Rhenium fluoride(ReF<sub>6</sub>), (OC-6-11)- supplier

Name
RHENIUM HEXAFLUORIDE
EINECS 233-172-2
CAS No. 10049-17-9
Article Data20
CAS DataBase
Density 6 g/cm³
Solubility soluble HNO3; soluble 1.75mol/1000g anhydrous HF [MER06]
Melting Point 18.8 °C
Formula F₆Re
Boiling Point 47.6 °C
Molecular Weight 300.197
Flash Point
Transport Information UN 3390 6.1/PG 1
Appearance Yellow feather crystal
Safety 53-9-23-30-36/37/39-43-45
Risk Codes 14-32-35
Molecular Structure
Hazard Symbols C
Synonyms Rheniumfluoride (ReF₆) (6CI,7CI,8CI);Hexafluororhenium;Rhenium hexafluoride;Rhenium hexafluoride 99%;AC1L24X3;
PSA 0.00000
LogP 2.52120

Synthetic route

: rhenium

: 7790-91-2
chlorine trifluoride

A: 10049-17-9
rhenium hexafluoride

B: 15192-42-4
rhenium(IV) fluoride

Conditions

Conditions	Yield
In hydrogen fluoride uncomplete reaction at -78°C or under reflux;; ReF4 or ReF6 in soln. obtained;;
In hydrogen fluoride HF (liquid); uncomplete reaction at -78°C or under reflux;; ReF4 or ReF6 in soln. obtained;;

...Expand

: rhenium

: 7790-91-2
chlorine trifluoride

: 10049-17-9
rhenium hexafluoride

Conditions

Conditions	Yield
In neat (no solvent) at 300°C;;

: rhenium

: 7782-41-4
fluorine

: 10049-17-9
rhenium hexafluoride

Conditions

Conditions	Yield
In neat (no solvent) F2 and powdered Re at about 125°C;;
In neat (no solvent) heating Re in fluorspar boat with Cl2-free F2 in fluorspar tube/copper tube to 125 °C for 1/2 h at reduced pressure, exclusion of O2 and moisture;; condensing vapour in quartz trap at -60 °C, ReOCl4-free, pure product;;
In neat (no solvent) heating Re in fluorspar boat with F2 in fluorspar tube to 125 °C for 1/2 h, exclusion of O2 and moisture;; condensing vapour in quartz trap at -60 °C, product contg. ReOF4;;

: 14285-68-8
decacarbonyldirhenium(0)

: xenon fluoride

: 10049-17-9
rhenium hexafluoride

Conditions

Conditions	Yield
With HF In hydrogen fluoride HF (liquid); vac. line; large excess of HF;

: rhenium

: 10049-17-9
rhenium hexafluoride

Conditions

Conditions	Yield
With F2 In neat (no solvent) sublimation;

: rhenium

: 7782-41-4
fluorine

A: 10049-17-9
rhenium hexafluoride

: 17029-21-9
rhenium heptafluoride

Conditions

Conditions	Yield
In neat (no solvent)	A n/a B 0%
In neat (no solvent)	A n/a B 0%

...Expand

: 17029-21-9
rhenium heptafluoride

: 10049-17-9
rhenium hexafluoride

Conditions

Conditions	Yield
With dichloromethane In dichloromethane byproducts: CH2ClF, CHClF2, CHCl2F; inert atmosphere; excess of CH2Cl2, warming to room temp., 4 h; further byproduct;

: rhenium

: 23377-53-9
rhenium oxide pentafluoride

A: 10049-17-9
rhenium hexafluoride

B: rhenium(VI) oxide fluoride

Conditions

Conditions	Yield
With H2 In neat (no solvent) anhydrous atmosphere; activation of Re by static hydrogenation (573 K), then heating with ReOF5 (stainless-steel autoclave, 473 K, 16 h); cooling to room temp., removal of volatiles (vac.);

...Expand

: rhenium(IV) oxide

: 7782-41-4
fluorine

A: 10049-17-9
rhenium hexafluoride

B: 23377-53-9
rhenium oxide pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) anhydrous conditions, prefluorinated Ni apparatus; 525 K; removal of volatiles (room temp.), vac. sublimation;

...Expand

: 14285-68-8
decacarbonyldirhenium(0)

: xenon fluoride

A: 10049-17-9
rhenium hexafluoride

B: abcde-pentacarbonyl-f-μ-fluoro-ghijk-pentafluororhenium(I)-rhenium(V)

Conditions

Conditions	Yield
With HF In hydrogen fluoride byproducts: CO, Xe; HF (liquid); vac. line; addn. of 4-5 molar equiv. of XeF2 to Re-complex; evapn. (vac.); unchanged Re2(CO)10 present in product with molar ratio of educts 1:1 and 1:2;

...Expand

: 10049-17-9
rhenium hexafluoride

: 313-72-4
octafluoronaphthalene

: 102747-22-8
octafluoronaphthalene hexafluororhenate(V)

Conditions

Conditions	Yield
In trichlorofluoromethane octafluoronaphthalene dissolved in dry trichlorofluoromethane at 273 K,excess rhenium hexafluoride added; solvent removed;	100%

: 14285-68-8
decacarbonyldirhenium(0)

: 10049-17-9
rhenium hexafluoride

: 7664-39-3
hydrogen fluoride

: 41944-00-7
hexacarbonylrhenium(I) μ-fluoro-bis[pentafluororhenate(V)]

Conditions

Conditions	Yield
In hydrogen fluoride HF (liquid); absence of air and moisture (vac. technique, Kel-F apparatus); condensing HF onto Re-carbonyl, addn. of 4 molar equivalents of ReF6 (by sublimation), slow warming to room temp., standing for several days (crystn.); decantation, drying (vac.); elem. anal.;	86%

...Expand

: 10049-17-9
rhenium hexafluoride

: 681-84-5
tetramethylorthosilicate

: Re(OCH3)6

Conditions

Conditions	Yield
byproducts: SiF(OCH3)3; sepn. by sublimation;	80%

: 10049-17-9
rhenium hexafluoride

: 681-84-5
tetramethylorthosilicate

: C10H30O10Re2

Conditions

Conditions	Yield
With Mg(OMe)2(HOMe)2 In tetrahydrofuran; acetonitrile Condensating ReF6 into an acetonitrile soln. of Si(OMe)4 at -40°C followed by slow warming to room temperature, isolating reaction mixt., reacting with excess Mg(OMe)2(HOMe)2 soln. in THF.;	60%

: 7790-91-2
chlorine trifluoride

: 10049-17-9
rhenium hexafluoride

: 4648-54-8
trimethylsilylazide

A: 84159-30-8
ReF5(NCl)

B: 84159-29-5
rhenium tetrafluoride nitride

Conditions

Conditions	Yield
In 1,1,2-Trichloro-1,2,2-trifluoroethane ReF6 was reacted with ligand at -50°C in CF3ClCFCl2, allowed to warm to 0°C, solvent was removed, residue was warmed to 70°C in vac., sublimed, involatile residue was reacted with ClF3 at 0°C; sublimed at 70°C in vac.;	A n/a B 10%

...Expand

: 10049-17-9
rhenium hexafluoride

: 7664-39-3
hydrogen fluoride

: 7732-18-5
water

: rhenium(VI) oxide fluoride

Conditions

Conditions	Yield
In hydrogen fluoride room temp., equimolar amts. of ReF6 and H2O, removal of HF;

...Expand

: 10049-17-9
rhenium hexafluoride

: 7681-11-0
potassium iodide

: 7553-56-2
iodine

Conditions

Conditions	Yield
In neat (no solvent) reaction below 0 °C;;

: 10049-17-9
rhenium hexafluoride

: zinc(II) oxide

A: zinc(II) fluoride

B: rhenium(VI) oxide fluoride

Conditions

Conditions	Yield
In melt melting ZnO and ReF6 at 300 °C;; product mixt.;;

...Expand

: 10049-17-9
rhenium hexafluoride

: 7664-39-3
hydrogen fluoride

: 11113-50-1
boric acid

A: 108122-10-7
H3O(1+)*Re2O2F9(1-)=H3ORe2O2F9

B: 17026-29-8, 52152-11-1
rhenium oxotetrafluoride

Conditions

Conditions	Yield
With H2O In hydrogen fluoride byproducts: BF3; HF (liquid); H3BO3 was dissolved in HF, BF3 was distilled off at -78°C, H2O was dissolved in HF, ReF6 was condensed onto the soln., the mixt. was allowed to warm to room temp.; identified by Raman spectroscopy;

...Expand

: rhenium

: 10049-17-9
rhenium hexafluoride

: 15192-42-4
rhenium(IV) fluoride

Conditions

Conditions	Yield
In neat (no solvent) heating to 400-500 °C;;

: 10049-17-9
rhenium hexafluoride

: 7664-39-3
hydrogen fluoride

: 112926-00-8, 7631-86-9
silica gel

A: 42246-24-2
rhenium(VII) oxide fluoride

B: rhenium(IV) oxide fluoride

Conditions

Conditions	Yield
In hydrogen fluoride byproducts: HF; treating a soln. of ReF6 in pure liq. H2F2 with F2 in presence of KF in quartz vessel;; pptn., ReOF2 main product;;
In hydrogen fluoride byproducts: HF; HF (liquid); treating a soln. of ReF6 in pure liq. H2F2 with F2 in presence of KF in quartz vessel;; pptn., ReOF2 main product;;

...Expand

: 10049-17-9
rhenium hexafluoride

: 771-60-8
2,3,4,5,6-pentafluoroaniline

A: 119604-53-4
ReF4(NC6F5)

B: C6F5NH3(1+)*F(1-)={C6F5NH3}F

Conditions

Conditions	Yield
In further solvent(s) solvent: Genetron 113, excess of ReF6, at -80°C, allowed to warm to room temp., allowed to stand overnight at room temp.; not isolated;

...Expand

: 10049-17-9
rhenium hexafluoride

: 1333-74-0
hydrogen

: 30937-52-1
rhenium pentafluoride

Conditions

Conditions	Yield
In hydrogen fluoride HF (liquid); large exess of H2 condensed onto hexafluoride in anhydrous HF at -196°C, allowed to warm to room temp.; volatile species removed, fractionated; IR;

: 10049-17-9
rhenium hexafluoride

: rhenium

Conditions

Conditions	Yield
With sulfur dioxide In neat (no solvent) heating above 400 °C;;
With carbon monoxide In neat (no solvent) heating above 300 °C;;
With hydrogen In neat (no solvent) heating in H2 above 250 °C;;
With Mg or Zn or Al; In neat (no solvent) redn. at red heat;;

: 10049-17-9
rhenium hexafluoride

A: rhenium(VI) oxide fluoride

B: 42246-24-2
rhenium(VII) oxide fluoride

Conditions

Conditions	Yield
With oxygen In neat (no solvent) heating in O2 to 200-300 °C;; product mixt.;;

: 10049-17-9
rhenium hexafluoride

: 15192-42-4
rhenium(IV) fluoride

Conditions

Conditions	Yield
With carbon monoxide In neat (no solvent) heating to 300 °C;;
With hydrogen In neat (no solvent) byproducts: H2F2; mixing ReF6-vapour with H2 and O2-free N2, passing through Pt-tube at 200 °C, exclusion of air and moisture;; evapn. of H2F2 and ReF6 in vac.;;
With hydrogen In neat (no solvent) heating in H2 to 200-250 °C;;

: 10049-17-9
rhenium hexafluoride

A: ReO2*2H2O

B: 207984-93-8
per-rhenic acid

Conditions

Conditions	Yield
With water In water hydrolysis;

: 10049-17-9
rhenium hexafluoride

: Re hexafluoride(1-)

Conditions

Conditions	Yield
In neat (no solvent, gas phase) Kinetics; other Radiation; 133 Pa of He at 297 K;

: 10049-17-9
rhenium hexafluoride

: 42847-47-2
molybdenum hexafluoride ion

: Re hexafluoride(1-)

Conditions

Conditions	Yield
In neat (no solvent, gas phase) Kinetics; other Radiation; 133 Pa of He at 304 K;

: 7722-64-7
potassium permanganate

: 10049-17-9
rhenium hexafluoride

A: rhenium(VI) oxide fluoride

B: 42246-24-2
rhenium(VII) oxide fluoride

Conditions

Conditions	Yield
In melt heating melt of KMnO4 and ReF6 at 100 °C;;

...Expand

: 10049-17-9
rhenium hexafluoride

: 112926-00-8, 7631-86-9
silica gel

A: 15192-42-4
rhenium(IV) fluoride

B: 42246-24-2
rhenium(VII) oxide fluoride

C: 7783-61-1
silicon tetrafluoride

Conditions

Conditions	Yield
In neat (no solvent) in presence of moisture or alkali;;

...Expand

: 10049-17-9
rhenium hexafluoride

: 112926-00-8, 7631-86-9
silica gel

: 7783-61-1
silicon tetrafluoride

Conditions

Conditions	Yield
In neat (no solvent) above 3o ° C;;

: rhenium

: 10049-17-9
rhenium hexafluoride

: 30937-52-1
rhenium pentafluoride

Conditions

Conditions	Yield
In gas redn. of ReF6 by Re vapor at 110-1250 K in a mass spectrometer fitted with a Knudsen chamber; not isolated, detected by MS;

Rhenium fluoride(ReF₆), (OC-6-11)- Specification

The Rhenium fluoride(ReF₆), (OC-6-11)- with CAS registry number of 10049-17-9 is also known as Rhenium(6+) hexafluoride. The IUPAC name is Hexafluororhenium. Its EINECS registry number is 233-172-2. In addition, the formula is F₆Re and the molecular weight is 300.20. This chemical is a yellow feather crystal and is prepared by reaction of rhenium powder and fluorine gas.

Physical properties about Rhenium fluoride(ReF₆), (OC-6-11)- are: (1)H-Bond Acceptor: 6; (2)Exact Mass: 300.94617; (3)MonoIsotopic Mass: 300.94617; (4)Heavy Atom Count: 7; (5)Complexity: 62.7; (6)Covalently-Bonded Unit Count: 1.

When you are using this chemical, please be cautious about it. As a chemical, it contacts with acids liberates very toxic gas and reacts violently with water. Besides, it may cause severe burns. During using it, wear suitable protective clothing, gloves and eye/face protection. Avoid exposure that keep container in a well-ventilated place. Do not breathe gas/fumes/vapour/spray and never add water to this product. In case of accident or if you feel unwell seek medical advice immediately. What's more, should be carefull about fire.

You can still convert the following datas into molecular structure:
1. Canonical SMILES: F[Re](F)(F)(F)(F)F
2. InChI: InChI=1S/6FH.Re/h6*1H;/q;;;;;;+6/p-6
3. InChIKey: YUCDNKHFHNORTO-UHFFFAOYSA-H

Product Name

RHENIUM HEXAFLUORIDE

Synthetic route

Rhenium fluoride(ReF₆), (OC-6-11)- Specification

Related Products

Hot Products

Product Name

RHENIUM HEXAFLUORIDE

Synthetic route

Rhenium fluoride(ReF6), (OC-6-11)- Specification

Related Products

Hot Products

Rhenium fluoride(ReF₆), (OC-6-11)- Specification