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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1-Methylindene

Cas:767-59-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1-Methyl-1H-indene

Cas:767-59-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Storage:2-8°C Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

1-Methylindene cas no. 767-59-9 97%

Cas:767-59-9

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

1-METHYLINDENE with good quality and competitive price from Henan Tianfu Chemical: Henan Tianfu Chemical Co.,LTD was built in 2009 with an ISO certificate in the past 5 years, we have grown up as a famous fine chemicals supplier in china and we h

767-59-9 1-METHYL-1H-INDENE

Cas:767-59-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1H-Indene, 1-methyl-

Cas:767-59-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

1H-Indene, 1-methyl- CAS 767-59-9

Cas:767-59-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Our own factory produces direct sales with absolute price advantage Application:Pharmaceutical industry Transportation:By sea Port:Shanghai/tianjin

1H-Indene, 1-methyl-

Cas:767-59-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

1-Methylindene cas 767-59-9Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1-Methylindene cas 767-59-9

Cas:767-59-9

Min.Order:0

Negotiable

Type:Other

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1-Methylindene

Cas:767-59-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

1-Methylindene

Cas:767-59-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Bide Pharmatech Ltd

Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

1-Methyl-1H-indene

Cas:767-59-9

Min.Order:0

Negotiable

Type:Other

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

1-methyl-1H-indene

Cas:767-59-9

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Hanhong Scientific Co.,Ltd.

factory,reasonable price Appearance:detailed see specifications Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:pharmaceutical intermediates Transportation:by courier,air or sea Port:S

1-Methyl-1H-indene767-59-9

Cas:767-59-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Capot Chemical Co., Ltd.

At Capot,We can synthesize and purify your complex molecules from 100 gram to 10 tons.Appearance:Clear colorless to light yellow liquid Storage:Dry,Seal and Cool place Package:1G,5G,10G,25G,100G,250G,500G,1KG,5KG,10KG,25KG,50KG,100KG,150KG,200KG. App

1-Methylindene

Cas:767-59-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 1-METHYLINDENE, CAS:767-59-9 with the most competitive price and the best quality. We

1-METHYLINDENE

Cas:767-59-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuxi Morality Chemical Co., Ltd

Do best quality products, erect the morality model Application:please email us, thanks

1-METHYLINDENE

Cas:767-59-9

Min.Order:0

Negotiable

Type:Other

inquiry

Debye Scientific

Debyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen

1-Methylindene

Cas:767-59-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ShangHai DanJingYiQiSheBei CO.LTD.

1-Methylindene

Cas:767-59-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Bosnalijek pharmaceutials

1H-Indene,1-methyl- CASNo.:767-59-9 Package:pack as requested

1-Methylindene

Cas:767-59-9

Min.Order:60 Kilogram

Negotiable

Type:Trading Company

inquiry

Synthetic route

1-indene
95-13-6

1-indene

methyl iodide
74-88-4

methyl iodide

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane at -78 - 20℃; for 8.25h; Inert atmosphere; Schlenk technique;84%
Stage #1: 1-indene With n-butyllithium In diethyl ether at 0 - 20℃; for 3h;
Stage #2: methyl iodide In diethyl ether at 0℃;
75%
Stage #1: 1-indene With n-butyllithium In diethyl ether; hexane at 0 - 20℃;
Stage #2: methyl iodide In diethyl ether; hexane at 0 - 20℃;
Stage #3: With water; ammonium chloride In diethyl ether; hexane
59%
indenyllithium
20669-47-0

indenyllithium

dimethyl sulfate
77-78-1

dimethyl sulfate

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
In tetrahydrofuran at -78 - 20℃;80%
(E)-2-(4-(o-tolyl)but-3-en-2-yl)benzaldehyde

(E)-2-(4-(o-tolyl)but-3-en-2-yl)benzaldehyde

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
With C25H19(1+)*BF4(1-) In dichloromethane at 20℃; for 0.5h; Schlenk technique; Inert atmosphere;78%
cis-3a,7a-dihydro-1-methyliden-1H-inden

cis-3a,7a-dihydro-1-methyliden-1H-inden

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
With chloranil In benzene for 168h; Ambient temperature;70%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

1-indene
95-13-6

1-indene

methyl iodide
74-88-4

methyl iodide

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
65%
indenyllithium
20669-47-0

indenyllithium

methyl iodide
74-88-4

methyl iodide

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
In diethyl ether at 20℃; for 2h; Glovebox; Schlenk technique;65%
5-methyl-3-phenyl-1H-pyrazole
3347-62-4

5-methyl-3-phenyl-1H-pyrazole

A

naphthalene
91-20-3

naphthalene

B

1-phenyl-1-butyne
622-76-4

1-phenyl-1-butyne

C

1-Methylinden
767-59-9

1-Methylinden

D

3-Methylindene
767-60-2

3-Methylindene

Conditions
ConditionsYield
at 750℃; Elimination; Title compound not separated from byproducts;A 48%
B 11%
C 5%
D 24%
2,3-dihydro-3-methyl-1H-inden-1-ol
22339-44-2

2,3-dihydro-3-methyl-1H-inden-1-ol

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
With potassium hydrogensulfate Heating;35%
With potassium hydrogensulfate
With magnesium sulfate at 140 - 155℃;
5-methyl-3-phenyl-1H-pyrazole
3347-62-4

5-methyl-3-phenyl-1H-pyrazole

A

naphthalene
91-20-3

naphthalene

B

buta-1,3-dien-1-ylbenzene
1515-78-2

buta-1,3-dien-1-ylbenzene

C

1-Methylinden
767-59-9

1-Methylinden

D

3-Methylindene
767-60-2

3-Methylindene

Conditions
ConditionsYield
at 700℃; Elimination; Title compound not separated from byproducts;A 35%
B 15%
C 6%
D 17%
4-methyl-4-phenyl-1,3-dioxane
1200-73-3

4-methyl-4-phenyl-1,3-dioxane

ethyl acetate
141-78-6

ethyl acetate

A

4-phenyl-3,6-dihydro-2H-pyran
3174-81-0

4-phenyl-3,6-dihydro-2H-pyran

B

1-Methylinden
767-59-9

1-Methylinden

C

1-acetoxy-3-phenyl-but-3-ene
7306-12-9

1-acetoxy-3-phenyl-but-3-ene

D

1-acetoxy-3-phenylbut-2-ene
20883-16-3

1-acetoxy-3-phenylbut-2-ene

Conditions
ConditionsYield
With sulfuric acid at 90℃; for 9h; metal ampul;A 30%
B 18%
C 5%
D 3%
4-methyl-4-phenyl-1,3-dioxane
1200-73-3

4-methyl-4-phenyl-1,3-dioxane

A

4-phenyl-3,6-dihydro-2H-pyran
3174-81-0

4-phenyl-3,6-dihydro-2H-pyran

B

1-Methylinden
767-59-9

1-Methylinden

C

1-acetoxy-3-phenyl-but-3-ene
7306-12-9

1-acetoxy-3-phenyl-but-3-ene

D

1-acetoxy-3-phenylbut-2-ene
20883-16-3

1-acetoxy-3-phenylbut-2-ene

Conditions
ConditionsYield
With sulfuric acid In ethyl acetate at 90℃; for 9h; metal ampul;A 30%
B 18%
C 5%
D 3%
methanol
67-56-1

methanol

1-indene
95-13-6

1-indene

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
With potassium hydroxide Heating;
1-indene
95-13-6

1-indene

dimethyl sulfate
77-78-1

dimethyl sulfate

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
(i) nBuLi, (ii) /BRN= 635994/; Multistep reaction;
2-Methylindene
2177-47-1

2-Methylindene

A

1-Methylinden
767-59-9

1-Methylinden

B

3-Methylindene
767-60-2

3-Methylindene

Conditions
ConditionsYield
In acetonitrile Quantum yield; Ambient temperature; Irradiation;
at 42℃; Product distribution; Irradiation; effect of excitation wavelength; various reaction times;
at 42℃; for 0.0166667h; Irradiation;
In gas Mechanism; Irradiation; also in solution; other substituted indenes;
2-Methylindene
2177-47-1

2-Methylindene

A

1-Methylinden
767-59-9

1-Methylinden

B

3-Methylindene
767-60-2

3-Methylindene

C

1-indene
95-13-6

1-indene

Conditions
ConditionsYield
at 42℃; for 0.0166667h; Product distribution; Irradiation; initial sample temperatures from -15 deg C to 25 deg C; also with varying pressures of n-butane;
3-Methylindene
767-60-2

3-Methylindene

A

2-Methylindene
2177-47-1

2-Methylindene

B

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
at 42℃; for 0.0166667h; Irradiation;
at 42℃; Product distribution; Irradiation; effect of excitation wavelength; various reaction times;
3-Methylindene
767-60-2

3-Methylindene

A

2-Methylindene
2177-47-1

2-Methylindene

B

1-Methylinden
767-59-9

1-Methylinden

C

1-indene
95-13-6

1-indene

Conditions
ConditionsYield
at 42℃; for 0.0166667h; Product distribution; Irradiation; initial sample temperatures from -15 deg C to 25 deg C; also with varying pressures of n-butane;
tert-butyl 1-methylindan-2-percarboxylate
75421-43-1

tert-butyl 1-methylindan-2-percarboxylate

A

1-methylindane
767-58-8

1-methylindane

B

1-Methylinden
767-59-9

1-Methylinden

C

3-Methylindene
767-60-2

3-Methylindene

D

1,2-dimethyl-2,3-dihydro-1H-indene
200426-03-5

1,2-dimethyl-2,3-dihydro-1H-indene

E

1-indene
95-13-6

1-indene

Conditions
ConditionsYield
at 327℃; under 0.01 Torr; Product distribution; flash vacuum pyrolysis, other reaction temperatures;A 11.1 % Chromat.
B 7.45 % Chromat.
C 7.44 % Chromat.
D 23.4 % Chromat.
E 48.8 % Chromat.
methyl magnesium iodide
917-64-6

methyl magnesium iodide

inden-1-one
83-33-0

inden-1-one

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
(i), (ii) aq. H2SO4; Multistep reaction;
1-phenylbut-1-ene
824-90-8

1-phenylbut-1-ene

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
With potassium
1-bromomethyl-indene
18926-25-5

1-bromomethyl-indene

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
With tri-n-butyl-tin hydride Irradiation;
1-Bromcycloprop<2,3>inden
18933-48-7, 18944-78-0, 55780-41-1

1-Bromcycloprop<2,3>inden

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
With tri-n-butyl-tin hydride Irradiation;
polyethylene

polyethylene

A

benzo[e]acephenanthrylene
205-99-2

benzo[e]acephenanthrylene

B

9-methylfluorene
2523-37-7

9-methylfluorene

C

picene
213-46-7

picene

D

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
With air at 900℃; Oxidation; Formation of xenobiotics; Further byproducts given;
1-indene
95-13-6

1-indene

methyl iodide
74-88-4

methyl iodide

potassium hydroxide

potassium hydroxide

1-Methylinden
767-59-9

1-Methylinden

(+-)-<3-hydroxy-buten-(1)-yl>-benzene

(+-)-<3-hydroxy-buten-(1)-yl>-benzene

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
With phosphoric acid
1-methyl-indanol-(3)

1-methyl-indanol-(3)

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
Destillation ueber KHSO4;
1-indene
95-13-6

1-indene

methyl halide

methyl halide

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride for 3h; ultrasound excitation;
3-methyl-1H-indene-2-carboxylic acid
34225-81-5

3-methyl-1H-indene-2-carboxylic acid

A

carbon dioxide
124-38-9

carbon dioxide

B

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
zerfaellt beim laengeren Erhitzen;
3-methyl-1H-indene-2-carboxylic acid
34225-81-5

3-methyl-1H-indene-2-carboxylic acid

soda lime

soda lime

A

carbon dioxide
124-38-9

carbon dioxide

B

1-Methylinden
767-59-9

1-Methylinden

Conditions
ConditionsYield
durch Gluehen;
1-Methylinden
767-59-9

1-Methylinden

3-Methylindene
767-60-2

3-Methylindene

Conditions
ConditionsYield
In pyridine for 1h; Heating;100%
With sodium methylate In methanol for 18h; Ambient temperature;58%
1,4-diaza-bicyclo[2.2.2]octane In toluene at 20℃; Rate constant; Mechanism; variation of base catalysts, and solvents; deuterium kinetic isotope effect;
methanol
67-56-1

methanol

1-Methylinden
767-59-9

1-Methylinden

(1S,2S,3S)-2-Bromo-3-methyl-indan-1-ol
81707-30-4, 81739-69-7

(1S,2S,3S)-2-Bromo-3-methyl-indan-1-ol

(1S,2S,3R)-2-Bromo-3-methyl-indan-1-ol
81707-30-4, 81739-69-7

(1S,2S,3R)-2-Bromo-3-methyl-indan-1-ol

Conditions
ConditionsYield
With N-bromoacetamide In 1,4-dioxane; water at 70℃; for 0.333333h;A n/a
B 95%
1-Methylinden
767-59-9

1-Methylinden

lithium 1-methyl-1H-inden-1-ide
55563-47-8

lithium 1-methyl-1H-inden-1-ide

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane at -78 - 25℃; for 4h; Inert atmosphere; Schlenk technique;94%
With n-butyllithium In hexane at 20℃; for 2.5h; Cooling;
1-Methylinden
767-59-9

1-Methylinden

chloro-diphenylphosphine
1079-66-9

chloro-diphenylphosphine

(3-methyl-1H-inden-1-yl)diphenylphosphine
718638-60-9

(3-methyl-1H-inden-1-yl)diphenylphosphine

Conditions
ConditionsYield
Stage #1: 1-Methylinden With n-butyllithium In diethyl ether at -78 - 20℃;
Stage #2: chloro-diphenylphosphine In diethyl ether at -78 - 20℃;
90%
1-Methylinden
767-59-9

1-Methylinden

palladium dichloride

palladium dichloride

C20H18Cl2Pd2

C20H18Cl2Pd2

Conditions
ConditionsYield
Stage #1: palladium dichloride With sodium chloride In methanol at 50℃; for 0.5h;
Stage #2: 1-Methylinden With sodium carbonate In methanol at 20℃; for 2h;
89%
(η(6)-benzene)(η(2)-methylacrylate)dicarbonylchromium
220118-13-8

(η(6)-benzene)(η(2)-methylacrylate)dicarbonylchromium

1-Methylinden
767-59-9

1-Methylinden

dicarbonyl[(1,2,3,3a,7a-η)-1-methyl-1H-inden-1-yl][2-methoxy-1-methyl-2-(oxo-κO)ethyl-.kapa.C]chromium
690229-19-7, 689261-57-2

dicarbonyl[(1,2,3,3a,7a-η)-1-methyl-1H-inden-1-yl][2-methoxy-1-methyl-2-(oxo-κO)ethyl-.kapa.C]chromium

Conditions
ConditionsYield
In further solvent(s) under N2 atm. using Schlenk techniques; soln. of Cr complex in 1-methyl-1H-indene stirred at room temp. for 5 h; mixt. evapd.; recrystd. (hexane) at -78°C;76%
1-Methylinden
767-59-9

1-Methylinden

4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy
14691-89-5, 136708-39-9

4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy

phenylboronic acid
98-80-6

phenylboronic acid

N-[2,2,6,6-tetramethyl-1-(3-methyl-2-phenyl-indan-1-yloxy)-piperidin-4-yl]-acetamide

N-[2,2,6,6-tetramethyl-1-(3-methyl-2-phenyl-indan-1-yloxy)-piperidin-4-yl]-acetamide

Conditions
ConditionsYield
With potassium fluoride; palladium diacetate; propionic acid at 20℃; for 1h; sealed tube; diastereoselective reaction;76%
pentamethylcyclopentadienylzirconium(IV) trichloride

pentamethylcyclopentadienylzirconium(IV) trichloride

1-Methylinden
767-59-9

1-Methylinden

(1-methylindenyl)(pentamethylcyclopentadienyl)zirconium(IV) dichloride
81476-75-7

(1-methylindenyl)(pentamethylcyclopentadienyl)zirconium(IV) dichloride

Conditions
ConditionsYield
Stage #1: 1-Methylinden With n-butyllithium In diethyl ether; hexane at 20℃; for 1h; Inert atmosphere; Glovebox;
Stage #2: pentamethylcyclopentadienylzirconium(IV) trichloride In diethyl ether; hexane at 20℃; Inert atmosphere;
67%
1-Methylinden
767-59-9

1-Methylinden

1-(chlorodimethylsilyl)-2,3,4,5-tetramethylcyclopenta-2,4-diene
125542-03-2

1-(chlorodimethylsilyl)-2,3,4,5-tetramethylcyclopenta-2,4-diene

C21H28Si
1430885-39-4

C21H28Si

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane at -78 - 20℃; for 20.25h; Inert atmosphere; Schlenk technique;65%
potassium 1,2-dicarbadodecahydroundecaborate

potassium 1,2-dicarbadodecahydroundecaborate

1-Methylinden
767-59-9

1-Methylinden

tetramethylammonium bromide
64-20-0

tetramethylammonium bromide

A

bis[(3)-1,2-dicarbollyl]iron(III) tetramethylammonium salt
12304-95-9

bis[(3)-1,2-dicarbollyl]iron(III) tetramethylammonium salt

B

η(5)-(1-methylindenyl)-η(5)-(3)-1,2-dicarbollyliron(III)

η(5)-(1-methylindenyl)-η(5)-(3)-1,2-dicarbollyliron(III)

Conditions
ConditionsYield
With sodium bromide In dimethyl sulfoxide Electrochem. Process; electrolysis: B-compd., indene, Fe anode, 0.1 N NaBr, 50°C, inertatmosphere, 2.5 mA/cm**2 (about 50 mF), mixture pouring to water; ppt. and filtrate washing (C6H6), benzene extracts washing (water), drying, evapn. to dryness, residue yielding indenyl complex (after extraction with ether, dilution with hexane, evapn.), aq. phase (with Me4NBr) yielding Fe-dicarbollide; elem. anal.;A 41%
B 54%
1-Methylinden
767-59-9

1-Methylinden

iron(II) chloride

iron(II) chloride

bis(η(5)-1-methylindenyl)iron(II)
56259-75-7, 861907-08-6, 861907-09-7

bis(η(5)-1-methylindenyl)iron(II)

Conditions
ConditionsYield
With n-BuLi In tetrahydrofuran (N2); Schlenk technique; soln. of n-BuLi was added to soln. of Me-indenein THF at -80°C; warmed to ambient temp.; stirred for 2 h; FeCl2 was added; mixt. was stirred for 2 h; solvent removed (vac.); residue dissolved in Et2O; filtered through Celite; solvent removed (vac.); sublimed (vac.);45%
N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

1-Methylinden
767-59-9

1-Methylinden

zinc(II) chloride
7646-85-7

zinc(II) chloride

[Zn(1-methyl-inden-3-yl)2(tetramethyl-ethylenediamine)]

[Zn(1-methyl-inden-3-yl)2(tetramethyl-ethylenediamine)]

Conditions
ConditionsYield
Stage #1: 1-Methylinden; zinc(II) chloride With potassium In tetrahydrofuran at 20℃; for 12h; Inert atmosphere; Schlenk technique;
Stage #2: N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran Inert atmosphere; Schlenk technique;
41%
Bromoform
75-25-2

Bromoform

1-Methylinden
767-59-9

1-Methylinden

2-bromo-1-methylnaphthalene
20601-22-3

2-bromo-1-methylnaphthalene

Conditions
ConditionsYield
Stage #1: Bromoform; 1-Methylinden With potassium tert-butylate In diethyl ether for 2.5h;
Stage #2: With potassium hydroxide In ethanol; hexane for 1h; Heating;
38%
With potassium tert-butylate In diethyl ether
maleic anhydride
108-31-6

maleic anhydride

1-Methylinden
767-59-9

1-Methylinden

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

2a,3,6,7,8,9-hexahydro-12-methyl-6,9-etheno-3,5a-methano-5aH-cyclobutanaphthalene-1,2,4,5,7,8-hexacarboxylic acid cyclic 7,8-anhydride tetramethyl ester
74843-96-2

2a,3,6,7,8,9-hexahydro-12-methyl-6,9-etheno-3,5a-methano-5aH-cyclobutanaphthalene-1,2,4,5,7,8-hexacarboxylic acid cyclic 7,8-anhydride tetramethyl ester

Conditions
ConditionsYield
In xylene for 24h; Heating;31%
1-Methylinden
767-59-9

1-Methylinden

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

tetramethyl 2a,3-dihydro-10-methyl-3,5a-methano-5aH-cyclobutanaphthalene-1,2,4,5-tetracarboxylate
74843-82-6

tetramethyl 2a,3-dihydro-10-methyl-3,5a-methano-5aH-cyclobutanaphthalene-1,2,4,5-tetracarboxylate

Conditions
ConditionsYield
In toluene for 24h; Heating;30%
potassium 1,2-dicarbadodecahydroundecaborate

potassium 1,2-dicarbadodecahydroundecaborate

1-Methylinden
767-59-9

1-Methylinden

cobalt
7440-48-4

cobalt

η(5)-(1-methylindenyl)-η(5)-(3)-1,2-dicarbollylcobalt(III)

η(5)-(1-methylindenyl)-η(5)-(3)-1,2-dicarbollylcobalt(III)

Conditions
ConditionsYield
With sodium bromide In dimethyl sulfoxide Electrolysis; 0.1 M NaBr, Co electrode, 50°C, 2.5 mA/cm**2, reaction mixture pouring into water; ppt. and supernatant extracting (benzene), extracts washing (water), drying (MgSO4), concentrating (vacuum), column chromy. (silica gel/benzene,acetone), eluent evapn., petroleum ether addn., ppt. filtration of, was hing (pentane), drying; elem. anal.;29%
1-Methylinden
767-59-9

1-Methylinden

zirconium(IV) chloride
10026-11-6

zirconium(IV) chloride

bis[1-methyl-indenyl]zirconium dichloride
198702-64-6, 329191-12-0, 329191-11-9

bis[1-methyl-indenyl]zirconium dichloride

Conditions
ConditionsYield
With n-BuLi In tetrahydrofuran; toluene (Ar); Standard Schlenk technique; n-BuLi added to soln. of ligand in THFat -78°C; warmed to room temp.; stirred for 4 h; solvent removed (vac.); toluene added; ZrCl4/toluene added dropwise at -78°C; wa rmed to room. temp.; stirred for 18 h; NMR monitoring; filtered through Celite pad; pad washed (toluene); filtrate concd. in vac.; crystd. at -18°C; elem. anal.;23%
1-Methylinden
767-59-9

1-Methylinden

A

3,3'-dimethyl-bis<1-indenyl>
110452-31-8

3,3'-dimethyl-bis<1-indenyl>

B

1,3'-dimethyl-bis<1-indenyl>
110452-30-7

1,3'-dimethyl-bis<1-indenyl>

Conditions
ConditionsYield
With n-butyllithium; copper dichloride 1.) ether, -30 deg C, 30 min, 2.) ether, -30 deg C, 30 min; Yield given. Title compound not separated from byproducts;A n/a
B 20%
With n-butyllithium; copper dichloride 1.) ether, -30 deg C, 30 min, 2.) ether, -30 deg C, 30 min; Yields of byproduct given;A n/a
B 20%
formaldehyd
50-00-0

formaldehyd

1-Methylinden
767-59-9

1-Methylinden

bis(1-methyl-3-indenyl)methane

bis(1-methyl-3-indenyl)methane

Conditions
ConditionsYield
With sodium ethanolate In N,N-dimethyl-formamide at 20℃; for 18h;18%

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