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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

FERROCENIUM TETRAFLUOROBORATE CAS 1282-37-7

Cas:1282-37-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 1282-37-7 with best quality

Cas:1282-37-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine chemicals, ph

Ferrocenium tetrafluoroborate

Cas:1282-37-7

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

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Qingdao Beluga Import and Export Co., LTD

FERROCENIUM TETRAFLUOROBORATE CAS:1282-37-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality org

FERROCENIUM TETRAFLUOROBORATE CAS:1282-37-7

Cas:1282-37-7

Min.Order:1 Gram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

cyclopenta-1,3-diene: iron(3+)

Cas:1282-37-7

Min.Order:10 Gram

FOB Price: $100.0

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

1282-37-7 CAS NO.1282-37-7

Cas:1282-37-7

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

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Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

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Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

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BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:clear liquid Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as primary a

cyclopenta-1,3-diene: iron(3+)

Cas:1282-37-7

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Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

1282-37-7

Cas:1282-37-7

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

FERROCENIUM TETRAFLUOROBORATE

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Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

1282-37-7

Cas:1282-37-7

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

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HENAN SUNLAKE ENTERPRISE CORPORATION

Henan Sunlake Enterprise Corporation Our Advantages 1, Any inquiry about ch

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

Min.Order:1 Kilogram

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Henan Wising Chem Co., Ltd

Henan Wising Chem specializes in sourcing chemicals in China. We are associated with many trusted manufacturers each having different areas of expertise required for meeting the needs of our local as well as overseas buyers. We have access to custom

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

Min.Order:500 Gram

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Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

1282-37-7 CAS NO.1282-37-7

Cas:1282-37-7

Min.Order:0

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Shanghai Run-Biotech Co., Ltd.

Shanghai, Run-Biotech Co., Ltd is a leading domestic pharmaceutical, biopharmaceutical, and health care products R & D outsourcing services company. As an innovation-driven and customer-focused company, Run Biotech provides a broad and integrated por

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

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Nanjing Raymon Biotech Co., Ltd.

FERROCENIUM TETRAFLUOROBORATEAppearance:Off white to slight yellow solid Storage:Store in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/Pharmaceutical intermediates Transportation:By Sea,by Air,By

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

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Sigma-Aldrich Chemie GmbH

Package:5 g in glass bottle

Ferrocenium tetrafluoroborate

Cas:1282-37-7

Min.Order:0

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Riedel-de Haen AG

FERROCENIUM TETRAFLUOROBORATE

Cas:1282-37-7

Min.Order:0

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Synthetic route

tetrafluoroboric acid diethyl ether
67969-82-8

tetrafluoroboric acid diethyl ether

ferrocene
102-54-5

ferrocene

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

Conditions
ConditionsYield
In nitromethane; dichloromethane addn. of nitromethane to Fe complex soln. (CH2Cl2) under Ar; addn. of HBF4*Et2O in two portions; stirring, 1h; evapn.; extn. (pentane); stirring with ether; dissoln. in heated CH3CN; filtration through Na2SO4 (free from water) in ether; pptn.; drying (high vac.); elem. anal.;95%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

ferrocene
102-54-5

ferrocene

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

Conditions
ConditionsYield
In tetrahydrofuran byproducts: Ag; (Ar or N2), ferrocene in THF treated with 0.8 equiv. of AgBF4 in THF at -78°C; filtered, evapd.(vac.), extd.(CH2Cl2), crystd. at room temp.;87%
tetrafluoroboric acid

tetrafluoroboric acid

ferrocene
102-54-5

ferrocene

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

Conditions
ConditionsYield
In diethyl ether; nitromethane; dichloromethane 12 h;; removing solvent; extn. with petroleum ether 4 times (40-60°C); stirring with ether; filtn.; drying; elem.anal.;;78%
With p-benzoquinone In diethyl ether; water
ferrocene
102-54-5

ferrocene

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; oxygen In not given passing O2 trough soln. of ferrocene and boron trifluoride etherate;;45%
With O2; boron trifluoride etherate In not given passing O2 trough soln. of ferrocene and boron trifluoride etherate;;45%
With p-benzoquinone In benzene addn. of BF3 or boron trifluoride etherate soln. of ferrocene and p-benzoquinone in benzene;;
With BF3 or boron trifluoride etherate; p-benzoquinone In benzene addn. of BF3 or boron trifluoride etherate soln. of ferrocene and p-benzoquinone in benzene;;
ferrocene
102-54-5

ferrocene

boron trifluoride
7637-07-2

boron trifluoride

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

Conditions
ConditionsYield
With oxygen In diethyl ether byproducts: O2(2-); presence of BF3;;
With O2 In diethyl ether byproducts: O2(2-); presence of BF3;;
ferrocene
102-54-5

ferrocene

tetrabutylammonium tetrafluoroborate
429-42-5

tetrabutylammonium tetrafluoroborate

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

Conditions
ConditionsYield
In acetonitrile Electrochem. Process; Ar atmosphere; oxidn. (Pt mesh, 48.0 C); removal of MeCN (vac., room temp.), no further purification;
sodium tetrafluoroborate
13755-29-8

sodium tetrafluoroborate

ferricinium chloroferrate

ferricinium chloroferrate

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

Conditions
ConditionsYield
In water cooling to -5°C, filtration, washing with water, then with THF, drying in vac.;
ferrocene
102-54-5

ferrocene

nitrosonium tetrafluoroborate

nitrosonium tetrafluoroborate

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane prepn. by oxidn. of Cp2Fe with nitrosonium tetrafluoroborate;
In dichloromethane
cyclopentadienyl iron(II) dicarbonyl dimer
38117-54-3

cyclopentadienyl iron(II) dicarbonyl dimer

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

dimethylsulfide
75-18-3

dimethylsulfide

{Fe(CO)2(Me2S)(η5-C5H5)}BF4

{Fe(CO)2(Me2S)(η5-C5H5)}BF4

Conditions
ConditionsYield
In dichloromethane byproducts: (C5H5)2Fe; addn. of ferricinium compd. to Fe complex soln. in the presence of SMe2under Ar; filtration; evapn. to 1/3 the volume; addn. of ether/pentane 3/1); pptn.; thoroughly washing (ether, pentane); drying (high vac.);99%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

dicarbonyl(η5-cyclopentadienyl)(η1-7-methoxy-1-cycloheptenyl)iron
95865-41-1

dicarbonyl(η5-cyclopentadienyl)(η1-7-methoxy-1-cycloheptenyl)iron

A

ferrocene
102-54-5

ferrocene

B

dicarbonyl(η5-cyclopentadienyl)(η1-7-methoxycycloheptene-1-carbonyl)iron
95865-47-7

dicarbonyl(η5-cyclopentadienyl)(η1-7-methoxycycloheptene-1-carbonyl)iron

Conditions
ConditionsYield
With `CO In dichloromethane Addn. of Cp2FeBF4 to iron-compd. (methylene chloride, 55 psiCO, 1h).; Removal of solvent (vacuo), elution with hexane (alumina column) gives yellow band of ferrocene, elution with CH2Cl2 gives yellow band of dicarbonyl complex, elem. anal.;A n/a
B 99%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

(Pd6(C7H8)4(CH3CN)4)(2+)*2BF4(1-)=(Pd6(C7H8)4(CH3CN)4)(BF4)2

(Pd6(C7H8)4(CH3CN)4)(2+)*2BF4(1-)=(Pd6(C7H8)4(CH3CN)4)(BF4)2

[Pd3(μ3-cycloheptatriene)2(acetonitrile)3][BF4]2

[Pd3(μ3-cycloheptatriene)2(acetonitrile)3][BF4]2

Conditions
ConditionsYield
In acetonitrile room temp.;99%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

[Pd6(μ3-C7H7)4(CH3CN)4][BF4]2

[Pd6(μ3-C7H7)4(CH3CN)4][BF4]2

[Pd3(μ3-C7H7)2(CH3CN)3][BF4]2

[Pd3(μ3-C7H7)2(CH3CN)3][BF4]2

Conditions
ConditionsYield
In [D3]acetonitrile99%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

(Pd6(C7H7C(CH3)3)4(CH3CN)4)(2+)*2BF4(1-)=(Pd6(C7H7C(CH3)3)4(CH3CN)4)(BF4)2

(Pd6(C7H7C(CH3)3)4(CH3CN)4)(2+)*2BF4(1-)=(Pd6(C7H7C(CH3)3)4(CH3CN)4)(BF4)2

[Pd3(μ3-C7H7-t-Bu)2(CH3CN)3][BF4]2

[Pd3(μ3-C7H7-t-Bu)2(CH3CN)3][BF4]2

Conditions
ConditionsYield
In acetonitrile room temp.;99%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

(Cp2Ti)3(μ3-HATNPh6)

(Cp2Ti)3(μ3-HATNPh6)

[(Cp2Ti)3(μ3-HATNPh6)][BF4]3

[(Cp2Ti)3(μ3-HATNPh6)][BF4]3

Conditions
ConditionsYield
In tetrahydrofuran; hexane at 20℃; Schlenk technique; Glovebox; Inert atmosphere;99%
cyclopentadienyl iron(II) dicarbonyl dimer
38117-54-3

cyclopentadienyl iron(II) dicarbonyl dimer

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

dimethylselenide
593-79-3

dimethylselenide

{C5H5Fe(CO)2(Se(CH3)2)}(1+)*BF4(1-)={C5H5Fe(CO)2(Se(CH3)2)}BF4

{C5H5Fe(CO)2(Se(CH3)2)}(1+)*BF4(1-)={C5H5Fe(CO)2(Se(CH3)2)}BF4

Conditions
ConditionsYield
In dichloromethane byproducts: (C5H5)2Fe; addn. of ferricinium compd. to Fe complex soln. in the presence of SeMe2 under Ar; filtration; evapn. to 1/3 the volume; addn. of ether/pentane3/1); pptn.; thoroughly washing (ether, pentane); drying (high vac.);98%
cyclopentadienyl iron(II) dicarbonyl dimer
38117-54-3

cyclopentadienyl iron(II) dicarbonyl dimer

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

[dicarbonyl(η5-cyclopentadienyl)iron(II)(PPh3)]BF4

[dicarbonyl(η5-cyclopentadienyl)iron(II)(PPh3)]BF4

Conditions
ConditionsYield
With triphenylphosphine In dichloromethane during intensive stirring addn. of ((C5H5)2Fe)BF4 to mixture of P(C6H5)3 and ((C5H5)Fe(CO)2)2;; crystn. from CH2Cl2/ether; drying; elem.anal.;;98%
With triphenylphosphine In dichloromethane byproducts: (C5H5)2Fe; addn. of ferricinium compd. to Fe complex soln. in the presence of PPh3under Ar; filtration; evapn. to 1/3 the volume; addn. of ether/pentane 3/1); pptn.; thoroughly washing (ether, pentane); drying (high vac.);97%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

Fe((phenylphosphino)tetramethylcyclopentadienyl)

Fe((phenylphosphino)tetramethylcyclopentadienyl)

[1,1'-bis(diphenylphosphino)octamethylferrocenium]BF4
459790-88-6

[1,1'-bis(diphenylphosphino)octamethylferrocenium]BF4

Conditions
ConditionsYield
In dichloromethane under Ar, soln. was stirred for 1 h; solvent was removed, ppt. was filtered off, washed with benzene repeatedly, dried in vac.; elem. anal.;98%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

(OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2)
877034-21-4, 877034-22-5

(OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2)

iodine
7553-56-2

iodine

[(1,2-bis(diphenylphosphino)ethane)Ni(2,2-dimethyl-1,3-propanedithiolate)IFe(CO)3]BF4

[(1,2-bis(diphenylphosphino)ethane)Ni(2,2-dimethyl-1,3-propanedithiolate)IFe(CO)3]BF4

Conditions
ConditionsYield
Stage #1: ferrocenium(III) tetrafluoroborate; (OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2) In dichloromethane for 0.0166667h;
Stage #2: iodine In dichloromethane for 0.00833333h;
98%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

(OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2)
877034-21-4, 877034-22-5

(OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2)

bromine
7726-95-6

bromine

[(1,2-bis(diphenylphosphino)ethane)Ni(2,2-dimethyl-1,3-propanedithiolate)BrFe(CO)3]BF4

[(1,2-bis(diphenylphosphino)ethane)Ni(2,2-dimethyl-1,3-propanedithiolate)BrFe(CO)3]BF4

Conditions
ConditionsYield
Stage #1: ferrocenium(III) tetrafluoroborate; (OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2) In dichloromethane for 0.0166667h;
Stage #2: bromine In dichloromethane for 0.00833333h;
98%
N-Bromosuccinimide
128-08-5

N-Bromosuccinimide

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

(OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2)
877034-21-4, 877034-22-5

(OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2)

[(1,2-bis(diphenylphosphino)ethane)Ni(2,2-dimethyl-1,3-propanedithiolate)BrFe(CO)3]BF4

[(1,2-bis(diphenylphosphino)ethane)Ni(2,2-dimethyl-1,3-propanedithiolate)BrFe(CO)3]BF4

Conditions
ConditionsYield
Stage #1: ferrocenium(III) tetrafluoroborate; (OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2) In dichloromethane for 0.0166667h;
Stage #2: N-Bromosuccinimide In dichloromethane for 0.00833333h;
98%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

(Cp2Ti)3(μ3-HATNPh6)

(Cp2Ti)3(μ3-HATNPh6)

[(Cp2Ti)3(μ3-HATNPh6)]BF4

[(Cp2Ti)3(μ3-HATNPh6)]BF4

Conditions
ConditionsYield
In hexane at 20℃; Schlenk technique; Glovebox; Inert atmosphere;98%
bis(cyclopentadienyl)chromium
1271-24-5

bis(cyclopentadienyl)chromium

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

[Cr(C5H5)2](1+)*BF4(1-)=[Cr(C5H5)2]BF4
106453-51-4

[Cr(C5H5)2](1+)*BF4(1-)=[Cr(C5H5)2]BF4

Conditions
ConditionsYield
In dichloromethane byproducts: (C5H5)2Fe; addn. of ferricenium compd. to Cr complex soln. under Ar; filtration; evapn. to 1/5 of the volume; addn. of ether; pptn.; recrystn. from CH3CN/ether (1/1); drying (high vac.); elem. anal.;97%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

[Fe2(η5-C5H5)2(μ-CO)2(CO)(CyPH2)]
869802-98-2

[Fe2(η5-C5H5)2(μ-CO)2(CO)(CyPH2)]

[Fe2(η5-C5H5)2(μ-CO)(CO)2(μ-PCyH)]BF4
869803-01-0

[Fe2(η5-C5H5)2(μ-CO)(CO)2(μ-PCyH)]BF4

Conditions
ConditionsYield
In dichloromethane (N2); std. Schlenk technique; solid (C5H5)2FeBF4 was added to stirred soln. of Fe-P complex in CH2Cl2 at 273 K; stirred for 10 min; evapd. (vac.); washed (petroleum ether); elem. anal.;97%
In not given byproducts: H2;
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

[Co(TC-5,5)]
169232-86-4

[Co(TC-5,5)]

[Co(TC-5,5)](BF4)

[Co(TC-5,5)](BF4)

Conditions
ConditionsYield
In dichloromethane Inert atmosphere; Glovebox;97%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

hexarutheniumhexadecacarbonylcarbido di(bis(triphenylphosphine)iminium)

hexarutheniumhexadecacarbonylcarbido di(bis(triphenylphosphine)iminium)

carbido heptadecacarbonyl hexaruthenium

carbido heptadecacarbonyl hexaruthenium

Conditions
ConditionsYield
With carbon monoxide In not given dropwise addn. of CO and Ru-cluster soln. (CH2Cl2 or MeCN) to soln. of Cp2FeBF4 (N2 purge, room temp.); IR monitoring;96%
cyclopentadienyl iron(II) dicarbonyl dimer
38117-54-3

cyclopentadienyl iron(II) dicarbonyl dimer

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

cyclopentadienyldicarbonyl(tetrahydrofuran)iron(II) tetrafluoroborate

cyclopentadienyldicarbonyl(tetrahydrofuran)iron(II) tetrafluoroborate

Conditions
ConditionsYield
With tetrahydrofuran In dichloromethane byproducts: (C5H5)2Fe; addn. of ferricinium compd. to Fe complex soln. in the presence of THF under Ar; filtration; evapn. to 1/3 the volume; addn. of ether/pentane 3/1); pptn.; thoroughly washing (ether, pentane); drying (high vac.);96%
nickelocene
1271-28-9

nickelocene

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

(C5H5)2Fe*(C5H5)2Ni(2+)*2BF4(1-) = {(C5H5)4FeNi}(BF4)2

(C5H5)2Fe*(C5H5)2Ni(2+)*2BF4(1-) = {(C5H5)4FeNi}(BF4)2

Conditions
ConditionsYield
In dichloromethane byproducts: Fe(C5H5)2; mixed, standed (1 min); ppt. washed (CH2Cl2), dried (vac.); elem. anal.;96%
nickelocene
1271-28-9

nickelocene

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

{nickelocenium} tetrafluoroborate

{nickelocenium} tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane byproducts: (C5H5)2Fe; addn. of ferricenium compd. to Ni complex soln. under Ar; filtration; evapn. to 1/5 of the volume; addn. of ether; pptn.; recrystn. from CH3CN/ether (1/1); drying (high vac.); elem. anal.;96%
In dichloromethane dissolving of nickelocene in a minimum of CH2Cl2, addn. of the ferrocenium tetrafluoroborate under Ar, standing for 72 h; filtn., concn., washing with cold CH2Cl2 and Et2O and placing in vac. for several hours;
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

Co(CO)3(P(C6H5)3)2(1+)*BF4(1-)=Co(CO)3(P(C6H5)3)2BF4
100852-19-5, 118400-45-6

Co(CO)3(P(C6H5)3)2(1+)*BF4(1-)=Co(CO)3(P(C6H5)3)2BF4

Conditions
ConditionsYield
With triphenylphosphine In dichloromethane addn. of ((C5H5)Fe)BF4 to mixture of P(C6H5)3 and Co(CO)8; addn. of ether to sol.;; elem.anal.;;96%
cyclopentadienyl iron(II) dicarbonyl dimer
38117-54-3

cyclopentadienyl iron(II) dicarbonyl dimer

ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

tri-tert-butyl phosphine
13716-12-6

tri-tert-butyl phosphine

[C5H5Fe(CO)2P(C(CH3)3)3](1+)*BF4(1-)=[C5H5Fe(CO)2P(C(CH3)3)3]BF4
106453-55-8

[C5H5Fe(CO)2P(C(CH3)3)3](1+)*BF4(1-)=[C5H5Fe(CO)2P(C(CH3)3)3]BF4

Conditions
ConditionsYield
In dichloromethane byproducts: (C5H5)2Fe; addn. of ferricinium compd. to Fe complex soln. in the presence of phosphane under Ar; filtration; evapn. to 1/3 the volume; addn. of ether/pentane (3/1); pptn.; thoroughly washing (ether, pentane); drying (high vac.); elem. anal.;96%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

[Co(CO)3(P(C6H5)3)2](1+)*BF4(1-)=[Co(CO)3(P(C6H5)3)2]BF4
100852-19-5, 118400-45-6

[Co(CO)3(P(C6H5)3)2](1+)*BF4(1-)=[Co(CO)3(P(C6H5)3)2]BF4

Conditions
ConditionsYield
With triphenylphosphine In dichloromethane byproducts: (C5H5)2Fe; addn. of ferricinium compd. to Co complex soln. in the presence of PPh3under Ar; filtration; evapn. to 1/3 the volume; addn. of ether/pentane (3/1); pptn.; thoroughly washing (ether, pentane); drying (high vac.); elem. anal.;96%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

bis(benzene)chromium(0)
1271-54-1

bis(benzene)chromium(0)

[Cr(C6H6)2](1+)*BF4(1-)=[Cr(C6H6)2]BF4
11077-48-8

[Cr(C6H6)2](1+)*BF4(1-)=[Cr(C6H6)2]BF4

Conditions
ConditionsYield
In dichloromethane byproducts: (C5H5)2Fe; addn. of ferricenium compd. to Cr complex soln. under Ar; filtration; evapn. to 1/5 of the volume; addn. of ether; pptn.; recrystn. from CH3CN/ether (1/1); drying (high vac.); elem. anal.;96%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

Cp(*)Fe(as-indacene)FeCp(*)

Cp(*)Fe(as-indacene)FeCp(*)

[Cp(*)Fe(as-indacene)FeCp(*)](.+)[BF4(1-)]
129500-53-4

[Cp(*)Fe(as-indacene)FeCp(*)](.+)[BF4(1-)]

Conditions
ConditionsYield
(N2); elem. anal.;96%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

[Fe2(η5-C5H5)2(μ-CO)2(CO)(PH2Ph)]
869802-99-3

[Fe2(η5-C5H5)2(μ-CO)2(CO)(PH2Ph)]

[Fe2(η5-C5H5)2(μ-CO)(CO)2(μ-PPhH)]BF4
869881-53-8

[Fe2(η5-C5H5)2(μ-CO)(CO)2(μ-PPhH)]BF4

Conditions
ConditionsYield
In dichloromethane (N2); std. Schlenk technique; solid (C5H5)2FeBF4 was added to stirred soln. of Fe-P complex in CH2Cl2 at 273 K; stirred for 10 min; evapd. (vac.); washed (petroleum ether); elem. anal.;96%
In not given byproducts: H2;
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

(triphenylphosphane)gold(I) tert-butylthiolate
122711-31-3

(triphenylphosphane)gold(I) tert-butylthiolate

A

ferrocene
102-54-5

ferrocene

B

tetrakis(triphenylphosphane)bis(tert-butylthiolate)tetragold(I) tetrafluoroborate

tetrakis(triphenylphosphane)bis(tert-butylthiolate)tetragold(I) tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane byproducts: (SC(CH3)3)2; N2, Fe:Au=0.136:0.276 molar ratio, Fe compd. added to a soln. of Au compd., stirred for 30 min; solvent evapd., residue washed (diethyl ether, benzene), dried (vac.), recrystd. (CH2Cl2, -5°C), org. phases evapd. to dryness, ferrocenesublimied (40°C, high vac.); elem. anal.;A n/a
B 96%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

dichloromethane
75-09-2

dichloromethane

(OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2)
877034-21-4, 877034-22-5

(OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2)

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

[(dppe)Ni(propaneditiolate)Fe(CO)2(P(p-C6H4OMe)3)]BF4*0.25CH2Cl2

[(dppe)Ni(propaneditiolate)Fe(CO)2(P(p-C6H4OMe)3)]BF4*0.25CH2Cl2

Conditions
ConditionsYield
With pentane In dichloromethane MBraun glovebox, under N2; soln. of NiFe compd. and FcBF4 in CH2Cl2, rapid stirring for 1 min, above soln. added to phosphine in CH2Cl2, 0.5 min, pentane added (-28°C, then 1 h at this temp.); filtered, washed (pentane, -28°C), dried; elem. anal.;96%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

[Fe(CO)2(2-[(di-tert-butylphosphino)methyl]-6-[1-(2,4,6-mesitylimino)ethyl]pyridine)]

[Fe(CO)2(2-[(di-tert-butylphosphino)methyl]-6-[1-(2,4,6-mesitylimino)ethyl]pyridine)]

[Fe(CO)2(2-[(di-tert-butylphosphino)methyl]-6-[1-(2,4,6-mesitylimino)ethyl]pyridine)](BF4)

[Fe(CO)2(2-[(di-tert-butylphosphino)methyl]-6-[1-(2,4,6-mesitylimino)ethyl]pyridine)](BF4)

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 3h; Inert atmosphere;96%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

[Cp2Ni2(ethanethiol)2]

[Cp2Ni2(ethanethiol)2]

[Cp2Ni2(ethanethiol)2]BF4

[Cp2Ni2(ethanethiol)2]BF4

Conditions
ConditionsYield
In dichloromethane96%

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