Gold trichloride supplier | CasNO.13453-07-1

Name
Gold trichloride
EINECS 236-623-1
CAS No. 13453-07-1
Article Data91
CAS DataBase
Density 3.9 g/mL at 25 °C
Solubility soluble in water
Melting Point 254 °C
Formula AuCl₃
Boiling Point 265 °C
Molecular Weight 303.326
Flash Point
Transport Information UN 3260 8/PG 3
Appearance orange-red to dark red crystals
Safety 26-36/37/39-45-37/39-36
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols C, Xi
Synonyms Auricchloride;Auric trichloride;Gold chloride;Gold(III)chloride;
PSA 0.00000
LogP -8.99050

Synthetic route

pyrosulfuryl chloride: pyrosulfuryl chloride

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
byproducts: SO2, SO3; in melt;

: sodium azide

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
With hydrogenchloride In water heating in sealed tube, 100°C;

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
With thionyl chloride In neat (no solvent) heating in sealed tube, 200°C (minimum 10 days);
With chlorine gaseous Cl2, at moderated temp.;
With chlorine gaseous Cl2, in presence of moisture, at ambient temp.;

: 7699-40-3
(198)AuCl3

: 7440-57-5, 457905-15-6
gold

A: gold-198

B: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
In not given Kinetics;
In not given Kinetics;

...Expand

: 7719-09-7
thionyl chloride

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) 200°C; 10 d (small yield);;
In neat (no solvent) 200°C; 10 d (small yield);;

: 100-34-5
benzene diazonium chloride

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
under acetone, in presence chalk;

: 13453-07-1
gold(III) chloride

: 738-70-5
5-(3,4,5-trimethoxybenzyl)pyrimidine-2,4-diamine

: 3(CH3O)3C6H2CH2C4HN2(NH2)2*Au(3+)*3Cl(1-)=((CH3O)3C6H2CH2C4HN2(NH2)2)3AuCl3

Conditions

Conditions	Yield
In methanol adding soln. of AuCl3 to soln. of trimethoprim in methanol; stirring for 24h at room temp.; evapn. (vac., 50°C), addn. of ether containing some MeOH, pptn.,filtn., dissolving in methanol, pptn. with ether, (this step was repeated three times), filtration, washing with ether, drying in vac. over P4O10 at 100°C; elem. anal.;	64%

: 758-16-7
N,N-dimethylthioformamide

: 13453-07-1
gold(III) chloride

: 142513-88-0
(gold(III) trichloride (N,N'-dimethylthioformamide))

Conditions

Conditions	Yield
In tetrahydrofuran addn. of AuCl3 to a soln. of N,N'-dimethylthioformamide in THF (under Ar), stirring at room temp. for 4 h; filtn. through anhydrous MgSO4, reducing volume in vacuo, slow addn. of pentane, soln. is left at -30°C until crystals appeared, decanting, drying in vacuo, elem. anal.;	62%

: 74959-64-1
2-(4-methoxybenzylidene)-N-phenylhydrazinecarbothioamide

: 13453-07-1
gold(III) chloride

: (Au(4-methoxybenzaldehyde)-4-phenyl-3-thiosemicarbazone)Cl3)2*2H2O

Conditions

Conditions	Yield
In methanol refluxed for about 30 min,pptn.; ppt. washed with water, dried under reduced pressure for 24 h, elem. anal.;	60%

: 90-34-6
Primaquine

: 13453-07-1
gold(III) chloride

: Au{8-(4-amino-1-methylbutylamino)-6-methoxyquinoline}3Cl3

Conditions

Conditions	Yield
In ethanol; water 1:1 aq. ethanolic soln. of AuCl3 and the ligand (in 1:3 molar ratio) was refluxed for about 1 h; concd., cooled to room temp., ppt. was sepd., washed with ice cold aq. ethanol, dried at room temp. over P4O10 under vac., recrystd. from acetone; elem. anal.;	60%

: 13453-07-1
gold(III) chloride

: 7787-60-2
bismuth(III) chloride

: AuBiCl6

Conditions

Conditions	Yield
In neat (no solvent) vac.; equimolar ratio, chemical transport (230-215°C, several d);	60%

: chloropentaammineiridium(III) chloride

: 13453-07-1
gold(III) chloride

: 900504-69-0
[Ir(NH3)5Cl](2+)*[AuCl4](1-)*Cl(1-)=[Ir(NH3)5Cl][AuCl4]Cl

Conditions

Conditions	Yield
In water addn. of freshly prepared aq. soln. of AuCl3 to warm aq. soln. of (Ir(NH3)5Cl)Cl2 (40°C) in ratio Ir-to-Au 1:1; crystn. for 2 h; filtration in vac., washing with min. amt. of H2O; drying in air;	60%

: 13453-07-1
gold(III) chloride

: 2633-66-1
2-mesitylmagnesium bromide

: (mesitylaurate(I))5

Conditions

Conditions	Yield
Stage #1: gold(III) chloride; 2-mesitylmagnesium bromide In tetrahydrofuran at -80℃; for 3h; Inert atmosphere; Schlenk technique; Stage #2: In tetrahydrofuran; 1,4-dioxane at 20℃; for 0.5h; Inert atmosphere; Schlenk technique;	55%

: 13453-07-1
gold(III) chloride

: [Au(CH3S(O)CH3)2Cl2](1+)*AuCl2(1-) = [Au(CH3S(O)CH3)2Cl2][AuCl2]

Conditions

Conditions	Yield
With dimethyl sulfoxide In ethanol; chloroform anhydrous conditions, DMSO added to soln. of AuCl3 in chloroform with 4% ethanol; precipitate filtered, washed with ether, dried in vacuum, elem. anal.;	53%

: 7791-27-7
pyrosulfuryl chloride

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
byproducts: SO2, SO3; in melt;

: sodium azide

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
With hydrogenchloride In water heating in sealed tube, 100°C;

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
With thionyl chloride In neat (no solvent) heating in sealed tube, 200°C (minimum 10 days);
With chlorine gaseous Cl2, at moderated temp.;
With chlorine gaseous Cl2, in presence of moisture, at ambient temp.;

: 7699-40-3
(198)AuCl3

: 7440-57-5, 457905-15-6
gold

A: gold-198

B: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
In not given Kinetics;
In not given Kinetics;

...Expand

: 7719-09-7
thionyl chloride

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) 200°C; 10 d (small yield);;
In neat (no solvent) 200°C; 10 d (small yield);;

: 100-34-5
benzene diazonium chloride

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
under acetone, in presence chalk;

: 7784-34-1
arsenic trichloride

: 7440-57-5, 457905-15-6
gold

A: arsenic

B: 13453-07-1
gold(III) chloride

...Expand

: 10025-67-9
disulfur dichloride

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
In not given

: 7647-18-9
antimonypentachloride

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
byproducts: PCl3;

: 7782-50-5
chlorine

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) slow reaction;;
In neat (no solvent) passing gaseous chlorine ovver gold sponge at 265°C;; recrystd. on the cool wall of reactor;;
In neat (no solvent) reacted at 250°C; sublimated at 250-280°C;

: 7782-50-5
chlorine

: 7440-57-5, 457905-15-6
gold

A: 13453-07-1
gold(III) chloride

B: gold(I) chloride

Conditions

Conditions	Yield
In neat (no solvent) powdery Au; at 180 to 190°C;; AuCl and small amounts of AuCl3 obtained;;
In neat (no solvent) powdery Au; at 180 to 190°C;; AuCl and small amounts of AuCl3 obtained;;

...Expand

: potassium tetrachloroaurate(III)

: silver carbonate

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
In further solvent(s) byproducts: AgCl, K2CO3; in abs. alc.;
In further solvent(s) byproducts: AgCl, K2CO3; in abs. alc.;

: gold(I) iodide

: 7782-50-5
chlorine

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
In water
In water

: gold(III) tetrachloride trihydrate

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
With SOCl2 In thionyl chloride byproducts: SO2, HCl; HAuCl4*3H2O heated under reflux with SOCl2; remaining SOCl2 removed by syringe; ppt. dried in vac. at 65°C for 4 h;

: 7784-34-1
arsenic trichloride

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
15°C; on surface of rest of Au pptd. As; AuCl3 dissolved in AsCl3;
15°C; on surface of rest of Au pptd. As; AuCl3 dissolved in AsCl3;

: 7791-25-5
sulfuryl dichloride

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) some hours (160°C); gold powder;;

: 7647-01-0
hydrogenchloride

: 7440-57-5, 457905-15-6
gold

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
With nitric acid dissolving Au in aqua regia by mild heating (60 ° C) under N2; heating for several hours at 140 ° C;;
With HNO3 In hydrogenchloride; nitric acid gold was dissolved in aqua regia; heating in a mineral oil bath at 120°C for 3 h;;

: gold(I) chloride - phosphorus trichloride

: 10025-91-9
antimony(III) chloride

A: 13453-07-1
gold(III) chloride

B: 7440-57-5, 457905-15-6
gold

...Expand

: 63947-88-6
silver tetrachloroaurate(III)

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
byproducts: AgCl; decompn.;
byproducts: AgCl; decompn.;

: tetrachloroauric(III) acid hydrate

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
In thionyl chloride stirring for 3 days, color changed from yellow to orange; removing thionyl chloride; drying (vac., room temp.);

: tetrachloroauric(III) acid hydrate

: 7782-50-5
chlorine

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) exposing H(AuCl4)*(H2O)x in dry dichlorine flow at 200°C for 30 min (Handbuch der praeparativen unorganishen Chemie, Ed. by G. Brauer (Ferdinand Enke, Stuttgart, 1981; Mir, Moscow, 1985), vol. 3);

: gold(III) chloride-phosphorus pentachloride

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
With water byproducts: HCl, H3PO4; effect of moisture;
byproducts: phosphoric acid; evapn. in vac.;
byproducts: phosphoric acid; evapn. in vac.;
With H2O byproducts: HCl, H3PO4; effect of moisture;

: gold(III) chloride-phosphorus pentachloride

A: 10026-13-8, 874483-75-7
phosphorus pentachloride

B: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
120°C; reaction started at ambient temp. (PCl5 gas developed);
120°C; reaction started at ambient temp. (PCl5 gas developed);

: gold(III) chloride-phosphorus pentachloride

: 7647-18-9
antimonypentachloride

A: 16551-08-9
SbCl5*PCl5

B: 13453-07-1
gold(III) chloride

...Expand

: rubidium aurate(III)

A: rubidium chloride

B: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
With hydrogenchloride
With HCl

: cesium aurate(III)

A: cesium chloride

B: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
With hydrogenchloride
With HCl

: gold(III) chloride-sulfur tetrachloride

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
With tin chloride also formed a double derivative of tin chloride with SCl4;
With tin chloride also formed a double derivative of tin chloride with SCl4;

: gold(III) chloride-sulfur tetrachloride

: 7784-34-1
arsenic trichloride

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
also formed a double derivative of AsCl3 with SCl4;
also formed a double derivative of AsCl3 with SCl4;

: gold(III) chloride-sulfur tetrachloride

: 7647-18-9
antimonypentachloride

: 13453-07-1
gold(III) chloride

Conditions

Conditions	Yield
also formed a double derivative of SbCl5 with SCl4;
also formed a double derivative of SbCl5 with SCl4;

: 201230-82-2
carbon monoxide

: 7783-70-2
antimony pentafluoride

: 13453-07-1
gold(III) chloride

: bis(carbonyl)gold(I) undecafluorodiantimonate(V)

Conditions

Conditions	Yield
In further solvent(s) byproducts: COF2; absence of air and moisture; stirring AuCl3 in SbF5 under 0.6 atm CO (60-70°C, 5 d); evapn. (vac., 55°C);	99%

...Expand

: 7440-69-9
bismuth

: 13453-07-1
gold(III) chloride

: 7440-57-5, 457905-15-6
gold

Conditions

Conditions	Yield
In melt in pyridinium chloride melt;	95%
In water
In not given excess AuCl3; slow redn.;
In hydrogenchloride fast redn.;
In not given excess AuCl3; slow redn.;

: 7440-36-0
antimony

: 13453-07-1
gold(III) chloride

: 7440-57-5, 457905-15-6
gold

Conditions

Conditions	Yield
In melt in pyridinium chloride melt;	95%
In not given
In further solvent(s) in melted pyridinium hydrogenchloride (C5H6NHCl2);

: 13453-07-1
gold(III) chloride

: mercury

: 7440-57-5, 457905-15-6
gold

Conditions

Conditions	Yield
In melt in pyridinium chloride melt;	95%
In not given excess AuCl3; slow redn.;
In hydrogenchloride moderate redn.;
In not given excess AuCl3; slow redn.;

: [dicadmium(diisobutyldithiocarbamate)4]

: 13453-07-1
gold(III) chloride

: 1379526-24-5
bis(N,N-di-iso-butyldithiocarbamato-S,S')gold(III) tetrachloroaurate(III)

Conditions

Conditions	Yield
With HCl In hydrogenchloride; water to corresponding Cd compd. soln. of AuCl3 in 2 M HCl added dropwise, stirred for 1 h; recrystn. (acetone); XRD;	93%

: Cd2(N,N-dipropyldithiocarbamate)4

: 13453-07-1
gold(III) chloride

: bis(N,N-dipropyldithiocarbamato-S,S')gold(III) hexachlorodicadmate(II)

Conditions

Conditions	Yield
With HCl In hydrogenchloride; water to corresponding Cd compd. soln. of AuCl3 in 2 M HCl added dropwise, stirred for 1 h; recrystn. (EtOH); XRD;	91%

: 24261-90-3
N,N,N'-tris(trimethylsilyl)benzamidine

: 13453-07-1
gold(III) chloride

: 122498-60-6
N,N'-bis(trimethylsilyl)benzamidinato-dichlorogold

Conditions

Conditions	Yield
In dichloromethane byproducts: ClSi(CH3)3; tris(trimethylsilyl)benzamidine added to a stirred suspension of AuCl3 in CH2Cl2 at 0°C, cooling removed, filtered; solvent removed, cooled down to 4°C, washed (cold CH2Cl2), dried in vacuo; elem. anal., IR;	90%

: cadmium(II) bis(dithiocarbamate)

: 13453-07-1
gold(III) chloride

: bis(N,N-dimethyldithiocarbamato-S,S')gold(III) tetrachlorocadmate(II)

Conditions

Conditions	Yield
With HCl In hydrogenchloride; water to corresponding Cd compd. soln. of AuCl3 in 2 M HCl added dropwise, stirred for 1 h; recrystn. (MeOH); XRD;	89%

: 498-66-8
norborn-2-ene

: 13453-07-1
gold(III) chloride

: 107657-95-4
AuCl(norbornene)

Conditions

Conditions	Yield
With carbon monoxide In dichloromethane CH2Cl2 soln. of anhyd. AuCl3 was stirred under carbon monoxide at atmospheric pressure at room temp. for 12 h, treated with a CH2Cl2 soln. of norbornene, stirred for 3 h at room temp.; evapd., pentane was added, the product was filtered and dried in vac.; elem. anal.;	88%

: cadmium diisopropyldithiocarbamate

: 13453-07-1
gold(III) chloride

: 1379526-23-4
bis(N,N-di-iso-propyldithiocarbamato-S,S')gold(III) tetrachloroaurate(III)

Conditions

Conditions	Yield
With HCl In hydrogenchloride; water to corresponding Cd compd. soln. of AuCl3 in 2 M HCl added dropwise, stirred for 1 h; recrystn. (acetone); XRD;	87%

: 201230-82-2
carbon monoxide

: 13453-07-1
gold(III) chloride

: 50960-82-2
carbonylgold(I) chloride

Conditions

Conditions	Yield
In thionyl chloride suspn. of anhyd. AuCl3 in SOCl2 stirred, dry CO, 1 h), red soln. filtered, CO uptake continued for 18 h (slow agitation); hexane added to soln. (CO atmosphere), crystals washed with CO-satd. hexane, dried (CO);	82.5%

: 13453-07-1
gold(III) chloride

: 14911-01-4
Au(py)Cl3

Conditions

Conditions	Yield
With C5H5N In water AuCl3 was dissolved in H2O and pyridine was added with stirring;; the ppt. was dried under vacuum;;	82%

: K10[P2W20(OH2)2O70]*22H2O

: 13453-07-1
gold(III) chloride

: 7K(1+)*2H(1+)*(AuO(OH2)P2W20O70(H2O)2)(9-)*27H2O=K7H2(AuO(H2O)P2W20O70(H2O)2)*27H2O

Conditions

Conditions	Yield
In water to aq. soln. K10(P2W20(OH2)2O70)*22H2O AuCl3 was added and stirred at 55°C for 2 h; soln. was cooled to room temp. and filtered, after 2 days at room temp. ppt. was filtered and dried under suction for 12 h; elem. anal.;	78%

: 60025-44-7
2-(2-phenylpropan-2-yl)pyridine

: 13453-07-1
gold(III) chloride

: 171509-71-0
HNC5H4C(CH3)2C6H5(1+)*AuCl4(1-)=[HNC5H4C(CH3)2C6H5][AuCl4]

Conditions

Conditions	Yield
In chloroform stirring (room temp., 1 h); concn., pptn. on Et2O addn.;	73%

: 13453-07-1
gold(III) chloride

A: 75-44-5
phosgene

: Au4Cl8

Conditions

Conditions	Yield
With CO In thionyl chloride AuCl3 suspended in SOCl2 under N2, reaction flask evacuated, filled with CO at atm. pressure, stirred at 20.1°C until Au2Cl6 disappeared(36 h); filtration, drying in vac.;	A n/a B 67%

: 13453-07-1
gold(III) chloride

: 738-70-5
5-(3,4,5-trimethoxybenzyl)pyrimidine-2,4-diamine

: 3(CH3O)3C6H2CH2C4HN2(NH2)2*Au(3+)*3Cl(1-)=((CH3O)3C6H2CH2C4HN2(NH2)2)3AuCl3

Conditions

Conditions	Yield
In methanol adding soln. of AuCl3 to soln. of trimethoprim in methanol; stirring for 24h at room temp.; evapn. (vac., 50°C), addn. of ether containing some MeOH, pptn.,filtn., dissolving in methanol, pptn. with ether, (this step was repeated three times), filtration, washing with ether, drying in vac. over P4O10 at 100°C; elem. anal.;	64%

Gold trichloride Consensus Reports

Reported in EPA TSCA Inventory.

Gold trichloride Specification

This chemical is called Gold trichloride, and it's also named as Gold chloride. With the classification codes of Mutation data; Reproductive Effect, its product categories are Inorganics; Gold Catalysts Metal and Ceramic Science; Gold Salts; Gold Catalysis and Inorganic Chemistry; GoldMetal and Ceramic Science; Catalysis and Inorganic Chemistry; Chemical Synthesis; Crystal Grade Inorganics. The CAS registry number of this chemical is 13453-07-1. Additionally, it's soluble in water.

Other characteristics of the chemical can be summarised as followings: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 0; (3)Rotatable Bond Count: 0; (4)Exact Mass: 301.87311; (5)MonoIsotopic Mass: 301.87311; (6)Topological Polar Surface Area: 0; (7)Heavy Atom Count: 4; (8)Formal Charge: 0; (9)Complexity: 8; (10)Isotope Atom Count: 0; (11)Covalently-Bonded Unit Count: 1.

When you are using this chemical, please be cautious about it as the following: This chemical is irritating to eyes, respiratory system and skin. You should wear suitable protective clothing if you use it. In case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
1.SMILES: Cl[Au](Cl)Cl
2.InChI: InChI=1/Au.3ClH/h;3*1H/q+3;;;/p-3/rAuCl3/c2-1(3)4
3.InChIKey: RJHLTVSLYWWTEF-LZHUSIJAAG

Product Name

Gold trichloride

Synthetic route

Gold trichloride Consensus Reports

Gold trichloride Specification

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