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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Methylindene Manufacturer/High quality/Best price/In stock

Cas:2177-47-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Methyl-1H-indene

Cas:2177-47-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

2-Methylindene CAS:2177-47-1

Cas:2177-47-1

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Standard CAS 2177-47-1 with high-quality service

Cas:2177-47-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1H-Indene, 2-methyl-

Cas:2177-47-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1H-Indene, 2-methyl-

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality moderate price & quick delivery Appearance:transparent to yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Use

1H-Indene, 2-methyl-

Cas:2177-47-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2-Methylindene

Cas:2177-47-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

2-Methylindene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Methylindene cas no. 2177-47-1 98%

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-Methyl-1H-indene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

2-Methyl-1H-indene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2-Methylindene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our advantage:Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scient

TIANFU-CHEM 2-Methylindene

Cas:2177-47-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

TIANFU-CHEM 2-MethylindeneAppearance:white powder Storage:room temperature Package:200KG Application:Industrial Grade Transportation:By sea , by air or express

TIANFU-CHEM 2-Methylindene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

2-Methylindene cas 2177-47-1Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-Methylindene cas 2177-47-1

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:transparent to yellow liquid Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

2-Methylindene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-Methylindene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

2-Methylindene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Bide Pharmatech Ltd

Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

2-Methyl-1H-indene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Other

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

2-methyl-1H-indene

Cas:2177-47-1

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

2-Methylindene Basic information Product Name: 2-Methylindene

2177-47-1 C10H10 2-Methylindene

Cas:2177-47-1

Min.Order:100 Gram

Negotiable

Type:Trading Company

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

2-Methylindene CAS NO.2177-47-1

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Yinghao Pharm Co.,Ltd.

Yinghao Pharm products include: leader molecule, heterocyclic compounds,chiral compounds, photoelectric materials, biochemical reagents etc. For example:benzene, pyrimidine, boricacid,pyridine, pyrazole, imidazole, pyrrole, fluorine and other derivat

2-Methyl-1H-indene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemical Technology Co.,LTD

1. Production capacity: we have three production base with high-tech production equipment and instruments, equipped with professional production personnel, meet your requirements.2. Quality assurance: we have a first-class testing equipment and testi

2-Methylindene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Other

inquiry

Capot Chemical Co., Ltd.

At Capot,We can synthesize and purify your complex molecules from 100 gram to 10 tons.Appearance:Clear colorless to light yellow liquid Storage:Dry,Seal and Cool place Package:1G,5G,10G,25G,100G,250G,500G,1KG,5KG,10KG,25KG,50KG,100KG,150KG,200KG. App

2-Methyl-1H-indene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai PotentPharm Science and Technology Co.,Ltd

1 good quality, better price and bettter service;2 Timely delivery;3 100% refunded if parcel is t delivered or poor quality.We will try to satisfy you upon receipt of your reply. I hope that we can become a long-term cooperative partner. Application:

1H-Indene, 2-methyl-

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHENFEI INDUSTRY CO.,LTD

Zhenfei industry Co., Ltd is a modern scientific research company specialized in the marketing of impurity reference substances, APIs, technology transfer and pharmaceutical raw materials,and intermediateAppearance:white crystalline powder Storage:St

2-Methyl-1H-indene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 2-Methylindene, CAS:2177-47-1 with the most competitive price and the best quality. W

2-Methylindene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

SHANGHAI ZZBIO CO., LTD.

Comprehensive range product, High quality, Quick shippment, COA with spectras Package:1g Application:pharmaceutical industry, food industry, research

2-Methyl-1H-indene

Cas:2177-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2,3-dihydro-2-methyl-1H-inden-1-one
17496-14-9

2,3-dihydro-2-methyl-1H-inden-1-one

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
With toluene-4-sulfonic acid; 2,2-Dimethyl-1,3-propanediol In toluene for 24h; Reflux;92%
With oxalic acid
Multi-step reaction with 2 steps
1: NaBH4 / tetrahydrofuran; methanol / 4 h / 25 °C
2: p-toluenesulfonic acid*H2O / benzene / 1 h / Heating
View Scheme
2-methylene-2,3-dihydro-1H-indene
68846-65-1

2-methylene-2,3-dihydro-1H-indene

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
With hydrogen bromide In acetonitrile for 1h; Heating;90%
2-bromoindene
10485-09-3

2-bromoindene

[3-(dimethylamino)propyl]dimethyl aluminium(III)

[3-(dimethylamino)propyl]dimethyl aluminium(III)

A

2-Methylindene
2177-47-1

2-Methylindene

B

1,2-dimethylindene
70063-93-3

1,2-dimethylindene

C

1-indene
95-13-6

1-indene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine)palladium dichloride In benzene at 80℃; for 2h; Yields of byproduct given;A 88%
B n/a
C n/a
2-Trimethylsilanylmethyl-indan-2-ol
105991-56-8

2-Trimethylsilanylmethyl-indan-2-ol

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
With potassium hydride In tetrahydrofuran Ambient temperature;86%
1,1-dibromo-3-(2-bromophenyl)-2-methylpropene
507261-02-1

1,1-dibromo-3-(2-bromophenyl)-2-methylpropene

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane at -90℃; for 0.5h;85%
Stage #1: 1,1-dibromo-3-(2-bromophenyl)-2-methylpropene With n-butyllithium In tetrahydrofuran; hexane at -90℃; for 0.5h;
Stage #2: With methanol; ammonium chloride In tetrahydrofuran; hexane
85%
1-allyl-2-(chloromethyl)benzene
89121-39-1

1-allyl-2-(chloromethyl)benzene

A

2-Methylindene
2177-47-1

2-Methylindene

B

2-methylene-2,3-dihydro-1H-indene
68846-65-1

2-methylene-2,3-dihydro-1H-indene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); triethylamine In acetonitrile for 1h; Heating;A 1%
B 82%
With tetrakis(triphenylphosphine) palladium(0); triethylamine In acetonitrile for 1h; Product distribution; Heating; other o-alkenyl- and o-alkynylbenzyl halides, other time, other reagents;A 1%
B 82%
1-allyl-2-(bromomethyl)benzene
120906-16-3

1-allyl-2-(bromomethyl)benzene

A

2-Methylindene
2177-47-1

2-Methylindene

B

2-methylene-2,3-dihydro-1H-indene
68846-65-1

2-methylene-2,3-dihydro-1H-indene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); triethylamine In acetonitrile for 0.5h; Heating;A 1%
B 82%
2-hydroxy-2-methylindan
33223-84-6

2-hydroxy-2-methylindan

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 4h; Dehydration; Heating;69%
With phosphoric acid at 150℃;37%
With phosphorus pentoxide; benzene
1-allyl-2-(iodomethyl)benzene
120906-17-4

1-allyl-2-(iodomethyl)benzene

A

2-Methylindene
2177-47-1

2-Methylindene

B

2-methylene-2,3-dihydro-1H-indene
68846-65-1

2-methylene-2,3-dihydro-1H-indene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); triethylamine In acetonitrile for 0.5h; Heating;A 18%
B 64%
Methanesulfonic acid 2-allyl-benzyl ester

Methanesulfonic acid 2-allyl-benzyl ester

A

2-Methylindene
2177-47-1

2-Methylindene

B

2-methylene-2,3-dihydro-1H-indene
68846-65-1

2-methylene-2,3-dihydro-1H-indene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); triethylamine In acetonitrile for 1h; Heating;A 1%
B 60%
C16H18O2S

C16H18O2S

methylmagnesium bromide
75-16-1

methylmagnesium bromide

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
With bis(triphenylphosphine)nickel(II) diiodide; tricyclohexylphosphine In tetrahydrofuran at 70℃; Kumada Cross-Coupling; Inert atmosphere; chemoselective reaction;57%
1-[(2-13C)ethynyl]-2-(prop-1-yn-1-yl)benzene

1-[(2-13C)ethynyl]-2-(prop-1-yn-1-yl)benzene

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold bis(trifluoromethanesulfonyl)imidate; water In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; Schlenk technique;53%
2,3-dihydro-2-methyl-1H-inden-1-one
17496-14-9

2,3-dihydro-2-methyl-1H-inden-1-one

2-hydroxy-2-methylindan
33223-84-6

2-hydroxy-2-methylindan

water
7732-18-5

water

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
With MeMgBr; toluene-4-sulfonic acid; hydroquinone In toluene48%
1-ethynyl-2-(prop-1-yn-1-yl)benzene
849799-68-4

1-ethynyl-2-(prop-1-yn-1-yl)benzene

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold bis(trifluoromethanesulfonyl)imidate; water In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; Schlenk technique;42%
sulfuric acid
7664-93-9

sulfuric acid

2-indanone
615-13-4

2-indanone

methyl iodide
74-88-4

methyl iodide

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
With magnesium In diethyl ether; dichloromethane; water; toluene30%
Carbonic acid 2-allyl-benzyl ester methyl ester

Carbonic acid 2-allyl-benzyl ester methyl ester

A

2-Methylindene
2177-47-1

2-Methylindene

B

2-methylene-2,3-dihydro-1H-indene
68846-65-1

2-methylene-2,3-dihydro-1H-indene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); triethylamine In acetonitrile for 120h; Heating;A 23%
B 26%
butyl magnesium bromide
693-04-9

butyl magnesium bromide

3-trifluoromethanesulfonyloxy-2-methyl-1H-indene

3-trifluoromethanesulfonyloxy-2-methyl-1H-indene

A

2-Methylindene
2177-47-1

2-Methylindene

B

3-butyl-2-methyl-1H-indene
229031-59-8

3-butyl-2-methyl-1H-indene

Conditions
ConditionsYield
1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In tetrahydrofuran; toluene at 55℃; for 2h;A n/a
B 24%
3-trifluoromethanesulfonyloxy-2-methyl-1H-indene

3-trifluoromethanesulfonyloxy-2-methyl-1H-indene

A

2-Methylindene
2177-47-1

2-Methylindene

B

3-butyl-2-methyl-1H-indene
229031-59-8

3-butyl-2-methyl-1H-indene

Conditions
ConditionsYield
With butyl magnesium bromide; 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In tetrahydrofuran; toluene at 55℃; for 2h;A n/a
B 24%
naphthalene-2-sulfonate
120-18-3

naphthalene-2-sulfonate

2-hydroxy-2-methylindan
33223-84-6

2-hydroxy-2-methylindan

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
at 140℃;
at 140℃;
2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
at 350 - 650℃; Pyrolysis;
2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
at 350 - 600℃; Pyrolysis;
2-methylindane
824-63-5

2-methylindane

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
With sodium acetate; acetic acid (electrolysis);
syn-9-Acetoxy-9-methylbicyclo <4.2.1> nona-2.4.7-trien

syn-9-Acetoxy-9-methylbicyclo <4.2.1> nona-2.4.7-trien

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
at 200℃;
tetralin
119-64-2

tetralin

decane
124-18-5

decane

A

styrene
292638-84-7

styrene

B

naphthalene
91-20-3

naphthalene

C

1,2-Dihydronaphthalene
447-53-0

1,2-Dihydronaphthalene

D

2-Methylindene
2177-47-1

2-Methylindene

E

3-Methylindene
767-60-2

3-Methylindene

F

1-indene
95-13-6

1-indene

Conditions
ConditionsYield
at 730℃; Product distribution; Mechanism; other temperature;A 4.4 % Chromat.
B 14 % Chromat.
C 35.7 % Chromat.
D 1.2 % Chromat.
E 4.3 % Chromat.
F 7.1 % Chromat.
INDANE
496-11-7

INDANE

A

naphthalene
91-20-3

naphthalene

B

1,2-Dihydronaphthalene
447-53-0

1,2-Dihydronaphthalene

C

2-Methylindene
2177-47-1

2-Methylindene

D

3-Methylindene
767-60-2

3-Methylindene

E

toluene
108-88-3

toluene

F

1-indene
95-13-6

1-indene

Conditions
ConditionsYield
at 800℃; Product distribution; Mechanism;A 2.5 % Chromat.
B 1.1 % Chromat.
C 2.6 % Chromat.
D 5.7 % Chromat.
E 4.7 % Chromat.
F 77.2 % Chromat.
1-methylene-2-phenylcyclopropane
29817-09-2, 22664-13-7

1-methylene-2-phenylcyclopropane

A

1-phenylmethylenecyclopropane
7555-67-1

1-phenylmethylenecyclopropane

B

2-Methylindene
2177-47-1

2-Methylindene

C

2-methylene-2,3-dihydro-1H-indene
68846-65-1

2-methylene-2,3-dihydro-1H-indene

Conditions
ConditionsYield
In gas at 150.7 - 280.8℃; Kinetics; Thermodynamic data; also further temperatures in the presence of O2; Ea, ΔH(excit.), ΔS(excit.);
1-Methylinden
767-59-9

1-Methylinden

2-Methylindene
2177-47-1

2-Methylindene

Conditions
ConditionsYield
In cyclohexane at 25℃; Quantum yield; Irradiation;
In hexane Quantum yield; Ambient temperature; Irradiation;
1-Methylinden
767-59-9

1-Methylinden

A

2-Methylindene
2177-47-1

2-Methylindene

B

3-Methylindene
767-60-2

3-Methylindene

Conditions
ConditionsYield
at 42℃; for 0.0166667h; Irradiation;
at 42℃; Product distribution; Irradiation; effect of excitation wavelength; various reaction times;
1-Methylinden
767-59-9

1-Methylinden

A

2-Methylindene
2177-47-1

2-Methylindene

B

3-Methylindene
767-60-2

3-Methylindene

C

1-indene
95-13-6

1-indene

Conditions
ConditionsYield
at 42℃; for 0.0166667h; Product distribution; Irradiation; initial sample temperatures from -15 deg C to 25 deg C; also with varying pressures of n-butane;
3-Methylindene
767-60-2

3-Methylindene

A

2-Methylindene
2177-47-1

2-Methylindene

B

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
at 42℃; for 0.0166667h; Irradiation;
at 42℃; Product distribution; Irradiation; effect of excitation wavelength; various reaction times;
2-Methylindene
2177-47-1

2-Methylindene

(2-methylindenyl)lithium
56423-64-4

(2-methylindenyl)lithium

Conditions
ConditionsYield
With n-butyllithium In hexane at 20℃; for 5h;98.4%
With n-butyllithium In hexane85%
1-iodo-butane
542-69-8

1-iodo-butane

2-Methylindene
2177-47-1

2-Methylindene

1-Butyl-2-methyl-1H-indene

1-Butyl-2-methyl-1H-indene

Conditions
ConditionsYield
Stage #1: 2-Methylindene With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 3h; Inert atmosphere; Cooling with ice;
Stage #2: 1-iodo-butane In tetrahydrofuran; hexane for 2h; Cooling with ice;
97%
2-Methylindene
2177-47-1

2-Methylindene

1-tert-butoxy-6-iodohexane
81060-09-5

1-tert-butoxy-6-iodohexane

3-(6-tert-butoxyhexyl)-2-methyl-1H-indene

3-(6-tert-butoxyhexyl)-2-methyl-1H-indene

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; potassium hydroxide In toluene at 25℃; for 24h;97%
2-Methylindene
2177-47-1

2-Methylindene

2-methylindane
824-63-5

2-methylindane

Conditions
ConditionsYield
With hydrogen; platinum(IV) oxide In tetrahydrofuran under 1034.3 - 1551.4 Torr;95%
With C7H14N3(1+)*Cl(1-); sodium triethylborohydride; cobalt(II) chloride In tetrahydrofuran at 60℃; under 37503.8 Torr; for 16h; Autoclave;95%
With hydrogen; palladium on activated charcoal In hexane for 5h; Catalytic hydrogenation;91%
2-Methylindene
2177-47-1

2-Methylindene

2,2'-dimethyl-1,1'-biindenyl
110452-27-2

2,2'-dimethyl-1,1'-biindenyl

Conditions
ConditionsYield
With n-butyllithium; copper dichloride 1.) ether, -30 deg C, 30 min, 2.) ether, -30 deg C, 30 min;95%
diiodomethane
75-11-6

diiodomethane

2-Methylindene
2177-47-1

2-Methylindene

5-Methyl-2,3-benzobicyclo<3.1.0>hex-2-en
78926-56-4

5-Methyl-2,3-benzobicyclo<3.1.0>hex-2-en

Conditions
ConditionsYield
Stage #1: diiodomethane With diethylzinc; trifluoroacetic acid In hexane; dichloromethane for 0.333333h; cooling;
Stage #2: 2-Methylindene In hexane; dichloromethane at 20℃; for 3h;
94%
2-Methylindene
2177-47-1

2-Methylindene

chloro-diphenylphosphine
1079-66-9

chloro-diphenylphosphine

3-(diphenylphosphino)-2-methylindene
718638-63-2

3-(diphenylphosphino)-2-methylindene

Conditions
ConditionsYield
Stage #1: 2-Methylindene With n-butyllithium In diethyl ether at -78 - 20℃;
Stage #2: chloro-diphenylphosphine In diethyl ether at -78 - 20℃;
94%
2-Methylindene
2177-47-1

2-Methylindene

7-(bromomethyl)-2-methyl-1H-indene
1126942-56-0

7-(bromomethyl)-2-methyl-1H-indene

2-methyl-1-[(2-methyl-1H-inden-7-yl)methyl]-1H-indene
1126942-68-4

2-methyl-1-[(2-methyl-1H-inden-7-yl)methyl]-1H-indene

Conditions
ConditionsYield
Stage #1: 2-Methylindene With n-butyllithium In diethyl ether; hexane at 0 - 20℃; for 2h;
Stage #2: 7-(bromomethyl)-2-methyl-1H-indene In tetrahydrofuran; diethyl ether; hexane at -80 - 20℃; for 12h;
92%
bromobenzene
108-86-1

bromobenzene

2-Methylindene
2177-47-1

2-Methylindene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

4,4,5,5-tetramethyl-2-(2-methyl-1-phenyl-2,3-dihydro-1H-inden-2-yl)-1,3,2-dioxaborolane

4,4,5,5-tetramethyl-2-(2-methyl-1-phenyl-2,3-dihydro-1H-inden-2-yl)-1,3,2-dioxaborolane

Conditions
ConditionsYield
Stage #1: bis(pinacol)diborane With potassium ethoxide In N,N-dimethyl acetamide at 20℃; for 1h; Inert atmosphere; Sealed tube;
Stage #2: bromobenzene; 2-Methylindene With (1,2-dimethoxyethane)dichloronickel(II) In N,N-dimethyl acetamide at 0 - 20℃; for 24h; Inert atmosphere; Sealed tube;
91%
2-Methylindene
2177-47-1

2-Methylindene

chloro(dimethyl)(2-methyl-1H-inden-7-yl)silane
1126942-58-2

chloro(dimethyl)(2-methyl-1H-inden-7-yl)silane

dimethyl(2-methyl-1H-inden-1-yl)(2-methyl-1H-inden-7-yl)silane
1126942-86-6

dimethyl(2-methyl-1H-inden-1-yl)(2-methyl-1H-inden-7-yl)silane

Conditions
ConditionsYield
Stage #1: 2-Methylindene With n-butyllithium In diethyl ether; hexane at 0 - 20℃; for 12h;
Stage #2: With copper(l) cyanide In diethyl ether; hexane at -50 - -30℃; for 1h;
Stage #3: chloro(dimethyl)(2-methyl-1H-inden-7-yl)silane In diethyl ether; hexane at -80 - 20℃; for 12h;
88%
1-methyl-1H-imidazole
616-47-7

1-methyl-1H-imidazole

2-Methylindene
2177-47-1

2-Methylindene

ammonium chloride

ammonium chloride

dimethylsilicon dichloride
75-78-5

dimethylsilicon dichloride

bis(2-methyl-1-indenyl)-dimethylsilane
143232-13-7

bis(2-methyl-1-indenyl)-dimethylsilane

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; toluene87%
2-Methylindene
2177-47-1

2-Methylindene

cyclohexa-2,5-dien-1-yltriethylgermane

cyclohexa-2,5-dien-1-yltriethylgermane

triethyl(2-methyl-2,3-dihydro-1H-inden-2-yl)germane

triethyl(2-methyl-2,3-dihydro-1H-inden-2-yl)germane

Conditions
ConditionsYield
With tris(pentafluorophenyl)borate at 20℃; for 3h; Glovebox;87%
2-Methylindene
2177-47-1

2-Methylindene

2-bromoindene
10485-09-3

2-bromoindene

dimethylsilicon dichloride
75-78-5

dimethylsilicon dichloride

C21H22Si

C21H22Si

Conditions
ConditionsYield
Stage #1: 2-bromoindene With iodine; magnesium In tetrahydrofuran at 80℃; for 3h; Inert atmosphere;
Stage #2: dimethylsilicon dichloride In tetrahydrofuran; hexane at -78℃; for 18h;
Stage #3: 2-Methylindene With 1,3-dimethyl-2-imidazolidinone; n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 5h; Inert atmosphere;
87%
dimethylmonochlorosilane
1066-35-9

dimethylmonochlorosilane

2-Methylindene
2177-47-1

2-Methylindene

3-dimethylsilyl-2-methylindene

3-dimethylsilyl-2-methylindene

Conditions
ConditionsYield
Stage #1: 2-Methylindene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h; Metallation;
Stage #2: dimethylmonochlorosilane In tetrahydrofuran; hexane at 20℃; for 12h; silylation; Further stages.;
86%
2-Methylindene
2177-47-1

2-Methylindene

2-methylindene oxide
3199-85-7

2-methylindene oxide

Conditions
ConditionsYield
With dihydrogen peroxide; Ru(2,2':6',2''-terpyridine)(2,6-pyridinedicarboxylate) In tert-Amyl alcohol at 20℃; for 12h; Conversion of starting material;86%
With dihydrogen peroxide; ruthenium(2,2',6':2''-terpyridine)(2,6-pyridinedicarboxylate) In tert-Amyl alcohol at 20℃; for 12h;86 % Chromat.
2-Methylindene
2177-47-1

2-Methylindene

chloro(1,3-dimethyl-1H-inden-2-yl)dimethylsilane

chloro(1,3-dimethyl-1H-inden-2-yl)dimethylsilane

(1,3-dimethyl-1H-inden-2-yl)(2-methyl-1H-inden-1-yl)dimethylsilane

(1,3-dimethyl-1H-inden-2-yl)(2-methyl-1H-inden-1-yl)dimethylsilane

Conditions
ConditionsYield
Stage #1: 2-Methylindene With n-butyllithium In diethyl ether; hexane at 20℃; Inert atmosphere;
Stage #2: chloro(1,3-dimethyl-1H-inden-2-yl)dimethylsilane In diethyl ether; hexane at -80 - 20℃; Inert atmosphere;
86%
ethyl bromide
74-96-4

ethyl bromide

2-Methylindene
2177-47-1

2-Methylindene

3-ethyl-2-methyl-1H-indene
51293-55-1

3-ethyl-2-methyl-1H-indene

Conditions
ConditionsYield
Stage #1: 2-Methylindene With n-butyllithium In diethyl ether; hexane at 0℃;
Stage #2: ethyl bromide In diethyl ether at 20℃;
85%
2-Methylindene
2177-47-1

2-Methylindene

dimethylsilicon dichloride
75-78-5

dimethylsilicon dichloride

bis(2-methyl-1-indenyl)-dimethylsilane
143232-13-7

bis(2-methyl-1-indenyl)-dimethylsilane

Conditions
ConditionsYield
Stage #1: 2-Methylindene With n-butyllithium In tetrahydrofuran; toluene at 20 - 80℃; for 1h;
Stage #2: dimethylsilicon dichloride In tetrahydrofuran; toluene at 20 - 60℃;
84%
Stage #1: 2-Methylindene With n-butyllithium In tetrahydrofuran; toluene at 80℃; for 1h;
Stage #2: dimethylsilicon dichloride In tetrahydrofuran; toluene at 40 - 60℃;
84%
With n-butyllithium 1) n-hexane, THF, reflux, 1 h , 2) r. t., 15 h; Multistep reaction;
With n-butyllithium In tetrahydrofuran; hexane; water
With n-butyllithium In tetrahydrofuran; water; toluene8.16 g (84%)
2-Methylindene
2177-47-1

2-Methylindene

2-methyl-2,3-dihydro-1H-inden-2-amine
312753-94-9

2-methyl-2,3-dihydro-1H-inden-2-amine

Conditions
ConditionsYield
With benzene-1,3-dicarbonitrile; 1,2,4-triphenylbenzene; ammonia In water; acetonitrile at 20℃; Irradiation;83%
Stage #1: 2-Methylindene With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; O-(2,4-dinitrophenyl)hydroxylamine In 2,2,2-trifluoroethanol at 0 - 5℃; for 5h;
Stage #2: With palladium on activated charcoal; hydrogen In 2,2,2-trifluoroethanol at 25℃; for 15h;
60%
Multi-step reaction with 2 steps
1: bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; O-(2,4-dinitrophenyl)hydroxylamine / 2,2,2-trifluoroethanol / 2.5 h / 0 - 5 °C / Inert atmosphere
2: palladium 10% on activated carbon; hydrogen / methanol / 15 h / 760.05 Torr
View Scheme
2-Methylindene
2177-47-1

2-Methylindene

Diethyl carbonate
105-58-8

Diethyl carbonate

ethyl 2-methyl-1H-indene-3-carboxylate

ethyl 2-methyl-1H-indene-3-carboxylate

Conditions
ConditionsYield
Stage #1: 2-Methylindene With sodium hydride In tetrahydrofuran at 0 - 20℃; for 0.5h;
Stage #2: Diethyl carbonate In tetrahydrofuran for 7h; Reflux;
83%
2-Methylindene
2177-47-1

2-Methylindene

methoxybenzene
100-66-3

methoxybenzene

(1RS,2RS)-1-(4-methoxyphenyl)-2-methyl-2,3-dihydro-1H-indene

(1RS,2RS)-1-(4-methoxyphenyl)-2-methyl-2,3-dihydro-1H-indene

Conditions
ConditionsYield
With toluene-4-sulfonic acid In chloroform-d1 at 20℃; for 5h; Friedel-Crafts Alkylation; Inert atmosphere; stereoselective reaction;83%
diethylchlorophosphine
686-69-1

diethylchlorophosphine

2-Methylindene
2177-47-1

2-Methylindene

tributyltin chloride
1461-22-9

tributyltin chloride

1-diethylphosphanyl-1-tributylstannyl-2-methylindene
247027-70-9

1-diethylphosphanyl-1-tributylstannyl-2-methylindene

Conditions
ConditionsYield
With n-BuLi In diethyl ether; hexane byproducts: LiCl; (anaerobic conds.); addn. of n-BuLi in hexane at 0°C to 2-methylindene in Et2O, stirring (room temp., 1 h), addn. of ClPEt2 at 0°C, stirring (r.t., ca. 1 h), addn. of n-BuLi at 0°C, stirring (1 h), addn. of Bu3SnCl, stirring (1.5 h); removal of volatiles (vac.), addn. of hexane, filtration, removal of solvent;80%
2,2'-bis-(bromomethyl)-1,1'-biphenyl
38274-14-5

2,2'-bis-(bromomethyl)-1,1'-biphenyl

2-Methylindene
2177-47-1

2-Methylindene

2,2'-bis(2-methylinden-3-ylmethyl) biphenyl

2,2'-bis(2-methylinden-3-ylmethyl) biphenyl

Conditions
ConditionsYield
Stage #1: 2-Methylindene With n-butyllithium In tetrahydrofuran at 0 - 20℃; for 3h; Inert atmosphere;
Stage #2: 2,2'-bis-(bromomethyl)-1,1'-biphenyl In tetrahydrofuran at -40 - 20℃; Inert atmosphere; Schlenk technique;
75%

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