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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 3-Nitro-2-Methyl benzoic acid(1975-50-4)

Cas:1975-50-4

Min.Order:100 Gram

Negotiable

Type:Other

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2-Methyl-3-nitrobenzoic acid Manufacturer/High quality/Best price/In stock

Cas:1975-50-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

1975-50-4 Product Description Product Name 2-Methyl-3-nitrobenzoic acid CAS No. 1975-50-4

3-Nitro-o-toluic acid

Cas:1975-50-4

Min.Order:1 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Methyl-3-Nitrobenzoic Acid supplier in China

Cas:1975-50-4

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Wuhan Fortuna Chemical Co.,Ltd

Unique advantages Guaranteed purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:White to pale yellow crystalline powder Storage:cool dry place Package:1kg/foil bag;25kg/drum Application:pharmace

Manufacturer high quality 2-Methyl-3-nitrobenzoic acid Cas 1975-50-4 with good price

Cas:1975-50-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

2-Methyl-3-nitrobenzoic acid

Cas:1975-50-4

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Methyl-3-Nitrobenzoic Acid

Cas:1975-50-4

Min.Order:1

Negotiable

Type:Other

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

2-Methyl-3-nitrobenzoic acid

Cas:1975-50-4

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-Methyl-3-Nitrobenzoic Acid

Cas:1975-50-4

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Chemwill Asia co.,Ltd is one of the leading manufacturer in CHINA. Product quality, process, price and service 2-Methyl-3-nitrobenzoic acid CAS 1975-50-4 3-Nitro-o-toluic acid IN STOCK 2-methyl-3-nitrobenzoate CAS 1975-50-4 2-Methyl-

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. High quality and competitive price: 1) Standard: BP/USP/EP/ enterprise standard 2) All purity ≥99% 3) We are manufacturers and can provide high quality products at factory prices. 2. Fast and safe delivery 1) The package c

2-Methyl-3-nitrobenzoic acid CAS:1975-50-4

Cas:1975-50-4

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

1975-50-4 2-Methyl-3-nitrobenzoic acid

Cas:1975-50-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 1975-50-4 with best quality

Cas:1975-50-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Chemical Name:2-Methyl-3-nitrobenzoic acid CAS No.:1975-50-4 Molecular Fomula:C8H7NO4 Molecular weight: 181.15 Appearance: White powder Assay:99%min Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg

2-Methyl-3-nitrobenzoic acid? CAS:1975-50-4

Cas:1975-50-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoicacid, 2-methyl-3-nitro- 1975-50-4

Cas:1975-50-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Methyl-3-nitro benzoic acid

Cas:1975-50-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Methyl-3-Nitrobenzoic Acid

Cas:1975-50-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2-METHYL-3-NITROBENZOIC ACID

Cas:1975-50-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Methyl-3-nitrobenzoic acid

Cas:1975-50-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

our strengths: 1: Fast and guaranteed shipment (TNT;EMS;FEDEX;DHL;UPS;EUB, special line) 2: Various payment items accepted (Btc; MoneyGram; WU) 3: Valued package (Paraffin coating; Double aluminum foil bag; Vacuum packaging) 4: Efficient delivery

High purity 2-Methyl-3-nitrobenzoic acid

Cas:1975-50-4

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and als

2-Methyl-3-nitrobenzoic acid

Cas:1975-50-4

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:white crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermediates Transportati

2-Methyl-3-nitrobenzoic acid

Cas:1975-50-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: 2-Methyl-3-Nitrobenzoic Acid CAS No.:1975-50-4 Molecule Formula:C8H6NO4 Molecule Weight:180.14 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard

Best Quality 2-Methyl-3-Nitrobenzoic Acid

Cas:1975-50-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2-Methyl-3-nitrobenzoic acid

Cas:1975-50-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)

2-Methyl-3-nitrobenzoic acid CAS NO.: 1975-50-4

Cas:1975-50-4

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2-Methyl-3-nitrobenzoicacid

Cas:1975-50-4

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

2-Methyl-3-nitrobenzoic acid Basic information Product Name: 2-Methyl-3-nitrobenzoic acid Synonyms: AKOS BB-9542;3-NITRO-O-TOLUIC ACID;3-NITRO-2-METHYLBENZOIC ACID;2-methyl-3-nitro-benzoicaci;Lenalidomide Impurity 26;1975-50-4 2-Methyl-3-nitro

2-Methyl-3-nitrobenzoic acid

Cas:1975-50-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

2-MeHangzhou Fandachem Co.,Ltd, a China-based chemical company, specialize in exporting 3-Nitro-o-toluic Acid (2-Methyl-3-nitrobenzoic acid;3-Nitro-2-methylbenzoic Acid),CAS:1975-50-4, Please contact us by email freely. We are leading exporte

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

1975-50-4 CAS NO.1975-50-4

Cas:1975-50-4

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

ProductName:2-Methyl-3-nitrobenzoic acid CAS:1975-50-4 Synonyms:Benzoicacid,2-methyl-3-nitro-;2-Methyl-3-Nitrobenzoic Acid;2-Methyl-nitrobenzoic acid;3-nitro-2-Methyl benzoate;3-Nitro-2-Toluic Acid; Benzoic acid,2-methyl-3-nitro;3-Nitro-o-tol

2-Methyl-3-nitrobenzoic acid

Cas:1975-50-4

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2,3-dimethylnitrobenzene
83-41-0

2,3-dimethylnitrobenzene

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

Conditions
ConditionsYield
With dihydrogen peroxide; cobalt(II) acetate; manganese(II) acetate; hexanoic acid at 60℃; for 12h; Temperature; Reagent/catalyst;87%
(i) Br2, KOH, (ii) (hydrolysis); Multistep reaction;
Multi-step reaction with 3 steps
1: H2SO4, CrO3
2: H2SO4
3: KMnO4, NaHCO3
View Scheme
With nitric acid at 125℃; for 1h; Temperature; High pressure;
With oxygen; cobalt(II) acetate; manganese(II) acetate; acetic acid; sodium bromide In water at 133 - 136℃; under 7500.75 - 11251.1 Torr; for 7.5h; Reagent/catalyst; Temperature; Pressure;32 g
2-methyl-3-nitro-benzoic acid methyl ester
59382-59-1

2-methyl-3-nitro-benzoic acid methyl ester

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

A

2-[trans-2-(4-fluorophenyl)-vinyl]-3-nitrobenzoic acid
917614-64-3

2-[trans-2-(4-fluorophenyl)-vinyl]-3-nitrobenzoic acid

B

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dimethyl sulfoxide at 20 - 50℃; for 12.5h;A 84%
B n/a
ortho-methylbenzoic acid
118-90-1

ortho-methylbenzoic acid

A

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

B

5-nitro-o-toluic acid
1975-52-6

5-nitro-o-toluic acid

Conditions
ConditionsYield
With nitric acid at 0℃;
With nitric acid
With nitric acid
2-Methyl-benzoic acid methyl ester
89-71-4

2-Methyl-benzoic acid methyl ester

A

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

B

methyl 2-methyl-5-nitrobenzoate
77324-87-9

methyl 2-methyl-5-nitrobenzoate

Conditions
ConditionsYield
bei der Nitrierung;
2-methyl-3-nitrobenzonitrile
71516-35-3

2-methyl-3-nitrobenzonitrile

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

Conditions
ConditionsYield
With sulfuric acid at 150℃;
2,3-dimethylnitrobenzene
83-41-0

2,3-dimethylnitrobenzene

A

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

B

2-methyl-6-nitrobenzoic acid
13506-76-8

2-methyl-6-nitrobenzoic acid

C

3-nitrophthalic acid
603-11-2

3-nitrophthalic acid

Conditions
ConditionsYield
With potassium permanganate; cetyltrimethylammonim bromide In water at 75℃; for 4h; Product distribution; effect of the amount of KMnO4; further catalysts;
With potassium permanganate; cetyltrimethylammonim bromide In water at 75℃; for 4h; Yield given. Yields of byproduct given;
With potassium permanganate; tetrabutylammomium bromide In water
With oxygen; nitric acid at 130 - 140℃; under 16501.7 - 18751.9 Torr; for 7h; Temperature; Pressure;
3-formyl-2-methyl-1-nitrobenzene
23876-12-2

3-formyl-2-methyl-1-nitrobenzene

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

Conditions
ConditionsYield
With potassium permanganate; sodium hydrogencarbonate
2-Methylbenzonitrile
529-19-1

2-Methylbenzonitrile

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: alcoholic potash
2: concentrated nitric acid
View Scheme
o-xylene
95-47-6

o-xylene

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: diluted nitric acid
2: concentrated nitric acid
View Scheme
Multi-step reaction with 2 steps
1: nitric acid; sulfuric acid / water / 0.5 h / -10 °C
2: nitric acid / 1 h / 125 °C / High pressure
View Scheme
3,4-dimethylbenzoic acid
619-04-5

3,4-dimethylbenzoic acid

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: bei der Destillation
2: diluted nitric acid
3: concentrated nitric acid
View Scheme
2-methyl-3-nitrobenzol-1-methandiol diacetate
23876-11-1

2-methyl-3-nitrobenzol-1-methandiol diacetate

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: H2SO4
2: KMnO4, NaHCO3
View Scheme
2,3-dimethylnitrobenzene
83-41-0

2,3-dimethylnitrobenzene

A

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

B

(2-methyl-3-nitrophenyl)methanol
23876-13-3

(2-methyl-3-nitrophenyl)methanol

C

3-formyl-2-methyl-1-nitrobenzene
23876-12-2

3-formyl-2-methyl-1-nitrobenzene

Conditions
ConditionsYield
Stage #1: 2,3-dimethylnitrobenzene With C88H64CrMnN16O; cobalt isooctanoate; oxygen; 4-methyl-2-hydroxy-1(H)-isoindole-1,3-dione at 100℃; under 750.075 Torr;
Stage #2: With water at 50℃; under 750.075 Torr;
2,3-dimethylnitrobenzene
83-41-0

2,3-dimethylnitrobenzene

A

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

B

2-methyl-6-nitrobenzoic acid
13506-76-8

2-methyl-6-nitrobenzoic acid

C

3-nitrophthalic acid
603-11-2

3-nitrophthalic acid

D

C8H7NO5

C8H7NO5

Conditions
ConditionsYield
With oxygen; nitric acid at 145 - 150℃; under 26252.6 - 30003 Torr; for 8h; Temperature; Pressure;
2,3-dimethylnitrobenzene
83-41-0

2,3-dimethylnitrobenzene

butan-1-ol
71-36-3

butan-1-ol

A

butyl 3-nitro-2-methylbenzoate
59383-02-7

butyl 3-nitro-2-methylbenzoate

B

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

C

2-methyl-6-nitrobenzoic acid
13506-76-8

2-methyl-6-nitrobenzoic acid

Conditions
ConditionsYield
Stage #1: 2,3-dimethylnitrobenzene With oxygen; nitric acid at 130 - 140℃; under 16501.7 - 18751.9 Torr; for 7h;
Stage #2: butan-1-ol With toluene-4-sulfonic acid Reflux;
butyl 3-nitro-2-methylbenzoate
59383-02-7

butyl 3-nitro-2-methylbenzoate

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

Conditions
ConditionsYield
With sodium hydroxide In water at 100℃;135 g
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

(2-methyl-3-nitrophenyl)methanol
23876-13-3

(2-methyl-3-nitrophenyl)methanol

Conditions
ConditionsYield
With borane In tetrahydrofuran100%
Stage #1: 2-methyl-3-nitrobenzic acid With sodium tetrahydroborate In tetrahydrofuran at 20℃; for 0.5h;
Stage #2: With methanesulfonic acid In tetrahydrofuran
84%
Multi-step reaction with 2 steps
1: SOCl2
2: NaBH4 / tetrahydrofuran
View Scheme
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

5-bromo-2-methyl-3-nitro-benzoic acid
107650-20-4

5-bromo-2-methyl-3-nitro-benzoic acid

Conditions
ConditionsYield
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; sulfuric acid at 20℃; for 5h; Product distribution / selectivity;100%
Stage #1: 2-methyl-3-nitrobenzic acid With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; sulfuric acid at 20℃; for 5h;
Stage #2: With water Product distribution / selectivity; Cooling;
100%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; sulfuric acid at 0℃; for 5h;100%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

copper(l) cyanide

copper(l) cyanide

C9H6N2O3

C9H6N2O3

Conditions
ConditionsYield
Stage #1: copper(l) cyanide With sodium iodide In acetonitrile at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: 2-methyl-3-nitrobenzic acid In acetonitrile at 20℃; for 1h; Inert atmosphere;
100%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

2-methyl-3-nitrobenzoyl chloride
39053-41-3

2-methyl-3-nitrobenzoyl chloride

Conditions
ConditionsYield
With thionyl chloride at 60℃; for 25.5h; Inert atmosphere;99%
With thionyl chloride for 6h; Reflux;99%
With thionyl chloride at 60℃; for 24h;98%
methanol
67-56-1

methanol

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

2-methyl-3-nitro-benzoic acid methyl ester
59382-59-1

2-methyl-3-nitro-benzoic acid methyl ester

Conditions
ConditionsYield
With sulfuric acid for 24h; Inert atmosphere; Reflux;99%
Stage #1: 2-methyl-3-nitrobenzic acid With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃;
Stage #2: methanol In dichloromethane for 0.0833333h;
99%
With thionyl chloride for 2h; Reflux;98%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

3-amino-2-methylbenzoic acid
52130-17-3

3-amino-2-methylbenzoic acid

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In ethanol at 20℃; Catalytic hydrogenation;98%
With palladium on activated charcoal; hydrogen In ethyl acetate for 15h;90%
With ammonium hydroxide; hydrogen sulfide
ethanol
64-17-5

ethanol

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

ethyl 2-methyl-3-nitrobenzoate
59382-60-4

ethyl 2-methyl-3-nitrobenzoate

Conditions
ConditionsYield
With sulfuric acid at 20℃; for 168h;98%
With thionyl chloride at 0 - 70℃;79%
1-bromo-hexane
111-25-1

1-bromo-hexane

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

hexyl 2-methyl-3-nitrobenzoate
59383-04-9

hexyl 2-methyl-3-nitrobenzoate

Conditions
ConditionsYield
With potassium carbonate In acetone for 96h; Reflux;98%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

dimethyl sulfate
77-78-1

dimethyl sulfate

2-methyl-3-nitro-benzoic acid methyl ester
59382-59-1

2-methyl-3-nitro-benzoic acid methyl ester

Conditions
ConditionsYield
Stage #1: 2-methyl-3-nitrobenzic acid With potassium carbonate In acetone at 20℃; for 0.166667h;
Stage #2: dimethyl sulfate In acetone for 4h; Reflux;
98%
Stage #1: 2-methyl-3-nitrobenzic acid; dimethyl sulfate In acetone at 25 - 30℃; for 0.166667h;
Stage #2: With potassium carbonate In acetone at 25 - 30℃; for 1.5h;
97.53%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

5-iodo-2-methyl-3-nitrobenzoic acid

5-iodo-2-methyl-3-nitrobenzoic acid

Conditions
ConditionsYield
With N-iodo-succinimide; sulfuric acid at 60℃; for 2h;98%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

4-bromo-aniline
106-40-1

4-bromo-aniline

N-(4-bromophenyl)-2-methyl-3-nitrobenzamide

N-(4-bromophenyl)-2-methyl-3-nitrobenzamide

Conditions
ConditionsYield
With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine In dichloromethane at 0 - 20℃; for 3h;89%
d(4)-methanol
811-98-3

d(4)-methanol

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

C9H6(2)H3NO4

C9H6(2)H3NO4

Conditions
ConditionsYield
With sulfuric acid for 72h; Heating;88%
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

3-<<(1,1-dimethylethoxy)carbonyl>amino>-2-methylbenzoic acid
143617-89-4

3-<<(1,1-dimethylethoxy)carbonyl>amino>-2-methylbenzoic acid

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In N,N-dimethyl-formamide under 2585.7 Torr; for 2.5h;86%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

methyl iodide
74-88-4

methyl iodide

2-methyl-3-nitro-benzoic acid methyl ester
59382-59-1

2-methyl-3-nitro-benzoic acid methyl ester

Conditions
ConditionsYield
With sodium hydrogencarbonate In N,N-dimethyl-formamide at 60℃; for 24h;86%
With potassium hydrogencarbonate 1.) DMF, 40 deg C, 2.) DMF, RT, 12 h; Yield given; Multistep reaction;
1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione
77-48-5

1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

5-bromo-2-methyl-3-nitro-benzoic acid
107650-20-4

5-bromo-2-methyl-3-nitro-benzoic acid

Conditions
ConditionsYield
With sulfuric acid at 20℃; for 5h;84%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

N,N-dimethyl-formamide dimethyl acetal
4637-24-5

N,N-dimethyl-formamide dimethyl acetal

Methyl trans-2-<β-(dimethylamino)vinyl>-3-nitrobenzoate
73816-11-2

Methyl trans-2-<β-(dimethylamino)vinyl>-3-nitrobenzoate

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 115℃; for 24h;80%
Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 12h; Inert atmosphere;80%
2'-hydroxy-6'-methoxyacetophenone
703-23-1

2'-hydroxy-6'-methoxyacetophenone

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

6'-methoxy-2'-(2-methyl-3-nitrobenzoyloxy)acetophenone
953129-19-6

6'-methoxy-2'-(2-methyl-3-nitrobenzoyloxy)acetophenone

Conditions
ConditionsYield
With POCl2 In pyridine at 60 - 70℃; for 3h;78%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

triphenyltin(IV) hydroxide
76-87-9

triphenyltin(IV) hydroxide

C27H25NO5Sn
1320287-24-8

C27H25NO5Sn

Conditions
ConditionsYield
In methanol for 1h; Reflux;77.7%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

magnesium bis(3-ethoxy-3-oxopropanoate)
37517-78-5

magnesium bis(3-ethoxy-3-oxopropanoate)

ethyl 3-(2-methyl-3-nitrophenyl)-3-oxopropionate
136774-69-1

ethyl 3-(2-methyl-3-nitrophenyl)-3-oxopropionate

Conditions
ConditionsYield
With 1,1'-carbonyldiimidazole In tetrahydrofuran76%
With 1,1'-carbonyldiimidazole In tetrahydrofuran
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

3-amino-2-methylbenzoic acid hydrochloride
141607-18-3

3-amino-2-methylbenzoic acid hydrochloride

Conditions
ConditionsYield
Stage #1: 2-methyl-3-nitrobenzic acid With hydrogen; sodium hydroxide In water at 150℃; under 76005.1 Torr; for 12h;
Stage #2: With hydrogenchloride In water pH=2;
75%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

2-(4-methoxyphenyl)quinoline-4-carbohydrazide
51842-77-4

2-(4-methoxyphenyl)quinoline-4-carbohydrazide

2-(4-methoxyphenyl)-4-(5-(2-methyl-3-nitrophenyl)-1,3,4-oxadiazol-2-yl)quinoline

2-(4-methoxyphenyl)-4-(5-(2-methyl-3-nitrophenyl)-1,3,4-oxadiazol-2-yl)quinoline

Conditions
ConditionsYield
With trichlorophosphate Reflux;75%
7-azaindoline
10592-27-5

7-azaindoline

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)(2-methylnitrophenyl)methanone

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)(2-methylnitrophenyl)methanone

Conditions
ConditionsYield
Stage #1: 2-methyl-3-nitrobenzic acid With N-Bromosuccinimide; triphenylphosphine In dichloromethane at 0℃; for 0.5h;
Stage #2: 7-azaindoline With triethylamine In dichloromethane at 20℃; for 1h;
75%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

N,O-dimethylhydroxylamine*hydrochloride
6638-79-5

N,O-dimethylhydroxylamine*hydrochloride

N-methoxy-N,2-dimethyl-3-nitrobenzamide
177963-15-4

N-methoxy-N,2-dimethyl-3-nitrobenzamide

Conditions
ConditionsYield
Stage #1: 2-methyl-3-nitrobenzic acid With N-Bromosuccinimide; triphenylphosphine In dichloromethane at 0℃; for 0.25h;
Stage #2: N,O-dimethylhydroxylamine*hydrochloride With triethylamine In dichloromethane at 20℃; for 1h; chemoselective reaction;
74%
Stage #1: 2-methyl-3-nitrobenzic acid With 1,1'-carbonyldiimidazole In dichloromethane at 0 - 20℃; for 2.5h;
Stage #2: N,O-dimethylhydroxylamine*hydrochloride In dichloromethane at 0 - 45℃; for 13.5h;
21%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

4-tert-butyl-5-(2,4-dichlorobenzyl)thiazol-2-amine

4-tert-butyl-5-(2,4-dichlorobenzyl)thiazol-2-amine

N-(4-(tert-butyl)-5-(2,4-dichlorobenzyl)thiazol-2-yl)-2-methyl-3-nitrobenzamide

N-(4-(tert-butyl)-5-(2,4-dichlorobenzyl)thiazol-2-yl)-2-methyl-3-nitrobenzamide

Conditions
ConditionsYield
Stage #1: 2-methyl-3-nitrobenzic acid; 4-tert-butyl-5-(2,4-dichlorobenzyl)thiazol-2-amine With dmap In dichloromethane at 20℃; for 0.5h;
Stage #2: With dicyclohexyl-carbodiimide In dichloromethane at 20℃;
74%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

6-methyldodec-7-yn-6-yl acetate

6-methyldodec-7-yn-6-yl acetate

C21H29NO4

C21H29NO4

Conditions
ConditionsYield
With [RhCl2(p-cymene)]2; potassium carbonate In ethanol at 50℃; for 48h;73%
active charcoal

active charcoal

2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

3-acetoxy-2-methylbenzoic acid
168899-58-9

3-acetoxy-2-methylbenzoic acid

Conditions
ConditionsYield
With sodium hydroxide; sulfuric acid; acetic anhydride; magnesium sulfate; sodium nitrite; palladium-carbon In pyridine; ethanol; ethyl acetate; toluene72%
2-methyl-3-nitrobenzic acid
1975-50-4

2-methyl-3-nitrobenzic acid

di(n-butyl)tin oxide
818-08-6

di(n-butyl)tin oxide

C64H96N4O18Sn4
1448543-52-9

C64H96N4O18Sn4

Conditions
ConditionsYield
In ethanol; hexane for 3h; Reflux;72%

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