Hebei yanxi chemical co.,LTD.
hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen
Luyunjia Chemistry Xiamen Limited
Quick Details Classification: Catalyst CAS No.: 102-54-5 Other Names: Ferrocene MF: Fe(C5H5)2 EINECS No.: none Purity: >99%, 98% Place of Ori
Cas:102-54-5
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryQingdao KMS Biochemical Technology Co.,Ltd.
We can supply different types of Ferrocene , crystal and powder, are 99% min . The main index can be provide according to customer requirements. Stable supply capacity manufacturer in China, also do Ferrocene series products,Liquid ferrocene, Octyl
Cas:102-54-5
Min.Order:1 Kilogram
FOB Price: $11.5 / 12.0
Type:Lab/Research institutions
inquirySimagchem Corporation
Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:102-54-5
Min.Order:1 Kilogram
Negotiable
Type:Manufacturers
inquiryShanxi Zorui Biotechnology Co.Ltd.
Zorui combines R&D, production and sales into its operations, While continuously providing high-quality raw materials, we also provide and optimize technical solutions for customers to achieve mutual benefit. We adhere to the "quality, integ
Cas:102-54-5
Min.Order:1 Kilogram
Negotiable
Type:Other
inquiryHefei Zhaobo Technology Co., Ltd.
Our Advantages Production: Advanced chemical equipment with years of experience.Staffs for producing various extract products. Quality Control：A complete set of Testing Professional and Analysis Equipment ensures the Quality Requirements and Speci
Cas:102-54-5
Min.Order:1 Kilogram
FOB Price: $18.0 / 20.0
Type:Trading Company
inquiryAecochem Corp.
Items Specification Appearance orange yellow powder Content 98%min Melting point 172-1
Cas:102-54-5
Min.Order:25 Kilogram
Negotiable
Type:Manufacturers
inquiryDayang Chem (Hangzhou) Co.,Ltd.
Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti
Cas:102-54-5
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryHangzhou Dingyan Chem Co., Ltd
Items Standard Result Appearance Orange yellow powder Orange yellow powder Assay 99%min
Cas:102-54-5
Min.Order:1 Kilogram
FOB Price: $10.0 / 15.0
Type:Manufacturers
inquiryHefei TNJ chemical industry co.,ltd
Product: ISO Certified Manufactory Supply Ferrocene,Dicyclopentadienyliron,CAS 102-54-5 Name Synonyms CAS Registry Number Molecular Formula Molecular Weight EINECS
Henan Allgreen Chemical Co.,Ltd
Good price Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:As per customer's demand Application:Biological buffer Transportation:By Sea or By Air or By Courier Port:shanghai
Xi'an Xszo Chem Co., Ltd.
1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
Cas:102-54-5
Min.Order:1 Gram
FOB Price: $0.1
Type:Manufacturers
inquiryChemwill Asia Co., Ltd.
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Henan Tianfu Chemical Co., Ltd.
TIANFUCHEM--102-54-5--Ferrocene in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relationships with
Cas:102-54-5
Min.Order:1 Metric Ton
FOB Price: $2000.0
Type:Lab/Research institutions
inquiryJinan Finer Chemical Co., Ltd
Product Description Product website: http://www.finerchem.com Product Name Ferrocene CAS No. 102-54-5 Appea
Hebei Nengqian Chemical Import and Export Co., LTD
Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva
Cas:102-54-5
Min.Order:1 Gram
FOB Price: $1000.0 / 1300.0
Type:Trading Company
inquiryZhuozhou Wenxi import and Export Co., Ltd
WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:102-54-5
Min.Order:10 Gram
FOB Price: $146.0 / 176.0
Type:Trading Company
inquiryWuhan Han Sheng New Material Technology Co.，Ltd
Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:102-54-5
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiryHenan Sinotech Import&Export Corporation
Name: Iron dicyclopentadienyl Synonyms: Ferrocene CAS: 102-54-5 MF: C10H10Fe Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:diesel additive Transportation:By sea or by air Port:
Shanghai Upbio Tech Co.,Ltd
1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:102-54-5
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHangzhou Fonlynn Health Technology Co., Ltd.
Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Appearance:Yellow powder Storage:Refer to COA / MSDS Packa
Cas:102-54-5
Min.Order:1 Metric Ton
Negotiable
Type:Trading Company
inquiryShanghai Minstar Chemical Co., Ltd
Product Name: Ferrocene CAS: 102-54-5 MF: C10H10Fe MW: 186.03 EINECS: 203-039-3 Mol File: 102-54-5.mol Ferrocene Structure Ferrocene Chemical Properties Melting point 172-174 °C (lit.) Boiling point 249 °C (lit.) d
Baoji Guokang Healthchem co.,ltd
Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present
Cas:102-54-5
Min.Order:1 Kilogram
FOB Price: $15.0
Type:Trading Company
inquiryQingdao Beluga Import and Export Co., LTD
Ferrocene CAS:102-54-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates, st
Cas:102-54-5
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHebei Mojin Biotechnology Co.,Ltd
Product quality: Our company have high quality product , and also the product we have good manufacture . First of all, this product is of fine quality. Every finish should be checked by quality inspection system.And every one should be also tried
Cas:102-54-5
Min.Order:1 Metric Ton
FOB Price: $11000.0 / 12000.0
Type:Trading Company
inquiryShanxi Ankesi Biotechnology Co., Ltd
Our Advantage 1. Rich experience We specialize in this filed for many years, our APIs exported to all over the world and and we established long friendly relations of cooperation with our clients. 2. Great quality,purity and favorable Good q
Cas:102-54-5
Min.Order:1 Kilogram
FOB Price: $45.0 / 60.0
Type:Trading Company
inquiryShandong Hanjiang Chemical Co., Ltd.
Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Hebei Quanhe Biotechnology Co. LTD
1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures
Lonwin Chemical Group Limited
Ferrocene CAS: 102-54-5 Specification items specification appearance orange yellow powder content 98%min melting point 172-174℃
Synthetic route
-
-
102-54-5
ferrocene
| Conditions | Yield |
|---|---|
| With potassium cyanide In chloroform; water byproducts: P(C6H5)3; (Ar); shaking a soln. of the Au complex in CHCl3 with aq. KCN, 8 h; sepn. of the org. layer, drying over K2CO3, evapn. to dryness; products determined by thin-layer chromy. and 1H-NMR; | 100% |
| In not given with electrophilic reacgents;; |
-
-
1282-37-7
ferrocenium(III) tetrafluoroborate
-
-
95865-41-1
dicarbonyl(η5-cyclopentadienyl)(η1-7-methoxy-1-cycloheptenyl)iron
-
A
-
102-54-5
ferrocene
-
B
-
95865-47-7
dicarbonyl(η5-cyclopentadienyl)(η1-7-methoxycycloheptene-1-carbonyl)iron
| Conditions | Yield |
|---|---|
| With `CO In dichloromethane Addn. of Cp2FeBF4 to iron-compd. (methylene chloride, 55 psiCO, 1h).; Removal of solvent (vacuo), elution with hexane (alumina column) gives yellow band of ferrocene, elution with CH2Cl2 gives yellow band of dicarbonyl complex, elem. anal.; | A n/a B 99% |
-
-
156301-37-0
ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
-
A
-
102-54-5
ferrocene
| Conditions | Yield |
|---|---|
| In benzene under N2 atm. to soln. Mo complex in benzene (Cp2Fe)(BAr'4) was added and stirred for 30 min; volatiles were removed in vacuo, residue was dissolved in heptane, ppt. was dried in high vac.; elem. anal.; | A n/a B 99% |
| Conditions | Yield |
|---|---|
| With C26H46ClO3Ru2S2(1+)*CF3O3S(1-); hydrogen In dichloromethane at 20℃; under 760.051 Torr; for 11h; Catalytic behavior; Inert atmosphere; | A 99% B 98% |
| Conditions | Yield |
|---|---|
| With iron; diethylamine In further solvent(s) further solvents: mixt. of HN(C2H5)2, CH3OH, DME and (C6H5CH2N(CH3)3)OH; amine method; FeBr2 and Fe from Fe and Br2, Fe excess;; | 98% |
| With diethylamine In 1,2-dimethoxyethane; diethylamine amine method; FeBr2 from Fe and Br2;; | 85% |
| With diethylamine In 1,2-dimethoxyethane; diethylamine amine method; FeBr2 from Fe and Br2;; | 85% |
| With diethylamine In diethylamine byproducts: HBr; | 4% |
-
A
-
102-54-5
ferrocene
-
B
-
7440-57-5, 457905-15-6
gold
| Conditions | Yield |
|---|---|
| In acetonitrile byproducts: CH4, C2H6; inert atmosphere; | A 92% B 98% |
| In tetrahydrofuran byproducts: CH4, C2H6; inert atmosphere; | A 94% B 95% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran byproducts: CH4; He-atmosphere; -196°C, addn. of Cp2FePF6 to soln. of aurate and PPh3; not sepd., NMR-spectroscopy; | A 98% B 98% |
| In diethyl ether byproducts: CH4, C2H6; inert atmosphere; | A 95% B 94% |
| In acetonitrile byproducts: CH4; inert atmosphere; -40°C; | A 94% B 89% |
-
A
-
102-54-5
ferrocene
-
B
-
153288-01-8
1,2-bis-(4-chlorophenoxy)benzene
| Conditions | Yield |
|---|---|
| In dichloromethane; acetonitrile Irradiation (UV/VIS); addn. of diiron-complex dissolved in CH2Cl2/CH3CN to a photolysis tube, purging with N2 for 30 min, irradiation under intense visible light (Xenon lamp) for 4 h; concn. by evapn. under reduced pressure, column chromy., elution (hexane) gives yellow band of ferrocene, elution (hexane/CHCl3) gives benzene-compd., evapn. to dryness, elem. anal.; | A n/a B 98% |
-
-
59501-96-1
[C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li
-
-
84430-52-4
(C5H5)Fe[P(OC6H5)3]2Cl
-
A
-
102-54-5
ferrocene
-
B
-
3561-67-9
bis(phenylthio)methane
-
C
-
622-20-8
1,2-bis(phenylthio)ethane
-
D
-
882-33-7
diphenyldisulfane
| Conditions | Yield |
|---|---|
| In tetrahydrofuran mixing reactants in THF at -78°C, slow warming to room temp. / further products; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation; | A 27% B 27% C 38% D 25% E 98% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran byproducts: CH4, C2H6; He-atmosphere; addn. of 1 equiv. of Cp2FePF6 to soln. of aurate at -196°C, warming to room temp.; | A 94% B 97% |
| In acetonitrile byproducts: CH4, C2H6; He-atmosphere; addn. of 1 equiv. of Cp2FePF6 to soln. of aurate at -196°C, warming to room temp.; | A 96% B 96% |
| Conditions | Yield |
|---|---|
| In acetonitrile byproducts: Fe(II), p-xylene; Irradiation (UV/VIS); a CH3CN soln. of Fe-compd. was degassed by bubbling with N2 for 10 min and irradiated with sunlight for 3 h 25 min at room temp.;; evapn. of the solvent and extn. the residue with cyclohexane; detected by NMR-expt.;; | 97% |
| In acetonitrile byproducts: Fe(II), p-xylene; Irradiation (UV/VIS); a CH3CN soln. of Fe-compd. was degassed by bubbling with N2 for 10 min and irradiated with an Oriel lamp for 3 h 25 min at room temp.;; evapn. of the solvent and extn. the residue with cyclohexane; detected by NMR-expt.;; | 93% |
-
-
135348-57-1
ferrocenium tetrakis(pentafluorophenyl)borate
-
A
-
102-54-5
ferrocene
| Conditions | Yield |
|---|---|
| In diethyl ether for 0.5h; Inert atmosphere; Schlenk technique; Glovebox; | A 80% B 97% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran anhyd. FeCl3, boiling abs. THF, under exclusion of air; preparation of small amts.;; | 96% |
| Conditions | Yield |
|---|---|
| In diethyl ether byproducts: LiCl; Ar; to a suspn. of PbCl2 added a suspn. of FcLi, stirred for 2 h; ppt. (Pb) filtered, washed (H2O), dried, analyzed; Fc not isolated, detected by NMR; | A 96% B n/a |
| Conditions | Yield |
|---|---|
| In dichloromethane; acetonitrile Irradiation (UV/VIS); addn. of diiron-complex dissolved in CH2Cl2/CH3CN to a photolysis tube, purging with N2 for 30 min, irradiation under intense visible light (Xenon lamp) for 4 h; concn. by evapn. under reduced pressure, column chromy., elution (hexane) gives yellow band of ferrocene, elution (hexane/CHCl3) gives benzene-compd., evapn. to dryness, elem. anal.; | A n/a B 96% |
-
A
-
102-54-5
ferrocene
-
B
-
153287-98-0
1,2-bis-(4-methylphenoxy)benzene
| Conditions | Yield |
|---|---|
| In dichloromethane; acetonitrile Irradiation (UV/VIS); addn. of diiron-complex dissolved in CH2Cl2/CH3CN to a photolysis tube, purging with N2 for 30 min, irradiation under intense visible light (Xenon lamp) for 4 h; concn. by evapn. under reduced pressure, column chromy., elution (hexane) gives yellow band of ferrocene, elution (hexane/CHCl3) gives benzene-compd., evapn. to dryness, elem. anal.; | A n/a B 96% |
-
-
1282-37-7
ferrocenium(III) tetrafluoroborate
-
-
122711-31-3
(triphenylphosphane)gold(I) tert-butylthiolate
-
A
-
102-54-5
ferrocene
| Conditions | Yield |
|---|---|
| In dichloromethane byproducts: (SC(CH3)3)2; N2, Fe:Au=0.136:0.276 molar ratio, Fe compd. added to a soln. of Au compd., stirred for 30 min; solvent evapd., residue washed (diethyl ether, benzene), dried (vac.), recrystd. (CH2Cl2, -5°C), org. phases evapd. to dryness, ferrocenesublimied (40°C, high vac.); elem. anal.; | A n/a B 96% |
-
A
-
102-54-5
ferrocene
| Conditions | Yield |
|---|---|
| In dichloromethane byproducts: ferrocene; 27 equivs. of (C5H5)Fe(C5H5)(PF6) in CH2Cl2 added to dendrimer complex in CH2Cl2 at room temp.; allowed to stir under N2 for 1 h at room temp.; Et2O added dropwise; filtered under N2 on Celite; dried in vac.; elem. anal.; | A 96% B 66.3% |
| Conditions | Yield |
|---|---|
| With potassium chloride In 1,2-dimethoxyethane; water ratio H2O:(CH2OCH3)2 = 50:50 %, 0.4 M KCl, boiling; not isolated; | A n/a B 35.9% C n/a D 95.3% E 3.9% |
| With KCl In 1,2-dimethoxyethane; water ratio H2O:(CH2OCH3)2 = 50:50 %, 0.4 M KCl, boiling; not isolated; | A n/a B 35.9% C n/a D 95.3% E 3.9% |
-
-
126572-58-5
di(t-butylimido)di(2,4,6-trimethylphenyl)rhenium(VI)
-
A
-
102-54-5
ferrocene
| Conditions | Yield |
|---|---|
| In tetrahydrofuran absence of air; stirring (1 h); solvent removal (vac.), washing (hexane), crystn. (THF/Et2O); elem. anal.; | A n/a B 95% |
| Conditions | Yield |
|---|---|
| In dichloromethane; acetonitrile Irradiation (UV/VIS); addn. of diiron-complex dissolved in CH2Cl2/CH3CN to a photolysis tube, purging with N2 for 30 min, irradiation under intense visible light (Xenon lamp) for 4 h; concn. (vac.), column chromy., elution (hexane) gives yellow band of ferrocene, elution (hexane/CHCl3) gives benzene-compd., evapn. to dryness, elem. anal.; | A n/a B 95% |
-
-
1282-37-7
ferrocenium(III) tetrafluoroborate
-
-
223424-75-7
bis[(1,2-bis(dimethylphosphino)ethane)(η(5)-methylcyclopentadienyl)manganese(I)](μ-2,3-diphenylbutadien-1,4-diylidene)
-
A
-
102-54-5
ferrocene
| Conditions | Yield |
|---|---|
| In dichloromethane N2-atmosphere; filtering, concg., pptn. on Et2O addn.; collecting, washing (Et2O), drying (vac.), repptn., recrystn. (CH2Cl2, room temp.); elem. anal.; | A n/a B 95% |
-
-
209473-49-4
(η(5)-2-cyclopentadienyl-2-indenyl-propane)Rh(1,5-cyclooctadiene)
-
-
232282-91-6
[(cyclopentadienyl)Fe(fluorene)]PF6
-
A
-
102-54-5
ferrocene
-
B
-
329985-01-5, 912572-47-5
[Rh(cyclooctadiene)(η5-cyclopentadienyl)C(CH3)2(η5-indenyl)Fe(η5-cyclopentadienyl)]
| Conditions | Yield |
|---|---|
| With BuLi In tetrahydrofuran byproducts: fluorene; (N2); (COD)Rh(Cp)C(CH3)2(C9H6) deprotonated with BuLi in THF; soln. prepared from (CpFe(fluorene))PF6 and BuLi added at 0 °C after 1 h; refluxed for 16 h; solvend removed; extracted by pentane/diethyl ether (1:1); chromy.(pentane/diethyl ether); elem. anal.; | A n/a B 95% |
-
-
1282-37-7
ferrocenium(III) tetrafluoroborate
-
-
1002113-69-0
(methyldiphenylphosphane)gold(I) tetr-butylthiolate
-
A
-
102-54-5
ferrocene
| Conditions | Yield |
|---|---|
| In dichloromethane byproducts: (SC(CH3)3)2; N2, Fe:Au=0.136:0.276 molar ratio, Fe compd. added to a soln. of Au compd., stirred for 30 min; solvent evapd., residue washed (diethyl ether, benzene), dried (vac.), recrystd. (CH2Cl2, -5°C), org. phases evapd. to dryness, ferrocenesublimied (40°C, high vac.); elem. anal.; | A n/a B 95% |
-
A
-
102-54-5
ferrocene
| Conditions | Yield |
|---|---|
| In benzene W-cluster was dissolved in benzene in Schlenk flask, soln. of Fe-complexwas added, stirred for 1 h; after 2 d filtered, washed with Et2O, dried; | A n/a B 95% |
| In dichloromethane W-cluster was dissolved in CH2Cl2 in Schlenk flask, soln. of Fe-complex in CH2Cl2 was added, stirred for 30 min; solvent was removed under vac. washed with benzene and Et2O; | A n/a B 85% |
| Conditions | Yield |
|---|---|
| With n-butyllithium In tetrahydrofuran under N2; n-BuLi in THF added dropwise at -35°C to soln. of Fe complex in THF; stirred at -35°C for 1 h; H2O added dropwise; warmed to room temp. over 1 h; extd. with Et2O; org. layer collected; washed with H2O; dried (Na2SO4); solvent removed under reduced pressure; bromoferrocene contaminated withferrocene (10%); | A n/a B 95% |
| Conditions | Yield |
|---|---|
| With C26H46ClO3Ru2S2(1+)*CF3O3S(1-); hydrogen In water at 20℃; under 760.051 Torr; for 1.2h; Catalytic behavior; Temperature; Reagent/catalyst; Inert atmosphere; Schlenk technique; | A 95% B n/a |
| With [(pentamethylcyclopentadienyl)Ru{PhP(C6H4-o-S)2}Ru(pentamethylcyclopentadienyl)](OTf)2; hydrogen In water at 20℃; under 760.051 Torr; for 20h; | A 87% B 86% |
| With [η5-C5Me5Ru(μ-SiPr)2Ru(OH2)-η5-C5Me5](OTf)2; hydrogen In methanol at 20℃; under 760.051 Torr; for 1.4h; Temperature; Reagent/catalyst; Solvent; Pressure; Schlenk technique; |
-
-
102-54-5
ferrocene
| Conditions | Yield |
|---|---|
| With tetramethylpiperidine; H2; Cp*Ru(dppf)H In acetone (Ar);; concn., extn. (hexanes); | 94% |
| With 1,7-dilithio-m-carborane In cyclohexane byproducts: LiPF6, m-carborane; (N2 or Ar); heated at 80°C for 24 h; quenched with wet n-hexane, passed through silica gel, washed (ether), the org. portions combined, evapd. (vac.), flash-chromd. (silica gel, n-hexane); | 49% |
| With sodium benzotriazolide In tetrahydrofuran at 20°C; |
| Conditions | Yield |
|---|---|
| In acetonitrile 20 °C; variable temp. NMR; | A n/a B 94% |
| Conditions | Yield |
|---|---|
| In dichloromethane; acetonitrile Irradiation (UV/VIS); addn. of diiron-complex dissolved in CH2Cl2/CH3CN to a photolysis tube, purging with N2 for 30 min, irradiation under intense visible light (Xenon lamp) for 4 h; concn. by evapn. under reduced pressure, column chromy., elution (hexane) gives yellow band of ferrocene, elution (hexane/CHCl3) gives benzene-compd., evapn. to dryness, elem. anal.; | A n/a B 94% |
| Conditions | Yield |
|---|---|
| With trifluorormethanesulfonic acid at 25℃; for 8h; Reagent/catalyst; Temperature; Inert atmosphere; | 100% |
| With aluminium trichloride | 25% |
| With AlCl3 | 25% |
| aluminium trichloride In carbon disulfide |
-
-
102-54-5
ferrocene
| Conditions | Yield |
|---|---|
| With hydrogenchloride; oxygen; iron(III) chloride In diethyl ether passing O2 through mixt. of ferrocene in ether and FeCl3 in aq. HCl;; | 100% |
| With FeCl3; O2; HCl In diethyl ether passing O2 through mixt. of ferrocene in ether and FeCl3 in aq. HCl;; | 100% |
| With sulfuryl dichloride In benzene in boiling benzene, equimolar amt. of ferrocene and SO2Cl2;; | 97% |
| Conditions | Yield |
|---|---|
| In water molar ratio cyclodextrin : ferrocene = 1:4, addn. of crystals of ferrocene to an aq. soln. of cyclodextrin at 60°C with stirring; washed with water, dried in vac., washed with THF, recrystn. from water or aq. alcohol; elem. anal.; | 100% |
| In ethanol; water molar ratio cyclodextrin : ferrocene = 2:1, an aq. alcohol soln. of cyclodextrin (40% ethanol) was mixed with an aq. alcohol soln. of ferrocene (60% ethanol); addn. of water and/or partial removal of ethanol by evapn.; elem. anal.; | 85% |
| In ethanol; water molar ratio cyclodextrin : ferrocene = 1:1, addn. of aq. soln. of cyclodextrin to an alcohol soln. of ferrocene with stirring and heating; elem. anal.; | 56% |
| In ethanol; water molar ratio cyclodextrin : ferrocene = 1:1, addn. of aq. soln. of cyclodextrin to an alcohol soln. of ferrocene with stirring and heating; elem. anal.; | 36% |
-
-
102-54-5
ferrocene
-
A
-
12125-80-3
ferrocenium
| Conditions | Yield |
|---|---|
| In not given stoichiometric amt.; | A n/a B 100% |
-
-
102-54-5
ferrocene
-
-
152602-97-6
2-methyl-4,6-bisferrocenyl pyridine
| Conditions | Yield |
|---|---|
| Stage #1: ferrocene With potassium tert-butylate In tetrahydrofuran Inert atmosphere; Schlenk technique; Stage #2: With tert.-butyl lithium In tetrahydrofuran; pentane at -30℃; for 1h; Inert atmosphere; Stage #3: 2-ferrocenyl-6-methyl-pyridin-4-yl nonaflate Further stages; | 100% |
| Conditions | Yield |
|---|---|
| With eosin In acetonitrile at 20℃; for 2h; Inert atmosphere; Schlenk technique; Irradiation; regioselective reaction; | 100% |
| Conditions | Yield |
|---|---|
| at -196 - 20℃; Sealed tube; | 100% |
| Conditions | Yield |
|---|---|
| With 4,4'-bipyridine at 150℃; for 48h; Reagent/catalyst; | 100% |
| Conditions | Yield |
|---|---|
| In dichloromethane soln. of (HgC6F5)3 (0.096 mol) in CH2Cl2 mixed with soln. ferrocene (0.538 mol) in CH2Cl2; crystd. by slow evapn. of solvent; crystals washed (hexane); elem. anal.; | 99% |
| In dichloromethane no react. in CH2Cl2 soln.; (199)Hg NMR; | 0% |
-
-
102-54-5
ferrocene
-
-
700-12-9
pentamethylbenzene,
-
-
112596-54-0
{(Cp)iron(II)(η6-pentamethylbenzene)}(PF6)
| Conditions | Yield |
|---|---|
| With aluminium trichloride; aluminium In neat (no solvent) ferrocene, Al-powder and AlCl3 are ground in a mortar, the arene is added and mixt. is reground, rapidly transferred to a microwave app. (react. time 3 min) and heated; complex is isolated by adding water and pptg. with HPF6 from the aq. soln.; | 99% |
| With aluminium trichloride; water; aluminium In not given treatment of ferrocene with benzene deriv. in presence of aluminium, AlCl3 and 1 equiv. of water at 100°C; Hamon J.R., Astruc D., MichaudP., J. Am. Chem. Soc., 1981, 103, 758-766; treatment with aq. ammonia, treatment with HPF6; |
-
-
135348-57-1
ferricenium tetrakis(pentafluorophenyl)borate
-
A
-
102-54-5
ferrocene
| Conditions | Yield |
|---|---|
| In diethyl ether for 0.5h; Inert atmosphere; Schlenk technique; Glovebox; | A 80% B 97% |
| Conditions | Yield |
|---|---|
| With trichlorophosphate In perchloric acid; diethyl ether aq. HClO4 addn. to ferrocene, carbonyl compd. and POCl3 (room temp., over 2 h), addn. of ether, standing (15 h), pptn.; collection (filtration), washing (ether); elem. anal.; | 99% |
| Conditions | Yield |
|---|---|
| With aluminium chloride In dichloromethane ferrocene (1.0 equiv.) added to a stirred suspension of benzoyl chloride(2.2 equiv.) and aluminium chloride (2.2 equiv.) in dichloromethane, st irred at room temp. overnight (16 h); washed with water, organic layer passed through a plug of alumina, washed with chloroform, washings concentrated in vacuo, crude product purified by flash column chromy. on silica gel (TLC Rf 0.26 (1:1 ether-hexane)), elem. anal.; | 99% |
| With aluminium trichloride In dichloromethane to suspn. of AlCl3 in CH2Cl2 ligand was added, soln. of Fe-complex in CH2Cl2 was added, stirred for 3 ds at room temp. under Ar; aq. soln. of NaHCO3 was added, extd. with CH2Cl2, washed with aq. NaHCO3, dried over MgSO4, concd. under reduced pressure, column chromy. on silica gel with pentane-Et2O; elem. anal.; | 87% |
| With aluminium trichloride; benzoyl chloride In dichloromethane soln. of C6H5COCl and AlCl3 in dry CH2Cl2 was added dropwise over a period of 1 h to a stirred soln. of ferrocene in dry CH2Cl2; soln. was refluxed for 30 min, hydrolized with 0.1 M HCl, product worked up; solid chromd. on alumina using benzene, following by ether ewluant; | 86% |
| With aluminum (III) chloride In dichloromethane at 0℃; for 0.5h; Inert atmosphere; Schlenk technique; | 75% |
| With AlCl3 In dichloromethane |
| Conditions | Yield |
|---|---|
| With trichlorophosphate In perchloric acid; diethyl ether aq. HClO4 addn. to ferrocene, carbonyl compd. and POCl3 (room temp., over 1 h), addn. of ether, standing (15 h), pptn.; collection (filtration), washing (ether); elem. anal.; | 99% |
-
-
102-54-5
ferrocene
-
-
13821-31-3
<33>(1,3,5)-cyclophane
| Conditions | Yield |
|---|---|
| With aluminium trichloride; aluminium In decalin Ar-atmosphere; heating cyclophane with excess of Fe-complex, AlCl3 and Al (160°C, 2 h), cooling in ice bath, washing aq. layer (Et2O), filtration, addn. of excess of aq. NH4PF6 (pptn.); filtration, drying (vac., room temp.); elem. anal.; | 99% |
-
-
102-54-5
ferrocene
-
-
212846-49-6
(C5H5)2Fe(1+)*Co(C27H34N4O4)(1-)=[(C5H5)2Fe][Co(C27H34N4O4)]
| Conditions | Yield |
|---|---|
| In cyclohexane excess Cp2Fe (pptn.); centrifugation; | 99% |
-
-
102-54-5
ferrocene
-
-
212846-59-8
(C5H5)2Fe(1+)*Co(C27H32Cl2N4O4)(1-)=[(C5H5)2Fe][Co(C27H32Cl2N4O4)]
| Conditions | Yield |
|---|---|
| In cyclohexane excess Cp2Fe (pptn.); centrifugation; | 99% |
| Conditions | Yield |
|---|---|
| In dichloromethane Irradiation (UV/VIS); irradiation (visible light, 250 W luminescence lamp), 0°C, 1 h, intense stirring; soln. concentrating in vacuum, residue washing repeatedly by petroleum ether, vacuum drying; elem. anal.; | 99% |
| Conditions | Yield |
|---|---|
| In methanol; diethyl ether; water addn. of soln. of ferocene (in Et2O) to soln. of Hg-salt (in MeOH), stirring (ambient temp., 15 - 30 min), pouring into ice H2O, satd. with NaCl, stirring (2 h); filtration, washing, (15 % aq. KI, satd. aq. NaCl, H2O, EtOH and ether),drying; elem. anal.; | 99% |
| In methanol; water 50°C; addn. of soln. of ferocene (in Et2O) to soln. of Hg-salt (in MeOH), stirring (ambient temp., 15 - 30 min), pouring into ice H2O, satd. with NaCl, stirring (2 h); filtration, washing, (15 % aq. KI, satd. aq. NaCl, H2O, EtOH and ether),drying; elem. anal.; | 99% |
| In methanol; water addn. of ferocene to soln. of Hg-salt (in MeOH), stirring (ambient temp., 15 - 30 min), pouring into ice H2O, satd. with NaCl, stirring (2 h); filtration, washing, (15 % aq. KI, satd. aq. NaCl, H2O, EtOH and ether),drying; | 99% |
-
-
102-54-5
ferrocene
-
-
132278-01-4
(E)-4,4-dimethyl-2-pentenoyl chloride
| Conditions | Yield |
|---|---|
| With AlCl3 In dichloromethane under N2; CH2Cl2 added with stirring to mixt. of Fe complex and AlCl3 (molar ratio 1:1); cooled to -78°C; soln. of t-BuCHCHC(O)Cl (1 equiv.) in CH2Cl2 added dropwise over 30 min; warmed slowly to room temp. over 20 min; quenched by dropwise addition of satd. aq. soln. of Na2S2O4; org. layer sepd.; washed with water and satd. aq. NaCl in air; dried (MgSO4); soln.filtered; volatiles removed in vac.; recrystd. from satd. soln. in hexa ne-Et2O at -30°C; elem. anal.; | 99% |
| Conditions | Yield |
|---|---|
| With aluminum (III) chloride In dichloromethane at 0 - 20℃; for 0.25h; Friedel-Crafts Acylation; Inert atmosphere; Schlenk technique; | 99% |
| With aluminum (III) chloride In dichloromethane at 20℃; for 3h; Inert atmosphere; | 0.243 g |
| Friedel-Crafts Acylation; |
-
-
102-54-5
ferrocene
-
-
26842-85-3
bis(nonafluoro-tert-butyl) peroxide
| Conditions | Yield |
|---|---|
| at 20℃; Schlenk technique; | 99% |
| Schlenk technique; Inert atmosphere; | 99% |
| Conditions | Yield |
|---|---|
| Stage #1: N-methyl-N-phenylformamide With trichlorophosphate at 0℃; for 0.25h; Stage #2: ferrocene at 20℃; Inert atmosphere; | 98% |
| With phosphorus oxychloride In neat (no solvent) anilide and P-compd. stirring at room temp. for 30 min, Fe-compd. addn.,mixt. stirring at room temp. for 3 d, quenching by pouring onto ice, aq . layer extn. after 2 h with Et2O, org. layer drying (MgSO4), vac. concn.; residue flash column chromy. (SiO2, petrol/E2O 7:3 to 5:5), recrystn. (hot petroleum); | 87% |
| With trichlorophosphate In neat (no solvent) Vilsmeyer formylation; double mol amt. of formylation mixt., few days at ambient temp.;; | 81% |
| Conditions | Yield |
|---|---|
| With boron trifluoride diethyl etherate In dichloromethane ferrocene and 2 equivs. of acid anhydride suspended in CH2Cl2 and cooledto 0°C, boron trifluoride etherate added over 10 min, stirred at room temp. for 3 h; poured into ice H2O, sepd., the org. layer washed (satd. NaHCO3 soln.), dried (MgSO4), solvent-removed, flash-chromd. (SiO2, cyclohexane/EtOAc); | 98% |
| With aluminum (III) chloride In chloroform at 4 - 40℃; for 1h; Friedel-Crafts Acylation; | 87% |
| With polyphosphoric acid In propionic acid anhydride Ar-atmosphere; addn. of excess of anhydride to Fe-complex soln., addn. of polyphosphoric acid, heating to 100°C for 15 min; pouring into ice water, neutralization (aq. Na2CO3), extn. into ether, washing of org. phase (H2O), drying (MgSO4), filtration, concn. (vac.), chromy. (SiO2, ether/pentane=1:3); | 80% |
| Conditions | Yield |
|---|---|
| With boron trifluoride diethyl etherate In dichloromethane ferrocene and 2 equivs. of acid anhydride suspended in CH2Cl2 and cooledto 0°C, boron trifluoride etherate added over 10 min, stirred at room temp. for 3 h; poured into ice H2O, sepd., the org. layer washed (satd. NaHCO3 soln.), dried (MgSO4), solvent-removed, flash-chromd. (SiO2, cyclohexane/EtOAc);obtained as oil; | 98% |
| With aluminum (III) chloride In chloroform at 4 - 40℃; for 1h; Friedel-Crafts Acylation; | 84% |
| With aluminum oxide In dichloromethane stirring (30 min); extraction (water, Et2O), chromy.; | 60% |
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