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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Tris(trimethylsilyl) phosphate

Cas:10497-05-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product description: Product name Tris(trimethylsilyl) phosphate CAS number 10497-05-9 Assay ≥99.5% Appearance Colorless transparent liquid Capacity 500mt/year Application Li

Tris(trimethylsilyl) phosphate

Cas:10497-05-9

Min.Order:100 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Factory low price Tris(trimethylsilyl)phosphate Cas 10497-05-9 with fast delivery Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediate

Factory low price Tris(trimethylsilyl)phosphate Cas 10497-05-9 with fast delivery

Cas:10497-05-9

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

good quality Appearance:white powder Storage:cold storage Package:meet the demand of customer Application:diagnostic reagent Transportation:by sea or by air Port:shanghai

Tris(trimethylsilyl)phosphate

Cas:10497-05-9

Min.Order:1 Gram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Tris(trimethylsilyl) phosphate

Cas:10497-05-9

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Tris-(trimethylsilyl)-phosphate

Cas:10497-05-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 10497-05-9 with competitive price

Cas:10497-05-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei yanxi chemical co.,LTD.

Details hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research

Tris(trimethylsilyl)phosphate

Cas:10497-05-9

Min.Order:20 Kilogram

FOB Price: $154.0 / 160.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Silanol,1,1,1-trimethyl-, 1,1',1''-phosphate 10497-05-9

Cas:10497-05-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

Tris(trimethylsilyl)phosphate CAS:10497-05-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality or

Tris(trimethylsilyl)phosphate CAS:10497-05-9

Cas:10497-05-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Silanol,1,1,1-trimethyl-, 1,1',1''-phosphate

Cas:10497-05-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Tris(Trimethylsilyl)Phosphate Tmsp

Cas:10497-05-9

Min.Order:0

Negotiable

Type:Manufacturers

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Henan Kanbei Chemical Co.,LTD

1. Well-equipped, stable and high-quality raw material supply chain, to provide customers with the best quality products. 2.Strict quality inspection process and professional certificate testing to ensure the quality level of the final product. 3.E

hot sale TRIS(TRIMETHYLSILYL) PHOSPHATE

Cas:10497-05-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 10497-05-9 Tris(trimethylsilyl)phosphate

Cas:10497-05-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Tris(Trimethylsilyl)Phosphate(TMSP)

Cas:10497-05-9

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Silanol,1,1,1-trimethyl-, 1,1',1''-phosphate

Cas:10497-05-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Tris(trimethylsilyl) phosphate 10497-05-9

Cas:10497-05-9

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

advantage: 1. The best price, satisfactory quality; 2. customers have the right to choose the delivery of parcels (EMS, DHL, FedEx, UPS); 3. customers have the right to choose from the recent effective packaging methods of their products packaging

10497-05-9 Tris(trimethylsilyl)phosphate with best quality

Cas:10497-05-9

Min.Order:1 Gram

Negotiable

Type:Other

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Henan Tianfu Chemical Co., Ltd.

Tianfu Chemical, built in 2009, is a professional supplier for API materials in China. With 10 years development, we have bulit our own factory and lab to produce a certain of products. And we have established stable business relationships with

TIANFU CHEM - Supply 10497-05-9 TRIS(TRIMETHYLSILYL) PHOSPHATE In Stock

Cas:10497-05-9

Min.Order:1 Kilogram

FOB Price: $200.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: Tris(Trimethylsilyl)Phosphate CAS No.:10497-05-9 Molecule Formula: C9H27O4PSi3 Molecule Weight:314.53 Purity: 99.0% Package: 25kg/drum Description:Colorless or light yellow liquid Manufacture Standards:Enterprise Standard

Lower Price Tris(Trimethylsilyl)Phosphate

Cas:10497-05-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Shanghai Minstar Chemical Co., Ltd

TRIS(TRIMETHYLSILYL) PHOSPHATE Basic information Product Name: TRIS(TRIMETHYLSILYL) PHOSPHATE Synonyms: Phosphoric acid, TMS;Phosphoric acid, tristrimethylsilyl;Phosphoric acid, triTMS;Silanol, trimethyl-, phosphate (3:1);Silanol,trimethyl-,ph

TRIS(TRIMETHYLSILYL) PHOSPHATE

Cas:10497-05-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Tris(trimethylsilyl) phosphate cas no. 10497-05-9 98%

Cas:10497-05-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Tris(Trimethylsilyl) Phosphate

Cas:10497-05-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Tris(trimethylsilyl)phosphate

Cas:10497-05-9

Min.Order:0

Negotiable

Type:Other

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Hangzhou Dingyan Chem Co., Ltd

high purity, manufacturer Application:Intermediate

Tris(Trimethylsilyl) Phosphate

Cas:10497-05-9

Min.Order:0

Negotiable

Type:Manufacturers

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Tris(Trimethylsilyl)Phosphate 100g

Cas:10497-05-9

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Shanghai Yui Sifluo Co.. Ltd.

In fluorine chemical, Yuji Tech has been dedicated to R&D of production of ODS alternatives, fluoropolymers and fluorinated fine chemicals for years, and has become an international leading innovation enterprise in fluorine chemical research an

Tris(trimethylsilyl) Phosphate

Cas:10497-05-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as: Frac

Tris(Trimethylsilyl)Phosphate

Cas:10497-05-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages? High purity, all above 98.5%, no impurities after dissolution? We will test each batch to ensure quality? OEM and private brand services designed for free? Various cap colors available? We can also provide MT1 peptide powder2.

TRIS(TRIMETHYLSILYL) PHOSPHATE

Cas:10497-05-9

Min.Order:0

Negotiable

Type:Trading Company

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Synthetic route

hexamethyldisilathiane
3385-94-2

hexamethyldisilathiane

A

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

B

O,O,O-tris(trimethylsilyl) phosphorothioate
20152-28-7

O,O,O-tris(trimethylsilyl) phosphorothioate

Conditions
ConditionsYield
With phosphorus pentoxide at 170 - 180℃; for 10h;A 85%
B 98%
potassium dihydrogenphosphate

potassium dihydrogenphosphate

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
In formamide for 1h; Inert atmosphere; Schlenk technique;98%
Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

N-trimethylsilyldihydropyrrole

N-trimethylsilyldihydropyrrole

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
Stage #1: Hexamethyldisiloxane With phosphoric acid at 160 - 170℃; under 4500.45 - 6000.6 Torr; for 5h; Autoclave; Reflux;
Stage #2: N-trimethylsilyldihydropyrrole at 100℃; under 760.051 Torr;
96.52%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With potassium dihydrogenphosphate In hexane Reflux;96%
With ammonium dihydrogen phosphate at 78℃; for 3h; Temperature; Reagent/catalyst; Time;89.6%
With phosphoric acid
With phosphoric acid Schlenk technique; Inert atmosphere;
With phosphoric acid Inert atmosphere;
1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

H3PO4

H3PO4

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With saccharin In acetonitrile for 1h; Heating;93%
N-trimethylsilyl-pyrrolidin-2-one
14468-90-7

N-trimethylsilyl-pyrrolidin-2-one

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With lithium dihydrogenphosphate at 20℃; for 1h;86%
tetrakis(trimethylsiloxy)phosphonium iodide
53380-41-9

tetrakis(trimethylsiloxy)phosphonium iodide

A

trimethylsilyl iodide
16029-98-4

trimethylsilyl iodide

B

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
In benzene Heating; during 5 h the solvent was distilled off, the temp. rose to 110 deg C;A n/a
B 85%
C22H50O10P2SSi5
1416767-26-4

C22H50O10P2SSi5

A

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

B

bis(trimethylsilyl) (1,1-dioxido-3Н-2,1-benzoxathiol-3-yl)phosphonate
1416767-27-5

bis(trimethylsilyl) (1,1-dioxido-3Н-2,1-benzoxathiol-3-yl)phosphonate

Conditions
ConditionsYield
at 90 - 110℃; under 1 Torr;A n/a
B 52%
N,O-bis-(trimethylsilyl)-acetamide
10416-59-8

N,O-bis-(trimethylsilyl)-acetamide

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With trichlorophosphate at 120℃; for 1h;26%
tris(trimethylsilyl) phosphite
1795-31-9

tris(trimethylsilyl) phosphite

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With trityl-glycidol at 130 - 150℃;24%
With styrene oxide at 130 - 150℃;
1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

A

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

B

Tetrakis(trimethylsilyl) pyrophosphate
18395-45-4

Tetrakis(trimethylsilyl) pyrophosphate

C

1,1,3,5,7,7-hexakis(trimethylsilyl) pyrophosphate
32284-31-4

1,1,3,5,7,7-hexakis(trimethylsilyl) pyrophosphate

D

1,1,3,5,5-pentakis(trimethylsilyl) pyrophosphate

1,1,3,5,5-pentakis(trimethylsilyl) pyrophosphate

Conditions
ConditionsYield
With phosphorus pentoxide at 100 - 140℃; for 2h; Further byproducts given;A 21%
B 6%
C 3%
D 3%
Methoxytrimethylsilane
1825-61-2

Methoxytrimethylsilane

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With phosphonic Acid; air
Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With phosphorus pentoxide
With phosphorus pentoxide durch langsame Destillation;
With phosphorus pentoxide In neat (no solvent) very slow distn. of (CH3)3SiOSi(CH3)3 over P2O5;;
With P4O10 In neat (no solvent) very slow distn. of (CH3)3SiOSi(CH3)3 over P2O5;;
phosphoric acid, bis(trimethylsilyl)monomethyl ester
18291-81-1

phosphoric acid, bis(trimethylsilyl)monomethyl ester

phenylthiotrimethylsilane
4551-15-9

phenylthiotrimethylsilane

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With perhydrodibenzo-18-crown-6; potassium thiophenolate In benzene
phosphoric acid ethyl ester-bis-trimethylsilanyl ester
17882-98-3

phosphoric acid ethyl ester-bis-trimethylsilanyl ester

phenylthiotrimethylsilane
4551-15-9

phenylthiotrimethylsilane

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With perhydrodibenzo-18-crown-6; potassium thiophenolate In benzene
phenylthiotrimethylsilane
4551-15-9

phenylthiotrimethylsilane

Bis-(trimethylsilyl)-n-propyl-phosphat

Bis-(trimethylsilyl)-n-propyl-phosphat

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With perhydrodibenzo-18-crown-6; potassium thiophenolate In benzene
trimethylsilyl acetate
2754-27-0

trimethylsilyl acetate

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With phosphorus(V) oxybromide at 90℃; for 3h;
Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

P2O5

P2O5

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
durch langsame Destillation;
1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With ammonium hypophosphite
bis(trimethylsilyl)phosphonite
30148-50-6

bis(trimethylsilyl)phosphonite

allyl-trimethyl-silane
762-72-1

allyl-trimethyl-silane

A

bis(trimethylsilyl) phosphonate
3663-52-3

bis(trimethylsilyl) phosphonate

B

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

C

trimethylsilyl [3-(trimethylsilyl)propyl]phosphinate
1219077-76-5

trimethylsilyl [3-(trimethylsilyl)propyl]phosphinate

D

bis(trimethylsilyl) [3-(trimethylsilyl)propyl]phosphonate
1219077-75-4

bis(trimethylsilyl) [3-(trimethylsilyl)propyl]phosphonate

E

trimethylsilylhypophosphite
38049-93-3

trimethylsilylhypophosphite

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); water for 7h; Reflux;A n/a
B 0.1 g
C 0.45 g
D 0.12 g
E n/a
tris(trimethylsilyl) phosphite
1795-31-9

tris(trimethylsilyl) phosphite

A

bis(trimethylsilyl) phosphonate
3663-52-3

bis(trimethylsilyl) phosphonate

B

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

C

Tetrakis(trimethylsilyl) pyrophosphate
18395-45-4

Tetrakis(trimethylsilyl) pyrophosphate

D

Trimethylsilyldifluorophosphat
4414-25-9

Trimethylsilyldifluorophosphat

E

bis(trimethylsilyl) phosphorofluoridate
5668-94-0

bis(trimethylsilyl) phosphorofluoridate

Conditions
ConditionsYield
With [1,3]-dioxolan-2-one; lithium hexafluorophosphate; water; Diethyl carbonate In [D3]acetonitrile at 20℃; Glovebox; Inert atmosphere;
tris(trimethylsilyl) phosphite
1795-31-9

tris(trimethylsilyl) phosphite

A

bis(trimethylsilyl) phosphonate
3663-52-3

bis(trimethylsilyl) phosphonate

B

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Conditions
ConditionsYield
With nickel(II) chloride hexahydrate at 160℃; for 42h; Schlenk technique; Inert atmosphere;
trimethylgallium

trimethylgallium

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Me3Ga*OP(OSiMe3)3

Me3Ga*OP(OSiMe3)3

Conditions
ConditionsYield
In hexane N2-atmosphere; addn. of soln. of GaMe3 (10% excess) to phosphate ester soln.; concn., crystd. on cooling (-24°C), collection (filtration), drying (vac.); elem. anal.;95%
Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

Conditions
ConditionsYield
With sodium fluoride 150 to 200 deg C;91.5%
Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

(fluoro)bis(cyclopentadienyl)vanadium
942422-03-9

(fluoro)bis(cyclopentadienyl)vanadium

tris(pentafluorophenyl)borate
1109-15-5

tris(pentafluorophenyl)borate

C41H29BF15O4PSiV2

C41H29BF15O4PSiV2

Conditions
ConditionsYield
Stage #1: Tris(trimethylsilyl) phosphate; tris(pentafluorophenyl)borate In dichloromethane at 20℃; for 1h; Inert atmosphere; Glovebox;
Stage #2: (fluoro)bis(cyclopentadienyl)vanadium In dichloromethane at 20℃; for 24h; Inert atmosphere; Glovebox;
90%
Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

trimethylsilylazide
4648-54-8

trimethylsilylazide

Conditions
ConditionsYield
With sodium azide at 150℃; for 0.166667h;87%
Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

A

trimethylsilylazide
4648-54-8

trimethylsilylazide

B

Na3PO4

Na3PO4

Conditions
ConditionsYield
With sodium azide at 150℃; for 0.166667h; other substrates, other reagents;A 87%
B n/a
hexaethyldialuminum

hexaethyldialuminum

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Et3Al*OP(OSiMe3)3

Et3Al*OP(OSiMe3)3

Conditions
ConditionsYield
In hexane N2-atmosphere; addn. of soln. of AlMe3 (10% excess) to phosphate ester soln. at cooling, warming to room temp.; evapn. (vac.); elem. anal.;87%
bis(trimethylsilyl) phosphonate
3663-52-3

bis(trimethylsilyl) phosphonate

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

ethyl N-phenylformimidate
6780-49-0

ethyl N-phenylformimidate

O,O',O'',O'''-tetra(trimethylsilyl) N-anilinomethylenebisphosphonate
1227665-11-3

O,O',O'',O'''-tetra(trimethylsilyl) N-anilinomethylenebisphosphonate

Conditions
ConditionsYield
With zinc(II) chloride at 150 - 160℃; for 1h; Reflux;86%
18-crown-6 ether
17455-13-9

18-crown-6 ether

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

potassium tert-butylate
865-47-4

potassium tert-butylate

C12H24KO6(1+)*C6H18O4PSi2(1-)

C12H24KO6(1+)*C6H18O4PSi2(1-)

Conditions
ConditionsYield
In 1,2-dimethoxyethane for 0.166667h;85%
Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

trimethylsilane adduct of trimethylsilylium tetrakis(pentafluorophenyl)borate
1331770-02-5

trimethylsilane adduct of trimethylsilylium tetrakis(pentafluorophenyl)borate

tetrakis(trimethylsiloxy)phosphonium tetrakis(pentafluorophenyl)borate

tetrakis(trimethylsiloxy)phosphonium tetrakis(pentafluorophenyl)borate

Conditions
ConditionsYield
In toluene for 1h; Sonication;83%
2,2,4,4-tetraethyl-1,3-dichlora(II)-2,4-dialumina(IV)cyclobutane

2,2,4,4-tetraethyl-1,3-dichlora(II)-2,4-dialumina(IV)cyclobutane

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

[Et2Al(μ-O)2P(OSiMe3)2]2

[Et2Al(μ-O)2P(OSiMe3)2]2

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; refluxing for 5 h; elem. anal.;82%
dimethylaluminum chloride dimer

dimethylaluminum chloride dimer

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

[Me2Al(μ-O)2P(OSiMe3)2]2

[Me2Al(μ-O)2P(OSiMe3)2]2

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; refluxing for 5 h; evapn., recrystn. (hexane); elem. anal.;81%
trimethylaluminium dimer

trimethylaluminium dimer

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

Me3Al*OP(OSiMe3)3

Me3Al*OP(OSiMe3)3

Conditions
ConditionsYield
In hexane N2-atmosphere; addn. of soln. of AlMe3 (10% excess) to phosphate ester soln. at cooling, warming to room temp.; concn., crystd. on cooling (-24°C), collection (filtration), drying (vac.); elem. anal.;74%
bis(bis(trimethylsilyl)amido)zinc(II)

bis(bis(trimethylsilyl)amido)zinc(II)

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

[Zn{N(SiMe3)2}2OP(OSiMe3)3]

[Zn{N(SiMe3)2}2OP(OSiMe3)3]

Conditions
ConditionsYield
In toluene at 20℃; Schlenk technique; Inert atmosphere;69%
Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

titanium tetrachloride
7550-45-0

titanium tetrachloride

Ti2Cl7(O2P(OSi(CH3)3)2)(OP(OSi(CH3)3)3)

Ti2Cl7(O2P(OSi(CH3)3)2)(OP(OSi(CH3)3)3)

Conditions
ConditionsYield
In further solvent(s) boiling gently soln. of OP(OSi(CH3)3)3 (0.51 mmol) and TiCl4 (0.50 mmol) in ClSi(CH3)3; allowing to cool;; pptn.;;66%
In benzene-d6 byproducts: ClSi(CH3)3; briefly heating to boiling in benzene-d6;; not isolated, detected by 1H- and 31P-NMR;;
VOCl3*CH3CN

VOCl3*CH3CN

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

(VO)6(O3POSi(CH3)3)8(1+)*Cl(1-)=(VO)6(O3POSi(CH3)3)8Cl

(VO)6(O3POSi(CH3)3)8(1+)*Cl(1-)=(VO)6(O3POSi(CH3)3)8Cl

Conditions
ConditionsYield
In acetonitrile inert atmosphere; crystn. (40-50°C, 4 h, room temp., 2 d); elem. anal.;59%
Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

tert-butylaluminium dichloride
50307-34-1

tert-butylaluminium dichloride

[((t)Bu)Al(μ2-O)3P(OSiMe3)]4

[((t)Bu)Al(μ2-O)3P(OSiMe3)]4

Conditions
ConditionsYield
In tetrahydrofuran dropwise addn. of 1 equiv. P-compd. to Al-compd. (stirring), refluxing for 2 h; vol. reduction (vac.), crystn. (-20°C, overnight); elem. anal.;56%
Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

bis(tert-butyl)aluminium chloride
22086-73-3

bis(tert-butyl)aluminium chloride

[((t)Bu)2Al(μ2-O)2P(OSiMe3)2]2

[((t)Bu)2Al(μ2-O)2P(OSiMe3)2]2

Conditions
ConditionsYield
In tetrahydrofuran dropwise addn. of 1 equiv. P-compd. to Al-compd. (stirring), refluxing for 2 h; vol. reduction (vac.), crystn. (-20°C, overnight); elem. anal.;56%
Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

sodium acetate
127-09-3

sodium acetate

trimethylsilyl acetate
2754-27-0

trimethylsilyl acetate

Conditions
ConditionsYield
150 to 200 deg C;45.5%
Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

(fluoro)bis(cyclopentadienyl)vanadium
942422-03-9

(fluoro)bis(cyclopentadienyl)vanadium

tris(pentafluorophenyl)borate
1109-15-5

tris(pentafluorophenyl)borate

C48H30BF15O4PV3

C48H30BF15O4PV3

Conditions
ConditionsYield
Stage #1: Tris(trimethylsilyl) phosphate; tris(pentafluorophenyl)borate In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Glovebox;
Stage #2: (fluoro)bis(cyclopentadienyl)vanadium In tetrahydrofuran at 20℃; for 48h; Inert atmosphere; Glovebox;
43.2%
tris[μ-[2,6-bis(1-methylethyl)benzenaminato]]trimethyltricycloaluminum
117960-70-0

tris[μ-[2,6-bis(1-methylethyl)benzenaminato]]trimethyltricycloaluminum

Tris(trimethylsilyl) phosphate
10497-05-9

Tris(trimethylsilyl) phosphate

(MeAl)[2,6-(i-Pr)2C6H3N]3(Al[OP(OSiMe3)3])2(O3POSiMe3)
482315-48-0

(MeAl)[2,6-(i-Pr)2C6H3N]3(Al[OP(OSiMe3)3])2(O3POSiMe3)

Conditions
ConditionsYield
In toluene under N2 atm. OP(OSiMe3)3 was added dropwise to alumazene in toluene andrefluxed for 24 h; react. mixt. was cooled to room temp.; elem. anal.;36%
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