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SEASONS BIOTECHNOLOGY CO., LTD

1. High-quality products, cost-effective prices, best reputation and professional services. 2. Strong technology team and service team, Professional data management system. 3. Professional synthesis and formulations laboratory and production

2,4-Dimethylthiophenol

Cas:13616-82-5

Min.Order:1 Gram

Negotiable

Type:

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2,4-Dimethylbenzenethiol

Cas:13616-82-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2,4-Dimethylbenzenethiol supplier in China

Cas:13616-82-5

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2,4-dimethylbenzenethiol

Cas:13616-82-5

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2,4-Dimethylbenzenethiol

Cas:13616-82-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

2,4-Dimethylbenzenethiol Basic information Product Name: 2,4-Dimethylbenzenethiol Synonyms: 2,4-dimethyl-benzenethio;2,4-DIMETHYLTHIOPHENOL;2,4-DIMETHYLBENZENETHIOL

13616-82-5

Cas:13616-82-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2,4-Dimethylbenzenethiol

Cas:13616-82-5

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 13616-82-5 with competitive price

Cas:13616-82-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, in

2,4-Dimethylbenzenethiol

Cas:13616-82-5

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzenethiol,2,4-dimethyl- 13616-82-5

Cas:13616-82-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 2,4-Dimethylbenzenethiol CAS: 13616-82-5 MF: C8H10S MW: 138.23 EINECS: 237-100-0 Mol File: 13616-82-5.mol 2,4-Dimethylbenzenethiol Structure 2,4-Dimethylbenzenethiol Chemical Properties Melting point -30°C (e

2,4-Dimethylbenzenethiol

Cas:13616-82-5

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Chem Industries, 2,4-Dimethylbenzenethiol CAS:13616-82-5

Cas:13616-82-5

Min.Order:1 Kilogram

FOB Price: $42.8 / 48.3

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

2,4-Dimethylbenzenethiol CAS:13616-82-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

2,4-Dimethylbenzenethiol CAS:13616-82-5

Cas:13616-82-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzenethiol,2,4-dimethyl-

Cas:13616-82-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2,4-Dimethyl thiophenol

Cas:13616-82-5

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2,4-DIMETHYLBENZENETHIOL

Cas:13616-82-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2,4-Dimethylthiophenol

Cas:13616-82-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Send Pharmaceutical Technology Co., Ltd.

low price high quality high purity good sevice stock Appearance:white Storage:Preserve In Well-Closed, Light-Resistant and Tight Containers. Store In Cool & Dry Place Package:1g、5g、10g…1kg、5kg… Application:Pharmaceutical intermediates Trans

2,4-Dimethylbenzenethiol

Cas:13616-82-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2,4-Dimethylbenzenethiol/High quality/Best price

Cas:13616-82-5

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

cas:13616-82-5

Cas:13616-82-5

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

2,4-Dimethylbenzenethiol manufacturerAppearance:White powder Storage:keep sealed and keep from direct light Package:according to customers' requirements Application:pharmaceutical Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB

2,4-Dimethylbenzenethiol manufacturer

Cas:13616-82-5

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity 2,4-Dimethylbenzenethiol

Cas:13616-82-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2,4-Dimethyl thiophenol

Cas:13616-82-5

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2,4-Dimethylbenzenethiol

Cas:13616-82-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2,4-Dimethyl thiophenol

Cas:13616-82-5

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2,4-Dimethylthiophenol

Cas:13616-82-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

LIDE PHARMACEUTICALS LIMITED

LIDE PHARMACEUTICALS LIMITED is a professional leading manufacturer of chemicals and APIs in China. Our core business line covers APIs, Intermediates, Flavours and fragrances, Specialty chemicals, Dietary additives etc.We are specialized in chemical

2,4-Dimethylbenzenethiol

Cas:13616-82-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

2,4-Dimethylbenzenethiol

Cas:13616-82-5

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2,4-Dimethyl thiophenol

Cas:13616-82-5

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2,4-Dimethyl thiophenol cas no. 13616-82-5 98%

Cas:13616-82-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2,4-dimethylbenzenesulfonyl chloride
609-60-9

2,4-dimethylbenzenesulfonyl chloride

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Conditions
ConditionsYield
With ISOPROPYLAMIDE; dimethylsilicon dichloride; zinc In 1,2-dichloro-ethane at 75℃; for 1.5h;95%
With sulfuric acid; zinc In water 1.) 0 deg C, 1 h, 2.) reflux, 6 h;69%
With sulfuric acid; zinc
With sulfuric acid; zinc
Multi-step reaction with 3 steps
1: sodium hydrogensulfite; sodium hydroxide / water / 3 h / 40 - 50 °C / pH 6 / Inert atmosphere
2: sulfur dioxide / water / 8 h / 115 °C / Inert atmosphere
3: sodium tetrahydroborate; sodium hydroxide / water; ethanol / 3 h / 78 - 80 °C / Inert atmosphere
View Scheme
2,4-dimethylphenyl ethyl xanthate
89816-81-9

2,4-dimethylphenyl ethyl xanthate

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether for 3h; Heating;93%
With potassium hydroxide In ethanol at 76 - 78℃;8.2 g
2,2'-dipyridyldisulphide
2127-03-9

2,2'-dipyridyldisulphide

2,4-dimethylbenzenesulfonic acid
88-61-9

2,4-dimethylbenzenesulfonic acid

triphenylphosphine
603-35-0

triphenylphosphine

A

2-Mercaptopyridine
2637-34-5

2-Mercaptopyridine

B

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

C

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

Conditions
ConditionsYield
In benzene for 2h; Product distribution; Mechanism; Heating; further reaction partners - various diaryl disulfides;A n/a
B 92%
C 88%
1,2-bis(2,4-dimethylphenyl)disulfane
13616-83-6

1,2-bis(2,4-dimethylphenyl)disulfane

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Conditions
ConditionsYield
With sodium tetrahydroborate; sodium hydroxide In ethanol; water at 78 - 80℃; for 3h; Inert atmosphere;90.4%
m-xylene-4-sulphonic acid sodium salt
827-21-4

m-xylene-4-sulphonic acid sodium salt

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Conditions
ConditionsYield
With triphenylphosphine; 18-crown-6 ether; iodine In benzene for 41h; Heating;63%
With 18-crown-6 ether; iodine; triphenylphosphine In benzene for 41h; Heating;63%
2,4-dimethyl-benzenesulfinic acid
45869-23-6

2,4-dimethyl-benzenesulfinic acid

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Conditions
ConditionsYield
With sulfuric acid; zinc
2,4-Xylidine
95-68-1

2,4-Xylidine

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Conditions
ConditionsYield
(i) aq. NaNO2, aq. HCl, (ii) potassium ethylxanthate, (iii) KOEt, EtOH; Multistep reaction;
(i) NaNO2, aq. HCl, (ii) aq. EtOCS2K; Multistep reaction;
Multi-step reaction with 2 steps
1: 1. conc. hydrochloric acid, NaNO2; / 1. 0 degC, 30min.; 2. 40 - 45 degC
2: 93 percent / LiAlH4 / diethyl ether / 3 h / Heating
View Scheme
Multi-step reaction with 2 steps
1.1: hydrogenchloride; sodium nitrite / water / 1 h / 0 - 5 °C
1.2: 2 h
2.1: potassium hydroxide / ethanol / 76 - 78 °C
View Scheme
2,4-dimethylbenzenesulfonic acid
88-61-9

2,4-dimethylbenzenesulfonic acid

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Conditions
ConditionsYield
With diphosphorus pentasulfide; lithium aluminium tetrahydride 1.) sulfolane, 90 deg C for 24 h 2.) ether, room temperature for 30 min; Yield given. Multistep reaction;
1-bromo-2,4-dimethylbenzene
583-70-0

1-bromo-2,4-dimethylbenzene

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Conditions
ConditionsYield
With sulfur; magnesium 1.) ether; Multistep reaction;
potassium ethyl xanthogenate
140-89-6

potassium ethyl xanthogenate

diazonium chloride from 4-amino-1.3-dimethyl-benzene

diazonium chloride from 4-amino-1.3-dimethyl-benzene

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Conditions
ConditionsYield
Verseifen des Reaktionsprodukts mit alkoh. Kali;
m-xylene
108-38-3

m-xylene

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: chlorosulfonic acid / CHCl3 / 1 h / -5 - 20 °C
2: 69 percent / Zn, H2SO4 / H2O / 1.) 0 deg C, 1 h, 2.) reflux, 6 h
View Scheme
m-xylene
108-38-3

m-xylene

air

air

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: ClSO3H
2: Zn, aq. H2SO4
View Scheme
bis(2,4-dimethylphenylthiomethyl)-(1-methylbenzimidazol-2-ylmethyl)amine
1442637-86-6

bis(2,4-dimethylphenylthiomethyl)-(1-methylbenzimidazol-2-ylmethyl)amine

A

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

B

bis((2,4-dimethylphenyl)thio)methane
1266253-61-5

bis((2,4-dimethylphenyl)thio)methane

C

1,2-bis(2,4-dimethylphenyl)disulfane
13616-83-6

1,2-bis(2,4-dimethylphenyl)disulfane

Conditions
ConditionsYield
With copper(II) perchlorate hexahydrate In [D3]acetonitrile Mechanism;
sodium 2,4-dimethylbenzenesulfinate

sodium 2,4-dimethylbenzenesulfinate

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sulfur dioxide / water / 8 h / 115 °C / Inert atmosphere
2: sodium tetrahydroborate; sodium hydroxide / water; ethanol / 3 h / 78 - 80 °C / Inert atmosphere
View Scheme
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

4-chlorobenzonitrile
100-00-5

4-chlorobenzonitrile

(2,4-dimethylphenyl)(4-nitrophenyl)sulfane
105456-67-5

(2,4-dimethylphenyl)(4-nitrophenyl)sulfane

Conditions
ConditionsYield
With 2.9-dimethyl-1,10-phenanthroline; sodium t-butanolate; La0.9Ce0.1Co0.6Cu0.4O3 In toluene at 110℃; for 48h; Ullmann reaction; microwave irradiation;100%
With sodium ethanolate In ethanol for 3h; Heating;68%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

2-Chloronitrobenzene
88-73-3

2-Chloronitrobenzene

2,4-dimethyl-1-[(2-nitro-phenyl)-sulfanyl]-benzene

2,4-dimethyl-1-[(2-nitro-phenyl)-sulfanyl]-benzene

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water at 50℃; for 5h;100%
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 2.5h; Inert atmosphere;99.79%
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere;97%
4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

1-(4-Fluoro-phenylsulfanyl)-2,4-dimethyl-benzene

1-(4-Fluoro-phenylsulfanyl)-2,4-dimethyl-benzene

Conditions
ConditionsYield
With 2.9-dimethyl-1,10-phenanthroline; sodium t-butanolate; La0.9Ce0.1Co0.6Cu0.4O3 In toluene at 110℃; for 48h; Ullmann reaction; microwave irradiation;100%
With bismuth(III) oxide; N,N-dimethylethylenediamine; potassium hydroxide In water at 100℃; for 26h; chemoselective reaction;84%
1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

(2′-bromophenyl)(2,4-dimethylphenyl)sulfane
960203-41-2

(2′-bromophenyl)(2,4-dimethylphenyl)sulfane

Conditions
ConditionsYield
With copper(l) iodide; 2.9-dimethyl-1,10-phenanthroline; sodium t-butanolate In toluene at 110℃; Solvent; Temperature; Reagent/catalyst;100%
With potassium phosphate; copper(l) iodide In isopropyl alcohol at 80 - 90℃; Concentration; Inert atmosphere;100%
With potassium tert-butylate; bis[2-(diphenylphosphino)phenyl] ether; bis(dibenzylideneacetone)-palladium(0) In toluene at 0 - 100℃; for 9.08333h; Product distribution / selectivity;100%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

acetyl chloride
75-36-5

acetyl chloride

S-(2,4-dimethylphenyl) ethanethioate
94602-20-7

S-(2,4-dimethylphenyl) ethanethioate

Conditions
ConditionsYield
With pyridine In dichloromethane at 5 - 15℃; for 1h;100%
With pyridine In dichloromethane at 0 - 25℃; for 2.16667h;57%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

2,4-dimethylbenzenesulphenyl chloride
74880-42-5

2,4-dimethylbenzenesulphenyl chloride

Conditions
ConditionsYield
With trichloroisocyanuric acid In ethyl acetate at 0℃; for 1h;99%
With trichloroisocyanuric acid In ethyl acetate at 0℃; for 1h;99%
With N-chloro-succinimide In dichloromethane for 2h; Ambient temperature;75%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

1,2-bis(2,4-dimethylphenyl)disulfane
13616-83-6

1,2-bis(2,4-dimethylphenyl)disulfane

Conditions
ConditionsYield
With (tetrabenzoporphinato)iron(II) In tetrahydrofuran at 20℃; under 760.051 Torr; for 0.333333h;99%
With sodium hydrogencarbonate; benzenesulfonyl chloride In water at 20℃; for 0.166667h;98%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In chloroform at 20℃; for 1h; Inert atmosphere;93%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

para-bromoacetophenone
99-90-1

para-bromoacetophenone

1-[4-(2,4-dimethyl-phenylsulfanyl)-phenyl]-ethanone

1-[4-(2,4-dimethyl-phenylsulfanyl)-phenyl]-ethanone

Conditions
ConditionsYield
With 2.9-dimethyl-1,10-phenanthroline; sodium t-butanolate; La0.9Ce0.1Co0.6Cu0.4O3 In toluene at 110℃; for 48h; Ullmann reaction; microwave irradiation;99%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

tert-butyl (2-oxo-1-propylindolin-3-ylidene)carbamate

tert-butyl (2-oxo-1-propylindolin-3-ylidene)carbamate

tert-butyl (3-((2,4-dimethylphenyl)thio)-2-oxo-1-propylindolin-3-yl)carbamate

tert-butyl (3-((2,4-dimethylphenyl)thio)-2-oxo-1-propylindolin-3-yl)carbamate

Conditions
ConditionsYield
With C12H15CoN2O6(1-)*K(1+) In dichloromethane at 20℃; for 0.0833333h; Schlenk technique; Green chemistry;99%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

rac-2-(2-bromophenyl)-1-tosylaziridine
200803-17-4

rac-2-(2-bromophenyl)-1-tosylaziridine

3-(2,4-dimethylphenylthio)-1-tosylindoline
1429656-45-0

3-(2,4-dimethylphenylthio)-1-tosylindoline

Conditions
ConditionsYield
Stage #1: 2,4-dimethyl-thiophenol; rac-2-(2-bromophenyl)-1-tosylaziridine With potassium carbonate In toluene at 20℃; for 0.416667h; Inert atmosphere;
Stage #2: With palladium diacetate; potassium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 110 - 115℃; for 4h; Inert atmosphere;
98%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

2,4-dimethyl-1-[(2-nitro-phenyl)-sulfanyl]-benzene

2,4-dimethyl-1-[(2-nitro-phenyl)-sulfanyl]-benzene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 25℃; for 2.5h;98%
Stage #1: 2,4-dimethyl-thiophenol With potassium carbonate In N,N-dimethyl-formamide at 25℃;
Stage #2: ortho-nitrofluorobenzene In N,N-dimethyl-formamide at 25℃; for 2.5h;
98%
With tetrabutylammomium bromide; potassium hydroxide In water at 20℃; for 10h; Reagent/catalyst;96%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

methyl 2-butoxy-6-methyl-3,4-dihydro-2H-pyran-5-carboxylate
1266617-35-9

methyl 2-butoxy-6-methyl-3,4-dihydro-2H-pyran-5-carboxylate

methyl 2-acetyl-5,5-bis((2,4-dimethylphenyl)thio)pentanoate
1266617-45-1

methyl 2-acetyl-5,5-bis((2,4-dimethylphenyl)thio)pentanoate

Conditions
ConditionsYield
With manganese(II) bromide In nitromethane at 80℃; for 6h;97%
1-chloro-2-fluorobenzene
348-51-6

1-chloro-2-fluorobenzene

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

(2-chlorophenyl)(2,4-dimethylphenyl)sulfane

(2-chlorophenyl)(2,4-dimethylphenyl)sulfane

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 120℃; for 72h; Reagent/catalyst; Temperature; Inert atmosphere;97%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

C26H25NO2S

C26H25NO2S

A

C26H25NO2S

C26H25NO2S

B

C26H25NO2S

C26H25NO2S

Conditions
ConditionsYield
With n-butyllithium; C23H25NO2 In 5,5-dimethyl-1,3-cyclohexadiene; benzene at -20℃; enantioselective reaction;A 97%
B n/a
formaldehyd
50-00-0

formaldehyd

2-(phenylsulfonyl)acetophenone
3406-03-9

2-(phenylsulfonyl)acetophenone

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

3-[(2,4-dimethylphenyl)thio]-1-phenyl-2-(phenylsulfonyl)propan-1-one
1370551-06-6

3-[(2,4-dimethylphenyl)thio]-1-phenyl-2-(phenylsulfonyl)propan-1-one

Conditions
ConditionsYield
With D-gluconic acid; 1-deoxy-1-(methylamino)-D-glucitol In water at 100℃; for 12h;96%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

dimethyl 5,7-dimethylbenzo[b]thiophene-2,3-dicarboxylate
1429655-26-4

dimethyl 5,7-dimethylbenzo[b]thiophene-2,3-dicarboxylate

Conditions
ConditionsYield
With benzoic acid; 9-(2-mesityl)-10-methylacridinium perchlorate In chloroform at 20℃; for 10h; Inert atmosphere; Irradiation;96%
With air In 1,4-dioxane at 80℃;86%
With oxygen; manganese(II) acetate; benzoic acid In 1,2-dichloro-ethane at 50℃; for 2h; Schlenk technique;65%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

methyl 2-acetyl-5-butoxy-5-(phenylthio)pentanoate

methyl 2-acetyl-5-butoxy-5-(phenylthio)pentanoate

methyl 2-acetyl-5-((2,4-dimethylphenyl)thio)-5-(phenylthio)pentanoate
1266617-56-4

methyl 2-acetyl-5-((2,4-dimethylphenyl)thio)-5-(phenylthio)pentanoate

Conditions
ConditionsYield
With manganese(II) bromide In nitromethane at 80℃; for 11h;95%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

silver nitrate

silver nitrate

silver 2,4-dimethylbenzenethiolate

silver 2,4-dimethylbenzenethiolate

Conditions
ConditionsYield
In acetonitrile for 24h;95%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

toluene
108-88-3

toluene

2,4‐dimethyl‐9H‐thioxanthene‐9‐one
76293-13-5

2,4‐dimethyl‐9H‐thioxanthene‐9‐one

Conditions
ConditionsYield
Stage #1: 2,4-dimethyl-thiophenol; toluene With lithium hydroxide; ortho-chlorobenzoic acid at 120℃; for 12h;
Stage #2: With chlorosulfonic acid; sulfuric acid at 20℃; for 7h;
94.4%
N-(2-bromophenyl)-N'-methylpiperazine

N-(2-bromophenyl)-N'-methylpiperazine

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

4-methyl-1-{2-[(2,4-dimethylphenyl)sulfanyl]phenyl}piperazine
1293489-87-8

4-methyl-1-{2-[(2,4-dimethylphenyl)sulfanyl]phenyl}piperazine

Conditions
ConditionsYield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 24h; Reflux;94.3%
1-(2-bromophenyl)piperazine
1011-13-8

1-(2-bromophenyl)piperazine

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

vortioxetine
508233-74-7

vortioxetine

Conditions
ConditionsYield
With sodium hydroxide In water; N,N-dimethyl-formamide at 80 - 90℃; for 4.5h; pH=8-9;94.1%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

ethane-1,1-diylbis((2,4-dimethylphenyl)sulfane)

ethane-1,1-diylbis((2,4-dimethylphenyl)sulfane)

Conditions
ConditionsYield
With oxygen; copper(ll) bromide at 50℃; for 3h; Sealed tube;94%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

dimedone
126-81-8

dimedone

2-{(4-chlorophenyl)[(2,4-dimethylphenyl)thio]methyl}-3-hydroxy-5,5-dimethylcyclohex-2-enone
1609076-50-7

2-{(4-chlorophenyl)[(2,4-dimethylphenyl)thio]methyl}-3-hydroxy-5,5-dimethylcyclohex-2-enone

Conditions
ConditionsYield
With L-proline In ethanol at 30℃; for 6h;93%
2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

methyl 3-((2,4-dimethylphenyl)thio)-2-hydroxy-2-methylpropanoate

methyl 3-((2,4-dimethylphenyl)thio)-2-hydroxy-2-methylpropanoate

Conditions
ConditionsYield
Stage #1: 2,4-dimethyl-thiophenol; methacrylic acid methyl ester In 1,2-dichloro-ethane; acetonitrile at 20℃; for 3h;
Stage #2: With triphenylphosphine In 1,2-dichloro-ethane; acetonitrile for 2h;
93%
With oxygen; copper diacetate; benzoic acid In 1,2-dichloro-ethane at 50℃; for 3h;66%
dibutyl hydrogen phosphite
1809-19-4

dibutyl hydrogen phosphite

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

O,O-dibutyl S-(2,4-dimethylphenyl) phosphorothioate

O,O-dibutyl S-(2,4-dimethylphenyl) phosphorothioate

Conditions
ConditionsYield
With 1,3-dichloro-5,5-dimethylhydantoin In dichloromethane at 20℃; for 0.166667h;93%
With tetra-(n-butyl)ammonium iodide In acetonitrile at 20℃; for 7h; Inert atmosphere; Electrochemical reaction; Green chemistry;54%
diisobutyl phosphite
1189-24-8

diisobutyl phosphite

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

S-(2,4-dimethylphenyl) O,O-diisobutyl thiophosphate

S-(2,4-dimethylphenyl) O,O-diisobutyl thiophosphate

Conditions
ConditionsYield
With 1,3-dichloro-5,5-dimethylhydantoin In dichloromethane at 20℃; for 0.166667h;93%
chloroauric acid

chloroauric acid

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

Au(1+)*C8H9S(1-)

Au(1+)*C8H9S(1-)

Conditions
ConditionsYield
In acetonitrile for 24h;93%
piperazine
110-85-0

piperazine

1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

2,4-dimethyl-thiophenol
13616-82-5

2,4-dimethyl-thiophenol

vortioxetine
508233-74-7

vortioxetine

Conditions
ConditionsYield
With copper(l) iodide; tetrabutylammomium bromide; potassium hydroxide In water at 70 - 80℃; for 10h; Temperature; Reagent/catalyst; Green chemistry;92.6%
With sodium t-butanolate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; bis(dibenzylideneacetone)-palladium(0) In toluene at 20℃; Product distribution / selectivity; Heating / reflux;
Stage #1: 1-Bromo-2-iodobenzene; 2,4-dimethyl-thiophenol With copper(l) iodide; N,N-dimethylethylenediamine; sodium t-butanolate In toluene at 110 - 120℃; for 20h; Inert atmosphere;
Stage #2: piperazine With potassium tert-butylate In toluene at 110 - 120℃; for 24h; Reagent/catalyst; Inert atmosphere;
13.7 g

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