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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Tris(2-methylphenyl)phosphine Manufacturer/High quality/Best price/In stock

Cas:6163-58-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Tri(O-Tolyl)Phosphine

Cas:6163-58-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name Tris(2-methylphenyl)phosphine CAS number 66163-58-2 Assay ≥98% Appearance White crystal Capacity 200mt/year Application Organic phosphine li

Tris(2-methylphenyl)phosphine

Cas:6163-58-2

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Good quality Tri(o-tolyl)phosphine CAS 6163-58-2 Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed additives, Fine chem

Good quality Tri(o-tolyl)phosphine CAS 6163-58-2

Cas:6163-58-2

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:Whit

Tri(o-tolyl)phosphine

Cas:6163-58-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Tris(2-methylphenyl)phosphine

Cas:6163-58-2

Min.Order:1

Negotiable

Type:Other

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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesi

High purity and quality 11-(2-chlorophenyl)-7H-benzo[c]carbazole

Cas:6163-58-2

Min.Order:100 Gram

Negotiable

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 6163-58-2 Tri(o-tolyl)phosphine Manufacturer

Cas:6163-58-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Qingdao Greenchem international Trading Co.,Ltd. is the commercial company which is invested by BeiJing Greenchem Technology Co.,Ltd. in Qingdao. It takes charge of export and production promotion, as well as imports and selling relevant produc

Tris(2-methylphenyl)phosphine

Cas:6163-58-2

Min.Order:10 Gram

Negotiable

Type:Manufacturers

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ANQING CHICO PHARMACEUTICAL CO.,LTD.

High quality. Factory supply. In stock. Best price.1.Quick response within 24 hours;2.Best quality in your requirement;?3.We pay more attention on delivery time, and usually ship on time;4.Under the premise of safety and effectiveness, we can produce

TRI(2-METHYLPHENYL)PHOSPHINE

Cas:6163-58-2

Min.Order:0

Negotiable

Type:Trading Company

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Tris-(o-tolyl)-phosphine

Cas:6163-58-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

tri(2-methylphenyl)phosphine

Cas:6163-58-2

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.

TIANFU CHEM TRI-O-TOLYLPHOSPHINE

Cas:6163-58-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

Tri(o-tolyl)phosphine

Cas:6163-58-2

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 6163-58-2 with best quality

Cas:6163-58-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name Tri(o-tolyl)phosphine Synonyms Tris(2-methylphenyl)phosphine Molecular Formula C21H21P Molecular Weight 304.37 CAS 6163-58-2

Tris(2-methylphenyl)phosphine CAS:6163-58-2

Cas:6163-58-2

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

TRI-O-TOLYLPHOSPHINE CAS6163-58-2

Cas:6163-58-2

Min.Order:1 Kilogram

FOB Price: $289.0 / 499.0

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:white or off-white powder Storage:Store in sealed containers

Professional Supplier Tri(o-tolyl)phosphine 6163-58-2

Cas:6163-58-2

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Phosphine,tris(2-methylphenyl)- 6163-58-2

Cas:6163-58-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: TRI-O-TOLYLPHOSPHINE Synonyms: Tri-o-tolylphosphine ,97%;c;tri-o-tolyl phopine;Tri(o-tolyl)phosphine,Tris(o-tolyl)phosphine;tris(2-Methylphenyl)phosphane;Tri-o-tolylphosphine, 99% 1GR;Tri-o-tolylphosphine, 99% 5GR;Tris(2-Methylphe

TRI-O-TOLYLPHOSPHINE

Cas:6163-58-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

TRI-O-TOLYLPHOSPHINE/CAS: 6163-58-2

Cas:6163-58-2

Min.Order:1 Gram

FOB Price: $15.0 / 20.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Tri(o-tolyl)phosphine CAS: 6163-58-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic in

Tri(o-tolyl)phosphine CAS: 6163-58-2

Cas:6163-58-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Tri-o-tolylphosphine

Cas:6163-58-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:6163-58-2

Cas:6163-58-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Hangzhou Yunuo Chemical Co., Ltd is located in Hangzhou city China. As a global supplier in the chemical industry, Yunuochem is to create added value for customers around the world. Sticking to such business idea of "Good faith wins the business

TRI-O-TOLYLPHOSPHINE

Cas:6163-58-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Tri(O-Tolyl)Phosphine

Cas:6163-58-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Email Us: admin07@hsnm.com.cn Quick details of Tri(o-tolyl)phosphine powder product name:Tri(o-tolyl)phosphine synonym:Tri-o-tolylphosphine,97%;Tris(o-methylphenyl)phosphine;tri-o- tolylphopine;Tri(o-tolyl)phosphine,Tris(o-tolyl)phosphine;tris(2

tri(2-methylphenyl)phosphine

Cas:6163-58-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

Tri-o-tolylphosphine

Cas:6163-58-2

Min.Order:1 Kilogram

FOB Price: $6.0 / 10.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Tri-o-tolylphosphine

Cas:6163-58-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

TRIS(O-TOLYL)PHOSPHINE

Cas:6163-58-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

ethanol
64-17-5

ethanol

tris(2-tolyl)phosphane-borane(1:1)
878809-28-0

tris(2-tolyl)phosphane-borane(1:1)

A

triethyl borate
150-46-9

triethyl borate

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
Inert atmosphere; Reflux;A n/a
B 96%
2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
Stage #1: 2-methylphenyl bromide With magnesium In tetrahydrofuran Reflux; Inert atmosphere;
Stage #2: With phosphorus trichloride In tetrahydrofuran for 24h; Inert atmosphere;
89%
Stage #1: 2-methylphenyl bromide With magnesium In tetrahydrofuran at 20℃; for 0.666667h;
Stage #2: With phosphorus trichloride In tetrahydrofuran for 1.5h;
85%
Stage #1: 2-methylphenyl bromide With iodine; magnesium In tetrahydrofuran at 20℃; for 2.5h; Schlenk technique; Inert atmosphere;
Stage #2: With phosphorus trichloride In tetrahydrofuran at -40℃; for 0.5h;
Stage #3: In tetrahydrofuran; ethanol for 5h;
75%
tri-o-tolylphosphine oxide
6163-63-9

tri-o-tolylphosphine oxide

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
With chloro-trimethyl-silane; magnesium at 20℃; for 4h;89%
With aluminum (III) chloride; N,N,N,N,-tetramethylethylenediamine; tetrabutyl-ammonium chloride; tert-butylammonium hexafluorophosphate(V) In acetonitrile at 60℃; Inert atmosphere; Glovebox; Electrolysis;69%
With chloro-trimethyl-silane; tetrabutylammomium bromide; copper; zinc In acetonitrile at 45℃; Electrochemical reaction; Inert atmosphere;58%
With oxalyl dichloride; hydrogen In chloroform-d1 at 130℃; under 60006 Torr; for 18h; Reagent/catalyst;51%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
With white phosphorus; 1,3-dicyano-5-fluoro-2,4,6-tris(diphenylamino)benzene; triethylamine In acetonitrile; benzene for 24h; Inert atmosphere; Glovebox; Sealed tube; Irradiation;43%
di-m-acetato-bis{2-(diortho-tolylphosphino)benzyl-C,P}dipalladium(II)

di-m-acetato-bis{2-(diortho-tolylphosphino)benzyl-C,P}dipalladium(II)

potassium diphenylphosphine
15475-27-1, 4346-39-8

potassium diphenylphosphine

A

[2-(di-ortho-tolylphosphino)benzyl]diphenylphosphine oxide

[2-(di-ortho-tolylphosphino)benzyl]diphenylphosphine oxide

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
Stage #1: di-m-acetato-bis{2-(diortho-tolylphosphino)benzyl-C,P}dipalladium(II); potassium diphenylphosphine In tetrahydrofuran at 20℃; for 48h;
Stage #2: With air
A 2%
B 30%
di-m-chloro-bis{2-(di-ortho-tolylphosphino)benzyl-C,P}dipalladium(II)
172418-37-0, 199609-05-7

di-m-chloro-bis{2-(di-ortho-tolylphosphino)benzyl-C,P}dipalladium(II)

potassium diphenylphosphine
15475-27-1, 4346-39-8

potassium diphenylphosphine

A

[2-(di-ortho-tolylphosphino)benzyl]diphenylphosphine oxide

[2-(di-ortho-tolylphosphino)benzyl]diphenylphosphine oxide

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
Stage #1: di-m-chloro-bis{2-(di-ortho-tolylphosphino)benzyl-C,P}dipalladium(II); potassium diphenylphosphine In tetrahydrofuran at 20℃; for 48h; Schlenk technique; Inert atmosphere;
Stage #2: With air In tetrahydrofuran for 48h; Schlenk technique;
A 20%
B 2%
2-Fluorotoluene
95-52-3

2-Fluorotoluene

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
With 1-methyl-pyrrolidin-2-one; potassium hydroxide monohydrate; phosphorus at 100 - 120℃; for 1h; Reagent/catalyst; Temperature; Inert atmosphere;19%
ortho-tolylmagnesium bromide
932-31-0

ortho-tolylmagnesium bromide

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
With diethyl ether; hydrogen; phosphorus trichloride
{(pyrimidine-2-thione)(tri-ortho-tolylphosphine)copper(I) chloride}

{(pyrimidine-2-thione)(tri-ortho-tolylphosphine)copper(I) chloride}

A

{Cu(C4H3N2(S))Cl}

{Cu(C4H3N2(S))Cl}

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In chloroform Irradiation (UV/VIS); decompn. at room temp. within minutes;
{(1,3-thiazolidine-2-thione)(tri-ortho-tolylphosphine)copper(I) iodide}

{(1,3-thiazolidine-2-thione)(tri-ortho-tolylphosphine)copper(I) iodide}

A

Cu(1+)*C3H6NS(S)*I(1-) = {Cu(C3H6NS(S))I}

Cu(1+)*C3H6NS(S)*I(1-) = {Cu(C3H6NS(S))I}

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In chloroform Irradiation (UV/VIS); decompn. at room temp. within minutes;
{(1,3-thiazolidine-2-thione)(tri-ortho-tolylphosphine)copper(I) chloride}

{(1,3-thiazolidine-2-thione)(tri-ortho-tolylphosphine)copper(I) chloride}

A

Cu(1+)*C3H6NS(S)*Cl(1-) = {Cu(C3H6NS(S))Cl}

Cu(1+)*C3H6NS(S)*Cl(1-) = {Cu(C3H6NS(S))Cl}

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In chloroform Irradiation (UV/VIS); decompn. at room temp. within minutes;
{(benz-1,3-imidazoline-2-thione)(tri-ortho-tolylphosphine)copper(I) iodide}

{(benz-1,3-imidazoline-2-thione)(tri-ortho-tolylphosphine)copper(I) iodide}

A

{Cu(C7H7N2(S))I}

{Cu(C7H7N2(S))I}

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In chloroform Irradiation (UV/VIS); decompn. at room temp. within minutes;
{(1-methyl-1,3-imidazole-2-thione)(tri-ortho-tolylphosphine)copper(I) chloride}

{(1-methyl-1,3-imidazole-2-thione)(tri-ortho-tolylphosphine)copper(I) chloride}

A

Cu(1+)*C3H2N2(CH3)(S)*Cl(1-) = {Cu(C3H2N2(CH3)(S))Cl}

Cu(1+)*C3H2N2(CH3)(S)*Cl(1-) = {Cu(C3H2N2(CH3)(S))Cl}

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In chloroform Irradiation (UV/VIS); decompn. at room temp. within minutes;
{(pyrimidine-2-thione)(tri-ortho-tolylphosphine)copper(I) iodide}

{(pyrimidine-2-thione)(tri-ortho-tolylphosphine)copper(I) iodide}

A

{Cu(C4H3N2(S))I}

{Cu(C4H3N2(S))I}

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In chloroform Irradiation (UV/VIS); decompn. at room temp. within minutes;
{(quinoline-2-thione)(tri-ortho-tolylphosphine)copper(I) iodide}

{(quinoline-2-thione)(tri-ortho-tolylphosphine)copper(I) iodide}

A

{Cu(C9H6N(S))I}

{Cu(C9H6N(S))I}

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In chloroform Irradiation (UV/VIS); decompn. at room temp. within minutes;
{(pyridine-2-thione)(tri-ortho-tolylphosphine)copper(I) chloride}

{(pyridine-2-thione)(tri-ortho-tolylphosphine)copper(I) chloride}

A

{Cu(C5H4N(S))Cl}

{Cu(C5H4N(S))Cl}

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In chloroform Irradiation (UV/VIS); decompn. at room temp. within minutes;
{(1-methyl-1,3-imidazole-2-thione)(tri-ortho-tolylphosphine)copper(I) iodide}

{(1-methyl-1,3-imidazole-2-thione)(tri-ortho-tolylphosphine)copper(I) iodide}

A

Cu(1+)*C3H2N2(CH3)(S)*I(1-) = {Cu(C3H2N2(CH3)(S))I}

Cu(1+)*C3H2N2(CH3)(S)*I(1-) = {Cu(C3H2N2(CH3)(S))I}

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In chloroform Irradiation (UV/VIS); decompn. at room temp. within minutes;
{(benz-1,3-imidazoline-2-thione)(tri-ortho-tolylphosphine)copper(I) chloride}

{(benz-1,3-imidazoline-2-thione)(tri-ortho-tolylphosphine)copper(I) chloride}

A

{Cu(C7H7N2(S))Cl}

{Cu(C7H7N2(S))Cl}

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In chloroform Irradiation (UV/VIS); decompn. at room temp. within minutes;
{(pyridine-2-thione)(tri-ortho-tolylphosphine)copper(I) iodide}

{(pyridine-2-thione)(tri-ortho-tolylphosphine)copper(I) iodide}

A

{Cu(C5H4N(S))I}

{Cu(C5H4N(S))I}

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In chloroform Irradiation (UV/VIS); decompn. at room temp. within minutes;
{(quinoline-2-thione)(tri-ortho-tolylphosphine)copper(I) chloride}

{(quinoline-2-thione)(tri-ortho-tolylphosphine)copper(I) chloride}

A

{Cu(C9H6N(S))Cl}

{Cu(C9H6N(S))Cl}

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In chloroform Irradiation (UV/VIS); decompn. at room temp. within minutes;
1,1,1-trifluoro-2,4-pentanedionato(1,1,1-trifluoro-2,4-pentanedionato-O)(trio-tolylphosphine)palladium(II)

1,1,1-trifluoro-2,4-pentanedionato(1,1,1-trifluoro-2,4-pentanedionato-O)(trio-tolylphosphine)palladium(II)

Pd(CH3COCHCOCF3)2

Pd(CH3COCHCOCF3)2

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In benzene Kinetics; monitored by UV;
[(o-C6H4Me)3PH][HB(p-C6F4H)3]
1094249-98-5

[(o-C6H4Me)3PH][HB(p-C6F4H)3]

A

tris(2,3,5,6-tetrafluorophenyl)borane triethylphosphine oxide
148892-95-9

tris(2,3,5,6-tetrafluorophenyl)borane triethylphosphine oxide

B

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
at 25 - 60℃; vacuum;
[(o-C6H4Me)3PH][HB(p-C6F4H)3]
1094249-98-5

[(o-C6H4Me)3PH][HB(p-C6F4H)3]

A

tris(2,3,5,6-tetrafluorophenyl)borane triethylphosphine oxide
148892-95-9

tris(2,3,5,6-tetrafluorophenyl)borane triethylphosphine oxide

B

hydrogen
1333-74-0

hydrogen

C

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

Conditions
ConditionsYield
In neat (no solvent, solid phase) (N2); keeping boron compd. at room temp. in vac. for 4 d;
In not given (N2); heating boron compd. at 60°C for few hs;
tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

tris(2-methylphenyl)phosphine selenide
32461-51-1

tris(2-methylphenyl)phosphine selenide

Conditions
ConditionsYield
With selenium In toluene for 6h; Heating;100%
With selenium In chloroform for 5h; Heating;23%
With potassium selenocyanate In methanol at 20℃;
With selenium In toluene at 100℃; for 48h; Inert atmosphere;
With selenium In chloroform-d1 at 70℃; for 16h; Glovebox; Sealed tube; Inert atmosphere;
tetrabutylammonium chloride monohydrate

tetrabutylammonium chloride monohydrate

3-(4-amino-naphthalen-1-yl)-acrylic acid methyl ester

3-(4-amino-naphthalen-1-yl)-acrylic acid methyl ester

4-Bromo-1-naphthylamine
2298-07-9

4-Bromo-1-naphthylamine

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

3-(4-amino-1-naphthyl)propanoic acid
436864-73-2

3-(4-amino-1-naphthyl)propanoic acid

Conditions
ConditionsYield
With hydrogenchloride; sodium hydroxide; potassium acetate; Pd-C; palladium diacetate In methanol; water; N,N-dimethyl-formamide100%
With hydrogenchloride; sodium hydroxide; potassium acetate; Pd-C; palladium diacetate In methanol; water; N,N-dimethyl-formamide100%
2-methyl-6-vinylpyridine
1122-70-9

2-methyl-6-vinylpyridine

1-[(4-cyano-5-methyl-4-phenyl)hexyl]-4-[2-(2-bromophenoxy)ethyl]piperazine
255847-81-5

1-[(4-cyano-5-methyl-4-phenyl)hexyl]-4-[2-(2-bromophenoxy)ethyl]piperazine

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

1-[(4-cyano-5-methyl-4-phenyl)hexyl]-4-{2-[2-(6-methyl-2-pyridyl)vinylphenoxy]ethyl}piperazine

1-[(4-cyano-5-methyl-4-phenyl)hexyl]-4-{2-[2-(6-methyl-2-pyridyl)vinylphenoxy]ethyl}piperazine

Conditions
ConditionsYield
With triethylamine; palladium diacetate In water; N,N-dimethyl-formamide100%
tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

palladium(II) bromide

palladium(II) bromide

Pd(P(C6H4CH3)3)2(Br)2
24554-43-6, 157183-46-5

Pd(P(C6H4CH3)3)2(Br)2

Conditions
ConditionsYield
With lithium bromide In methanol N2 or Ar-atmosphere;100%
tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

(HP(o-tolyl)3)BF4

(HP(o-tolyl)3)BF4

Conditions
ConditionsYield
With tetrafluoroboric acid In diethyl ether at 20℃; Inert atmosphere;100%
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

tris(2-pyridyl)methane
77429-58-4

tris(2-pyridyl)methane

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

[Cu(tris(2-pyridyl)methane)(tri(orthotolyl)phosphine)] hexafluorophosphate

[Cu(tris(2-pyridyl)methane)(tri(orthotolyl)phosphine)] hexafluorophosphate

Conditions
ConditionsYield
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; tris(2-pyridyl)methane In dichloromethane for 0.166667h; Inert atmosphere;
Stage #2: tris-(o-tolyl)phosphine In dichloromethane at 20℃; for 12h; Inert atmosphere;
100%
tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

tri-o-tolylphosphine oxide
6163-63-9

tri-o-tolylphosphine oxide

Conditions
ConditionsYield
With dihydrogen peroxide In tetrahydrofuran; water for 0.533333h;99%
With water; Selectfluor In acetonitrile at 20℃; for 0.0833333h;99%
With fluorosulfonylchloride In dichloromethane for 1h; Ambient temperature;98%
CH2Cl2/MeOH

CH2Cl2/MeOH

4-(benzenesulfonylamino)phenyl iodide
21226-24-4

4-(benzenesulfonylamino)phenyl iodide

acrylic acid
79-10-7

acrylic acid

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

3-[4-(benzenesulfonylamino)phenyl]acrylic acid
501682-73-1

3-[4-(benzenesulfonylamino)phenyl]acrylic acid

Conditions
ConditionsYield
With triethylamine; tris-(dibenzylideneacetone)dipalladium(0) In N,N-dimethyl-formamide99%
Os3(μ-H)2(CO)10
41766-80-7

Os3(μ-H)2(CO)10

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

(μ-H)HOs3(CO)10(P(o-tolyl)3)

(μ-H)HOs3(CO)10(P(o-tolyl)3)

Conditions
ConditionsYield
In n-heptane; dichloromethane in CH2Cl2/heptane=1:10 v/v, excess phosphine, room temp. (UV-control); vol. reduction (Ar-stream), crystn. (-15°C);99%
tris(2,3,5,6-tetrafluorophenyl)borane triethylphosphine oxide
148892-95-9

tris(2,3,5,6-tetrafluorophenyl)borane triethylphosphine oxide

hydrogen
1333-74-0

hydrogen

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

[(o-C6H4Me)3PH][HB(p-C6F4H)3]
1094249-98-5

[(o-C6H4Me)3PH][HB(p-C6F4H)3]

Conditions
ConditionsYield
In not given99%
In hexane High Pressure; (N2); mixing hexane soln. of phosphine deriv. and borane deriv. in C6H5Br, freezing at -196°C, exposure to H2, warming to room temp., stirring overnight; pressure of H2 after warming to room temp. was 4 atm; evapn., recrystn. by addn. of hexanes to concd. CH2Cl2 soln. and keepingat -35°C for wk, elem. anal.;
[Pd(1-dicyclohexylphosphino-2-di-tert-butylphosphinoethylferrocene)(H)(4-methoxybenzothiolate)]
1154042-85-9, 1154049-74-7

[Pd(1-dicyclohexylphosphino-2-di-tert-butylphosphinoethylferrocene)(H)(4-methoxybenzothiolate)]

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

[Pd(1-dicyclohexylphosphino-2-di-tert-butylphosphinoethylferrocene)(P(o-tolyl)3)]
583872-37-1

[Pd(1-dicyclohexylphosphino-2-di-tert-butylphosphinoethylferrocene)(P(o-tolyl)3)]

Conditions
ConditionsYield
With sodium t-butanolate In toluene 1 h, 100°C;99%
tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

tris(2-tolyl)phosphane-borane(1:1)
878809-28-0

tris(2-tolyl)phosphane-borane(1:1)

Conditions
ConditionsYield
Stage #1: tris-(o-tolyl)phosphine With dimethylsulfide borane complex In dichloromethane at 20℃; Inert atmosphere;
Stage #2: With ammonium chloride In dichloromethane; water
99%
hydrogen tetrachloroaurate(III) tetrahydrate

hydrogen tetrachloroaurate(III) tetrahydrate

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

chloro{tris(o-tolyl)phosphine}gold(I)
28978-10-1

chloro{tris(o-tolyl)phosphine}gold(I)

Conditions
ConditionsYield
Stage #1: hydrogen tetrachloroaurate(III) tetrahydrate With propyl sulfide In ethanol at 40℃; for 0.166667h;
Stage #2: tris-(o-tolyl)phosphine In ethanol at 40℃; for 1h;
99%
tris(pentafluorophenyl)borate
1109-15-5

tris(pentafluorophenyl)borate

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

1-(4-chlorophenyl)buta-2,3-dien-1-one
196953-02-3

1-(4-chlorophenyl)buta-2,3-dien-1-one

C49H28BClF15OP

C49H28BClF15OP

Conditions
ConditionsYield
In chloroform-d1 Inert atmosphere; Glovebox;99%
ferrocenium trifluoromethanesulfonate

ferrocenium trifluoromethanesulfonate

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

A

ferrocene
102-54-5

ferrocene

B

tri(o-tolyl)phosphonium trifluoromethanesulfonate salt

tri(o-tolyl)phosphonium trifluoromethanesulfonate salt

Conditions
ConditionsYield
With C26H46ClO3Ru2S2(1+)*CF3O3S(1-); hydrogen In dichloromethane at 20℃; under 760.051 Torr; for 11h; Catalytic behavior; Inert atmosphere;A 99%
B 98%
perfluorophenyl azide
1423-15-0

perfluorophenyl azide

trityl tetrafluoroborate
341-02-6

trityl tetrafluoroborate

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

pentane
109-66-0

pentane

C46H36F5N3P(1+)*C24BF20(1-)*0.5C5H12

C46H36F5N3P(1+)*C24BF20(1-)*0.5C5H12

Conditions
ConditionsYield
Stage #1: perfluorophenyl azide; trityl tetrafluoroborate; tris-(o-tolyl)phosphine In dichloromethane at 20℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;
Stage #2: pentane
99%
2-methoxy-5-bromopyridine
13472-85-0

2-methoxy-5-bromopyridine

aqueous NaCl

aqueous NaCl

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

tert-butyl (2E)-3-(6-methoxypyridin-3-yl)prop-2-enoate
339555-37-2

tert-butyl (2E)-3-(6-methoxypyridin-3-yl)prop-2-enoate

Conditions
ConditionsYield
With sodium hypochlorite; triethylamine; palladium diacetate In toluene98.4%
copper(I) thiocyanate
1111-67-7, 15192-76-4, 26656-82-6

copper(I) thiocyanate

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

acetonitrile
75-05-8

acetonitrile

[CuSCN(tri-o-tolylphosphine)MeCN]2

[CuSCN(tri-o-tolylphosphine)MeCN]2

Conditions
ConditionsYield
In acetonitrile CuSCN ground with P(o-Tol)3 dry, then with MeCN; dried in air; detd. by IR;98.1%
In methanol CuSCN reacted with P(o-Tol)3 in MeOH for 4 h; recrystd. from MeCN; elem. anal.;80%
palladium tetraammine di(hydrogen carbonate)

palladium tetraammine di(hydrogen carbonate)

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

bis(tri-ortho-tolylphosphine)palladium(0)
69861-71-8

bis(tri-ortho-tolylphosphine)palladium(0)

Conditions
ConditionsYield
In methanol for 3h; Heating / reflux;98%
C12H10ClNPd

C12H10ClNPd

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

C21H21P*C12H10ClNPd

C21H21P*C12H10ClNPd

Conditions
ConditionsYield
In acetone at 25℃;98%
cyclohexa-1,4-diene
1165952-92-0

cyclohexa-1,4-diene

trityl tetrafluoroborate
341-02-6

trityl tetrafluoroborate

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

A

triphenylmethane
519-73-3

triphenylmethane

B

(HP(o-tolyl)3)BF4

(HP(o-tolyl)3)BF4

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;A 98%
B 97%
trityl tetrafluoroborate
341-02-6

trityl tetrafluoroborate

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

4-n-methylphenylacetylene
766-97-2

4-n-methylphenylacetylene

A

(HP(o-tolyl)3)BF4

(HP(o-tolyl)3)BF4

B

C28H22

C28H22

Conditions
ConditionsYield
In dichloromethane at 20℃; for 2h; Inert atmosphere; Schlenk technique; Glovebox;A 92%
B 98%
tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

C21H21OP*H2O2

C21H21OP*H2O2

Conditions
ConditionsYield
With dihydrogen peroxide In dichloromethane; water at 0 - 23℃; for 0.5h; Inert atmosphere; Schlenk technique;98%
3-oxo-4-(2(benzyloxy)ethyl)-8-(trifluoromethanesulfonlyloxy)-3,4-dihydro-2H-1,4-benzoxazine

3-oxo-4-(2(benzyloxy)ethyl)-8-(trifluoromethanesulfonlyloxy)-3,4-dihydro-2H-1,4-benzoxazine

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

methyl (E)-3-(3-oxo-4-(2-(benzyloxy)ethyl)-3,4-dihydro-2H-1,4-benzoxazin-8-yl)acrylate
258532-94-4

methyl (E)-3-(3-oxo-4-(2-(benzyloxy)ethyl)-3,4-dihydro-2H-1,4-benzoxazin-8-yl)acrylate

Conditions
ConditionsYield
With triethylamine; lithium chloride; palladium diacetate In N,N-dimethyl-formamide97%
aqueous DMF

aqueous DMF

4-bromocyclobutabenzene

4-bromocyclobutabenzene

[(4-benzocyclobutenyl)vinyl] phenol

[(4-benzocyclobutenyl)vinyl] phenol

[(4-benzocyclobutenyl)-vinyl] phenyl acetate

[(4-benzocyclobutenyl)-vinyl] phenyl acetate

p-acetoxystyrene
2628-16-2

p-acetoxystyrene

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

[(4-cyclobutenyl)vinyl] phenol

[(4-cyclobutenyl)vinyl] phenol

Conditions
ConditionsYield
With potassium acetate; palladium diacetate In water; N,N-dimethyl-formamide97%
tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

palladium(II) iodide

palladium(II) iodide

[Pd(P(C6H4CH3)3)I2]2
176725-01-2

[Pd(P(C6H4CH3)3)I2]2

Conditions
ConditionsYield
With lithium iodide In methanol N2 or Ar-atmosphere; refluxing (30 min); filtering (room temp.), washing (MeOH, Et2O), drying (vac.); elem. anal.;97%
[Pd(μ-Cl)(Cl)(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)]2

[Pd(μ-Cl)(Cl)(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)]2

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

[PdCl2(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)(P(o-tolyl)3)]

[PdCl2(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)(P(o-tolyl)3)]

Conditions
ConditionsYield
In dichloromethane at 20℃; Schlenk technique; Inert atmosphere; Glovebox;97%
1,2-bis(2-phenylethynyl)benzene
13203-60-6

1,2-bis(2-phenylethynyl)benzene

tris(pentafluorophenyl)borate
1109-15-5

tris(pentafluorophenyl)borate

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

C21H21P*C38H13BF15S(1-)*H(1+)

C21H21P*C38H13BF15S(1-)*H(1+)

Conditions
ConditionsYield
In pentane at 20℃;97%
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

2-(2-quinolyl)benzimidazole
14044-48-5

2-(2-quinolyl)benzimidazole

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

C37H32CuN3P(1+)*F6P(1-)

C37H32CuN3P(1+)*F6P(1-)

Conditions
ConditionsYield
In dichloromethane97%
2-(2-fluoropyridin-1-ium-1-yl)-1,1-bis((trifluoromethyl)sulfonyl)ethan-1-ide
1469887-23-7

2-(2-fluoropyridin-1-ium-1-yl)-1,1-bis((trifluoromethyl)sulfonyl)ethan-1-ide

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

2-(tri-o-tolylphosphonio)-1,1-bis((trifluoromethyl)sulfonyl)ethan-1-ide

2-(tri-o-tolylphosphonio)-1,1-bis((trifluoromethyl)sulfonyl)ethan-1-ide

Conditions
ConditionsYield
In acetonitrile at 20℃; for 0.25h; Inert atmosphere;97%

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