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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

Cyclic octaatomic sulfur CAS 10544-50-0

Cas:10544-50-0

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 10544-50-0 with competitive price

Cas:10544-50-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Sulfur, mol. (S8) 10544-50-0

Cas:10544-50-0

Min.Order:1 Kilogram

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Qingdao Beluga Import and Export Co., LTD

Cyclic octaatomic sulfur CAS:10544-50-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

Cyclic octaatomic sulfur CAS:10544-50-0

Cas:10544-50-0

Min.Order:1 Gram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Sulfur, mol. (S8)

Cas:10544-50-0

Min.Order:1 Kilogram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Sulfur, mol. (S8)

Cas:10544-50-0

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Sulfur, mol. (S8)

Cas:10544-50-0

Min.Order:10 Gram

FOB Price: $100.0

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

cyclooctasulfur

Cas:10544-50-0

Min.Order:1 Gram

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Type:Lab/Research institutions

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Buy Top Purity Cyclic octaatomic sulfur

Cas:10544-50-0

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Cyclic octaatomic sulfur

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Cyclic octaatomic sulfur

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Min.Order:1 Gram

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis:

Sulfur, mol. (S8)

Cas:10544-50-0

Min.Order:0

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Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

Cyclic octaatomic sulfur

Cas:10544-50-0

Min.Order:1 Kilogram

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Type:Other

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Hebei Mojin Biotechnology Co.,Ltd

We produce carbomer by our own factory,carbomer 940 is our best seller.It is used for cosmetic and medical.And we also become agent for lubrizol.Our carbomer 940 get high viscosity and good transparency.The price will depond on the market,surely supp

Sulfur, mol. (S8)

Cas:10544-50-0

Min.Order:0

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Sulfur, mol. (S8)

Cas:10544-50-0

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Hangzhou Dingyan Chem Co., Ltd

Hangzhou Dingyan Chem is a leading manufacturer and supplier of chemicals in China.We develop,produce and distribute high quality pharmaceuticals, intermediates, special chemicals and other fine chemicals.Appearance:A white or almost white crystallin

High quality 10544-50-0 cyclooctasulfur

Cas:10544-50-0

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

Cyclic octaatomic sulfur

Cas:10544-50-0

Min.Order:0

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Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

Cyclic octaatomic sulfur

Cas:10544-50-0

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Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Sulfur, mol. (S8)

Cas:10544-50-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

Cyclic octaatomic sulfur

Cas:10544-50-0

Min.Order:0

Negotiable

Type:Manufacturers

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Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world.2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%.3,our staff consists of highly qualified in

Cyclic octaatomic sulfur

Cas:10544-50-0

Min.Order:0

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Sulfur, mol. (S8)

Cas:10544-50-0

Min.Order:0

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DB BIOTECH CO., LTD

best seller Application:API

Cyclic octaatomic sulfur

Cas:10544-50-0

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Hangzhou Fandachem Co.,Ltd

Cyclic octaatomic sulfurAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:pharmaceutical intermediate Transportation:by air, by sea, by express

Cyclic octaatomic sulfur

Cas:10544-50-0

Min.Order:0

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Cyclic octaatomic sulfur

Cas:10544-50-0

Min.Order:0

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

Cyclic octaatomic sulfur

Cas:10544-50-0

Min.Order:0

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Changzhou Helios Biomedical Science and Technology Co.,LTD.

Changzhou Helios Biochemical Co., Ltd is a leading manufacturer and supplier for medical intermediates and pesticide intermediates . We specialize in custom synthesis of benzene ring, pyridine and pyrimidine derivatives to help customers to accelerat

Cyclic octaatomic sulfur

Cas:10544-50-0

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Shanghai Terui OP New Material Technology Co., Ltd.

The factory supplies Application:manufacturing supplies

Sulfur,mol.(S8)

Cas:10544-50-0

Min.Order:0

Negotiable

Type:Trading Company

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Hebei Muhuang Technology Co., Ltd

best seller Application:API

Cyclic octaatomic sulfur

Cas:10544-50-0

Min.Order:0

Negotiable

Type:Trading Company

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Cyclic octaatomic sulfur

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Synthetic route

Cu2Pt4S8

Cu2Pt4S8

A

sulfur
10544-50-0

sulfur

B

platinum(II) sulfide

platinum(II) sulfide

C

copper(I) sulfide
22205-45-4

copper(I) sulfide

Conditions
ConditionsYield
decompn. under argon at about 800 K;A 100%
B 100%
C 100%
3-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)pyridin-2-ol

3-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)pyridin-2-ol

A

sulfur
10544-50-0

sulfur

B

oxazolo[5,4-b]pyridine-2-carbonitrile

oxazolo[5,4-b]pyridine-2-carbonitrile

Conditions
ConditionsYield
In chlorobenzene at 132℃; for 1h; Solvent; Reagent/catalyst; Inert atmosphere;A 100%
B 96%
hydrogen sulfide
7783-06-4

hydrogen sulfide

oxygen
80937-33-3

oxygen

A

sulfur
10544-50-0

sulfur

B

Sulfate
14808-79-8

Sulfate

C

sulfite(2-)
14265-45-3

sulfite(2-)

Conditions
ConditionsYield
With air; iron(III) chloride In water H2S and air were bubbled into soln. FeCl3 in N-methylpyrrolidinone-H2O (95:5) at room temp. for 300 h;A 98.72%
B 0.09%
C 0.02%
With air; Iron(III) nitrate nonahydrate In water H2S and air were bubbled into soln. Fe(NO3)3*9H2O in N-methylpyrrolidinone-H2O (95:5) at room temp. for 24 h;A 63.03%
B n/a
C n/a
With air; iron(III) chloride In further solvent(s) H2S and air were bubbled into soln. FeCl3 in N-methylpyrrolidinone at room temp. for 100-313 h; sulfur was filtered off;
With air; iron(III) chloride hexahydrate In water H2S and air were bubbled into soln. FeCl3*6H2O in N-methylpyrrolidinone-H2O (95:5) at room temp. for 198 h;
With air; iron(III) chloride In water H2S and air were bubbled into soln. FeCl3 in N-methylpyrrolidinone-H2O (95:5) at room temp. for 300 h;
2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

dibenzylamine
103-49-1

dibenzylamine

A

sulfur
10544-50-0

sulfur

B

1,3-dibenzyl-2-(3,5-dicyano-6-ethoxy-4-phenylpyridin-2-yl)guanidine

1,3-dibenzyl-2-(3,5-dicyano-6-ethoxy-4-phenylpyridin-2-yl)guanidine

Conditions
ConditionsYield
In dichloromethane for 7h; Reflux;A 98%
B 82%
[1,2,3]dithiazolo[5,4-e]pyrido[3,2-b][1,4]oxazine

[1,2,3]dithiazolo[5,4-e]pyrido[3,2-b][1,4]oxazine

A

sulfur
10544-50-0

sulfur

B

oxazolo[5,4-b]pyridine-2-carbonitrile

oxazolo[5,4-b]pyridine-2-carbonitrile

Conditions
ConditionsYield
at 230℃; for 0.166667h; Reagent/catalyst; Solvent; Inert atmosphere;A 97%
B 65%
(CH3)3SiCHCH2(SFe(CO)3)2

(CH3)3SiCHCH2(SFe(CO)3)2

copper dichloride

copper dichloride

A

sulfur
10544-50-0

sulfur

B

1,4-bis(trimethylsilyl)-2,3,6,7-tetrathiacyclooctane
87495-58-7

1,4-bis(trimethylsilyl)-2,3,6,7-tetrathiacyclooctane

C

iron(II) chloride

iron(II) chloride

D

ethenyltrimethylsilane
754-05-2

ethenyltrimethylsilane

Conditions
ConditionsYield
In benzene byproducts: Cu2Cl2, CO; 80°C, 8 h; filtn., washing ppt. (hot benzene), chromy. of filtrate after removing solvent;A 90%
B 10%
C n/a
D 96%
dichloro(oxo)(η5-pentamethylcyclopentadienyl)rhenium(V)

dichloro(oxo)(η5-pentamethylcyclopentadienyl)rhenium(V)

A

sulfur
10544-50-0

sulfur

(C5(CH3)5)ReS3S4

(C5(CH3)5)ReS3S4

Conditions
ConditionsYield
With (NH4)2S(x) In tetrahydrofuran; methanol addn. of a soln. of (NH4)2S(x) in methanol to a soln. of (C5Me5)ReOCl2 in THF and stirring for 4 h; removal of the solvent and chromatography of the residue on silica gel, elution of S8 with toluene/hexane and elution of (C5Me5)ReS3S4 with CH2Cl2, recrystn. from CHCl3/hexane at -25°C;A n/a
B 95.8%
pyrrolidine
123-75-1

pyrrolidine

2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

A

sulfur
10544-50-0

sulfur

B

7-ethoxy-5-phenyl-4-(pyrrolidin-1-yl)pyrido[2,3-d]pyrimidine-2,6-dicarbonitrile

7-ethoxy-5-phenyl-4-(pyrrolidin-1-yl)pyrido[2,3-d]pyrimidine-2,6-dicarbonitrile

C

2-(dipyrrolidin-1-ylmethyleneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

2-(dipyrrolidin-1-ylmethyleneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

D

2-amino-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile
30464-12-1

2-amino-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

Conditions
ConditionsYield
In dichloromethane for 0.166667h; Solvent; Temperature; Time; Reflux;A 95%
B 78%
C 14%
D 6%
piperidine
110-89-4

piperidine

2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

A

sulfur
10544-50-0

sulfur

B

7-ethoxy-5-phenyl-4-(piperidin-1-yl)pyrido[2,3-d]pyrimidine-2,6-dicarbonitrile

7-ethoxy-5-phenyl-4-(piperidin-1-yl)pyrido[2,3-d]pyrimidine-2,6-dicarbonitrile

C

2-(dipiperidin-1-ylmethyleneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

2-(dipiperidin-1-ylmethyleneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

D

2-amino-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile
30464-12-1

2-amino-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

Conditions
ConditionsYield
In dichloromethane for 3.5h; Time; Reflux;A 94%
B 74%
C 11%
D 10%
2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

N-butylamine
109-73-9

N-butylamine

A

sulfur
10544-50-0

sulfur

B

1,3-di-n-butyl-2-(3,5-dicyano-6-ethoxy-4-phenylpyridin-2-yl)guanidine

1,3-di-n-butyl-2-(3,5-dicyano-6-ethoxy-4-phenylpyridin-2-yl)guanidine

Conditions
ConditionsYield
In dichloromethane for 4h; Reflux;A 94%
B 32%
carbon disulfide
75-15-0

carbon disulfide

2-Aminophenyl disulfide
1141-88-4

2-Aminophenyl disulfide

A

sulfur
10544-50-0

sulfur

B

2-Mercaptobenzothiazole
149-30-4

2-Mercaptobenzothiazole

Conditions
ConditionsYield
With sodium hydrogensulfide In water at 80℃; for 10h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Autoclave; Green chemistry;A 73%
B 94%
{(C5Me5)2Mo2S4}

{(C5Me5)2Mo2S4}

A

sulfur
10544-50-0

sulfur

B

(C5Me5)2Mo2(μ-S2)(μ-S)(μ-S2O3)

(C5Me5)2Mo2(μ-S2)(μ-S)(μ-S2O3)

Conditions
ConditionsYield
With SO2 In sulfur dioxide under inert atmosphere, SO2 condensed into the flask, allowed to stand overnight at 25°C; removal of SO2, extn. (CS2), filtered, removal of CS2, washed with CHCl3: S8, Mo-compd. isolated from the extn. residue;A n/a
B 92%
15-crown-5
33100-27-5

15-crown-5

2Mo(4+)*8Cl(1-)*2NSCl = {MoCl4(NSCl)}2

2Mo(4+)*8Cl(1-)*2NSCl = {MoCl4(NSCl)}2

A

sulfur
10544-50-0

sulfur

{Na-15-crown-5}2{MoNF4}2*2CH3CN

{Na-15-crown-5}2{MoNF4}2*2CH3CN

C

sulfur tetrafluoride
7783-60-0

sulfur tetrafluoride

Conditions
ConditionsYield
With NaF In acetonitrile byproducts: NaCl; exclusion of moisture; addn. of org.compd. suspn. of Mo-compd. and NaF in MeCN, refluxing (4 h); filtn., partial evapn., cooling (5°C), filtn., washing (MeCN), drying (N2 stream); elem. anal.;A n/a
B 90%
C n/a
carbon disulfide
75-15-0

carbon disulfide

bis(2-amino-5-methoxyphenyl)disulfide
7732-36-7

bis(2-amino-5-methoxyphenyl)disulfide

A

sulfur
10544-50-0

sulfur

B

6-methoxy-1,3-benzothiazole-2-thiol
2182-73-2

6-methoxy-1,3-benzothiazole-2-thiol

Conditions
ConditionsYield
With sodium hydrogensulfide In water at 80℃; for 4h; Inert atmosphere; Green chemistry;A n/a
B 90%
morpholine
110-91-8

morpholine

2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

A

sulfur
10544-50-0

sulfur

B

7-ethoxy-5-phenyl-4-(morpholin-4-yl)pyrido[2,3-d]pyrimidine-2,6-dicarbonitrile

7-ethoxy-5-phenyl-4-(morpholin-4-yl)pyrido[2,3-d]pyrimidine-2,6-dicarbonitrile

C

2-(dimorpholinomethyleneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

2-(dimorpholinomethyleneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

D

2-amino-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile
30464-12-1

2-amino-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

Conditions
ConditionsYield
In dichloromethane for 13h; Time; Reflux;A 89%
B 77%
C 2%
D 12%
carbon disulfide
75-15-0

carbon disulfide

2-[(2-amino-5-methylphenyl)dithio]-4-methylphenylamine
31183-91-2

2-[(2-amino-5-methylphenyl)dithio]-4-methylphenylamine

A

sulfur
10544-50-0

sulfur

B

2-mercapto-6-methylbenzothiazole
2268-79-3

2-mercapto-6-methylbenzothiazole

Conditions
ConditionsYield
With sodium hydrogensulfide In water at 80℃; for 10h; Inert atmosphere; Green chemistry;A n/a
B 89%
hydrogen sulfide
7783-06-4

hydrogen sulfide

oxygen
80937-33-3

oxygen

A

sulfur
10544-50-0

sulfur

B

sulfite(2-)
14265-45-3

sulfite(2-)

Conditions
ConditionsYield
With air; iron(III) sulfate pentahydrate In water H2S and air were bubbled into soln. Fe2(SO4)3*5H2O in N-methylpyrrolidinone-H2O (95:5) at room temp. for 80.5 h;A 88.5%
B n/a
2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)pyridin-3-ol

2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)pyridin-3-ol

A

sulfur
10544-50-0

sulfur

B

oxazolo[4,5-b]pyridine-2-carbonitrile

oxazolo[4,5-b]pyridine-2-carbonitrile

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran at 66℃; for 2h; Reagent/catalyst; Solvent;A 88%
B 88%
2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

2-(4-chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

diethylamine
109-89-7

diethylamine

A

sulfur
10544-50-0

sulfur

B

4-(diethylamino)-7-ethoxy-5-phenylpyrido[2,3-d]pyrimidine-2,6-dicarbonitrile

4-(diethylamino)-7-ethoxy-5-phenylpyrido[2,3-d]pyrimidine-2,6-dicarbonitrile

C

2-[4-(diethylamino)-5H-1,2,3-dithiazol-5-ylideneamino]-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

2-[4-(diethylamino)-5H-1,2,3-dithiazol-5-ylideneamino]-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

D

6,6'-{(1Z,1'Z)-[(E)-4,4'-bis(diethylamino)-5H,5'H-(2,2′-bithiazolylidene)-5,5'-diylidene]bis(azanylylidene)}bis(2-ethoxy-4-phenylpyridine-3,5-dicarbonitrile)

6,6'-{(1Z,1'Z)-[(E)-4,4'-bis(diethylamino)-5H,5'H-(2,2′-bithiazolylidene)-5,5'-diylidene]bis(azanylylidene)}bis(2-ethoxy-4-phenylpyridine-3,5-dicarbonitrile)

E

2-amino-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile
30464-12-1

2-amino-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile

Conditions
ConditionsYield
In dichloromethane for 3.5h; Reflux;A 86%
B 84%
C 5%
D 2%
E 6%
carbon disulfide
75-15-0

carbon disulfide

6,6′-disulfanediylbis(2-methylaniline)
86749-03-3

6,6′-disulfanediylbis(2-methylaniline)

A

sulfur
10544-50-0

sulfur

B

2-Mercapto-4-methyl-benzothiazole
2268-77-1

2-Mercapto-4-methyl-benzothiazole

Conditions
ConditionsYield
With sodium hydrogensulfide In water at 80℃; for 10h; Inert atmosphere; Green chemistry;A n/a
B 86%
(Z)-2-((4-chloro-5H-1,2,3-dithiazol-5-ylidene)amino)phenol

(Z)-2-((4-chloro-5H-1,2,3-dithiazol-5-ylidene)amino)phenol

A

sulfur
10544-50-0

sulfur

B

benzo[d]oxazole-2-carbonitrile
3313-37-9

benzo[d]oxazole-2-carbonitrile

Conditions
ConditionsYield
at 200℃; for 0.0166667h; Reagent/catalyst; Solvent; Inert atmosphere;A 60%
B 85%
benzo[b][1,2,3]dithiazolo[5,4‐e][1,4]oxazine

benzo[b][1,2,3]dithiazolo[5,4‐e][1,4]oxazine

A

sulfur
10544-50-0

sulfur

B

benzo[d]oxazole-2-carbonitrile
3313-37-9

benzo[d]oxazole-2-carbonitrile

Conditions
ConditionsYield
With triethylamine In chlorobenzene at 132℃; for 24h; Solvent; Reagent/catalyst;A 85%
B 45%
2,2′-disulfanediylbis(4-bromoaniline)
182499-80-5

2,2′-disulfanediylbis(4-bromoaniline)

carbon disulfide
75-15-0

carbon disulfide

A

sulfur
10544-50-0

sulfur

B

6-bromo-2-mercaptobenzothiazole
51618-30-5

6-bromo-2-mercaptobenzothiazole

Conditions
ConditionsYield
With sodium hydrogensulfide In water at 80℃; for 4h; Inert atmosphere; Green chemistry;A n/a
B 85%
15-crown-5
33100-27-5

15-crown-5

2Mo(4+)*8Cl(1-)*2NSCl = {MoCl4(NSCl)}2

2Mo(4+)*8Cl(1-)*2NSCl = {MoCl4(NSCl)}2

A

sulfur
10544-50-0

sulfur

B

{Na-15-crown-5}2{(μ-dinitrosulfate(II))(MoF5)2}

{Na-15-crown-5}2{(μ-dinitrosulfate(II))(MoF5)2}

C

sulfur tetrafluoride
7783-60-0

sulfur tetrafluoride

Conditions
ConditionsYield
With NaF In acetonitrile byproducts: NaCl; exclusion of moisture; addn. of NaF to suspn. of Mo-compd. in MeCN, addn. of org. compd. with stirring (room temp.), stirring (2 h); filtn., parial evapn., cooling (5°C), filtn., washing (MeCN), drying (vac.); elem. anal.;A n/a
B 78%
C n/a
carbon disulfide
75-15-0

carbon disulfide

2-[(2-amino-5-chlorophenyl)dithio]-4-chlorophenylamine
31183-89-8

2-[(2-amino-5-chlorophenyl)dithio]-4-chlorophenylamine

A

sulfur
10544-50-0

sulfur

B

6-chloro-2-mercaptobenzothiazole
51618-29-2

6-chloro-2-mercaptobenzothiazole

Conditions
ConditionsYield
With sodium hydrogensulfide In water at 80℃; for 4h; Inert atmosphere; Green chemistry;A n/a
B 76%
sulfuryl dichloride
7791-25-5

sulfuryl dichloride

bissulphane
18243-89-5

bissulphane

sulfur dichloride
10545-99-0

sulfur dichloride

A

sulfur
10544-50-0

sulfur

B

1,5-Se2S2N4

1,5-Se2S2N4

Conditions
ConditionsYield
In carbon disulfide Ar; S-compds. soln. addn. dropwise to Se-compd. soln. at -78°C; elem. anal., (77)Se-NMR;A n/a
B 73%
{Re3S7Cl6}Cl

{Re3S7Cl6}Cl

A

sulfur
10544-50-0

sulfur

B

Re3S4Cl6*4(CH3)2NCOH*3H2O

Re3S4Cl6*4(CH3)2NCOH*3H2O

Conditions
ConditionsYield
With N,N-dimethyl-formamide In N,N-dimethyl-formamide; toluene dissolving in DMF/toluene mixt. 4:3 (shaking, 8 h); sepn. of S8 (filtration off), addn. of toluene and hexane to filtrate, washing (toluene), drying (vac., heating on water bath); elem. anal.;A n/a
B 72%
carbon disulfide
75-15-0

carbon disulfide

2-[2-amino-5-(methylsulfonyl)phenyl]dithio-4-(methylsulfonyl)phenylamine
304660-65-9

2-[2-amino-5-(methylsulfonyl)phenyl]dithio-4-(methylsulfonyl)phenylamine

A

sulfur
10544-50-0

sulfur

B

6-(methylsulfonyl)benzo[d]thiazole-2-thiol

6-(methylsulfonyl)benzo[d]thiazole-2-thiol

Conditions
ConditionsYield
With sodium hydrogensulfide In water at 80℃; for 8h; Inert atmosphere; Green chemistry;A n/a
B 71%
bissulphane
18243-89-5

bissulphane

selenium tetrachloride
10026-03-6

selenium tetrachloride

A

sulfur
10544-50-0

sulfur

B

1,5-Se2S2N4

1,5-Se2S2N4

Conditions
ConditionsYield
In carbon disulfide Ar; S-compd. soln. addn. dropwise to Se-compd. soln. at -78°C, mixt. allowing to warm slowly to room temp. (stirring, 12 h); elem. anal., (77)Se-NMR;A n/a
B 70%
carbon disulfide
75-15-0

carbon disulfide

6,6′-disulfanediylbis(2-fluoroaniline)
63755-09-9

6,6′-disulfanediylbis(2-fluoroaniline)

A

2-mercapto-4-fluorobenzothiazole
154327-24-9

2-mercapto-4-fluorobenzothiazole

B

sulfur
10544-50-0

sulfur

Conditions
ConditionsYield
With sodium hydrogensulfide In water at 80℃; for 10h; Inert atmosphere; Green chemistry;A 65%
B n/a
sulfur
10544-50-0

sulfur

sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

ammonia
7664-41-7

ammonia

ammonia borane complex
10043-11-5

ammonia borane complex

Conditions
ConditionsYield
In ammonia to NaBH4 in a flask at -40°C NH3 is condensed, then slowly S8 isadded (5 h), to the mixt. (after 3 h) CH2Cl2 is added, then the mixt. is warmed to room temp.; residue is extd. with CH2Cl2, the soln. is evapd., elem. anal.;100%
sulfur
10544-50-0

sulfur

(μ3-η1-benzylidyne)(μ3-η1-propylidyne)tris(η5-cyclopentadienylcobalt)

(μ3-η1-benzylidyne)(μ3-η1-propylidyne)tris(η5-cyclopentadienylcobalt)

A

2Co(2+)*Co(3+)*3C5H5(1-)*2S(2-)=((C5H5)Co)3S2

2Co(2+)*Co(3+)*3C5H5(1-)*2S(2-)=((C5H5)Co)3S2

B

C5H5CoS2C6H5CCC2H5

C5H5CoS2C6H5CCC2H5

Conditions
ConditionsYield
In chloroform complex was reacted with excess S8, CHCl3, 48 h, heating;A 33%
B 100%
sulfur
10544-50-0

sulfur

bis(μ3-η1-benzylidyne)(η5-methylpentadienylcobalt)

bis(μ3-η1-benzylidyne)(η5-methylpentadienylcobalt)

methylcyclopentadienylcobalt(diphenyldithiolene)

methylcyclopentadienylcobalt(diphenyldithiolene)

Conditions
ConditionsYield
In chloroform complex was reacted with excess S8, CHCl3, 48 h, heating;100%
In chloroform N2 bubbled through soln. of S in CHCl3 for several hours, Co-compd. added and mixt. boiled for 2d, alumina added and solvent removed; chromy. (alumina, hexane, hexane-ether);97%
sulfur
10544-50-0

sulfur

bis(μ3-η1-pentylidyne)tris(η5-cyclopentadienylcobalt)

bis(μ3-η1-pentylidyne)tris(η5-cyclopentadienylcobalt)

A

2Co(2+)*Co(3+)*3C5H5(1-)*2S(2-)=((C5H5)Co)3S2

2Co(2+)*Co(3+)*3C5H5(1-)*2S(2-)=((C5H5)Co)3S2

B

C5H5CoS2C(C4H9)C(C4H9)

C5H5CoS2C(C4H9)C(C4H9)

Conditions
ConditionsYield
In chloroform complex was reacted with excess S8, CHCl3, 48 h, heating;A 33%
B 100%
sulfur
10544-50-0

sulfur

bis(μ3-η1-benzylidyne)tris(η5-cyclopentadienylcobalt)

bis(μ3-η1-benzylidyne)tris(η5-cyclopentadienylcobalt)

A

(η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III)
86543-64-8

(η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III)

B

2Co(2+)*Co(3+)*3C5H5(1-)*2S(2-)=((C5H5)Co)3S2

2Co(2+)*Co(3+)*3C5H5(1-)*2S(2-)=((C5H5)Co)3S2

Conditions
ConditionsYield
In chloroform complex was reacted with excess S8, CHCl3, 48 h, heating;A 100%
B 33%
sulfur
10544-50-0

sulfur

bis(cyclopentadienylchromium tricarbonyl)

bis(cyclopentadienylchromium tricarbonyl)

[(η5-cyclopentadienyl)Cr(CO)2]2S

[(η5-cyclopentadienyl)Cr(CO)2]2S

Conditions
ConditionsYield
In toluene inert atmosphere; molar ratio Cr:S=2:1, ambient temp.;100%
In tetrahydrofuran inert atmosphere; molar ratio Cr:S=2:1, ambient temp.;100%
In tetrahydrofuran Soln. of reagents (1 equiv of S) in THF was stirred at ambient temp. for 1 h (inert atm.); chromy. on silica column; eluent - benzene-ether; evapd., dissolved in hexane-ether, cooling overnight at -17°C; elem. anal.;;99%
sulfur
10544-50-0

sulfur

uranium hexafluoride
7783-81-5

uranium hexafluoride

uranium(IV) tetrafluoride
10049-14-6

uranium(IV) tetrafluoride

Conditions
ConditionsYield
With hydrogen fluoride at -83.37 - 20℃; for 72h; Schlenk technique;100%
sulfur
10544-50-0

sulfur

bromine
7726-95-6

bromine

arsenic pentafluoride
7784-36-3

arsenic pentafluoride

A

S3Br3(1+)*AsF6(1-) = [S3Br3]AsF6

S3Br3(1+)*AsF6(1-) = [S3Br3]AsF6

B

arsenic(III) fluoride
7784-35-2

arsenic(III) fluoride

Conditions
ConditionsYield
In sulfur dioxide 1 d; slow removal of solvent, cooling to 0°C;A 99.7%
B n/a
sulfur
10544-50-0

sulfur

arsenic pentafluoride
7784-36-3

arsenic pentafluoride

A

S8(AsF6)2

S8(AsF6)2

B

S16(2+)*2AsF6(1-)=S16(AsF6)2

S16(2+)*2AsF6(1-)=S16(AsF6)2

Conditions
ConditionsYield
In liquid sulphur dioxide byproducts: AsF3; 77 K, then room temp; 13 d;; elem. anal.;;A 99.1%
B n/a
sulfur
10544-50-0

sulfur

antimony(III) sulfide

antimony(III) sulfide

caesium carbonate
534-17-8

caesium carbonate

5Cs(1+)*Sb8S18(4-)*HCO3(1-)=Cs5Sb8S18(HCO3)

5Cs(1+)*Sb8S18(4-)*HCO3(1-)=Cs5Sb8S18(HCO3)

Conditions
ConditionsYield
In ammonia NH3 (liquid); Ar-atmosphere; stoich. amts., sealed silica tube, 160°C, 4 d; solvent removal; elem. anal.;99%
sulfur
10544-50-0

sulfur

(μ3-η1-benzylidyne)(μ3-η1-pentadeuteriobenzylidyne)tris(η5-cyclopentadienylcobalt)

(μ3-η1-benzylidyne)(μ3-η1-pentadeuteriobenzylidyne)tris(η5-cyclopentadienylcobalt)

C5H5CoS2C6H5CCC6(2)H5

C5H5CoS2C6H5CCC6(2)H5

Conditions
ConditionsYield
In chloroform N2 bubbled through soln. of S in CHCl3 for several hours, Co-compd. added and mixt. boiled for 2d, alumina added and solvent removed; chromy. (alumina, hexane, hexane-ether);99%
sulfur
10544-50-0

sulfur

bis(μ3-η1-pentylidyne)tris(η5-cyclopentadienylcobalt)

bis(μ3-η1-pentylidyne)tris(η5-cyclopentadienylcobalt)

C5H5CoS2C(C4H9)C(C4H9)

C5H5CoS2C(C4H9)C(C4H9)

Conditions
ConditionsYield
In chloroform N2 bubbled through soln. of S in CHCl3 for several hours, Co-compd. added and mixt. boiled for 2d, alumina added; chromy. (alumina, hexane, hexane-ether);99%
sulfur
10544-50-0

sulfur

bis(μ3-η1-benzylidyne)tris(η5-cyclopentadienylcobalt)

bis(μ3-η1-benzylidyne)tris(η5-cyclopentadienylcobalt)

A

(η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III)
86543-64-8

(η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III)

B

{CoCp}3(S)2

{CoCp}3(S)2

Conditions
ConditionsYield
In chloroform N2 bubbled through soln. of S in CHCl3 for several hours, Co-compd. added and mixt. boiled for 2d, alumina added and solvent removed; chromy. (alumina, hexane, hexane-ether), elem. anal.;A 99%
B 10%
pyridine
110-86-1

pyridine

sulfur
10544-50-0

sulfur

decamethyltitanocene ethylene

decamethyltitanocene ethylene

(pentamethylcyclopentadienyl)2Ti(S)(pyridine)

(pentamethylcyclopentadienyl)2Ti(S)(pyridine)

Conditions
ConditionsYield
In toluene N2-atmosphere; S8 (1/8 eqiuv.); stirring overnight;99%
In toluene crystn. on pentane addn. and cooling (-40°C);76%
In toluene inert atmosphere; stirring (-40°C, 40 h); solvent redn. (vac.), crystn. (pentane layering, -40°C); elem. anal.;76%
sulfur
10544-50-0

sulfur

cis-{bis(dicyclohexylphosphino)ethane}hydridophenylplatinum(II)

cis-{bis(dicyclohexylphosphino)ethane}hydridophenylplatinum(II)

cis-sulfhydrylphenyl[bis(dicyclohexylphosphino)ethane]platinum(II)
220214-06-2

cis-sulfhydrylphenyl[bis(dicyclohexylphosphino)ethane]platinum(II)

Conditions
ConditionsYield
In benzene-d6 N2-atmosphere, NMR tube; stirring (room temp., 2 h); not isolated, detd. by NMR spectroscopy;99%
sulfur
10544-50-0

sulfur

cis-[bis-(dicyclohexylphosphino)ethane]hydridoneopentylplatinum(II)

cis-[bis-(dicyclohexylphosphino)ethane]hydridoneopentylplatinum(II)

cis-sulfhydrylneopentenyl[bis(dicyclohexylphosphino)ethane]platinum(II)
220214-04-0

cis-sulfhydrylneopentenyl[bis(dicyclohexylphosphino)ethane]platinum(II)

Conditions
ConditionsYield
In tetrahydrofuran-d8 N2-atmosphere, NMR tube; stirring (room temp., 1 h); not isolated, detd. by NMR spectroscopy;99%
sulfur
10544-50-0

sulfur

cis-methylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II)
111848-50-1

cis-methylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II)

cis-sulfhydrylmethyl[bis(dicyclohexylphosphino)ethane]platinum(II)
220214-03-9

cis-sulfhydrylmethyl[bis(dicyclohexylphosphino)ethane]platinum(II)

Conditions
ConditionsYield
In tetrahydrofuran-d8 N2-atmosphere, NMR tube; stirring (room temp., 0.5 h); not isolated, detd. by NMR spectroscopy;99%
sulfur
10544-50-0

sulfur

C5H5FeC5H4P(CH2OH)2
406462-25-7

C5H5FeC5H4P(CH2OH)2

C5H5FeC5H4PS(CH2OH)2
406462-28-0

C5H5FeC5H4PS(CH2OH)2

Conditions
ConditionsYield
In tetrahydrofuran Sonication; sonication of a mixt. of iron complex with sulfur in THF for 30 minr 15 min; evapn.; elem. anal.;99%
sulfur
10544-50-0

sulfur

n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

N,N-dimethylferrocenesulfonamide
63453-42-9

N,N-dimethylferrocenesulfonamide

water
7732-18-5

water

2,2''-bis(N,N-dimethylsulfanoylferrocenyl)-1,1''-disulfide
874912-07-9, 874912-05-7

2,2''-bis(N,N-dimethylsulfanoylferrocenyl)-1,1''-disulfide

Conditions
ConditionsYield
With O2 In tetrahydrofuran; hexane (N2); addn. of BuLi in hexane to soln. of iron compd. with stirring at 0°C, stirring for 1 h, addn. of sulphur, stirring at room temp. for 2 h, stirring at room temp. under O2; pouring into cold aqueous HCl, extn. (CHCl3), drying under MgSO4, evapn., chromy. (silica gel, chloroform), elem. anal.;99%
sulfur
10544-50-0

sulfur

bismuth
7440-69-9

bismuth

potassium sulfide

potassium sulfide

phosphorous

phosphorous

1.5K(1+)*2.5Bi(3+)*3PS4(3-)=K1.5Bi2.5(PS4)3

1.5K(1+)*2.5Bi(3+)*3PS4(3-)=K1.5Bi2.5(PS4)3

Conditions
ConditionsYield
In neat (no solvent) mixt. K2S, Bi, P, and S in sealed evacuated ampule was heated in furnaceto 600°C over 12 h, held there for 12 h, and cooled to room temp . for 6 h;99%
sulfur
10544-50-0

sulfur

[O(CCH2CH2CH3)4CW(CO)5]

[O(CCH2CH2CH3)4CW(CO)5]

[O(CCH2CH2CH3)4CSW(CO)5]
1043964-21-1

[O(CCH2CH2CH3)4CSW(CO)5]

Conditions
ConditionsYield
With sodium tetrahydroborate In ethanol treatment of (O(CC3H7)4C)W(CO)5 with sulfur in the presence of NaBH4 in EtOH;99%
sulfur
10544-50-0

sulfur

(S)-(-)-2-di-ortho-tolyl-phosphino-1-dimethylaminoferrocene
1262899-33-1

(S)-(-)-2-di-ortho-tolyl-phosphino-1-dimethylaminoferrocene

(S)-(+)-2-di-ortho-tolyl-phosphinothioyl-1-dimethylaminoferrocene
1262899-12-6

(S)-(+)-2-di-ortho-tolyl-phosphinothioyl-1-dimethylaminoferrocene

Conditions
ConditionsYield
In toluene (Ar); Schlenk technique; mixt. of Fe complex and S8 in toluene was heated at 40°C for 2 h; cooled to room temp.; filtered; chromd. (silica gel, hexane/Et2O, 90/10); elem. anal.;99%
sulfur
10544-50-0

sulfur

{SCl3}(1+)*{AsF6}(1-)=SCl3AsF6
27075-96-3

{SCl3}(1+)*{AsF6}(1-)=SCl3AsF6

S3Cl3(1+)*AsF6(1-) = [S3Cl3]AsF6

S3Cl3(1+)*AsF6(1-) = [S3Cl3]AsF6

Conditions
ConditionsYield
In sulfur dioxide stirring (room temp., overnight); slow removal of solvent over 4 h, filtration;98.5%
sulfur
10544-50-0

sulfur

sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

methylamine-borane
1722-33-4

methylamine-borane

Conditions
ConditionsYield
With methylamine In neat (no solvent) to NaBH4 in a flask at -10°C is condensed MeNH2, then is slowly added sulfur (2 h), the mixt. is stirred overnight and MeNH2 evapd., to the mixt. is added benzene and warmed to room temp.; residue is extd. with benzene, the soln. is evapd., elem. anal.;98%
sulfur
10544-50-0

sulfur

bis(cyclopentadienyl)titanium dichloride
1271-19-8

bis(cyclopentadienyl)titanium dichloride

bis(η-cyclopentadienyl)titana(IV)cyclohexasulfane

bis(η-cyclopentadienyl)titana(IV)cyclohexasulfane

Conditions
ConditionsYield
With lithium triethylborohydride In tetrahydrofuran byproducts: LiCl; A soln. of S and LiEt3BH was treated dropwise with a THF soln. of complex, stirred at room temp. overnight (N2 atm.);; evapd., extd. with CH2Cl2, filtered, evapd., elem. anal.;;98%
With hydrogen sulfide; ammonia In water S8 and concd. aq. NH3 placed in bottle, H2S bubbled with stirring for 1h, degassed for 10 min (vac.), H2O and CHCl3 added with stirring, complex added with stirring, reacted for 20 h; H2O added, extd. (CHCl3), extracts filtered, solvent removed (vac.), dried (vac. at 75°C);88%
In dimethyl sulfoxide stirring (90°C, 20-30 min);; solvent removal (reduced pressure), extn. (CH2Cl2), filtration, chromy. (SiO2, CH2Cl2);;20%
sulfur
10544-50-0

sulfur

GeN(C(CH3)3)Si(CH3)N(C(CH3)3)Si(NC(CH3)3)(CH3)N(C(CH3)3)
122093-35-0

GeN(C(CH3)3)Si(CH3)N(C(CH3)3)Si(NC(CH3)3)(CH3)N(C(CH3)3)

GeSN(C(CH3)3)Si(CH3)N(C(CH3)3)Si(CH3)(NC(CH3)3)N(C(CH3)3)*0.5C6H6

GeSN(C(CH3)3)Si(CH3)N(C(CH3)3)Si(CH3)(NC(CH3)3)N(C(CH3)3)*0.5C6H6

Conditions
ConditionsYield
In toluene soln. added S8; evapd.;98%
sulfur
10544-50-0

sulfur

(μ3-η1-benzylidyne)(μ3-η1-propylidyne)tris(η5-cyclopentadienylcobalt)

(μ3-η1-benzylidyne)(μ3-η1-propylidyne)tris(η5-cyclopentadienylcobalt)

C5H5CoS2C6H5CCC2H5

C5H5CoS2C6H5CCC2H5

Conditions
ConditionsYield
In chloroform N2 bubbled through soln. of S in CHCl3 for several hours, Co-compd. added and mixt. boiled for 2d, alumina added and solvent removed; chromy. (alumina, hexane, hexane-ether), elem. anal.;98%

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