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SICHUAN ZHONGBANG NEW MATERIAL CO., LTD

ProName:2,5-Dimethyl-2,5-hexanediol Curing age... CasNo:110-03-2 Molecular Formula:C8H18O2 Appearance:Pls see the Details Application:Pesan is specialized in pharmaceutical... DeliveryTime:as requests PackAge:as requests

2,5-Dimethyl-2,5-hexanediol

Cas:110-03-2

Min.Order:1 Kilogram

FOB Price: $4.7 / 5.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product Name 2,5-Dimethyl-2,5-hexanediol CAS No. 110-03-2 Appearance White crystalline flake or powder Assay ≥99% Capacity 500mt/year Min.

2,5-Dimethyl-2,5-hexanediol

Cas:110-03-2

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2,5-Dimethyl-2,5-hexanediol Manufacturer/High quality/Best price/In stock

Cas:110-03-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2,5-Dimethyl-2,5-Hexanediol supplier in China

Cas:110-03-2

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2,5-dimethylhexane-2,5-diol

Cas:110-03-2

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

CHemwill -- 2,5-Dimethyl-2,5-hexanediol

Cas:110-03-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Leader Biochemical Group

About Product Details Item Specification Test Results Appearance White crystalline powder Conform

China Biggest factory Supply High Quality 2,5-Dimethyl-2,5-hexanediol CAS 110-03-2

Cas:110-03-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 5.0

Type:Lab/Research institutions

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

2,5-Hexanediol,2,5-dimethyl- / LIDE PHARMA- Factory supply / Best price

Cas:110-03-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU-CHEM 110-03-2 2,5-Dimethyl-2,5-hexanediol

Cas:110-03-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

2,5-Dimethyl-2,5-hexanediol 110-03-2

Cas:110-03-2

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 110-03-2 with best price

Cas:110-03-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:White crystal or flake Storage:ln stock Package:25kg/Barrel Application:Used as an intermediate in organic synthesis Transportation:Express/Sea/Air Port:Any port in china

China supplier 2,5-Dimethyl-2,5-hexanediol cas:110-03-2

Cas:110-03-2

Min.Order:1 Kilogram

FOB Price: $8.3

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2,5-Hexanediol,2,5-dimethyl- 110-03-2

Cas:110-03-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Xi'an Faithful Biotech Co., Ltd.

We are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery

Qingdao Beluga Import and Export Co., LTD

2,5-Dimethyl-2,5-hexanediol CAS:110-03-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

2,5-Dimethyl-2,5-hexanediol CAS:110-03-2

Cas:110-03-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2,5-Hexanediol,2,5-dimethyl-

Cas:110-03-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

2,5-DiMethyl-2,5-Hexanediol

Cas:110-03-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

cas 110-03-2 2,5-Dimethyl-2,5-hexanediol

Cas:110-03-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

2,5-Dimethyl-2,5-hexanediol

Cas:110-03-2

Min.Order:1 Kilogram

FOB Price: $20.0 / 50.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2,5-Hexanediol,2,5-dimethyl-

Cas:110-03-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Purestar Chem Enterprise Co.,Ltd

【Chemical Name】2,5-Dimethyl-2,5-Hexanediol 【Synonym】Dimethylhexanediol; 1,1,4,4-tetramethyl-1,4-butanediol 【CAS No】110-03-2 【Molecular Formula】C8H18O2 【Molecular Weight】146.23 【Structural Formula】 【Properties】White crystal or flake; Den

2,5-Dimethyl-2,5-Hexanediol

Cas:110-03-2

Min.Order:1 Metric Ton

FOB Price: $6.0

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2,5-Dimethyl-2,5-Hexanediol

Cas:110-03-2

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou ZeErRui Chemical Co., Ltd.

CAS NO : 110-03-2 EC NO : 203-731-5 Molecular Formula : C8H18O2 Main Specifications : 99% Synonyms : 2,5-Dimethyl-2,5-Hexandiol;2,5-dimethylhexane-2,5-diol; Molecular Structure: Product des

high quality 2,5-Dimethyl-2,5-hexanediol? manufacture

Cas:110-03-2

Min.Order:1 Kilogram

FOB Price: $6.1

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2,5-Dimethyl-2,5-hexanediol

Cas:110-03-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2,5-Dimethyl-2,5-hexanediol

Cas:110-03-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2,5-Dimethyl-2,5-Hexanediol

Cas:110-03-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

our strengths: 1: Fast and guaranteed shipment (TNT;EMS;FEDEX;DHL;UPS;EUB, special line) 2: Various payment items accepted (Btc; MoneyGram; WU) 3: Valued package (Paraffin coating; Double aluminum foil bag; Vacuum packaging) 4: Efficient delivery

Factory Supply 99.5% 2,5-Dimethyl-2,5-hexanediol

Cas:110-03-2

Min.Order:1 Gram

Negotiable

Type:Other

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2,5-DiMethyl-2,5-Hexanediol

Cas:110-03-2

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: 2,5-Dimethyl-2,5-Hexanediol CAS No.:110-03-2 Molecule Formula:C8H18O2 Molecule Weight:146.23 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard

High Quality 2,5-Dimethyl-2,5-Hexanediol

Cas:110-03-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2,5-Dimethyl-2,5-hexanediol

Cas:110-03-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2,5-dihydroxy-2,5-dimethyl-3-hexyne
142-30-3

2,5-dihydroxy-2,5-dimethyl-3-hexyne

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
With hydrogen; 0.25% Pd/Al2O3 In xylene at 80℃; under 22502.3 Torr; Product distribution / selectivity;98.5%
With palladium on activated charcoal; hydrogen In ethyl acetate at 20℃; under 7500.75 Torr; for 12h; Autoclave;84%
bei der katalytischen Hydrierung entstehen je nach den Bedingungen verschiedene Produkte.Hydrogenation;
2,5-dimethyl-1-hexene
6975-92-4

2,5-dimethyl-1-hexene

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
With sodium tetrahydroborate; iron(II) phthalocyanine; dimethylsulfide; oxygen In ethanol at 20℃; under 760.051 Torr;51%
2,5-dimethylhex-2-ene
3404-78-2

2,5-dimethylhex-2-ene

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
With sodium tetrahydroborate; iron(II) phthalocyanine; dimethylsulfide; oxygen In ethanol at 20℃; under 760.051 Torr;41%
tert-butyl alcohol
75-65-0

tert-butyl alcohol

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
With sulfuric acid; dihydrogen peroxide; iron(II) sulfate36%
With sulfuric acid; dihydrogen peroxide; iron(II) sulfate
With mercury under 760 Torr; Heating; Irradiation; Yield given;
zinc sulfide In water for 4h; Irradiation;
With sulfuric acid; dihydrogen peroxide; iron(II) sulfate In water at 0 - 20℃; for 0.5h; pH=1; Dimerization;0.130 mmol
2,5-dibromo-2,5-dimethyl-hexane
54462-71-4

2,5-dibromo-2,5-dimethyl-hexane

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
With water; potassium carbonate
methyl magnesium iodide
917-64-6

methyl magnesium iodide

2,5-hexanedione
110-13-4

2,5-hexanedione

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
das Reaktionsprodukt liefert beim Zerlegen mit Wasser;
methylmagnesium bromide
75-16-1

methylmagnesium bromide

2,5-hexanedione
110-13-4

2,5-hexanedione

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

methylmagnesium iodide

methylmagnesium iodide

2,5-hexanedione
110-13-4

2,5-hexanedione

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

methylmagnesium bromide
75-16-1

methylmagnesium bromide

4-oxopentanoic acid ethyl ester
539-88-8

4-oxopentanoic acid ethyl ester

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

methylmagnesium iodide

methylmagnesium iodide

4-oxopentanoic acid ethyl ester
539-88-8

4-oxopentanoic acid ethyl ester

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

methyl magnesium (1+); bromide

methyl magnesium (1+); bromide

4-oxopentanoic acid ethyl ester
539-88-8

4-oxopentanoic acid ethyl ester

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

methyl magnesium iodide
917-64-6

methyl magnesium iodide

succinic acid diethyl ester
123-25-1

succinic acid diethyl ester

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

methylmagnesium iodide

methylmagnesium iodide

succinic acid diethyl ester
123-25-1

succinic acid diethyl ester

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

2,5-dihydroxy-2,5-dimethyl-3-hexyne
142-30-3

2,5-dihydroxy-2,5-dimethyl-3-hexyne

A

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

B

2,5-dimethylhexan-2-ol
3730-60-7

2,5-dimethylhexan-2-ol

Conditions
ConditionsYield
bei der katalytischen Hydrierung entstehen je nach den Bedingungen verschiedene Produkte.Hydrogenation;
With hydrogen; platinum
trans-2,5-dimethyl-3-hexene-2,5-diol
927-81-1

trans-2,5-dimethyl-3-hexene-2,5-diol

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In methanol
2,5-dimethylhexan-2-ol
3730-60-7

2,5-dimethylhexan-2-ol

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
With potassium permanganate In water
With 3,3-dimethyldioxirane In acetone for 24h; Ambient temperature;
With 3,3-dimethyldioxirane In acetone Rate constant; Ambient temperature; different solvents;
Multi-step reaction with 2 steps
1: aq. H2SO4, aq. H2O2
2: FeSO4*7H2O, aq. H2SO4
View Scheme
2-Hydroperoxy-2,5-dimethylhexane
90951-87-4

2-Hydroperoxy-2,5-dimethylhexane

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
With sulfuric acid; iron(II) sulfate
isopropyl alcohol
67-63-0

isopropyl alcohol

acetylene
74-86-2

acetylene

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
With acetone Irradiation;
2,5-dimethylhexane
592-13-2

2,5-dimethylhexane

A

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

B

2,5-dimethylhexan-2-ol
3730-60-7

2,5-dimethylhexan-2-ol

Conditions
ConditionsYield
With 4-nitroperbenzoic acid In chloroform at 60℃; for 36h; Yield given. Yields of byproduct given;
With 4-nitroperbenzoic acid In chloroform at 60℃; for 36h; Rate constant; proportion of velocity of the hydroxylation of tert- and sec. C-H-bonds;
2,5-hexanedione
110-13-4

2,5-hexanedione

methyl iodide
74-88-4

methyl iodide

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
With magnesium In diethyl ether Ambient temperature;
tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With hydrogen; Pt/titania In water for 10h; Ambient temperature; Irradiation;A 0.018 mmol
B 0.0016 mmol
tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

B

methane
34557-54-5

methane

C

acetone
67-64-1

acetone

D

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
With water G-values; Further Variations:; concentration; Decomposition; sonolysis;
tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

B

3-chloro-2-methylpropan-2-ol
558-42-9

3-chloro-2-methylpropan-2-ol

Conditions
ConditionsYield
With dihydrogen peroxide; iron(II) chloride In water at 0 - 20℃; for 0.5h; pH=2; Dimerization; chlorination;A 0.017 mmol
B 0.127 mmol
sulfuric acid
7664-93-9

sulfuric acid

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

iron(II) sulfate

iron(II) sulfate

tert-butyl alcohol
75-65-0

tert-butyl alcohol

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

4-oxopentanoic acid ethyl ester
539-88-8

4-oxopentanoic acid ethyl ester

methyl magnesium halide

methyl magnesium halide

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

water
7732-18-5

water

tert-butyl alcohol
75-65-0

tert-butyl alcohol

hydrogen

hydrogen

oxygen

oxygen

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
Leiten einer wss.Loesung durch den inneren Kegel einer Wasserstoff-Sauerstoff-Flamme;
tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

tert-Amyl alcohol
75-85-4

tert-Amyl alcohol

B

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

C

methane
34557-54-5

methane

D

ethane
74-84-0

ethane

E

acetone
67-64-1

acetone

F

H2 (35.3 μ mol)

H2 (35.3 μ mol)

Conditions
ConditionsYield
Pt on TiO2 In water at 27℃; for 5h; Product distribution; Mechanism; Irradiation; reactions between var. conditions;A 0.0074 mmol
B 0.0159 mmol
C 0.0121 mmol
D 0.0013 mmol
E 0.0151 mmol
F n/a
2,5-dihydroxy-2,5-dimethyl-3-hexyne
142-30-3

2,5-dihydroxy-2,5-dimethyl-3-hexyne

platinum

platinum

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
Hydrogenation;
methanol
67-56-1

methanol

2,5-dihydroxy-2,5-dimethyl-3-hexyne
142-30-3

2,5-dihydroxy-2,5-dimethyl-3-hexyne

Raney nickel

Raney nickel

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Conditions
ConditionsYield
at 25℃; under 147102 Torr; Hydrogenation;
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

2,2,5,5-tetramethyltetrahydrofuran
15045-43-9

2,2,5,5-tetramethyltetrahydrofuran

Conditions
ConditionsYield
With beta-zeolite HCZB 25 at 0.85 - 105℃; for 1.5h; Reagent/catalyst;100%
Nafion-H at 130℃; for 2h;94%
With penthaethoxyphosphorane In dichloromethane for 450h; Ambient temperature;79.1%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

2,5-dichloro-2,5-dimethyl hexane
6223-78-5

2,5-dichloro-2,5-dimethyl hexane

Conditions
ConditionsYield
With hydrogenchloride In water100%
With hydrogenchloride In water at 0℃; Inert atmosphere; Schlenk technique;99%
With hydrogenchloride In water at 20℃; for 5.5h;98%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

2,5-dihypochloro-2,5-dimethylhexane
103603-61-8

2,5-dihypochloro-2,5-dimethylhexane

Conditions
ConditionsYield
With sodium hypochlorite In tetrachloromethane; acetic acid100%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

A

Succinimide
123-56-8

Succinimide

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With N-iodo-succinimide In benzene for 0.916667h; Product distribution; Mechanism; Irradiation; varying reaction time;A 88%
B 99%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

benzene
71-43-2

benzene

1,1,4,4-Tetramethyl-1,2,3,4-tetrahydro-naphthalene
6683-46-1

1,1,4,4-Tetramethyl-1,2,3,4-tetrahydro-naphthalene

Conditions
ConditionsYield
With aluminium trichloride at 55℃; for 6h;99%
titanium(IV) isopropylate
546-68-9

titanium(IV) isopropylate

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Ti(O(CH3)2CCH2CH2C(CH3)2O)(O(CH3)2CCH2CH2C(CH3)2OH)2

Ti(O(CH3)2CCH2CH2C(CH3)2O)(O(CH3)2CCH2CH2C(CH3)2OH)2

Conditions
ConditionsYield
In benzene byproducts: isopropyl alcohol; to a benzene soln. of Ti(OPr-i)4 was added a soln. of glycol in benzene,the mixt. was refluxed for 12 h, cooled to room temp.; isopropanol was sepd. during the reaction azeotropically, the volatiles were removed at room temp. under reduced pressure, recrystd. from toluene-hexane at -20°C; elem. anal.;99%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

phenyl isocyanate
103-71-9

phenyl isocyanate

2,5-dimethyl-2,5-bis-(N-phenylcarbamoyloxy)hexane
1417339-50-4

2,5-dimethyl-2,5-bis-(N-phenylcarbamoyloxy)hexane

Conditions
ConditionsYield
With MoCl2O2(dmf)2 In N,N-dimethyl-formamide at 60℃; for 0.5h; Inert atmosphere;98%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

aluminum isopropoxide
555-31-7

aluminum isopropoxide

N-2,6-triethylphenylsalicylaldimine
54220-62-1

N-2,6-triethylphenylsalicylaldimine

[OC(CH3)2CH2CH2C(CH3)2O]AlOC6H4CHNC6H3(C2H5)2

[OC(CH3)2CH2CH2C(CH3)2O]AlOC6H4CHNC6H3(C2H5)2

Conditions
ConditionsYield
In benzene byproducts: i-PrOH; equimolar amounts of Al-comp., glycol and aldimine refluxed ca.24 h; solv. removed in vac., recrystd. from toluene/hexane 1:2 at -20°C, elem. anal.;97%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

aluminum isopropoxide
555-31-7

aluminum isopropoxide

2-(((2,6-dimethylphenyl)imino)methyl)phenol
54220-52-9

2-(((2,6-dimethylphenyl)imino)methyl)phenol

[OC(CH3)2CH2CH2C(CH3)2O]AlOC6H4CHNC6H3(CH3)2

[OC(CH3)2CH2CH2C(CH3)2O]AlOC6H4CHNC6H3(CH3)2

Conditions
ConditionsYield
In benzene byproducts: i-PrOH; equimolar amounts of Al-comp., glycol and aldimine refluxed ca.24 h; solv. removed in vac., recrystd. from toluene/hexane 1:2 at -20°C, elem. anal.;97%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Tert-butyl isocyanate
1609-86-5

Tert-butyl isocyanate

2,5-dimethyl-2,5-bis-(N-tert-butylcarbamoyloxy)hexane
1417339-53-7

2,5-dimethyl-2,5-bis-(N-tert-butylcarbamoyloxy)hexane

Conditions
ConditionsYield
With MoCl2O2(dmf)2 In dichloromethane for 4h; Inert atmosphere; Reflux;94%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

(diethylamino)titanatrane

(diethylamino)titanatrane

2-(titanatranyloxy)-2,6-dimethyl-6-hydroxyhexane
147244-59-5

2-(titanatranyloxy)-2,6-dimethyl-6-hydroxyhexane

Conditions
ConditionsYield
In dichloromethane under Ar or N2, react. of (diethylamino)titanatrane and 2,5-dimethyl-2,5-hexandiol in equimolar amts., stirring for 1.5 h at room temp.; concg. under vac. to half volume, layering with pentane, cooling to -25°C, pptn. after 24 h;92%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Mo2(O-t-Bu)6
51956-21-9

Mo2(O-t-Bu)6

[Mo2(OtBu)2(O2DMH)2]
1293913-57-1

[Mo2(OtBu)2(O2DMH)2]

Conditions
ConditionsYield
In hexane byproducts: tBuOH; hexane soln. of ligand (0.64 mmol) added dropwise to hexane soln. of Mo compd. (0.32 mmol) at room temp., mixt. stirred for 3 h; filtered off, washed (hexane), recrystd. (CH2Cl2, -20°C), elem. anal.;89%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Dimethylphenylsilane
766-77-8

Dimethylphenylsilane

2,4,4,7,7-pentamethyl-2-phenyl-1,3,2-dioxasilepane

2,4,4,7,7-pentamethyl-2-phenyl-1,3,2-dioxasilepane

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran; N,N-dimethyl-formamide at 60℃; for 24h; Sealed tube;89%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

dichlorophenylsilane
1631-84-1

dichlorophenylsilane

4,4,7,7-tetramethyl-2-phenyl-1,3,2-dioxasilepane

4,4,7,7-tetramethyl-2-phenyl-1,3,2-dioxasilepane

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 12h;88%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

zirconium(IV) tetraisopropoxide 2-propanol
14717-56-7

zirconium(IV) tetraisopropoxide 2-propanol

Zr(O(CH3)2CCH2CH2C(CH3)2O)(O(CH3)2CCH2CH2C(CH3)2OH)2

Zr(O(CH3)2CCH2CH2C(CH3)2O)(O(CH3)2CCH2CH2C(CH3)2OH)2

Conditions
ConditionsYield
In benzene byproducts: isopropyl alcohol; to a benzene soln. of Zr(OPr-i)4 was added a soln. of glycol in benzene,the mixt. was refluxed for 12 h, cooled to room temp.; isopropanol was sepd. during the reaction azeotropically, the volatiles were removed at room temp. under reduced pressure, recrystd. from toluene-hexane at -20°C; elem. anal.;87%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

pivalaldehyde
630-19-3

pivalaldehyde

2-tert.-butyl-4,4,7,7-tetramethyl-1,3-dioxacycloheptane

2-tert.-butyl-4,4,7,7-tetramethyl-1,3-dioxacycloheptane

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene85%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

acryloyl chloride
814-68-6

acryloyl chloride

3-(2,5-dimethylhexane-2,5-diyl)diacrylate

3-(2,5-dimethylhexane-2,5-diyl)diacrylate

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 15h;84%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

(diethylamino)titanatrane

(diethylamino)titanatrane

2,6-bis(titanatranyloxy)-2,6-dimethylhexane

2,6-bis(titanatranyloxy)-2,6-dimethylhexane

Conditions
ConditionsYield
In dichloromethane under Ar or N2, react. of (diethylamino)titanatrane and 2,5-dimethyl-2,5-hexandiol in 2:1 molar ratio, stirring for 1.5 h at room temp.; concg. under vac. to half volume, layering with pentane, cooling to -25°C, pptn. after 24 h;83%
monomethyl oxalyl chloride
5781-53-3

monomethyl oxalyl chloride

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

5-hydroxy-2,5-dimethylhexan-2-yl methyl oxalate

5-hydroxy-2,5-dimethylhexan-2-yl methyl oxalate

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere;81%
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 12h; Inert atmosphere;62%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

1,5-bis(tetrazol-5-yl)-3-oxapentane
66012-50-8

1,5-bis(tetrazol-5-yl)-3-oxapentane

2,2,5,5-tetramethyl-12-oxa-1,6,7,8,16,17,18,19-octaaza-tricyclo-[13.2.1.16,9]nonadeca-7,9(19),15(18),16-tetraene
1412453-66-7

2,2,5,5-tetramethyl-12-oxa-1,6,7,8,16,17,18,19-octaaza-tricyclo-[13.2.1.16,9]nonadeca-7,9(19),15(18),16-tetraene

Conditions
ConditionsYield
With perchloric acid In water at 20℃; for 72h;80%
With perchloric acid In water at 20℃; for 72h; regioselective reaction;80%
monomethyl oxalyl chloride
5781-53-3

monomethyl oxalyl chloride

2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

2,5-dimethylhexane-2,5-diyl dimethyl dioxalate

2,5-dimethylhexane-2,5-diyl dimethyl dioxalate

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere;78%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

5-phenyl-2H-1,2,3,4-tetrazole
18039-42-4

5-phenyl-2H-1,2,3,4-tetrazole

2,5-dimethyl-2,5-di(5-phenyl-2-tetrazolyl)hexane

2,5-dimethyl-2,5-di(5-phenyl-2-tetrazolyl)hexane

Conditions
ConditionsYield
With perchloric acid at 20℃; for 2h; Alkylation;76%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

A

2,2,5,5-tetramethyltetrahydrofuran
15045-43-9

2,2,5,5-tetramethyltetrahydrofuran

B

2,5-dimethyl-4-hexen-2-ol
14908-27-1

2,5-dimethyl-4-hexen-2-ol

Conditions
ConditionsYield
With chloro-trimethyl-silane; dimethyl sulfoxide In benzene at 20℃; for 75h;A 75%
B 21%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

hexakis(dimethylamido)ditungsten(III)
54935-70-5

hexakis(dimethylamido)ditungsten(III)

W2(μ-2,5-dimethylhexane-2,5-diolate)(η(2)-2,5-dimethylhexane-2,5-diolate)2(dimethylamine)2
139728-87-3

W2(μ-2,5-dimethylhexane-2,5-diolate)(η(2)-2,5-dimethylhexane-2,5-diolate)2(dimethylamine)2

Conditions
ConditionsYield
In tetrahydrofuran; hexane; toluene byproducts: HNMe2; N2-atmosphere; addn. of excess diol (in THF) to metal compd. (in hexane/PhMe=2:1 v/v) at -10°C, stirring at -10°C for 4 h; vol. reduction (vac.), crystn. (-20°C, 12 h), decantation, washing (cold hexane); elem. anal.;75%
In diethyl ether; hexane -20°C, under N2; elem. anal.;
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

acrylic acid
79-10-7

acrylic acid

3-(2,5-dimethylhexane-2,5-diyl)diacrylate

3-(2,5-dimethylhexane-2,5-diyl)diacrylate

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; acetic anhydride at 60℃; for 5h; Cooling with ice;75%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

phenylacetonitrile
140-29-4

phenylacetonitrile

A

5-Benzyl-4-isopropylidene-2,2-dimethyl-3,4-dihydro-2H-pyrrole
76528-08-0

5-Benzyl-4-isopropylidene-2,2-dimethyl-3,4-dihydro-2H-pyrrole

B

tetrahydrobenzindol
76527-93-0

tetrahydrobenzindol

Conditions
ConditionsYield
sulfuric acid at 0 - 20℃; for 4h;A 15%
B 72%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

Mo2(O-t-Bu)6
51956-21-9

Mo2(O-t-Bu)6

Mo2(μ-2,5-dimethylhexane-2,5-diolate)3
188107-81-5

Mo2(μ-2,5-dimethylhexane-2,5-diolate)3

Conditions
ConditionsYield
In tetrahydrofuran; hexane byproducts: t-BuOH; N2-atmosphere; dropwise addn. of 3 equiv. diol (in THF) to metal compd. (in hexane) over 5 min, stirring at room temp. for 2 d (pptn.); solvent removal (vac.), washing (Et2O at 0°C), dissoln. in PhMe at 60°C, crystn. (-20°C, overnight), collection (filtration), washing (hexane);72%
In not given under N2; elem. anal.;
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

antimony isopropoxide

antimony isopropoxide

Sb(OC(CH3)2CH2CH2C(CH3)2O)OC3H7
402789-89-3

Sb(OC(CH3)2CH2CH2C(CH3)2O)OC3H7

Conditions
ConditionsYield
In benzene byproducts: isopropanol; the mixt. in benzene was refluxed fo 16 h; isopropanol was fractionated out azeotropically, the solvent was removedunder reduced pressure, distilled at 95°C/10 mm ; elem. anal.;72%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

9H-fluorene
86-73-7

9H-fluorene

1,1,4,4-tetramethyl-2,2,3,3-tetrahydrobenzo[b]fluorene
77308-47-5

1,1,4,4-tetramethyl-2,2,3,3-tetrahydrobenzo[b]fluorene

Conditions
ConditionsYield
aluminium trichloride In dichloromethane 0 deg C, 2 h, then rt, 24 h;70%

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