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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Methyl (2R,3S)-3-(4-methoxyphenyl)-2-oxiranecarboxylate Manufacturer/High quality/Best price/In stock

Cas:105560-93-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl 2R,3S-(-)-3-(4-methoxyphenyl)oxiranecarboxylate

Cas:105560-93-8

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Methyl (2R,3S)-3-(4-methoxyphenyl)oxirane-2-carboxylate -- CHemwill

Cas:105560-93-8

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE CAS:105560-93-8

Cas:105560-93-8

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 105560-93-8 with best price

Cas:105560-93-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE 1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Pow

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE

Cas:105560-93-8

Min.Order:10 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Oxiranecarboxylicacid, 3-(4-methoxyphenyl)-, methyl ester, (2R,3S)- 105560-93-8

Cas:105560-93-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE CAS:105560-93-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specia

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE CAS:105560-93-8

Cas:105560-93-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Oxiranecarboxylicacid, 3-(4-methoxyphenyl)-, methyl ester, (2R,3S)-

Cas:105560-93-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Oxiranecarboxylicacid, 3-(4-methoxyphenyl)-, methyl ester, (2R,3S)-

Cas:105560-93-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

(-)-(2R,3S)-2,3-Epoxy-3-(4Methoxyphenyl)Propronate

Cas:105560-93-8

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE

Cas:105560-93-8

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Taizhou Crene Biotechnology co.ltd

Our company provides one-stop services of research - development - production for a variety of special prouducts. Not only do we make effective use of our strong technological strength, but also establish of cooperative relations with several well-

diltiazem intermediate 105560-93-8

Cas:105560-93-8

Min.Order:50 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE

Cas:105560-93-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE

Cas:105560-93-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyl (2R,3S)-2,3-epoxy-3-(4-methoxyphenyl)propionate

Cas:105560-93-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality (-)-(2R,3S)-2,3-Epoxy-3-(4Methoxyphenyl)Propronate

Cas:105560-93-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:10g/bag,or as your request Application:Used as Pharmaceutical Intermediates Transporta

2-Oxiranecarboxylicacid, 3-(4-methoxyphenyl)-, methyl ester, (2R,3S)-

Cas:105560-93-8

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Methyl (2R,3S)-3-(4-methoxyphenyl)-2-oxiranecarboxylate

Cas:105560-93-8

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Top Purity SupplierMETHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE

Cas:105560-93-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE

Cas:105560-93-8

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE

Cas:105560-93-8

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE

Cas:105560-93-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE

Cas:105560-93-8

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Methyl (-)-(2R,3S)-2,3-epoxy-3-(4methoxyphenyl)propronate

Cas:105560-93-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE

Cas:105560-93-8

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

METHYL (2R,3S)-2,3-EPOXY-3-(4-METHOXYPHENYL)PROPIONATE

Cas:105560-93-8

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

2-Oxiranecarboxylicacid, 3-(4-methoxyphenyl)-, methyl ester, (2R,3S)-

Cas:105560-93-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

(-)-(2R,3S)-2,2-Epoxy-3-(4-methoxyphenyl)propionate

Cas:105560-93-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

2-Oxiranecarboxylicacid, 3-(4-methoxyphenyl)-, methyl ester, (2R,3S)-

Cas:105560-93-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

methyl (2S,3S)-2-chloro-3-hydroxy-3-(4-methoxyphenyl)propionate
134931-62-7

methyl (2S,3S)-2-chloro-3-hydroxy-3-(4-methoxyphenyl)propionate

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 20℃; for 2h;90%
methanol
67-56-1

methanol

(-)-(2R,3S)-sodium 3-(4-methoxyphenyl)glycidate
136597-65-4

(-)-(2R,3S)-sodium 3-(4-methoxyphenyl)glycidate

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
With triethylamine; 2-chloro-1-methylpyridinium sulfate In dichloromethane; 1,2-dichloro-ethane Ambient temperature;83%
methanol
67-56-1

methanol

(2R,2'R,3'S)-N-[3'-{(4-methoxyphenyl)oxyranyl}methanone]bornanesultam

(2R,2'R,3'S)-N-[3'-{(4-methoxyphenyl)oxyranyl}methanone]bornanesultam

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane at -78℃; Inert atmosphere;79%
3-(4-methoxy-phenyl)acrylic acid methyl ester
3901-07-3

3-(4-methoxy-phenyl)acrylic acid methyl ester

butan-1-ol
71-36-3

butan-1-ol

A

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

B

(2S,3R)-trans-(4-methoxyphenyl)glycidic acid butyl ester
139345-88-3

(2S,3R)-trans-(4-methoxyphenyl)glycidic acid butyl ester

C

(2S,3R)-methyl p-methoxycinnamate epoxide
137173-40-1

(2S,3R)-methyl p-methoxycinnamate epoxide

Conditions
ConditionsYield
Stage #1: 3-(4-methoxy-phenyl)acrylic acid methyl ester With Oxone; (R)-1,1'-binaphthyl-2,2'-dicarboxylic acid cyclic ester In 1,4-dioxane; water for 26h;
Stage #2: butan-1-ol With Serratia marcescens lipase on celit for 25h; Further stages.;
A 76%
B 6.2%
C 1.6%
methyl (2S,3S)-(+)-2-bromo-3-hydroxy-3-(4-methoxyphenyl)propionate
153829-67-5

methyl (2S,3S)-(+)-2-bromo-3-hydroxy-3-(4-methoxyphenyl)propionate

A

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

B

(2S,3R)-methyl p-methoxycinnamate epoxide
137173-40-1

(2S,3R)-methyl p-methoxycinnamate epoxide

Conditions
ConditionsYield
With potassium carbonate In methanol; diethyl ether at 0 - 5℃; for 0.5h; Yields of byproduct given. Title compound not separated from byproducts;A 74%
B n/a
methyl trans-3-(4-methoxyphenyl)glycidate
96125-49-4

methyl trans-3-(4-methoxyphenyl)glycidate

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol
100-79-8

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol

trans-3-(4-methoxyphenyl)-glycidic acid 2,2-dimethyl-1,3-dioxolane-4-methyl ester

trans-3-(4-methoxyphenyl)-glycidic acid 2,2-dimethyl-1,3-dioxolane-4-methyl ester

B

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

C

(2S,3R)-methyl p-methoxycinnamate epoxide
137173-40-1

(2S,3R)-methyl p-methoxycinnamate epoxide

Conditions
ConditionsYield
With lipase type VII In cyclohexane at 33℃; for 9.5h; Enzymatic reaction;A 45.6%
B n/a
C n/a
With lipase type VII In diethyl ether; hexane at 26℃; for 13.5h; Enzymatic reaction;A 23.1%
B n/a
C n/a
methyl trans-3-(4-methoxyphenyl)glycidate
96125-49-4

methyl trans-3-(4-methoxyphenyl)glycidate

trans-3-(4-methoxyphenyl)-glycidic acid 2-butyl ester

trans-3-(4-methoxyphenyl)-glycidic acid 2-butyl ester

B

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

C

(2S,3R)-methyl p-methoxycinnamate epoxide
137173-40-1

(2S,3R)-methyl p-methoxycinnamate epoxide

Conditions
ConditionsYield
With lipase AMANO for 9h; Enzymatic reaction;A 37.6%
B n/a
C n/a
With lipase AMANO In cyclohexane at 40℃; for 12h; Enzymatic reaction;A 30%
B n/a
C n/a
2-(N,N-dimethylamino)ethanol
108-01-0

2-(N,N-dimethylamino)ethanol

methyl trans-3-(4-methoxyphenyl)glycidate
96125-49-4

methyl trans-3-(4-methoxyphenyl)glycidate

A

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

B

(2S,3R)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-dimethylamino-ethyl ester

(2S,3R)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-dimethylamino-ethyl ester

Conditions
ConditionsYield
With 5A molecular sieve; Novozym 435 (Candida antarctica lipase, EC 3.1.1.3) In toluene at 20℃; for 4h; Product distribution; Enzyme kinetics; Further Variations:; Solvents; Reagents; Reaction partners; Enzymatic reaction;A 37.5%
B n/a
methyl trans-3-(4-methoxyphenyl)glycidate
96125-49-4

methyl trans-3-(4-methoxyphenyl)glycidate

A

4-Methoxyphenylacetaldehyde
5703-26-4

4-Methoxyphenylacetaldehyde

B

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

C

(2S,3R)-trans-(4-methoxyphenyl)glycidic acid
106003-21-8

(2S,3R)-trans-(4-methoxyphenyl)glycidic acid

Conditions
ConditionsYield
In cyclohexane; water for 1.5h; Ambient temperature; enzymatic hydrolysis by lipase from Candida cylindracea (CCL), pH 7.4, other enzymes; enzymatic transesterification;A n/a
B 35%
C n/a
In cyclohexane; water for 1.5h; Ambient temperature; enzymatic hydrolysis by lipase from Candida cylindracea (CCL), pH 7.4;A n/a
B 35%
C n/a
methyl 3-(4-methoxyphenyl)glycidate
42245-42-1

methyl 3-(4-methoxyphenyl)glycidate

A

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

B

(2S,3R)-trans-(4-methoxyphenyl)glycidic acid
106003-21-8

(2S,3R)-trans-(4-methoxyphenyl)glycidic acid

Conditions
ConditionsYield
With water In acetone at 25℃; Rhizopus arrhizus mycelium lipase, pH 7;
methyl 3-(4-methoxyphenyl)glycidate
42245-42-1

methyl 3-(4-methoxyphenyl)glycidate

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

3-(4-methoxyphenyl)acrylic acid methyl ester
19310-29-3

3-(4-methoxyphenyl)acrylic acid methyl ester

A

(2R,3R)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid methyl ester
126060-70-6

(2R,3R)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid methyl ester

B

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

C

(2S,3R)-methyl p-methoxycinnamate epoxide
137173-40-1

(2S,3R)-methyl p-methoxycinnamate epoxide

D

methyl (-)-(2R,3S)-3-(4-methoxyphenyl)glycidate
134931-64-9

methyl (-)-(2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
With sodium hypochlorite; 4-Phenylpyridine 1-oxide; (salen)Mn(III)-complex In water; 1,2-dichloro-ethane at 4℃; for 12h; Yield given. Yields of byproduct given;
methyl 2-chloro-3-hydroxy-3-(4-methoxyphenyl)propionate

methyl 2-chloro-3-hydroxy-3-(4-methoxyphenyl)propionate

A

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

B

(2S,3R)-methyl p-methoxycinnamate epoxide
137173-40-1

(2S,3R)-methyl p-methoxycinnamate epoxide

Conditions
ConditionsYield
With sodium methylate In methanol at 0 - 20℃; for 1.66667h; Yield given. Title compound not separated from byproducts;
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 20℃; for 4h; Title compound not separated from byproducts;
methanol
67-56-1

methanol

Lithium; (S)-2-tert-butoxycarbonyl-2-chloro-1-(4-methoxy-phenyl)-ethanolate

Lithium; (S)-2-tert-butoxycarbonyl-2-chloro-1-(4-methoxy-phenyl)-ethanolate

A

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

B

methyl (-)-(2R,3S)-3-(4-methoxyphenyl)glycidate
134931-64-9

methyl (-)-(2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
In tetrahydrofuran; hexane at -20 - 0℃; for 2.5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
(S)-2-Chloro-3-hydroxy-3-(4-methoxy-phenyl)-propionic acid methyl ester
336113-23-6

(S)-2-Chloro-3-hydroxy-3-(4-methoxy-phenyl)-propionic acid methyl ester

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
With sodium methylate In methanol at 0 - 20℃;
With sodium methylate In methanol at 0 - 20℃; for 0.75h;894 mg
1-pyrrolidineethanol
2955-88-6

1-pyrrolidineethanol

methyl trans-3-(4-methoxyphenyl)glycidate
96125-49-4

methyl trans-3-(4-methoxyphenyl)glycidate

A

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

B

(2S,3R)-methyl p-methoxycinnamate epoxide
137173-40-1

(2S,3R)-methyl p-methoxycinnamate epoxide

C

(2S,3R)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-pyrrolidin-1-yl-ethyl ester

(2S,3R)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-pyrrolidin-1-yl-ethyl ester

D

(2R,3S)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-pyrrolidin-1-yl-ethyl ester

(2R,3S)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-pyrrolidin-1-yl-ethyl ester

Conditions
ConditionsYield
With 5A molecular sieve; Novozym 435 (Candida antarctica lipase, EC 3.1.1.3) In toluene at 20℃; Enzymatic reaction; Title compound not separated from byproducts.;
1-piperidinoethanol
3040-44-6

1-piperidinoethanol

methyl trans-3-(4-methoxyphenyl)glycidate
96125-49-4

methyl trans-3-(4-methoxyphenyl)glycidate

A

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

B

(2S,3R)-methyl p-methoxycinnamate epoxide
137173-40-1

(2S,3R)-methyl p-methoxycinnamate epoxide

C

(2S,3R)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-piperidin-1-yl-ethyl ester

(2S,3R)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-piperidin-1-yl-ethyl ester

D

(2R,3S)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-piperidin-1-yl-ethyl ester

(2R,3S)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-piperidin-1-yl-ethyl ester

Conditions
ConditionsYield
With 5A molecular sieve; Novozym 435 (Candida antarctica lipase, EC 3.1.1.3) In toluene at 20℃; Enzymatic reaction; Title compound not separated from byproducts.;
3-Dimethylamino-1-propanol
3179-63-3

3-Dimethylamino-1-propanol

methyl trans-3-(4-methoxyphenyl)glycidate
96125-49-4

methyl trans-3-(4-methoxyphenyl)glycidate

A

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

B

(2S,3R)-methyl p-methoxycinnamate epoxide
137173-40-1

(2S,3R)-methyl p-methoxycinnamate epoxide

C

(2S,3R)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 3-dimethylamino-propyl ester

(2S,3R)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 3-dimethylamino-propyl ester

D

(2R,3S)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 3-dimethylamino-propyl ester

(2R,3S)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 3-dimethylamino-propyl ester

Conditions
ConditionsYield
With 5A molecular sieve; Novozym 435 (Candida antarctica lipase, EC 3.1.1.3) In toluene at 20℃; Enzymatic reaction; Title compound not separated from byproducts.;
methyl trans-3-(4-methoxyphenyl)glycidate
96125-49-4

methyl trans-3-(4-methoxyphenyl)glycidate

2-(Diethylamino)ethanol
100-37-8

2-(Diethylamino)ethanol

A

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

B

(2S,3R)-methyl p-methoxycinnamate epoxide
137173-40-1

(2S,3R)-methyl p-methoxycinnamate epoxide

C

(2S,3R)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-diethylamino-ethyl ester

(2S,3R)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-diethylamino-ethyl ester

D

(2R,3S)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-diethylamino-ethyl ester

(2R,3S)-3-(4-Methoxy-phenyl)-oxirane-2-carboxylic acid 2-diethylamino-ethyl ester

Conditions
ConditionsYield
With 5A molecular sieve; Novozym 435 (Candida antarctica lipase, EC 3.1.1.3) In toluene at 20℃; Enzymatic reaction; Title compound not separated from byproducts.;
3-(4-methoxy-phenyl)acrylic acid methyl ester
3901-07-3

3-(4-methoxy-phenyl)acrylic acid methyl ester

A

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

B

(2S,3R)-methyl p-methoxycinnamate epoxide
137173-40-1

(2S,3R)-methyl p-methoxycinnamate epoxide

Conditions
ConditionsYield
With Oxone; sodium hydrogencarbonate; chiral binaphthyl ketone C25H16O5 In 1,4-dioxane; water at 5 - 27℃; for 27h; Product distribution; Further Variations:; Catalysts; Solvents;
With Oxone; (R)dinaphtho[2,1-g:1,2-i][1,5]dioxacycloundecin-3,6,9-trione; sodium hydrogencarbonate In 1,4-dioxane; water at 5 - 27℃; for 50h;
With Oxone; (2S,5R)-2-fluoro-2-methyl5-(2-methyl-oxiranyl)cyclohexanone In 1,4-dioxane; water at 20℃; for 8h; Title compound not separated from byproducts;
methanol
67-56-1

methanol

1-[(2E)-3-(4-methoxyphenyl)-1-oxo-2-propenyl]-4-phenyl-1H-imidazole

1-[(2E)-3-(4-methoxyphenyl)-1-oxo-2-propenyl]-4-phenyl-1H-imidazole

A

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

B

(2S,3R)-methyl p-methoxycinnamate epoxide
137173-40-1

(2S,3R)-methyl p-methoxycinnamate epoxide

Conditions
ConditionsYield
Stage #1: 1-[(2E)-3-(4-methoxyphenyl)-1-oxo-2-propenyl]-4-phenyl-1H-imidazole With tert.-butylhydroperoxide; La-(S)-BINOL-Ph3AsO; 4 A molecular sieve In tetrahydrofuran; toluene at 20℃; for 5h;
Stage #2: methanol In tetrahydrofuran; toluene at 20℃; Title compound not separated from byproducts;
Stage #1: 1-[(2E)-3-(4-methoxyphenyl)-1-oxo-2-propenyl]-4-phenyl-1H-imidazole With tert.-butylhydroperoxide; lanthanum(III) isopropoxide; 4 A molecular sieve; triphenylarsineoxide; (S)-[1,1']-binaphthalenyl-2,2'-diol In tetrahydrofuran; decane at 20℃; for 6h;
Stage #2: methanol In tetrahydrofuran; toluene Further stages. Title compound not separated from byproducts.;
methyl (2S,3S)-(+)-2-bromo-3-hydroxy-3-(4-methoxyphenyl)propionate
153829-67-5

methyl (2S,3S)-(+)-2-bromo-3-hydroxy-3-(4-methoxyphenyl)propionate

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 5 - 20℃; for 0.583333h;
(2S,3S)-methyl 3-hydroxy-2-iodo-3-(4-methoxyphenyl)-propanoate

(2S,3S)-methyl 3-hydroxy-2-iodo-3-(4-methoxyphenyl)-propanoate

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 5 - 20℃; for 0.583333h;
3-(4-methoxy-phenyl)acrylic acid methyl ester
3901-07-3

3-(4-methoxy-phenyl)acrylic acid methyl ester

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: 66 percent / KBrO3; aq. H2SO4; aq. NaHSO3 / acetonitrile / 36 h
2.1: 94 percent / DMAP / CH2Cl2 / 20 °C
3.1: lipase AS Amano; aq. phosphate buffer / toluene / 48 h / 30 °C / pH 7.0
3.2: lipase AS Amano; aq. phosphate buffer / toluene / 33 h / 30 °C / pH 7.0
4.1: HCl / methanol / 24 h / 20 °C
5.1: DBU / CH2Cl2 / 0.58 h / 5 - 20 °C
View Scheme
Multi-step reaction with 5 steps
1: 65 percent / HIO4*2H2O; aq. NaHSO3 / acetonitrile / 48 h / 25 °C
2: 90 percent / DMAP / CH2Cl2 / 20 °C
3: lipase AS Amano; aq. phosphate buffer / toluene / 45 h / 30 °C / pH 7.0
4: HCl / methanol / 24 h / 20 °C
5: DBU / CH2Cl2 / 0.58 h / 5 - 20 °C
View Scheme
methyl (2RS,3RS)-(+)-2-bromo-3-hydroxy-3-(4-methoxyphenyl)propionate

methyl (2RS,3RS)-(+)-2-bromo-3-hydroxy-3-(4-methoxyphenyl)propionate

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: 94 percent / DMAP / CH2Cl2 / 20 °C
2.1: lipase AS Amano; aq. phosphate buffer / toluene / 48 h / 30 °C / pH 7.0
2.2: lipase AS Amano; aq. phosphate buffer / toluene / 33 h / 30 °C / pH 7.0
3.1: HCl / methanol / 24 h / 20 °C
4.1: DBU / CH2Cl2 / 0.58 h / 5 - 20 °C
View Scheme
methyl (+/-)-3-hydroxy-2-iodo-3-(4-methoxyphenyl)-propanoate

methyl (+/-)-3-hydroxy-2-iodo-3-(4-methoxyphenyl)-propanoate

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 90 percent / DMAP / CH2Cl2 / 20 °C
2: lipase AS Amano; aq. phosphate buffer / toluene / 45 h / 30 °C / pH 7.0
3: HCl / methanol / 24 h / 20 °C
4: DBU / CH2Cl2 / 0.58 h / 5 - 20 °C
View Scheme
(2S,3S)-methyl 3-acetoxy-2-bromo-3-(4-methoxyphenyl)-propanoate
800368-87-0

(2S,3S)-methyl 3-acetoxy-2-bromo-3-(4-methoxyphenyl)-propanoate

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: HCl / methanol / 24 h / 20 °C
2: DBU / CH2Cl2 / 0.58 h / 5 - 20 °C
View Scheme
methyl (+/-)-3-acetoxy-2-bromo-3-(4-methoxyphenyl)-propanoate

methyl (+/-)-3-acetoxy-2-bromo-3-(4-methoxyphenyl)-propanoate

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: lipase AS Amano; aq. phosphate buffer / toluene / 48 h / 30 °C / pH 7.0
1.2: lipase AS Amano; aq. phosphate buffer / toluene / 33 h / 30 °C / pH 7.0
2.1: HCl / methanol / 24 h / 20 °C
3.1: DBU / CH2Cl2 / 0.58 h / 5 - 20 °C
View Scheme
(2S,3S)-methyl 3-acetoxy-2-iodo-3-(4-methoxyphenyl)-propanoate
800368-89-2

(2S,3S)-methyl 3-acetoxy-2-iodo-3-(4-methoxyphenyl)-propanoate

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: HCl / methanol / 24 h / 20 °C
2: DBU / CH2Cl2 / 0.58 h / 5 - 20 °C
View Scheme
methyl (+/-)-3-acetoxy-2-iodo-3-(4-methoxyphenyl)-propanoate

methyl (+/-)-3-acetoxy-2-iodo-3-(4-methoxyphenyl)-propanoate

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: lipase AS Amano; aq. phosphate buffer / toluene / 45 h / 30 °C / pH 7.0
2: HCl / methanol / 24 h / 20 °C
3: DBU / CH2Cl2 / 0.58 h / 5 - 20 °C
View Scheme
methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

2-amino-benzenethiol
137-07-5

2-amino-benzenethiol

(2S,3S)-3-hydroxy-2-(4-methoxyphenyl)-2,3-dihydro-1,5-benzothiazepin-4(5H)-one
42399-49-5

(2S,3S)-3-hydroxy-2-(4-methoxyphenyl)-2,3-dihydro-1,5-benzothiazepin-4(5H)-one

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 6h; Reflux; optical yield given as %ee;90%
With triethylamine In trichloroacetic acid
methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

2-mercapto-3-nitrothiophene
167030-74-2

2-mercapto-3-nitrothiophene

(-)-(2S,3S)-methyl-2-hydroxy-3-(4-methoxyphenyl)-3-(3-nitro-2-thienylthio)propionate
1011797-49-1

(-)-(2S,3S)-methyl-2-hydroxy-3-(4-methoxyphenyl)-3-(3-nitro-2-thienylthio)propionate

Conditions
ConditionsYield
In chlorobenzene at 130℃; for 2h;42%
methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

2-amino-benzenethiol
137-07-5

2-amino-benzenethiol

(+)-(2S,3S)-2-hydroxy-3-(4-methoxyphenyl)-3-(2-aminophenylthio)propanoic acid methyl ester
99109-07-6

(+)-(2S,3S)-2-hydroxy-3-(4-methoxyphenyl)-3-(2-aminophenylthio)propanoic acid methyl ester

Conditions
ConditionsYield
With iron(III) chloride In chlorobenzene at 115℃; for 0.75h;
In toluene
In 5,5-dimethyl-1,3-cyclohexadiene
methyl (2R,3S)-3-(4-methoxyphenyl)glycidate
105560-93-8

methyl (2R,3S)-3-(4-methoxyphenyl)glycidate

Potassium; (2R,3S)-3-(4-methoxy-phenyl)-oxirane-2-carboxylate

Potassium; (2R,3S)-3-(4-methoxy-phenyl)-oxirane-2-carboxylate

Conditions
ConditionsYield
With potassium hydroxide In ethanol for 3h; Ambient temperature;

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