Best Service for Best quality and Best price. Shikimic Acid 98%min Item Specification Method Description Appearance White fine powder
Product Advantages: 1. Shikimic acid is a competitive product of our company, and free samples can be applied. 2. Available in stock for quick shipment. 3. Biological synthesis, natural, healthy, can be safely used in medicine, dyes, feed and othe
Cas:138-59-0
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inquiryAbout us We are a Professionally Managed Biotech Company exclusively into the manufacturing, Marketing and Exporting of Plant Extracts and Health Care Products.There are 15 experts in our research team. We insist in innovation and pr
1.high purity 2.consistent quality 3.competitive price 4.fast shipping Binbo Biological Products Co. Ltd., is a professional high-tech enterprise which engaged in Biological products and raw materials. Binbo is engaged in R&D with perfect eq
Cas:138-59-0
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryAnise seed Extract Product Name: Lllicium Verum Extract Latin Name: Illicium verum Hook.f Active Ingredients: Shikimic acid Extraction origin: Fruit Specification: 98% Color: White fine Powder Test Method
Cas:138-59-0
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Cas:138-59-0
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Cas:138-59-0
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Cas:138-59-0
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Cas:138-59-0
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inquiryShikimic acid CAS No.:138-59-0 Name Shikimic acid Synonyms (3R,4S,5R)-(-)-3,4,5-Trihydroxy-1-cyclohexenecarboxylic acid; 3,4,5-Trihydroxy-1-cyclohexene-1-carboxylic acid Molecular Structure Molecular Formula C7H10
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Cas:138-59-0
Min.Order:1
Negotiable
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inquiry1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
Cas:138-59-0
Min.Order:1 Gram
FOB Price: $0.1
Type:Manufacturers
inquiryCangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap
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Name:Shikimic Acid Alias: Star anise extract English Name: Shikimic Acid English aliases:3,4,5-Trihydroxy-1-cyclohexene-1-carboxylic acid; Shikimicacid; 97%; (3R,4S,5R)-3,4,5-trihydroxycyclohex-1-enecarboxylic acid; (-)-Shikimic acid; Kava Kava Ex
Cas:138-59-0
Min.Order:25 Kilogram
FOB Price: $1.0 / 2.0
Type:Other
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Cas:138-59-0
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
Cas:138-59-0
Min.Order:1 Kilogram
FOB Price: $3.0 / 10.0
Type:Trading Company
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:138-59-0
Min.Order:1 Kilogram
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inquiry1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:white powder Storage:Store in sealed containers at cool & dr
Cas:138-59-0
Min.Order:100 Gram
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inquiryAppearance:white solid powder Storage:Room temperature Package:25kg/drum Application:Fennel Extract Transportation:Express/Sea/Air Port:Any port in china
Cas:138-59-0
Min.Order:25 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHanways chempharm is a specialized company concentrating on the R&D, production, marketing and technical service of APIs and pharmaceutical intermediates. The marketing department is located in Wuhan. We have two GMP facilities in Hubei Pr
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Min.Order:1 Kilogram
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Cas:138-59-0
Min.Order:10 Gram
FOB Price: $8.8
Type:Trading Company
inquiryProduct Name: Shikimic acid CAS: 138-59-0 MF: C7H10O5 MW: 174.15 EINECS: 205-334-2 Mol File: 138-59-0.mol Shikimic acid Structure Shikimic acid Chemical Properties Melting point 185-187 °C (lit.) alpha -180 º (c=4
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Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present
Cas:138-59-0
Min.Order:1 Kilogram
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Type:Trading Company
inquiryShikimic acid CAS:138-59-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates
Cas:138-59-0
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
methyl shikimate
shikimic acid
Conditions | Yield |
---|---|
With sodium hydroxide In tetrahydrofuran; water for 5.5h; Ambient temperature; | 97% |
With sodium hydroxide In tetrahydrofuran; water | 96% |
With sodium hydroxide; water In tetrahydrofuran for 1h; Ambient temperature; | 96% |
(3R,4S,5R)-3,4-Diacetoxy-5-hydroxy-cyclohex-1-enecarboxylic acid methyl ester
shikimic acid
Conditions | Yield |
---|---|
With sodium hydroxide In methanol at 5 - 25℃; for 2.5h; | 90% |
With sodium hydroxide 1.) in methanol-water, 5 deg C, 0.5h; 2.) room temp., 2h; Multistep reaction; |
(3aR,4S,7R,7aS)-methyl 4,7-dihydroxy-2,2-dimethylhexahydrobenzo[d][1,3]dioxole-5-carboxylate
shikimic acid
Conditions | Yield |
---|---|
Stage #1: (3aR,4S,7R,7aS)-methyl 4,7-dihydroxy-2,2-dimethylhexahydrobenzo[d][1,3]dioxole-5-carboxylate With dmap; acetic anhydride; triethylamine In tetrahydrofuran for 3.66667h; Inert atmosphere; Stage #2: With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran for 10h; Inert atmosphere; enantioselective reaction; | 80% |
(1S,2R,6R)-4-(ethoxycarbonyl)-6-(4-nitrobenzoyloxy)-cyclohex-3-ene-1,2-diyl diacetate
shikimic acid
Conditions | Yield |
---|---|
With sodium hydroxide | 65% |
shikimic acid
Conditions | Yield |
---|---|
With hydrogenchloride; water at 80℃; for 3h; | 62% |
shikimic acid
Conditions | Yield |
---|---|
With trifluoroacetic acid In water | 53% |
methyl shikimate
A
shikimic acid
B
3(S),4(S),5(R)-trihydroxy-1-cyclohexene-1-carboxylic acid
C
4-hydroxy-benzoic acid
Conditions | Yield |
---|---|
With hydrogenchloride; water at 100℃; for 30h; | A 8% B 21% C 21% |
Conditions | Yield |
---|---|
Stage #1: D-Glucose With Bacillus pumilus ATCC 21143; oxygen In various solvent(s) at 30℃; for 96h; Microbiological reaction; Stage #2: Escherichia coli SP1.1/pJG6.181B With oxygen In various solvent(s) at 37℃; Microbiological reaction; | A n/a B 5% |
Conditions | Yield |
---|---|
With cultures of escherichia coli; water at 35℃; |
3a,6,7,7a-tetrahydro-7-hydroxy-2,2-dimethyl-[3aR-(3aα,7α,7aα)]-1,3-benzodioxole-5-carboxylic acid
shikimic acid
Conditions | Yield |
---|---|
With water; trifluoroacetic acid Ambient temperature; Yield given; | |
With trifluoroacetic acid for 10h; Ambient temperature; Yield given; | |
Multi-step reaction with 3 steps 1: CDCl3; pyridine / 48 h / Ambient temperature 2: aq. acetic acid / 2 h / 100 °C 3: aq. HCl / reflux 30 min, room temp. overnight View Scheme |
Conditions | Yield |
---|---|
With NADPH at 20℃; Escherichia coli shikimate dehydrogenase, aq. phosphate buffer; | |
With Escherichia coli shikimate dehydrogenase; NADPH at 20℃; Kinetics; in aq. phosphate buffer; | |
With shikimate dehydrogenase | |
With NADP; ethylenediaminetetraacetic acid; D-glucose In phosphate buffer at 25℃; for 1.25h; pH=7; |
(-)-shikimic acid 3-O-gallate
A
3,4,5-trihydroxybenzoic acid
B
shikimic acid
Conditions | Yield |
---|---|
tannase In water at 37℃; for 3h; Product distribution; | A 40 mg B 43 mg |
Acetic acid (1R,4R,6S)-4-acetoxy-6-((S)-2-hydroxy-3,3-dimethyl-butyryl)-cyclohex-2-enyl ester
shikimic acid
Conditions | Yield |
---|---|
Multistep reaction; |
(-)-t-butyl 3,4-O-isopropylideneshikimate
shikimic acid
Conditions | Yield |
---|---|
With trifluoroacetic acid for 12h; Ambient temperature; Yield given; |
Conditions | Yield |
---|---|
In hydrogenchloride reflux 30 min, room temp. overnight; |
(-)-shikimic acid 3,4-O-digallate
A
3,4,5-trihydroxybenzoic acid
B
shikimic acid
Conditions | Yield |
---|---|
tannase In water at 37℃; for 3h; Product distribution; | A 28 mg B 11 mg |
3,5-Di-O-galloylshikimic acid
A
3,4,5-trihydroxybenzoic acid
B
shikimic acid
Conditions | Yield |
---|---|
tannase In water at 37℃; for 3h; Product distribution; | A 78 mg B 37 mg |
hydrogen cyanide
Acetic acid (2R,6R)-2,6-diacetoxy-4-methylene-cyclohexyl ester
shikimic acid
Conditions | Yield |
---|---|
Multistep reaction; |
D-Glucose
A
shikimic acid
B
D-(-)-quinic acid
C
(-)-3-dehydroshikimic acid
Conditions | Yield |
---|---|
With E. coli SP1.1; pKD12112 for 12h; Product distribution; var. time; | |
With air; Escherichia coli SP1.1PTS-; pSC6.090B at 33℃; for 60h; pH=7; | |
With air; Escherichia coli SP1.1PTS-; pSC6.090B at 33℃; for 30h; pH=7; |
methyl (3R,4S,5R)-3-benzoyloxy-4,5-dihydroxy-cyclohex-1-en-1-carboxylate
shikimic acid
Conditions | Yield |
---|---|
With potassium hydroxide In tetrahydrofuran Hydrolysis; |
D-Glucose
phosphoenolpyruvic acid
A
shikimic acid
B
D-(-)-quinic acid
C
(-)-3-dehydroshikimic acid
Conditions | Yield |
---|---|
With dipotassium hydrogenphosphate; E. coli SP1.1; pKD12138; citric acid In water at 33℃; pH=7.0; Enzyme kinetics; Further Variations:; Reagents; |
(3R-(3α,4α,5β))-O-3-phospho-O-5-(1S-1-carboxy-1-(phosphooxy)-ethyl)shikimic acid
A
phosphoenolpyruvic acid
B
shikimic acid
C
5-enol-pyruvoylshikimate 3-phosphate (EPSP)
Conditions | Yield |
---|---|
With glycine at 25℃; pH=2.5 - 3.5; Product distribution; Kinetics; Further Variations:; pH-values; Reagents; |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: Gluconobacter oxydans IFO 3244 cells / various solvent(s) / 20 h / 30 °C / pH 7 2: NADP; SKDH; GDH / D-glucose; EDTA / aq. phosphate buffer / 1.25 h / 25 °C / pH 7 View Scheme |
shikimic acid
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 59 percent / NaOH; BuNCl / toluene / 0.83 h / 5 °C 2: 52 percent / diphenyl ether / 1 h / 300 °C 3: 94 percent / BF3*OEt2 / toluene / 20 °C 4: KOH / tetrahydrofuran View Scheme |
(1R,5R,6R)-5-Benzoyloxy-7-oxa-bicyclo[4.1.0]hept-3-ene-3-carboxylic acid methyl ester
shikimic acid
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 94 percent / BF3*OEt2 / toluene / 20 °C 2: KOH / tetrahydrofuran View Scheme |
shikimic acid
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: NaBH4; NaOH / methanol; H2O / 0 °C 2: 59 percent / NaOH; BuNCl / toluene / 0.83 h / 5 °C 3: 52 percent / diphenyl ether / 1 h / 300 °C 4: 94 percent / BF3*OEt2 / toluene / 20 °C 5: KOH / tetrahydrofuran View Scheme |
shikimic acid
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 52 percent / diphenyl ether / 1 h / 300 °C 2: 94 percent / BF3*OEt2 / toluene / 20 °C 3: KOH / tetrahydrofuran View Scheme |
(-)-(1S,4R,4aS,5R,8aR)-5-tert-Butyldimethylsilyloxy-1,4,4a,6,7,8a-hexahydro-endo-1,4-methanonaphthalen-8(5H)-one
shikimic acid
Conditions | Yield |
---|---|
Multi-step reaction with 12 steps 1: 86 percent / NaH / tetrahydrofuran / 23 h / Ambient temperature 2: 90 percent / O2, KF, P(OEt)3 / dimethylsulfoxide / 22 h / Ambient temperature 3: 100 percent / pyridine / 38 h / Ambient temperature 4: 100 percent / diphenyl ether / 1 h / 280 °C 5: 86 percent / OsO4, NMO, H2O / tetrahydrofuran / 72 h / 0 °C 6: PPTS / 65 h 7: NaBH4 / methanol / 1.5 h / -78 °C 8: DBU, MeOH / 20 h / -20 °C 9: 23 h / Ambient temperature 10: Tf2O, (i-Pr)2NEt / toluene / 1 h / 50 °C 11: 95 percent / HCl / methanol / 40 h / Ambient temperature 12: 96 percent / NaOH, H2O / tetrahydrofuran / 1 h / Ambient temperature View Scheme |
(2S,3S,4aR,6S,8R,8aR)-6,8-Dihydroxy-2,3-dimethoxy-2,3-dimethyl-octahydro-benzo[1,4]dioxine-6-carboxylic acid methyl ester
shikimic acid
Conditions | Yield |
---|---|
Multi-step reaction with 6 steps 1: 94 percent / imidazole / CH2Cl2 2: 97 percent / DIBAL / tetrahydrofuran / 0 °C 3: 92 percent / n-Bu3P / tetrahydrofuran / Ambient temperature 4: 1.) m-chloroperoxybenzoic acid; 2.) TFAA, 2,6-lutidine / 1.) CH2Cl2, 0 deg C; 2.) CH2Cl2 5: 59 percent / NaClO2, Na2PO4, 2-methyl-2-butene / H2O; 2-methyl-propan-2-ol 6: 53 percent / TFA / H2O View Scheme |
Conditions | Yield |
---|---|
With Amberlite IR 120 for 16h; Heating; | 100% |
With Amberlite-IR120 at 65℃; for 18h; Esterification; | 100% |
With hydrogenchloride at 60℃; for 6h; | 100% |
Conditions | Yield |
---|---|
In methanol; diethyl ether for 15h; Ambient temperature; | 99% |
In methanol | |
In methanol; diethyl ether at -20 - -15℃; |
shikimic acid
dimethylglyoxal
trimethyl orthoformate
methyl (3R,4S,5R)-3-hydroxy-4,5-<(2S,3S)-2,3-dimethoxybutan-2,3-dioxy>-cyclohex-1-en-1-carboxylate
Conditions | Yield |
---|---|
With sulfuric acid In methanol for 48h; Inert atmosphere; Reflux; | 95% |
With 10-camphorsufonic acid In methanol at 85℃; Condensation; | 80% |
With CSA In methanol for 48h; Inert atmosphere; Reflux; | 70% |
With (1S)-10-camphorsulfonic acid In methanol for 72h; Reflux; Inert atmosphere; | 62% |
ethanol
shikimic acid
(3R,4S,5R)-3,4,5-trihydroxycyclohex-1-ene-1-carboxylic acid ethyl ester
Conditions | Yield |
---|---|
With KU-2-8 cationite for 15h; Reflux; | 93% |
With thionyl chloride at 140℃; under 7500.75 Torr; for 0.133333h; Reagent/catalyst; Temperature; Time; | 93% |
With thionyl chloride for 3h; Reflux; | 83% |
methanol
shikimic acid
cyclohexanone
methyl (3aS,4R,7aR)-4-hydroxy-3a,4,5,7a-tetrahydrospiro[benzo[d][1,3]dioxole-2,1'-cyclohexane]-6-carboxylate
Conditions | Yield |
---|---|
With (1S)-10-camphorsulfonic acid In toluene at 160℃; for 0.5h; Microwave irradiation; | 92% |
With camphor-10-sulfonic acid In toluene at 160℃; Microwave irradiation; |
Conditions | Yield |
---|---|
In water at 35℃; for 6h; dark; shikimate-p-hydroxycinnamoyl transferase; | 68% |
Isopropenyl acetate
shikimic acid
(3R,4S,5R)-3,4,5-triacetoxycyclohex-1-ene-1-carboxylic acid
Conditions | Yield |
---|---|
With iron(III) trifluoromethanesulfonate at 20℃; for 5h; Schlenk technique; | 66% |
Conditions | Yield |
---|---|
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran at 65℃; | 60% |
With NAD(P)-independent quinate dehydrogenase EC 1.1.99.25; potassium hexacyanoferrate(III) Enzyme kinetics; Further Variations:; Reagents; | |
With oxygen In water at 20℃; under 760.051 Torr; for 336h; pH=6.5 - 7; |
Conditions | Yield |
---|---|
With sulfuric acid; acetic acid at 120℃; for 16h; | A 9% B 57% |
With hydrogenchloride for 14h; Heating; | A 13% B 40% |
Conditions | Yield |
---|---|
Stage #1: shikimic acid In water at 350℃; for 0.5h; Stage #2: With copper In water at 350℃; | A 18 % Chromat. B 51% C 1 % Chromat. |
shikimic acid
(-)-shikimate 3-phosphate trisodium salt
Conditions | Yield |
---|---|
With ATP shikimate kinase, 1.) 6 h, 2.) 13 deg C., overnight; | 47% |
Multi-step reaction with 11 steps 1: 95 percent / Amberlite IR 120 / 12 h / Heating 2: 96 percent / camphorsulfonic acid / 0.25 h / Ambient temperature 3: 100 percent / 4-(dimethylamino)pyridine / CH2Cl2 / 2 h / Ambient temperature 4: 94 percent / aq. HOAc / tetrahydrofuran / 6 h / 70 °C 5: 1.) dibutyltin oxide / 1.) benzene, reflux, 1 h, 2.) DMF, 30 min 6: 100 percent / 4-(dimethylamino)pyridine / CH2Cl2 / 1 h / 50 °C 7: 89 percent / 80percent aq. HOAc / 0.25 h 8: tetrazole / CH2Cl2 / 2 h / Ambient temperature 9: 0.304 g / m-CPBA / CH2Cl2 / 2 h / -40 °C 10: 80 percent / bromotrimethylsilane / CH2Cl2 / 1 h / 0 °C 11: 99 percent / 1 N NaOH / 3 h / 0 °C View Scheme |
shikimic acid
2-(bromomethyl)-3,5,6-trimethylpyrazine
(3,5,6-trimethyl pyrazine-2-yl)methyl 3,4,5-trihydroxycyclohexyl-1-ene formate
Conditions | Yield |
---|---|
With triethylamine In N,N-dimethyl-formamide for 3.5h; Reflux; | 43.8% |
shikimic acid
Conditions | Yield |
---|---|
Stage #1: shikimic acid; H-Lys-Cys(StBu)-Gly-2,2,5,7,8-pentamethylchroma-6-sulfonyl peptidyl-resin With benzotriazol-1-ol; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃; for 0.666667h; Stage #2: With chlorotriisopropylsilane; trifluoroacetic acid In water at 20℃; for 1h; | 40% |
Conditions | Yield |
---|---|
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane; N,N-dimethyl-formamide at 0 - 20℃; | 33% |
shikimic acid
Conditions | Yield |
---|---|
Stage #1: shikimic acid; H-Lys-Cys(StBu)-Arg(Pmc)-2,2,5,7,8-pentamethylchroma-6-sulfonyl peptidyl-resin With benzotriazol-1-ol; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃; for 0.666667h; Stage #2: With chlorotriisopropylsilane; trifluoroacetic acid In water at 20℃; for 1h; | 26% |
shikimic acid
(R)-3-tert-Butylsulfanyl-2-(9H-fluoren-9-ylmethoxycarbonylamino)-propionic acid
N-2,N-6-bis(9-fluorenylmethyloxycarbonyl)-L-lysine
Conditions | Yield |
---|---|
Multistep reaction; | 14% |
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