	77%

: 917-54-4
methyllithium

: 33704-65-3
Butyl-phenylsulfanylmethyl-amine; hydrochloride

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
In diethyl ether at -60℃;	76%

: 75-04-7
ethylamine

: 109-73-9
N-butylamine

A: 102-82-9
tributyl-amine

B: 13360-63-9
N-ethylbutylamine

C: 4444-68-2
N,N-diethylbutylamine

D: 4458-33-7
di-n-butylethylamine

E: 111-92-2
dibutylamine

F: 109-89-7
diethylamine

G: 121-44-8
triethylamine

Conditions

Conditions	Yield
With hydrogen at 200℃; under 6000.6 Torr; Reagent/catalyst; Temperature;	A n/a B 60.7% C n/a D n/a E n/a F n/a G n/a

...Expand

: 75-04-7
ethylamine

: 71-36-3
butan-1-ol

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
With hydrogen at 150℃; under 3750.38 Torr; for 8h; Temperature; Pressure; Reagent/catalyst;	55.3%
With hydrogen; nickel at 150℃;

: 109-74-0
propyl cyanide

: 64-17-5
ethanol

A: 13360-63-9
N-ethylbutylamine

B: 4853-56-9
(butylidene)butylamine

C: 109-73-9
N-butylamine

Conditions

Conditions	Yield
With Co(9.8%)/SiO2 catalyst; hydrogen at 129.84℃; under 9750.98 Torr; Reagent/catalyst; Temperature;	A 30.5% B 25.6% C 42.3%

...Expand

: 14925-83-8
N,N-dichloro-n-butylamine

: 557-20-0
diethylzinc

A: 13360-63-9
N-ethylbutylamine

B: 109-73-9
N-butylamine

Conditions

Conditions	Yield
With Petroleum ether

...Expand

: 1611-12-7
ethyl-butyliden-amine

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
With nickel; Petroleum ether at 75℃; under 154457 Torr; Hydrogenation;
With ethanol; sodium
With ethanol; platinum Hydrogenation;

: 77228-69-4
N-benzyl-N-ethylbutan-1-amine

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
With platinum(IV) oxide; acetic acid at 65 - 75℃; Hydrogenolyse;

: 75-04-7
ethylamine

: 123-72-8
butyraldehyde

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
With ethanol; platinum Hydrogenation;
(i), (ii) H2, Pd-C, EtOH; Multistep reaction;
With potassium hydroxide; dipotassium hydrogenphosphate; phosphoric acid at 10 - 12℃; for 4h; electrochemical reductive amination, lead cathode, current density 0.05 A/cm2, pH 12; Yield given;

: 75-04-7
ethylamine

: 123-73-9
crotonaldehyde

A: 32280-46-9
N,N'-Diaethyl-1-methyl-1,3-propandiamin

B: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
With methanol; nickel at 125℃; Hydrogenation;

...Expand

: 75-04-7
ethylamine

: 123-73-9
crotonaldehyde

A: 13360-63-9
N-ethylbutylamine

B: 4444-68-2
N,N-diethylbutylamine

Conditions

Conditions	Yield
With methanol; nickel at 125℃; Hydrogenation;

...Expand

: 64-17-5
ethanol

: 109-73-9
N-butylamine

A: 13360-63-9
N-ethylbutylamine

B: 111-92-2
dibutylamine

Conditions

Conditions	Yield
With nickel

...Expand

: 6898-74-4
Acetaldehyd-butylimin

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
With ethanol; platinum Hydrogenation;

: 109-65-9
1-bromo-butane

: 1946-09-4
diethyl N-ethylphosphoramidate

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
(i) aq. NaOH, HSO4, (ii) HCl; Multistep reaction;

: 26683-07-8
butyl-ethyl-tetrahydropyran-2-yl-amine

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
(hydrolysis);

: 74-85-1
ethene

: 109-73-9
N-butylamine

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
With N,N,N,N,-tetramethylethylenediamine at 130 - 150℃; under 183877 Torr;

: 54944-19-3
phenyl-trichloromethyl-phosphinic acid ethyl ester

: 109-73-9
N-butylamine

: 13360-63-9
N-ethylbutylamine

: 64-67-5
diethyl sulfate

: 1077-18-5
N-benzylidenebutan-1-amine

: 13360-63-9
N-ethylbutylamine

: 97-94-9
triethyl borane

: 7332-00-5
n-butylazide

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
In xylene for 6h; Heating;	72 % Chromat.
In xylene for 6h; Rate constant; Heating;	72 % Chromat.

: 102711-05-7
C24H29NP(1+)*I(1-)

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
With water; hydroxide

: (R)-5-Butylaminomethyl-2,7,8-trimethyl-2-((4R,8R)-4,8,12-trimethyl-tridecyl)-chroman-6-ol; hydrobromide

EtHal: EtHal

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
With sodium hydroxide 1.) CH2Cl2, -20 deg C, 10 min, 2.) room temperature, 30 min, 3.) 70 deg C, 1 h; Yield given. Multistep reaction;

: (CO)5CrC(Me)(n-butylamine)

: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
With Li{AlH4}

: 110-89-4
piperidine

: 885663-12-7
C14H21NO

A: 13707-23-8
N-(4-methylbenzoyl)piperidine

B: 13360-63-9
N-ethylbutylamine

Conditions

Conditions	Yield
With Al2(NMe2)6 In toluene at 90℃; for 16h; Equilibrium constant;

...Expand

: 885663-12-7
C14H21NO

: 103-67-3
benzyl-methyl-amine

A: 13360-63-9
N-ethylbutylamine

B: 57409-40-2
4-methyl-N-benzyl-N-methylbenzamide

Conditions

Conditions	Yield
With Al2(NMe2)6 In toluene at 90℃; for 16h; Equilibrium constant;

...Expand

: 13360-63-9
N-ethylbutylamine

: 287721-05-5
4-[phenyl(endo-8-methyl-8-azabicyclo[3.2.1]octan-3-yl)amino]benzoic acid

: N-butyl-N-ethyl-4-[(8-methyl-8-aza-bicyclo[3.2.1]oct-3-yl)-phenyl-amino]-benzamide

Conditions

Conditions	Yield
With N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate Acylation;	100%

: 13360-63-9
N-ethylbutylamine

: 1286315-70-5
N-[3-(trimethylamino)methyl-4-hydroxyphenyl]-1,8-naphthalimide iodide

: 1286315-76-1
N-[3-(butylethylamino)methyl-4-hydroxyphenyl]-1,8-naphthalimide

Conditions

Conditions	Yield
In water; acetonitrile at 25℃; for 0.166667h; Quantum yield; Inert atmosphere; Irradiation;	100%

: 13360-63-9
N-ethylbutylamine

: 175140-70-2
4-N-(2,4,6-trimethylphenyl)-6-chloro-2-methyl-5-nitropyrimidin-4-amine

: 175139-13-6
4-N-(2,4,6-trimethylphenyl)-6-(N-n-butylethylamino)-2-methyl-5-nitropyrimidin-4-amine

Conditions

Conditions	Yield
With triethylamine In acetone Ambient temperature;	98%

: 75-15-0
carbon disulfide

: 13360-63-9
N-ethylbutylamine

: 163594-66-9
(N-ethyl-N'-n-butyldithiocarbamato) sodium

Conditions

Conditions	Yield
Stage #1: N-ethylbutylamine With sodium hydroxide In methanol; water at 0℃; for 0.333333h; Stage #2: carbon disulfide In methanol; water at 20℃;	98%
Stage #1: N-ethylbutylamine With sodium hydroxide In methanol; water at 0℃; for 0.333333h; Stage #2: carbon disulfide In methanol; water at 0 - 20℃;	98%
With sodium hydroxide In water	98%
With sodium hydroxide In water for 2h; Cooling with ice;

: 1945-84-2
2-ethynylpyridine

: 13360-63-9
N-ethylbutylamine

: (E)-N-ethyl-N-(2-(pyridine-2-yl)vinyl)butan-1-amine

Conditions

Conditions	Yield
With ethylene glycol at 150℃; for 8h; Inert atmosphere; Sealed tube; Green chemistry; regioselective reaction;	98%

: 13360-63-9
N-ethylbutylamine

: 169882-29-5
3-[2-bromo-4-(1-methylethyl)phenyl]-7-chloro-5-methyl-3H-1,2,3-triazolo[4,5-d]pyrimidine

: [3-(2-bromo-4-isopropyl-phenyl)-5-methyl-3H-[1,2,3]triazolo[4,5-d]pyrimidin-7-yl]-butyl-ethyl-amine

Conditions

Conditions	Yield
With triethylamine In ethanol Heating;	97%

: 13360-63-9
N-ethylbutylamine

: 1-methyl-3-{4-[tris-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-silanyl]-benzyloxycarbonyl}-3H-imidazol-1-ium; trifluoro-methanesulfonate

: (4-{tris[2-(perfluorohexyl)ethyl]silyl}benzyl) (butyl)(ethyl)carbamate

Conditions

Conditions	Yield
With dmap In dichloromethane at 20℃; for 16h;	91%

: 13360-63-9
N-ethylbutylamine

dichloromethylenedimethyliminium chloride: dichloromethylenedimethyliminium chloride

: 672953-00-3
[bis-(ethylbutylamino)-dimethylguanidinium] chloride

Conditions

Conditions	Yield
Stage #1: N-ethylbutylamine; dichloromethylenedimethyliminium chloride With triethylamine In dichloromethane at 0 - 20℃; for 4h; Stage #2: With sodium hydroxide In water Stage #3: With hydrogenchloride In diethyl ether; water pH=7;	91%

: N,N'-bis[3-(trimethylammonio)methyl-4-hydroxyphenyl]-1,4,5,8-naphthalenetetracarboxylic diimide diiodide

: 13360-63-9
N-ethylbutylamine

: C40H44N4O6

Conditions

Conditions	Yield
Stage #1: N,N'-bis[3-(trimethylammonio)methyl-4-hydroxyphenyl]-1,4,5,8-naphthalenetetracarboxylic diimide diiodide; N-ethylbutylamine With sodium dithionite In water; acetonitrile at 25℃; for 0.5h; Stage #2: With air In water; acetonitrile for 0.166667h; cooling; Further stages.;	90%

: 2579-22-8
Phenylpropargyl aldehyde

: 13360-63-9
N-ethylbutylamine

: (Z)-3-(butyl(ethyl)amino)-1-phenylprop-2-en-1-one

Conditions

Conditions	Yield
In ethanol at 60℃; for 0.25h; regioselective reaction;	90%

: 13360-63-9
N-ethylbutylamine

: 157286-81-2
4-chloro-2,5-dimethyl-7-(2,4,6-trimethylphenyl)-7H-pyrrolo-[2,3-d]pyrimidine

: butyl[2,5-dimethyl-7-(2,4,6-trimethylphenyl)-7H-pyrrolo[2,3-d]pyrimidin-4-yl]ethylamine

Conditions

Conditions	Yield
	89%
In dimethyl sulfoxide at 130℃; for 3h;	88%

: 75-15-0
carbon disulfide

: 13360-63-9
N-ethylbutylamine

: 10025-82-8
indium(III) chloride

: 878385-08-1
tris(N,N-ethylbutyldithiocarbamato)indium(III)

Conditions

Conditions	Yield
With sodium hydroxide In methanol NaOH and N,N-ethylbutylamine were dissplved in MeOH, CS2 was dropped slowly at 0°C for 1 h, InCl3 was added; ppt. was filtered, dtied in vacuo, and recrystd.; elem. anal.;	89%

...Expand

: 13360-63-9
N-ethylbutylamine

: 197803-09-1
7-chloro-5-methyl-3-(2,4,6-trimethyl-pyridin-3-yl)-3H-[1,2,3]triazolo[4,5-d]pyrimidine

: butyl-ethyl-[5-methyl-3-(2,4,6-trimethyl-pyridin-3-yl)-3H-[1,2,3]triazolo[4,5-d]pyrimidin-7-yl]-amine

Conditions

Conditions	Yield
With triethylamine In ethanol Heating;	86%

: 110-52-1
1,4-dibromo-butane

: 13360-63-9
N-ethylbutylamine

: 90076-65-6
bis(trifluoromethane)sulfonimide lithium

: 1119616-46-4
N-butyl-N-ethylpyrrolidinium bis(trifluoromethanesulfonyl)imide

Conditions

Conditions	Yield
Stage #1: 1,4-dibromo-butane; N-ethylbutylamine With potassium carbonate In water at 120℃; for 0.333333h; Autoclave; Microwave irradiation; Green chemistry; Stage #2: bis(trifluoromethane)sulfonimide lithium In water at 20℃; for 1h; Green chemistry;	86%

...Expand

: 111-24-0
1,5-dibromo-pentane

: 13360-63-9
N-ethylbutylamine

: 90076-65-6
bis(trifluoromethane)sulfonimide lithium

: 1174233-40-9
N-butyl-N-ethylpiperidinium bis(trifluoromethanesulfonyl)imide

Conditions

Conditions	Yield
Stage #1: 1,5-dibromo-pentane; N-ethylbutylamine With potassium carbonate In water at 120℃; for 0.666667h; Autoclave; Microwave irradiation; Green chemistry; Stage #2: bis(trifluoromethane)sulfonimide lithium In water at 20℃; for 1h; Green chemistry;	86%

...Expand

: 13360-63-9
N-ethylbutylamine

: 3-[(benzyloxy)(5-bromopentanoyl)amino]propanoic acid tert-butyl ester

: tert-butyl 3-{N-(benzyloxy)-5-[butyl(ethyl)amino]pentanamido}propanoate

Conditions

Conditions	Yield
In acetonitrile Reflux;	86%

: 13360-63-9
N-ethylbutylamine

: 102536-14-1
C18H16NO2P

: 102536-06-1
N-Butyl-N-ethyl-N'-phenyl-hydrazine

Conditions

Conditions	Yield
	85%

: 17426-48-1
1-(propa-1,2-dien-1-yl)pyrrolidin-2-one

: 13360-63-9
N-ethylbutylamine

: C13H24N2O

Conditions

Conditions	Yield
With tetrakis(actonitrile)copper(I) hexafluorophosphate In tetrahydrofuran at 20℃; for 18h; Inert atmosphere; diastereoselective reaction;	85%

: 13360-63-9
N-ethylbutylamine

: 40307-11-7
1-ethyl-4-ethynylbenzene

: (E)-N-ethyl-N-(4-ethylstyryl)butan-1-amine

Conditions

Conditions	Yield
With ethylene glycol at 150℃; for 8h; Inert atmosphere; Sealed tube; Green chemistry; regioselective reaction;	85%

: 13360-63-9
N-ethylbutylamine

: 557099-37-3
2-chloro-1,3-dinitro-5-(trifluoromethylthio)benzene

: 2,6-dinitro-4-trifluoromethylthio-N-ethyl-N-butylaniline

Conditions

Conditions	Yield
In ethanol for 0.5h;	84%
In methanol for 0.5h; Heating;	84%

: 13360-63-9
N-ethylbutylamine

: 842158-34-3
1-chloro-2,6-dinitrobenzene-4-(pentafluorosulfanyl)benzene

: 2,6-dinitro-4-pentafluorosulfanyl-N-ethyl-N-butylaniline

Conditions

Conditions	Yield
In ethanol for 0.5h;	84%

Ethylbutylamine Chemical Properties

The molecular formula of N-ETHYLBUTYLAMINE(13360-63-9) is C₆H₁₅N and its formula weight is 101.19g/mol.Its EINECS is 236-415-0.Its liansport information is UN 2733.The appearance of N-ETHYLBUTYLAMINE(13360-63-9) is colorless liquid.The density of ) is 0.74 g/mL at 25 °C(lit.).The boiling point is 108 °C(lit.).The refractive index is about n20/D 1.405(lit.) and molar refractivity is 33.44 cm³.Its fiash point is 18.3 °C and the vapor pressenge is 18 mm Hg ( 20 °C).Its enthalpy of vaporization is 33.97 kJ/mol.Surface Tension is 23 dyne/cm.N-ETHYLBUTYLAMINE(13360-63-90) has the property of being soluble in alcohol, ether and other organic solvents,partly dissolved in water.
The chemical synonyms of are 1-Butanamine,N-ethyl-;butyl(ethyl)amine;Butylamine, N-ethyl-;Butylamine,N-ethyl-;Butylethylamine;N-Butylethylamine;N-Butyl-N-ethylamine;n-ethyl-1-butanamin .Its product categories is Amines;C2 to C6 and Nitrogen Compounds.The molecular structure of N-ETHYLBUTYLAMINE(13360-63-9) is

Ethylbutylamine Uses

N-ETHYLBUTYLAMINE(13360-63-9) can be used as intermediate of herbicide .

Ethylbutylamine Production

Its preparation method is that alcohol and ammonia react with ethanol in the deoxidation and the presence of hydrogenation catalyst in the 170 ~ 210 ℃ / 1013 kPa , at the same time aminating and aminating derived products.

Ethylbutylamine Toxicity Data With Reference

1.		orl-rat LD50:310 mg/kg		GISAAA Gigiena i Sanitariya. 39 (3)(1974),106.
2.		orl-mus LD50:418 mg/kg		GISAAA Gigiena i Sanitariya. 39 (3)(1974),106.

Ethylbutylamine Consensus Reports

Reported in EPA TSCA Inventory.

Ethylbutylamine Safety Profile

A poison by ingestion. When heated to decomposition it emits toxic vapors of NO_x. Risk Codes:R11;R22;R34
Hazard codes is F, C .
Risk statements is 11-22-34 and safety statements is 16-26-36/37/39-45-33.
HazardClass is 3.

Product Name

Ethylbutylamine

Synthetic route

Ethylbutylamine Chemical Properties

Ethylbutylamine Uses

Ethylbutylamine Production

Ethylbutylamine Toxicity Data With Reference

Ethylbutylamine Consensus Reports

Ethylbutylamine Safety Profile

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