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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

trans-Stilbene oxide

Cas:1439-07-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

(E)-Stilbene oxide

Cas:1439-07-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

TRANS-STILBENE OXIDE

Cas:1439-07-2

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 1439-07-2 with best quality

Cas:1439-07-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Oxirane, 2,3-diphenyl-,(2R,3R)-rel-

Cas:1439-07-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

TRANS-STILBENE OXIDE

Cas:1439-07-2

Min.Order:1 Kilogram

FOB Price: $10.0 / 100.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Oxirane, 2,3-diphenyl-,(2R,3R)-rel-

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Oxirane, 2,3-diphenyl-,(2R,3R)-rel-

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

1439-07-2 TRANS-STILBENE OXIDE

Cas:1439-07-2

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Trans-Stilbene Oxide

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

trans-Stilbene oxide

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Trans-2,3-Diphenylethylene Oxide 5g

Cas:1439-07-2

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

trans-Stilbene Oxide

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

TRANS-STILBENE OXIDE

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

trans-Stilbene Oxide

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as pri

trans-2,3-Diphenylethylene Oxide

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

TRANS-STILBENE OXIDE

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

(2R,3R)-2,3-diphenyloxirane

Cas:1439-07-2

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Chemlin Chemical Co., Ltd.

Nanjing Chemlin Chemical Industry Co., Ltd was established in Aug,1999, located in the industrial park of Nanjing University of Technology, It is a private enterprises in Jiangsu Province with 1200 square meters’ R&D center. Our R&D center has a well

1439-07-2

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Capot Chemical Co., Ltd.

At Capot,We can synthesize and purify your complex molecules from 100 gram to 10 tons.Appearance:Clear colorless to light yellow liquid Storage:Dry,Seal and Cool place Package:1G,5G,10G,25G,100G,250G,500G,1KG,5KG,10KG,25KG,50KG,100KG,150KG,200KG. App

Trans-Stilbene oxide

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Run-Biotech Co., Ltd.

Shanghai, Run-Biotech Co., Ltd is a leading domestic pharmaceutical, biopharmaceutical, and health care products R & D outsourcing services company. As an innovation-driven and customer-focused company, Run Biotech provides a broad and integrated por

TRANS-STILBENE OXIDE

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the TRANS-STILBENE OXIDE, CAS:1439-07-2 with the most competitive price and the best qual

TRANS-STILBENE OXIDE

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuxi Morality Chemical Co., Ltd

Do best quality products, erect the morality model Application:please email us, thanks

TRANS-STILBENE OXIDE

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Other

inquiry

Debye Scientific

Debyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen

1,2-Diphenylethylene oxide

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Foreign Trade Corp

CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio

trans-α,α-epoxydibenzyl

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

NovaChemistry

high purity Application:Drug intermediates Materials intermediates and active molecules

trans-Stilbene oxide

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Sigma-Aldrich Chemie GmbH

Package:1, 5, 25 g in glass bottle

trans-Stilbene oxide

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ChemService Inc.

TRANS-STILBENE OXIDE

trans-Stilbene oxide

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

EMKA-Chemie Gmbh & Co. KG

Oxirane, 2,3-diphenyl-,(2R,3R)-rel-

Cas:1439-07-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Panslavia Chemicals

trans-Stilbene oxide

Cas:1439-07-2

Min.Order:0

Negotiable

Type:

inquiry

Synthetic route

(E)-1,2-diphenyl-ethene
103-30-0

(E)-1,2-diphenyl-ethene

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid; iron(III) perchlorate In acetonitrile at -10℃; for 0.0833333h;100%
With sodium periodate; 5-Nitro-1,10-phenanthroline; iron(II) sulfate In dichloromethane; water at 20℃; for 20h;100%
With (5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II); oxygen; isobutyraldehyde In acetonitrile for 3h; Ambient temperature;100%
cis-stilben
645-49-8

cis-stilben

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With sodium chlorite; edetate disodium In water; acetonitrile at 55 - 65℃; for 14h;100%
With urea hydrogen peroxide adduct; ruthenium(2,2',6':2''-terpyridine)(2,6-pyridinedicarboxylate) In tert-Amyl alcohol at 20℃; for 1h; Product distribution; Further Variations:; Catalysts; Reagents;99%
With Oxone; ethylenediaminetetraacetic acid; sodium carbonate In water; acetonitrile at 0 - 20℃; for 6h;98%
benzaldehyde
100-52-7

benzaldehyde

dimethyl<(phenyl)trimethylsilylmehyl>sulfoniumtrifluoromethanesulfonate
119547-76-1

dimethyl<(phenyl)trimethylsilylmehyl>sulfoniumtrifluoromethanesulfonate

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With cesium fluoride In 1,2-dimethoxyethane at 45℃; for 18h;98%
benzaldehyde
100-52-7

benzaldehyde

sodium (E)-2-benzylidene-1-tosylhydrazin-1-ide

sodium (E)-2-benzylidene-1-tosylhydrazin-1-ide

A

cis-1,2-diphenyloxirane
1689-71-0

cis-1,2-diphenyloxirane

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With thiophene; N-benzyl-N,N,N-triethylammonium chloride; dirhodium tetraacetate In acetonitrile at 40℃; for 24h;A n/a
B 98%
phenyldiazomethane
908094-04-2

phenyldiazomethane

benzaldehyde
100-52-7

benzaldehyde

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With hydrotris(3,4,5-tribromopyrazolyl)borate Cu (NCMe); dimethylsulfide In dichloromethane; toluene at 20℃; for 2h; Catalytic behavior; Reagent/catalyst; Solvent; Inert atmosphere; diastereoselective reaction;95%
With copper acetylacetonate; ethyl isopropyl sulfide In dichloromethane73%
sodium 2-benzylidene-1-tosylhydrazin-1-ide
27992-27-4, 40154-38-9

sodium 2-benzylidene-1-tosylhydrazin-1-ide

benzaldehyde
100-52-7

benzaldehyde

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With thiophene; dirhodium tetraacetate; N-benzyl-N,N,N-triethylammonium chloride In acetonitrile at 40℃; for 3h;95%
cis-stilben
645-49-8

cis-stilben

A

cis-1,2-diphenyloxirane
1689-71-0

cis-1,2-diphenyloxirane

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With 1H-imidazole; chloro(meso-tetrakis(2,6-dichlorophenyl)porphyrinato)manganese(III); dihydrogen peroxide In dichloromethane; acetonitrile for 2h; Ambient temperature;A 94%
B 3%
With 1H-imidazole; manganese(III) meso-tetraphenylporphyrin acetate; tetrabutylammonium periodite In dichloromethane; tert-butyl alcohol at 22℃; for 5h; Inert atmosphere;A 92%
B 3%
With oxygen In water at 25℃; under 760.051 Torr; for 4h;A n/a
B 92%
cis-stilben
645-49-8

cis-stilben

A

phenyl benzyl ketone
451-40-1

phenyl benzyl ketone

B

cis-1,2-diphenyloxirane
1689-71-0

cis-1,2-diphenyloxirane

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With 1H-imidazole; dihydrogen peroxide; Mn(TDCPP)Cl In dichloromethane; acetonitrile for 0.25h; Ambient temperature;A 2%
B 92%
C 2%
With tert.-butylhydroperoxide In water; acetonitrile at 85℃; for 24h; Catalytic behavior;A 7.2 %Chromat.
B 42.3%
C 8.3%
With O(3P) prepared by O2 discharge at 0℃; for 0.5h;A 29%
B 31%
C 40%
(E)-1,2-diphenyl-ethene
103-30-0

(E)-1,2-diphenyl-ethene

A

benzaldehyde
100-52-7

benzaldehyde

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene; ruthenium(2,2',6':2''-terpyridine)(2,6-pyridinedicarboxylate) In dichloromethane for 72h; Ambient temperature;A n/a
B 92%
With oxygen; isobutyraldehyde; 4 In water; 1,2-dichloro-ethane at 40℃; for 72h;A 15%
B 83%
With pyridine N-oxide; oxochromium(V) complex of tetramethylsalen IIb In acetonitrileA 10%
B 81%
stilbene
588-59-0

stilbene

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃;91%
With Perbenzoic acid; chloroform
With 3-chloro-benzenecarboperoxoic acid
1-benzyl-3-methylbenzotriazolium iodide
1334478-48-6

1-benzyl-3-methylbenzotriazolium iodide

benzaldehyde
100-52-7

benzaldehyde

A

2-(1H-benzo[d][1,2,3]triazol-1-yl)-1-phenylethan-1-ol

2-(1H-benzo[d][1,2,3]triazol-1-yl)-1-phenylethan-1-ol

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With potassium tert-butylate In dimethyl sulfoxide; tert-butyl alcohol at 20℃; optical yield given as %de; diastereoselective reaction;A 90%
B 70%
benzaldehyde
100-52-7

benzaldehyde

sodium (E)-2-benzylidene-1-tosylhydrazin-1-ide

sodium (E)-2-benzylidene-1-tosylhydrazin-1-ide

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With triphenyl-arsane; N-benzyl-N,N,N-triethylammonium chloride; dirhodium tetraacetate In acetonitrile at 40℃;89%
benzyl bromide
100-39-0

benzyl bromide

benzaldehyde
100-52-7

benzaldehyde

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With dimethyl sulfoxide; sodium hydroxide at 20℃; for 4h; Reagent/catalyst;89%
With (1R,2R,4R)-(+)-isobornyl methyl sulfide; sodium hydroxide In acetonitrile for 72h;50%
cyclic sulfate of meso-hydrobenzoin
89366-17-6

cyclic sulfate of meso-hydrobenzoin

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran; methanol at 20℃; for 1h;86%
(E)-1,2-diphenyl-ethene
103-30-0

(E)-1,2-diphenyl-ethene

A

cis-1,2-diphenyloxirane
1689-71-0

cis-1,2-diphenyloxirane

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With dihydrogen peroxide; iron(III) perchlorate In acetonitrile Product distribution; Heating; other oxidant, other catalysts;A 85%
B 15%
With 2MnIVTPP; 5,15,10,20-tetraphenylporphyrin In chlorobenzene at 25℃;A n/a
B 37%
With pyridine; sodium hypochlorite; benzyldimethyltetradecylammonium chloride; [MnIII(TPP)(OAc)] In dichloromethane; water for 5h; Ambient temperature; Yields of byproduct given;A n/a
B 20%
(1S,2R)-1,2-diphenylethane-1,2-diol
579-43-1

(1S,2R)-1,2-diphenylethane-1,2-diol

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With trifluoromethylsulfonic anhydride; polymer-supported triphenylphosphine oxide; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃;85%
With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃;85%
With diethoxyltriphenylphosphorane In toluene at 100℃; for 18h;
benzyl bromide
100-39-0

benzyl bromide

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With dimethyl sulfoxide; sodium hydroxide at 20℃; for 12h; Reagent/catalyst;85%
With dimethyl sulfoxide; silver(l) oxide at 20℃; Inert atmosphere;48%
Multi-step reaction with 3 steps
1: 1.) n-butyllithium / 1.) ether, -20 deg C, 1 h., 2.) ether
2: 100 percent / benzene / 0 °C
3: 80 percent / flame-dried cesium fluoride / 1,2-dimethoxy-ethane / 12 h / 40 °C
View Scheme
benzyldiethylsulfonium bromide

benzyldiethylsulfonium bromide

benzaldehyde
100-52-7

benzaldehyde

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
In acetonitrile at 22℃; Corey-Chaikovsky reaction; Electrolysis;83%
benzaldehyde
100-52-7

benzaldehyde

methyl (phenylmethyl)<(trimethylsilyl)methyl>sulfonium trifluoromethanesulfonate
119547-81-8

methyl (phenylmethyl)<(trimethylsilyl)methyl>sulfonium trifluoromethanesulfonate

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With cesium fluoride In 1,2-dimethoxyethane at 40℃; for 12h;80%
(1S,2R)-1,2-diphenylethane-1,2-diol
579-43-1

(1S,2R)-1,2-diphenylethane-1,2-diol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

trans-hydrobenzoin tosylate

trans-hydrobenzoin tosylate

Conditions
ConditionsYield
With triethylamine; di(n-butyl)tin oxide In dichloromethane at 20℃; for 0.666667h;A 5%
B 80%
With di(n-butyl)tin oxide; triethylamine In dichloromethane at 20℃; for 0.666667h; Tosylation;
1-benzyltetrahydro-1H-thiophen-1-ium bromide
41570-67-6

1-benzyltetrahydro-1H-thiophen-1-ium bromide

benzyl alcohol
100-51-6

benzyl alcohol

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With barium manganate; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In acetonitrile at 60℃; for 1h; Corey-Tschaikosky Epoxidation;78%
Stage #1: benzyl alcohol With manganese(IV) oxide In chloroform for 2h; Reflux;
Stage #2: 1-benzyltetrahydro-1H-thiophen-1-ium bromide With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In chloroform for 0.333333h;
68%
cis-stilben
645-49-8

cis-stilben

A

benzaldehyde
100-52-7

benzaldehyde

B

cis-1,2-diphenyloxirane
1689-71-0

cis-1,2-diphenyloxirane

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With meso-tetrakis(pentafluorophenyl)porphirinato Fe(IV) nitrate; dihydrogen peroxide In dichloromethane; acetonitrile at 20℃; for 0.166667h; Product distribution; Further Variations:; Reagents; Epoxidation; Oxidation;A 3%
B 74%
C 3%
With Ni(N-(2-pyridylmethyl)-N’-(2-hydroxyethyl)ethylenediamine)(N3)2; 3-chloro-benzenecarboperoxoic acid In dichloromethane; acetonitrile at 20℃; for 0.166667h;A 16.1%
B 6.8%
C 64.6%
With iodosylbenzene; tetraphenylporphyrine aluminum chloride In toluene for 24h; Ambient temperature;A 0.0008 mmol
B 62%
C 0.005 mmol
(+/-)-trans-5,6-diphenyl-1,4-dioxane-2,3-dione
74888-53-2, 74888-54-3

(+/-)-trans-5,6-diphenyl-1,4-dioxane-2,3-dione

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
In acetonitrile for 0.5h; Irradiation;73%
C18H20Cl2O
131423-70-6

C18H20Cl2O

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With potassium tert-butylate In dimethyl sulfoxide at 25℃; for 0.75h;70%
trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With sodium hydroxide; methanesulfonyl chloride; N-benzyl-N,N,N-triethylammonium chloride In dichloromethane for 0.5h; Heating;70%
benzaldehyde
100-52-7

benzaldehyde

C28H28As(1+)*BF4(1-)

C28H28As(1+)*BF4(1-)

A

(E)-1,2-diphenyl-ethene
103-30-0

(E)-1,2-diphenyl-ethene

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With phenyllithiumA 7%
B 66%
benzaldehyde
100-52-7

benzaldehyde

benzylmethyl <(1S,2S,3R)-3-pinanyl>sulfonium perchlorate

benzylmethyl <(1S,2S,3R)-3-pinanyl>sulfonium perchlorate

A

cis-1,2-diphenyloxirane
1689-71-0

cis-1,2-diphenyloxirane

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With sodium hydroxide; Aliquat 336 In dichloromethane at 0℃; for 24h; Product distribution; other sulfonium salts and aldehydes; also without phase transfer catalyst;A 6%
B 66%
1,3-dibenzylbenzotriazolium iodide

1,3-dibenzylbenzotriazolium iodide

benzaldehyde
100-52-7

benzaldehyde

2-(1H-benzo[d][1,2,3]triazol-1-yl)-1,2-diphenylethanol

2-(1H-benzo[d][1,2,3]triazol-1-yl)-1,2-diphenylethanol

2-(1H-benzo[d][1,2,3]triazol-1-yl)-1,2-diphenylethanol

2-(1H-benzo[d][1,2,3]triazol-1-yl)-1,2-diphenylethanol

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With potassium tert-butylate In dimethyl sulfoxide; tert-butyl alcohol at 20℃; optical yield given as %de; diastereoselective reaction;A n/a
B n/a
C 66%
(E)-1,2-diphenyl-ethene
103-30-0

(E)-1,2-diphenyl-ethene

A

benzaldehyde
100-52-7

benzaldehyde

B

cis-1,2-diphenyloxirane
1689-71-0

cis-1,2-diphenyloxirane

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With Ni(N-(2-pyridylmethyl)-N’-(2-hydroxyethyl)ethylenediamine)(N3)2; 3-chloro-benzenecarboperoxoic acid In dichloromethane; acetonitrile at 20℃; for 0.166667h;A 17.8%
B 9.4%
C 64.5%
With iodosylbenzene; tetraphenylporphyrine aluminum chloride In toluene for 24h; Ambient temperature;A 0.002 mmol
B 0.003 mmol
C 6.4%
With tert.-butylhydroperoxide; molecular sieve In Petroleum ether for 24h; Ambient temperature;A 0.27 % Spectr.
B 0.18 % Spectr.
C 9.35 % Spectr.
With Ru(VI)(octaethylporphyrin)(O)2 In dichloromethane for 24h; Yield given. Yields of byproduct given;
With iodoxybenzene; bis(acetylacetonato) oxovanadium(IV) In benzene for 4h; Product distribution;A 38 % Chromat.
B 10 % Chromat.
C 13 % Chromat.
(E)-1,2-diphenyl-ethene
103-30-0

(E)-1,2-diphenyl-ethene

A

styrene oxide
96-09-3

styrene oxide

B

benzoic acid
65-85-0

benzoic acid

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Conditions
ConditionsYield
With tetrachloromethane; 18-crown-6 ether In acetonitrile at 10℃;A 11%
B 11%
C 62%
sodium methylate
124-41-4

sodium methylate

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

erythro-2-methoxy-1,2-diphenylethanol
6941-71-5

erythro-2-methoxy-1,2-diphenylethanol

Conditions
ConditionsYield
In methanol for 108h; Heating;100%
trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

(E)-1,2-diphenyl-ethene
103-30-0

(E)-1,2-diphenyl-ethene

Conditions
ConditionsYield
With <(n-C4H9)3SnAl(C2H5)3>(1-)*Li(1+) In tetrahydrofuran; hexane at 25℃; for 24h; Product distribution; (C6H5)(CH3)2SiAl(C2H5)2 as deoxygenation reagent;100%
With vanadium monochloride In tetrahydrofuran at 25℃; for 12h; Inert atmosphere;100%
With n-Bu3Sn-AlMe3Li In tetrahydrofuran; hexane at 25℃; for 3h;98%
(1S,2R)-(+)-ephedrine
321-98-2

(1S,2R)-(+)-ephedrine

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

(1S,2R)-2-[(2-Hydroxy-1,2-diphenyl-ethyl)-methyl-amino]-1-phenyl-propan-1-ol

(1S,2R)-2-[(2-Hydroxy-1,2-diphenyl-ethyl)-methyl-amino]-1-phenyl-propan-1-ol

Conditions
ConditionsYield
With lithium bromide at 150℃; for 4h;100%
piperidine
110-89-4

piperidine

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

1,2-diphenyl-2-(piperidin-1-yl)ethanol
78792-49-1

1,2-diphenyl-2-(piperidin-1-yl)ethanol

Conditions
ConditionsYield
bismuth(lll) trifluoromethanesulfonate at 160℃; for 0.25h; microwave irradiation;100%
trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

Diphenylacetaldehyde
947-91-1

Diphenylacetaldehyde

Conditions
ConditionsYield
With erbium(III) triflate In dichloromethane at 20℃; for 0.75h;99%
With trimethylaluminum; 1,3-bis(3-t-butyl-5-methylsalicyl)benzene In dichloromethane Ambient temperature;98%
With copper(II) tetrafluoroborate hydrate In dichloromethane for 1.5h; Meinwald rearrangement; Reflux; regioselective reaction;95%
trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

1,2-Diphenylethanol
5773-56-8, 614-29-9

1,2-Diphenylethanol

Conditions
ConditionsYield
With formic acid; triethylamine; Pd0-EnCatTM In ethyl acetate at 23℃; for 5h;99%
With ammonium formate In ethyl acetate at 25℃; for 24h; Inert atmosphere;99%
With hydrogen; Pd/magnetite In ethyl acetate at 23℃; under 760.051 Torr; for 0.5h;94%
ethanolamine
141-43-5

ethanolamine

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

2-(2-hydroxyethylamino)-1,2-diphenylethanol

2-(2-hydroxyethylamino)-1,2-diphenylethanol

Conditions
ConditionsYield
at 90℃; for 3h;99%
cyclohexylamine
108-91-8

cyclohexylamine

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

2-(cyclohexylamino)-1,2-diphenylethanol
212394-42-8

2-(cyclohexylamino)-1,2-diphenylethanol

Conditions
ConditionsYield
bismuth(lll) trifluoromethanesulfonate at 160℃; for 0.25h; microwave irradiation;99%
Conditions
ConditionsYield
With Dowex-50WX8-supported thiourea for 0.0166667h; Microwave irradiation; neat (no solvent);98%
With ammonium chloride; thiourea at 60 - 70℃; for 0.75h; neat (no solvent);96%
With thiourea In methanol for 0.3h; Molecular sieve; Reflux;95%
With indium(III) bromide; potassium thioacyanate In acetonitrile at 60℃; for 3h;93%
With ammonium thiocyanate at 60℃; for 2h; Neat (no solvent);90%
carbon dioxide
124-38-9

carbon dioxide

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

(4R,5R)-4,5-diphenyl-1,3-dioxolan-2-one
19456-17-8, 27797-53-1, 28521-60-0, 68114-27-2

(4R,5R)-4,5-diphenyl-1,3-dioxolan-2-one

Conditions
ConditionsYield
With [La{N(SiHMe2)2}2{k3-2,2-bis(3,5-dimethylpyrazol-1-yl)-1,1-diphenylethylcyclopentadienyl}]; tetrabutylammomium bromide In neat (no solvent) at 90℃; under 7500.75 Torr; for 18h;98%
With C30H41Al2N5S; tetrabutylammomium bromide In neat (no solvent) at 90℃; under 7500.75 Torr; for 16h; stereoselective reaction;93%
With C30H34BrCrN2O4; tetrabutylammomium bromide In neat (no solvent) at 80℃; under 7500.75 Torr; for 24h; Temperature;89%
trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

trimethyl orthoformate
149-73-5

trimethyl orthoformate

2,2-diphenylacetaldehyde dimethyl acetal
51936-06-2

2,2-diphenylacetaldehyde dimethyl acetal

Conditions
ConditionsYield
With mesoporous aluminosilicate catalyst, Si/Al ratio = 14:1 In chloroform at 20 - 55℃;98%
aniline
62-53-3

aniline

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

C14H12O

C14H12O

1,2-diphenyl-2-anilinoethanol

1,2-diphenyl-2-anilinoethanol

Conditions
ConditionsYield
With (S,S)-(+)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino chromium(III) chloride at 20℃; for 4h; Ionic liquid; Inert atmosphere; optical yield given as %ee; enantioselective reaction;A n/a
B 98%
allyltributylstanane
24850-33-7

allyltributylstanane

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

rel-(1R,2R)-1,2-diphenylpent-4-en-1-ol

rel-(1R,2R)-1,2-diphenylpent-4-en-1-ol

Conditions
ConditionsYield
ytterbium(III) triflate In tetrahydrofuran at 60℃; for 22h;96%
2,6-dimethylphenyl isonitrile
119072-54-7, 2769-71-3

2,6-dimethylphenyl isonitrile

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

3-(2,6-dimethylphenylamino)-2-(2,6-dimethylphenylimino)-4,5-diphenyl-2,5-dihydrofuran

3-(2,6-dimethylphenylamino)-2-(2,6-dimethylphenylimino)-4,5-diphenyl-2,5-dihydrofuran

Conditions
ConditionsYield
With gallium(III) trichloride In diethyl ether; dichloromethane at 40℃; for 2h;96%
orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

2,2-diphenylacetaldehyde diethyl acetal
67820-48-8

2,2-diphenylacetaldehyde diethyl acetal

Conditions
ConditionsYield
With mesoporous aluminosilicate catalyst, Si/Al ratio = 14:1 In chloroform at 20 - 55℃;96%
trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

cis-stilben
645-49-8

cis-stilben

Conditions
ConditionsYield
With Amberlyst 15; sodium iodide In acetone at 20℃; for 3h; deoxygenation;95%
With lithium; di-o-anisylphosphinyl chloride; methyl iodide 1.) THF, 4.5 h, 2.) THF, RT; 1 h; Yield given. Multistep reaction;
Multi-step reaction with 3 steps
1: NaH / acetonitrile / 24 h / 20 °C
2: Oxone / methanol; H2O / 24 h / 20 °C
3: KOH; tetrabutylammonium bromide / tetrahydrofuran / 16 h / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: 1.) n-BuLi / 1.) THF, room t., 2.) THF, room t.
2: t-BuOK / CD3CN / -10 °C
View Scheme
Multi-step reaction with 3 steps
1: 75 percent / KOH / propan-1-ol / 8 h / Heating
2: 75 percent / m-chloroperoxybenzoic acid / CH2Cl2
3: 51 percent / N-chlorosuccinimide / benzene / 1 h / Heating
View Scheme
lithium diphenylphosphide
65567-06-8, 4541-02-0

lithium diphenylphosphide

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

(1RS,2SR)-1,2-diphenyl-2-diphenylphosphinoylmethan-1-ol
88652-80-6, 88652-81-7, 101896-50-8, 103786-11-4, 103786-12-5

(1RS,2SR)-1,2-diphenyl-2-diphenylphosphinoylmethan-1-ol

Conditions
ConditionsYield
In tetrahydrofuran93%
trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

(±)-trans-2-bromo-1,2-diphenylethan-1-ol
10368-43-1

(±)-trans-2-bromo-1,2-diphenylethan-1-ol

Conditions
ConditionsYield
With magnesium bromide In diethyl ether at 0℃; for 4h;92%
With diethyl ether; hydrogen bromide
2-Mercaptopyridine
2637-34-5

2-Mercaptopyridine

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

(S*,R*)-2-<(2-hydroxy-1,2-diphenylethyl)thio>pyridine

(S*,R*)-2-<(2-hydroxy-1,2-diphenylethyl)thio>pyridine

Conditions
ConditionsYield
With triethylamine In methanol for 18h; 0 deg C to r.t.;92%
2-buten-4-olide
497-23-4

2-buten-4-olide

trans-Stilbene oxide
1439-07-2

trans-Stilbene oxide

2,4-Diphenyl-3,7-dioxabicyclo<3.3.0>octan-8-one
72510-99-7, 90582-00-6

2,4-Diphenyl-3,7-dioxabicyclo<3.3.0>octan-8-one

Conditions
ConditionsYield
With naphthalene-1,4-dicarbonitrile In acetonitrile Irradiation;92%
With naphthalene-1,4-dicarbonitrile In acetonitrile Irradiation;90%

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