Tetrabutylammonium hexafluorophosphate supplier

Name
Tetrabutylammonium hexafluorophosphate
EINECS 221-472-6
CAS No. 3109-63-5
Article Data21
CAS DataBase
Density
Solubility
Melting Point 244-246 ºC
Formula C₁₆H₃₆N^.PF₆
Boiling Point 242-246 °C
Molecular Weight 387.433
Flash Point
Transport Information 1759
Appearance off-white powder
Safety 26-36/37
Risk Codes 36/37/38-22
Molecular Structure
Hazard Symbols ,Xn
Synonyms 1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-);1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-) (1:1);
PSA 13.59000
LogP 8.38600

Synthetic route

: 1643-19-2
tetrabutylammomium bromide

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
With trimethyl phosphite; hexafluorophosphoric acid at 0 - 60℃; for 15h; Inert atmosphere; neat (no solvent);	96%
With potassium hexafluorophosphate In dichloromethane; water at 20℃; for 24h;	88%
With potassium hexafluorophosphate In dichloromethane; water at 20℃; for 24h;	88%

[N(nBu)4]X; X = halide: [N(nBu)4]X; X = halide

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
With silver(I) hexafluorophosphate In dichloromethane; acetonitrile at 20℃; for 10h; Darkness;	92%

: 1112-67-0
tetrabutyl-ammonium chloride

: 762-04-9
phosphonic acid diethyl ester

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
Stage #1: phosphonic acid diethyl ester With potassium fluoride; oxalyl dichloride In acetonitrile at 20℃; Glovebox; Sealed tube; Inert atmosphere; Stage #2: tetrabutyl-ammonium chloride In water at 20℃; for 0.166667h; Glovebox; Sealed tube; Inert atmosphere;	59%

: 67-56-1
methanol

: C16H36N(1+)*CH4O*F6P(1-)

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In dichloromethane at 26℃; Equilibrium constant; 1.3 - 1.5 M-1;

: ammonium hexafluorophosphate

: 1643-19-2
tetrabutylammomium bromide

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In not given recrystn.(ethanol/water), drying (vacuo, 24 h, 80°C);

: ((η3-methallyl)Ni(cod))PF6

: tri(3-sulfonatophenyl)phosphine tri(tetrabutylammonium)

A: (CH2C(CH3)CH2)Ni(C8H12)P(C6H4SO3Ni(CH2C(CH3)CH2))2(C6H4SO3)(1-)

B: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

C: 5259-72-3, 10060-40-9, 111-78-4
1,5-dicyclooctadiene

Conditions

Conditions	Yield
In dichloromethane addn. of TPPTSNBu4 to Ni-compd. (high 2/1 ratio) in CH2Cl2, room temp.; detd. spectr.; sepn. of cod by evapn.; pptn. of NBu4PF6;

...Expand

: ((η3-methallyl)Ni(cod))PF6

: tri(3-sulfonatophenyl)phosphine tri(tetrabutylammonium)

A: (CH2C(CH3)CH2)Ni(C8H12)P(C6H4SO3)3(3-)*2N(C4H9)4(1+)

B: (CH2C(CH3)CH2)Ni(C8H12)P(C6H4SO3)2(C6H4SO3Ni(CH2C(CH3)CH2))(2-)*N((CH2)3CH3)4(1+)

C: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

D: 5259-72-3, 10060-40-9, 111-78-4
1,5-dicyclooctadiene

Conditions

Conditions	Yield
In dichloromethane addn. of TPPTSNBu4 to Ni-compd. (low 2/1 ratio) in CH2Cl2, room temp.; detd. spectr.; sepn. of cod by evapn.; pptn. of NBu4PF6;

...Expand

: 2052-49-5
tetra(n-butyl)ammonium hydroxide

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
With hexafluorophosphate In water
With hexafluorophosphoric acid In water
With hexafluorophosphoric acid In water Inert atmosphere; Schlenk technique;

: 17084-13-8
potassium hexafluorophosphate

: 1112-67-0
tetrabutyl-ammonium chloride

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In water for 24h;

: ammonium hexafluorophosphate

: 1643-19-2
tetrabutylammomium bromide

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In water

: hexafluorophosphoric acid

: 2052-49-5
tetra(n-butyl)ammonium hydroxide

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In water

: 1112-67-0
tetrabutyl-ammonium chloride

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
With hexafluorophosphoric acid; sodium hydroxide

: C15H16IO3(1+)*F6P(1-)

: 18819-89-1
tetrabutylammonium benzoate

A: C25H27IO8

B: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;

...Expand

: C15H16IO3(1+)*F6P(1-)

: 3002-48-0
tetra-n-butylammonium p-nitrophenoxide

A: C24H26INO9

B: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;

...Expand

: 1112-67-0
tetrabutyl-ammonium chloride

: C15H16IO3(1+)*F6P(1-)

A: C18H22ClIO6

B: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In acetonitrile at 20℃; Equilibrium constant; Thermodynamic data; Inert atmosphere;

...Expand

: (3,5-bis(trifluoromethyl)phenyl)(phenyl)iodonium hexafluorophosphate

: 18819-89-1
tetrabutylammonium benzoate

A: C21H13F6IO2

B: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;

...Expand

: 951037-67-5
(perfluorophenyl)(phenyl)iodonium hexafluorophosphate

: 18819-89-1
tetrabutylammonium benzoate

A: C19H10F5IO2

B: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;

...Expand

: (3,5-bis(trifluoromethyl)phenyl)(phenyl)iodonium hexafluorophosphate

: 3002-48-0
tetra-n-butylammonium p-nitrophenoxide

A: C20H12F6INO3

B: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;

...Expand

: 951037-67-5
(perfluorophenyl)(phenyl)iodonium hexafluorophosphate

: 3002-48-0
tetra-n-butylammonium p-nitrophenoxide

A: C18H9F5INO3

B: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;

...Expand

: (3,5-bis(trifluoromethyl)phenyl)(phenyl)iodonium hexafluorophosphate

: 1112-67-0
tetrabutyl-ammonium chloride

A: C14H8ClF6I

B: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In acetonitrile at 20℃; Equilibrium constant; Thermodynamic data; Inert atmosphere;

...Expand

: 3002-48-0
tetra-n-butylammonium p-nitrophenoxide

: 58109-40-3
diphenyliodonium hexafluorophosphate

A: diphenyliodonium 4-nitrophenolate

B: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

Conditions

Conditions	Yield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;

...Expand

: trans-rhenium(V)-oxo-(Cl)(N,N'-propylenebis(acetylacetone)diimine)

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 554-70-1
triethylphosphine

: cis-[Re(V)O(triethylphosphine)(N,N'-propylenebis(acetylacetonate) diimine)][PF6]

Conditions

Conditions	Yield
In ethanol; dichloromethane Re complex dissolved in ethanol, soln. of triethylphosphine in CH2Cl2 added, reflued for 1 h under N2, tetrabutylammonium hexafluorophosphate added; concd., frozen overnight, crystal collected, washed with toluene, ether;elem. anal.;	99%

...Expand

: trans-rhenium(V)-oxo-(Cl)(N,N'-propylenebis(acetylacetone)diimine)

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 1605-53-4
diethyl-phenyl-phosphine

: cis-[Re(V)O(diethylphenylphosphine)(N,N'-propylenebis(acetylacetonate) diimine)][PF6]

Conditions

Conditions	Yield
In ethanol; dichloromethane Re complex dissolved in ethanol, soln. of diethylphenylphosphine in CH2Cl2 added, heated for 1 h under N2, tetrabutylammonium hexafluorophosphate added to warm soln.; cooled to room temp., ppt. filtered, washed with toluene, cold ethanol, ether; elem. anal.;	99%

...Expand

: trans-rhenium(V)-oxo-(Cl)(N,N'-propylenebis(acetylacetone)diimine)

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 603-35-0
triphenylphosphine

: cis-[Re(V)O(triphenylphosphine)(N,N'-propylenebis(acetylacetonate) diimine)][PF6]

Conditions

Conditions	Yield
In ethanol; dichloromethane Re complex dissolved in ethanol, soln. of triphenylphosphine in CH2Cl2 added, heated for 1 h under N2, tetrabutylammonium hexafluorophosphate added to warm soln.; cooled to room temp., ppt. filtered, washed with toluene, cold ethanol, ether; elem. anal.;	99%

...Expand

: 87761-77-1
aqua[N,N'-ethylenebis(acetylacetone iminato)]oxotechnetium(V) bromide

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 607-01-2
ethyl-diphenyl-phosphane

: 93427-02-2
trans-bis(diphenylethylphosphine)(N,N'-ethylenebis(acetylacetone iminato))technetium(III) hexafluorophosphate

Conditions

Conditions	Yield
In methanol adding of PEtPh2 to MeOH soln. of Tc(V) complex, stirring for 15 min atroom temp., adding of Bu4NPF6; filtration, concn., cooling overnight, filtration, washing with H2O, drying in vac. over P2O5;	98%

...Expand

: 1186470-04-1
2-[(2-pyridylmethyl)(2'-pyridylethyl)amino-methyl]-4-methyl-6-(methylthio)phenol

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: copper dichloride

: [Cu3Cl2(2-[(2-pyridylmethyl)(2'-pyridylethyl)amino-methyl]-4-methyl-6(methylthio)phenolate)2](hexafluorphosphate)2

Conditions

Conditions	Yield
With N(CH2CH3)3 In methanol refluxing mixt. of 2 equiv. of copper compd., 3 equiv. of phenol. deriv.and amine deriv. in methanol for 1 h, addn. of hexafluorophosphate salt; filtration, washing with cold methanol, drying in vac., elem. anal.;	97%

...Expand

: 2Os(3+)*4CH3CO2(1-)*2Cl(1-)=Os2(O2CCH3)4Cl2

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: (n-Bu4N)2{Os2Cl8}

Conditions

Conditions	Yield
With HCl In ethanol (under N2), a sample of the Os-compound was suspended in EtOH, which had been chilled in an ice bath and saturated with gaseous HCl, mixture was refluxed for 1.5 h, treated with an EtOH soln. containing an excess of n-Bu4NPF6; removal of the solvent, resulting green oil was dissolved in CH2Cl2, addn. of ethanol, diethyl ether was carefully layered over the soln., pptn., filtn., product was washed (ethanol, diethyl ether), drying under vacuum;	96%

Yield

With HCl In ethanol (under N2), a sample of the Os-compound was suspended in EtOH, which had been chilled in an ice bath and saturated with gaseous HCl, mixture was refluxed for 1.5 h, treated with an EtOH soln. containing an excess of n-Bu4NPF6; removal of the solvent, resulting green oil was dissolved in CH2Cl2, addn. of ethanol, diethyl ether was carefully layered over the soln., pptn., filtn., product was washed (ethanol, diethyl ether), drying under vacuum;

96%

: {(triphos)Rh(μ-C2S4)Rh(triphos)}Cl2

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: {(triphos)Rh(μ-C2Se4)Rh(triphos)}(PF6)2

Conditions

Conditions	Yield
In dichloromethane under N2; solid (NBu4)(PF6) added to the Rh-complex in CH2Cl2; crystn. on addn. of ethanol, elem. anal.;	95%

: [(C41H39P3)Rh(C2S4)Rh(C41H39P3)](2+)*2Cl(1-) = [(C41H39P3)Rh(C2S4)Rh(C41H39P3)]Cl2

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: [(C41H39P3)Rh(C2S4)Rh(C41H39P3)](2+)*2PF6(1-)=[(C41H39P3)Rh(C2S4)Rh(C41H39P3)](PF6)2

Conditions

Conditions	Yield
In dichloromethane under N2; solid (NBu4)(PF6) added to the Rh-complex in CH2Cl2; crystn. on addn. of ethanol, elem. anal.;	95%

: 12354-84-6, 12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

: 2633-03-6
2,2'-azopyridine

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 545436-48-4
[(η5-C5Me5)Ir(2,2'-azobis(pyridine))Cl]PF6

Conditions

Conditions	Yield
In methanol suspn. of complex and azo compound in CH3OH stirred for 3 h, concd., treated with 3 equiv of Bu4NPF6 in methanol; ppt. filtered off, washed with methanol and diethyl ether, dried under vac.; elem. anal.;	95%

...Expand

: 639518-84-6
di[1,4-bis(dimethylamino)-η6-benzene]chromium

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 639518-86-8
di[1,4-bis(dimethylamino)-η6-benzene]chromium hexafluorophosphate

Conditions

Conditions	Yield
With 4-pyridine carbaldehyde In tetrahydrofuran a soln. of n-Bu4NPF6 added to a soln. of Cr complex, stirred for 10 min at ambient temp., 4-pyridine carbaldehyde added dropwise, stirred for 30min; pptd. (Et2O), collected, washed (Et2O, H2O), dissolved in acetone, layered with Et2O; elem. anal.;	95%

: 12354-84-6, 12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

: glyoxalbis(2,6-dimethylphenylimine)

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: [(C5Me5)Ir(1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene)]PF6

Conditions

Conditions	Yield
In methanol stirring Ir-complex with 2.5 equiv. of diene for 4 h, pptn. on addn. of excess Bu4NCl; elem. anal.;	95%

...Expand

: 949566-81-8
2-[(bis(2-pyridylmethyl)amino)methyl]-4-methyl-6-(methylthio)phenol

: 7732-18-5
water

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: copper dichloride

: [CuCl(2-[(bis(2-pyridylmethyl)amino)methyl]-4-methyl-6-(methylthio)phenol)](hexafluorphosphate)*0.75water

Conditions

Conditions	Yield
In methanol refluxing 1:1 mixt. of copper compd. and phenol. deriv. in methanol for 1 h, addn. of hexafluorophosphate salt; filtration, washing with cold methanol, drying in vac., elem. anal.;	93%

...Expand

: 7677-24-9
trimethylsilyl cyanide

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: tetra-n-butylammonium mer-tricyanido(trifluorido)phosphate

Conditions

Conditions	Yield
With tris(pentafluorophenyl)borate at 25℃; for 80h; Inert atmosphere; Schlenk technique;	93%

: 67-56-1
methanol

: [Rh2(μ-OOCCH3)2(CH3CN)6](BF4)2

: 25005-97-4
2,3,5,6-tetrakis(2-pyridyl)pyrazine

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: Rh4(μ-OOCCH3)2(2,3,5,6-tetra-2-pyridylpirazine)2(CH3OH)4(PF6)4*2CH3OH

Conditions

Conditions	Yield
In methanol; dichloromethane (Rh2(OOCCH3)2(CH3CN)6)(BF4)2 dissolved in CH3OH and added to CH2Cl2 soln. of 2,3,5,6-tetra-2-pyridylpyrazine under N2 and heated for 1 h; treated with excess of (C4H9)4NPF6; soln. concd., treated with diethyl ether, solid collected by filtrn., recrystd. from a CH3OH/benzene soln.;	92%

...Expand

: 67-56-1
methanol

: 1186470-02-9
2-[(2-pyridylmethyl)(2'-pyridylethyl)amino-methyl]-4-methylphenol

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: copper dichloride

: [CuCl(2-[(2-pyridylmethyl)(2'-pyridylethyl)amino-methyl]-4-methylphenol)](hexafluorphosphate)*methanol

Conditions

Conditions	Yield
In methanol refluxing 1:1 mixt. of copper compd. and phenol. deriv. in methanol for 1 h, addn. of hexafluorophosphate salt; filtration, washing with cold methanol, drying in vac., elem. anal.;	92%

...Expand

: 12354-84-6, 12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

: 59742-91-5
2-acetylpyridine hydrazone

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 1370365-92-6
(η5-pentamethylcyclopentadienylato)IrCl(2-(1-hydrazonoethyl)pyridine)(PF6)

Conditions

Conditions	Yield
In ethanol Ar, Schlenk technique; mixt. of Ir-complex and pyridine-imine stirred atroom temp. for 5 min, Bu4NPF6 added; filtered, residue washed (THF, ether), dried (vac.); elem. anal.;	92%

...Expand

: cobalt(II) chloride hexahydrate

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride

: C20H28CoN6(2+)*2F6P(1-)

Conditions

Conditions	Yield
Stage #1: cobalt(II) chloride hexahydrate; 2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride With sodium hydroxide In water for 2h; pH=7; Stage #2: tert-butylammonium hexafluorophosphate(V) In water	92%

...Expand

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 7646-85-7
zinc(II) chloride

: 2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride

: (2,9-bis(2',5'-diazahexanyl)-1,10-phenanthroline)zinc(II) bis(hexafluorophosphate)

Conditions

Conditions	Yield
Stage #1: zinc(II) chloride; 2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride With sodium hydroxide In water for 2h; pH=7; Stage #2: tert-butylammonium hexafluorophosphate(V) In water	92%

...Expand

: 7677-24-9
trimethylsilyl cyanide

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: tetra-n-butylammonium monocyanido(pentafluorido)phosphate

Conditions

Conditions	Yield
at 25℃; for 20h; Time; Inert atmosphere;	92%

: trimethylaluminium dimer

: 214750-04-6
(Cl2BC5H4)Co(C5H4BCl3)

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 848891-30-5
Co(C5H4B(CH3)2)2(1+)*PF6(1-)=[Co(C5H4B(CH3)2)2]PF6

Conditions

Conditions	Yield
In dichloromethane; toluene N2-atmosphere; stirring (room temp., 2 h), evapn. (vac.), CH2Cl2 addn., pptn. on hexane addn., filtering, washing (hexane), Bu4NPF6 addn.; crystn. (CH2Cl2, -30°C); elem. anal.;	91%

...Expand

: 12354-84-6, 12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 51479-97-1
N1,N2-bis(o-tolyl)ethane-1,2-diimine

: 405316-13-4
[(CH3C6H4NCHCHNC6H4CH3)C5(CH3)5ClIr](1+)*PF6(1-)=[(CH3C6H4NCHCHNC6H4CH3)C5(CH3)5ClIr]PF6

Conditions

Conditions	Yield
In methanol addn. of diene deriv. to a suspn. of Ir complex in MeOH (in ultrasonic bath), stirred for 3 h at room temp.; concd. of soln., addn. of (C4H9)4NPF6 soln. in MeOH; ppt. collected, washed with MeOH and Et2O, dried under vac.; elem. anal.;	90%

...Expand

: nickel(II) chloride hexahydrate

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride

: (2,9-bis(2',5'-diazahexanyl)-1,10-phenanthroline)nickel(II) bis(hexafluorophosphate)

Conditions

Conditions	Yield
Stage #1: nickel(II) chloride hexahydrate; 2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride With sodium hydroxide In water for 2h; pH=7; Stage #2: tert-butylammonium hexafluorophosphate(V) In water	90%

...Expand

: copper(II) nitrate pentahydrate

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride

: C20H28CuN6(2+)*2F6P(1-)

Conditions

Conditions	Yield
Stage #1: copper(II) nitrate pentahydrate; 2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride With sodium hydroxide In water for 2h; pH=7; Stage #2: tert-butylammonium hexafluorophosphate(V) In water	90%

...Expand

: tetraacetatodiruthenium chloride

: 1338090-17-7
2-(pyrazin-2-yl)-1,8-naphthyridine

: 7732-18-5
water

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 75-05-8
acetonitrile

: cis-[Ru2(2-(2-pyrazinyl)-1,8-naphthyridine)2(OAc)2][PF6]2(CH3CN)(H2O)

Conditions

Conditions	Yield
Stage #1: tetraacetatodiruthenium chloride; 2-(pyrazin-2-yl)-1,8-naphthyridine; tert-butylammonium hexafluorophosphate(V) In methanol Inert atmosphere; Schlenk technique; Reflux; Stage #2: water; acetonitrile Inert atmosphere; Schlenk technique;	90%

...Expand

: N2,N6-bis(diethylcarbamothioyl)pyridine-2,6-dicarboxamide

: iron(III) chloride hexahydrate

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 7647-14-5
sodium chloride

: C51H69Fe2N15NaO6S6(1+)*F6P(1-)

Conditions

Conditions	Yield
Stage #1: N2,N6-bis(diethylcarbamothioyl)pyridine-2,6-dicarboxamide; iron(III) chloride hexahydrate; sodium chloride In methanol; water at 20℃; for 0.5h; Stage #2: With triethylamine In methanol; water at 20℃; for 0.5h; Stage #3: tert-butylammonium hexafluorophosphate(V) In methanol; water at 20 - 50℃; for 2h;	90%

...Expand

Tetrabutylammonium hexafluorophosphate Chemical Properties

IUPAC Name: Tetrabutylazanium hexafluorophosphate
Molecular Weight 387.42792 [g/mol]
Molecular Formula C₁₆H₃₆F₆NP
Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.F[P-](F)(F)(F)(F)F
InChI: InChI=1S/C16H36N.F6P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4; 1-7(2,3,4,5)6/h5-16H2,1-4H3; /q+1; -1
InChIKey: BKBKEFQIOUYLBC-UHFFFAOYSA-N
EINECS: 221-472-6
Product Categories: Ammonium Polyhalides, etc. (Quaternary); Quaternary Ammonium Compounds; Ammonium SaltsAnalytical Reagents; Electrochemistry; Greener Alternatives: Catalysis; Phase Transfer Catalysts; Supporting Electrolytes for Electrochemistry; Ammonium Salts
Boiling Point: 242-246 °C
solubility: acetonitrile: 0.1 g/mL, clear, colorless
Sensitive: Hygroscopic
Appearance: off-white powder
Melting Point: 244-246 °C(lit.)
Classification Code of Tetrabutylammonium hexafluorophosphate (CAS NO.3109-63-5): TSCA Flag P [A commenced PMN (Premanufacture Notice) substance]

Tetrabutylammonium hexafluorophosphate Safety Profile

Hazard Codes: Irritant Xi, Harmful Xn
Risk Statements: 36/37/38-22
R36/37/38:Irritating to eyes, respiratory system and skin.
R22:Harmful if swallowed.
Safety Statements: 26-36/37
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37:Wear suitable protective clothing and gloves.
RIDADR: 1759
WGK Germany: 3
Hazard Note; Irritant/Hygroscopic

Tetrabutylammonium hexafluorophosphate Specification

Tetrabutylammonium hexafluorophosphate (CAS NO.3109-63-5), its Synonyms are 1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-) ; 1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-) (1:1) .

Product Name

Tetrabutylammonium hexafluorophosphate

Synthetic route

Tetrabutylammonium hexafluorophosphate Chemical Properties

Tetrabutylammonium hexafluorophosphate Safety Profile

Tetrabutylammonium hexafluorophosphate Specification

Related Products

Hot Products