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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our

2378-02-1 PERFLUORO-TERT-BUTANOL 99%

Cas:2378-02-1

Min.Order:1 Kilogram

FOB Price: $1150.0 / 1200.0

Type:Lab/Research institutions

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Perfluoro-tert-butanol

Cas:2378-02-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 2378-02-1 with best quality

Cas:2378-02-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

Perfluoro-tert-butanolCAS2378-02-1

Cas:2378-02-1

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1,1,1,3,3,3-Hexafluoro-2-(trifluoro-methyl)-2-propanol

Cas:2378-02-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

Perfluoro-tert-butanol CAS 2378-02-1

Cas:2378-02-1

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

PERFLUORO-TERT-BUTANOL CAS:2378-02-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic in

PERFLUORO-TERT-BUTANOL CAS:2378-02-1

Cas:2378-02-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:2378-02-1

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply perfluoro-tert-butyl alcohol

Cas:2378-02-1

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Perfluoro-tert-butanol CAS NO.2378-02-1

Cas:2378-02-1

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and als

PERFLUORO-TERT-BUTANOL

Cas:2378-02-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

PERFLUORO-TERT-BUTANOL

Cas:2378-02-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

high purity PERFLUORO-TERT-BUTANOL

Cas:2378-02-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

PERFLUORO-TERT-BUTANOL

Cas:2378-02-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Perfluoro-tert-butanol

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

PERFLUORO-TERT-BUTANOL cas no. 2378-02-1 98%

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

tris-(Trifluoromethyl)-methanol

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

perfluoro-tert-butyl alcohol

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Perfluoro-tert-butanol 1g

Cas:2378-02-1

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

Perfluoro-tert-butanol

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Perfluoro-tert-butanol

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

2378-02-1

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

PERFLUORO-TERT-BUTANOL

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Trading Company

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Beantown Chemical

in stock Application:2378-02-1

Perfluoro-tert-butanol, 99%

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Trading Company

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LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

PERFLUORO-TERT-BUTANOL

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shaanxi Mingqi Chemical Co., Ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Our advantages:1, High quality with competitive price:1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%4) We are manufactureAp

perfluoro-tert-butyl alcohol manufacturer

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Ruishun Trade Co.,Ltd

Hebei ruishun trade co.,ltd, registered capital one million,have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center,seek development by credit reputation.our products have a large price advanta

Perfluoro-tert-butanol

Cas:2378-02-1

Min.Order:10 Gram

FOB Price: $0.9 / 1.2

Type:Trading Company

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1.Best service, high quality and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). ? 3. It's customers' right to choose the packing way for his products fro

Best price/ Perfluoro-tert-butanol CAS NO.2378-02-1

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

Perfluoro-tert-butanol

Cas:2378-02-1

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Strem Chemicals, Inc.

1.High Quality Specialty Chemicals2.Expertise and Experience in Manufacturing High Purity, High Quality Chemicals3.Long Term Focus in Inorganics, Organometallics and Metals4.ISO 9001 CertifiedAppearance:colorless liq.

Perfluoro-t-butanol, min. 97%

Cas:2378-02-1

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

bismuth
7440-69-9

bismuth

tris-(trifluoromethyl)methyl hypochlorite
27579-40-4

tris-(trifluoromethyl)methyl hypochlorite

A

Bi(3+)*3(CF3)3CO(1-) = Bi{(CF3)3CO}3
88392-03-4

Bi(3+)*3(CF3)3CO(1-) = Bi{(CF3)3CO}3

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
byproducts: (CF3)2CO, CF3Cl, Cl2; reaction mixt. maintained at 0°C for 40 h and at room temp. for 94 h and between 25 and 30°C for 6 h; addn. of additional (CF3)3COCl; volatiles removed at room temp. under vac.; elem. anal.;A 93%
B n/a
(trifluoromethyl)trimethylsilane
81290-20-2

(trifluoromethyl)trimethylsilane

Hexafluoroacetone
684-16-2

Hexafluoroacetone

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
With potassium fluoride In acetonitrile Mechanism; a) 9 h, -40 deg C, b) 3 h, 18 deg C; other carbonyl compounds, variation of conditions: xfluorinated tertiary alcohols and alkoxides from nucleophilic trifluoromethylation of carbonyl compounds;91.3%
With potassium fluoride In acetonitrile 1) -40 deg C, 9 h, 2) 18 deg C, 3 h;91.3%
(trifluoromethyl)trimethylsilane
81290-20-2

(trifluoromethyl)trimethylsilane

trifluoroacetic anhydride
407-25-0

trifluoroacetic anhydride

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
With tetramethylammonium fluoride In 1,2-dimethoxyethane at -30 - 20℃;87%
1,1,1-trichloro-3,3,3-trifluoro-2-(trifluoromethyl)propan-2-ol
7594-49-2

1,1,1-trichloro-3,3,3-trifluoro-2-(trifluoromethyl)propan-2-ol

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
With antimony pentafluoride for 3h; Heating;85%
With antimony pentafluoride
Carbonyl fluoride
353-50-4

Carbonyl fluoride

(trifluoromethyl)trimethylsilane
81290-20-2

(trifluoromethyl)trimethylsilane

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
With potassium fluoride In acetonitrile for 18h; -40 deg C to r.t.;77.1%
nanofluoro-tert-butylamine
2809-92-9

nanofluoro-tert-butylamine

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
With trifluoroacetic acid; sodium nitrite In water at 20℃; for 1h;70%
Vinylidene fluoride
75-38-7

Vinylidene fluoride

C4BrF9O
178984-96-8

C4BrF9O

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

Hexafluoroacetone
684-16-2

Hexafluoroacetone

C

2-(2-Bromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

2-(2-Bromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

D

2-(2,2-Dibromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

2-(2,2-Dibromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

Conditions
ConditionsYield
at -88 - 24℃; for 12h; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;A n/a
B n/a
C 31%
D n/a
at -88 - 24℃; for 12h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
C4BrF9O
178984-96-8

C4BrF9O

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

Hexafluoroacetone
684-16-2

Hexafluoroacetone

C

2-(2-Bromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

2-(2-Bromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

D

2-(2,2-Dibromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

2-(2,2-Dibromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

Conditions
ConditionsYield
at -88 - 24℃; for 12h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
CH3C6H3CH2OS(OC(CF3)3)2

CH3C6H3CH2OS(OC(CF3)3)2

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

A

CH3C6H3CH2OSCO(CF3)3(1+)*CF3SO3(1-)

CH3C6H3CH2OSCO(CF3)3(1+)*CF3SO3(1-)

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

bis(nonafluoro-tert-butoxy)(pentafluorophenylsulfanyl)trifluorophenylsulfur(IV)
71212-59-4

bis(nonafluoro-tert-butoxy)(pentafluorophenylsulfanyl)trifluorophenylsulfur(IV)

water
7732-18-5

water

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

bis(pentafluorophenyl) disulfide
1494-06-0

bis(pentafluorophenyl) disulfide

C

pentafluorophenyl pentafluorobenzenethiosulfonate
63113-87-1

pentafluorophenyl pentafluorobenzenethiosulfonate

Conditions
ConditionsYield
hydrolysis at 25°C;
bis(nonafluoro-tert-butoxy)(trifluoromethyl)trifluoromethylsulfanylsulfur(IV)
71192-83-1

bis(nonafluoro-tert-butoxy)(trifluoromethyl)trifluoromethylsulfanylsulfur(IV)

water
7732-18-5

water

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

Trifluoro-methanethiosulfonic acid S-trifluoromethyl ester
358-15-6

Trifluoro-methanethiosulfonic acid S-trifluoromethyl ester

C

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
hydrolysis at 25°C;
nanofluoro-tert-butylamine
2809-92-9

nanofluoro-tert-butylamine

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

1,1,1,3,3,3-hexafluoro-2-nitroso-2-trifluoromethyl-propane
354-93-8

1,1,1,3,3,3-hexafluoro-2-nitroso-2-trifluoromethyl-propane

Conditions
ConditionsYield
With sodium nitrite In sulfuric acid At 0°C then at -10°C;
With NaNO2 In sulfuric acid aq. H2SO4; At 0°C then at -10°C;
nonafluoro-tert-butyl trifluoromethanesulfinate
52225-54-4

nonafluoro-tert-butyl trifluoromethanesulfinate

A

Carbonyl fluoride
353-50-4

Carbonyl fluoride

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

C

silicon tetrafluoride
7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
byproducts: SO2; hydrolyzes in moist air at 25°C;
CrO2{(CF3)3CO}2
88391-99-5

CrO2{(CF3)3CO}2

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

chromic acid
7738-94-5

chromic acid

Conditions
ConditionsYield
With water detected by NMR;
C16H12F9NO4
1192744-27-6

C16H12F9NO4

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
With NADPH:cytochrome P450 reductase; NADPH In water-d2; water; acetonitrile at 37℃; for 0.25h; pH=7.6; Kinetics; Concentration; Reagent/catalyst; aq. phosphate buffer; Inert atmosphere; Enzymatic reaction;
C3H7NO*C4HF9O

C3H7NO*C4HF9O

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

Conditions
ConditionsYield
In octanol at 24.84℃; Equilibrium constant;
C4HF9O*C4H9NO

C4HF9O*C4H9NO

A

N,N-dimethyl acetamide
127-19-5

N,N-dimethyl acetamide

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
In octanol at 24.84℃; Equilibrium constant;
C2H6OS*C4HF9O

C2H6OS*C4HF9O

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

Conditions
ConditionsYield
In octanol at 24.84℃; Equilibrium constant;
C4HF9O*C6H15O4P

C4HF9O*C6H15O4P

A

triethyl phosphate
78-40-0

triethyl phosphate

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
In octanol at 24.84℃; Equilibrium constant;
C4HF9O*C6H18N3OP

C4HF9O*C6H18N3OP

A

N,N,N,N,N,N-hexamethylphosphoric triamide
680-31-9

N,N,N,N,N,N-hexamethylphosphoric triamide

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
In octanol at 24.84℃; Equilibrium constant;
PhF-Al(OC(CF3)3)3
1086659-07-5

PhF-Al(OC(CF3)3)3

water
7732-18-5

water

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

C

C8HAlF18O3

C8HAlF18O3

Conditions
ConditionsYield
In fluorobenzene Schlenk technique;
C15H9AlF28O3Si

C15H9AlF28O3Si

tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

B

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

C

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

D

C15H10AlF27O4Si

C15H10AlF27O4Si

Conditions
ConditionsYield
In dichloromethane; dichloromethane-d2 at -30 - 20℃; Inert atmosphere; Schlenk technique; Glovebox;
tert-butyldimethylsilanol
18173-64-3

tert-butyldimethylsilanol

C15H9AlF28O3Si

C15H9AlF28O3Si

A

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

C

tert-butyldimethylfluorosilane
2357-76-8

tert-butyldimethylfluorosilane

D

C18H16AlF27O4Si

C18H16AlF27O4Si

E

C15H10AlF27O4Si

C15H10AlF27O4Si

Conditions
ConditionsYield
In dichloromethane; dichloromethane-d2 at -78℃; Inert atmosphere; Schlenk technique; Glovebox;
1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

nonafluoro-tert-butyl hypofluorite
2203-56-7

nonafluoro-tert-butyl hypofluorite

Conditions
ConditionsYield
With fluorine; cesium fluoride at -196 - 10℃; for 3 - 4h; Inert atmosphere;100%
With cesium fluoride; fluorine at -78℃; for 0.333333h;98%
Stage #1: 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol With cesium fluoride at -196 - 20℃;
Stage #2: With fluorine at -78℃; for 0.333333h;
97%
With fluorine
With fluorine; cesium fluoride at -78 - 20℃; under 225.023 Torr;
1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

sodium 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-olate

sodium 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-olate

Conditions
ConditionsYield
With sodium hydroxide In water at 20℃; for 0.5h;100%
With sodium hydride In diethyl ether at 20℃; for 2h; Inert atmosphere; Glovebox;84%
With sodium hydride In diethyl ether at 20℃; for 3h; Inert atmosphere; Glovebox; Cooling with ice;80%
With sodium hydride In diethyl ether
lithium aluminium tetrahydride
16853-85-3

lithium aluminium tetrahydride

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Li[AlPFTB4]
274933-96-9

Li[AlPFTB4]

Conditions
ConditionsYield
In pentane at 20℃;100%
In diethyl ether; toluene for 21h; Inert atmosphere; Reflux;
1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

1,2,3,4-tetra-O-acetyl-β-D-glucopyranose
13100-46-4

1,2,3,4-tetra-O-acetyl-β-D-glucopyranose

C18H19F9O10

C18H19F9O10

Conditions
ConditionsYield
Stage #1: 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol; 1,2,3,4-tetra-O-acetyl-β-D-glucopyranose With triphenylphosphine In tetrahydrofuran at 20 - 75℃; for 0.0833333h; Inert atmosphere;
Stage #2: With di-isopropyl azodicarboxylate In tetrahydrofuran at 75℃; for 3.3h; Inert atmosphere;
99.9%
Re(C3(OH)(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3)
380907-37-9

Re(C3(OH)(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3)

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Re(CCHC(OH)(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3)(1+)

Re(CCHC(OH)(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3)(1+)

Conditions
ConditionsYield
In dichloromethane-d2 under N2, in NMR tube; 10 equiv. of HOC(CF3)3 syringed into soln. of Re complex in CD2Cl2 cooled to -78°C (dry ice-acetone bath); not isolated; detd. by (31)P NMR spectroscopy;99%
1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

potassium perfluoro-tert-butoxide
29646-16-0

potassium perfluoro-tert-butoxide

Conditions
ConditionsYield
With potassium hydride In diethyl ether at -78 - 20℃; Inert atmosphere;99%
With potassium hydroxide In ethanol at 0 - 20℃; for 0.5h; Glovebox;93%
With potassium hydride In diethyl ether Inert atmosphere; Glovebox;
With potassium hydride In diethyl ether
bismuth
7440-69-9

bismuth

tris-(trifluoromethyl)methyl hypochlorite
27579-40-4

tris-(trifluoromethyl)methyl hypochlorite

A

Bi(3+)*3(CF3)3CO(1-) = Bi{(CF3)3CO}3
88392-03-4

Bi(3+)*3(CF3)3CO(1-) = Bi{(CF3)3CO}3

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
byproducts: (CF3)2CO, CF3Cl, Cl2; reaction mixt. maintained at 0°C for 40 h and at room temp. for 94 h and between 25 and 30°C for 6 h; addn. of additional (CF3)3COCl; volatiles removed at room temp. under vac.; elem. anal.;A 93%
B n/a
(trifluoromethyl)trimethylsilane
81290-20-2

(trifluoromethyl)trimethylsilane

Hexafluoroacetone
684-16-2

Hexafluoroacetone

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
With potassium fluoride In acetonitrile Mechanism; a) 9 h, -40 deg C, b) 3 h, 18 deg C; other carbonyl compounds, variation of conditions: xfluorinated tertiary alcohols and alkoxides from nucleophilic trifluoromethylation of carbonyl compounds;91.3%
With potassium fluoride In acetonitrile 1) -40 deg C, 9 h, 2) 18 deg C, 3 h;91.3%
(trifluoromethyl)trimethylsilane
81290-20-2

(trifluoromethyl)trimethylsilane

trifluoroacetic anhydride
407-25-0

trifluoroacetic anhydride

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
With tetramethylammonium fluoride In 1,2-dimethoxyethane at -30 - 20℃;87%
1,1,1-trichloro-3,3,3-trifluoro-2-(trifluoromethyl)propan-2-ol
7594-49-2

1,1,1-trichloro-3,3,3-trifluoro-2-(trifluoromethyl)propan-2-ol

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
With antimony pentafluoride for 3h; Heating;85%
With antimony pentafluoride
Carbonyl fluoride
353-50-4

Carbonyl fluoride

(trifluoromethyl)trimethylsilane
81290-20-2

(trifluoromethyl)trimethylsilane

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
With potassium fluoride In acetonitrile for 18h; -40 deg C to r.t.;77.1%
nanofluoro-tert-butylamine
2809-92-9

nanofluoro-tert-butylamine

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
With trifluoroacetic acid; sodium nitrite In water at 20℃; for 1h;70%
Vinylidene fluoride
75-38-7

Vinylidene fluoride

C4BrF9O
178984-96-8

C4BrF9O

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

Hexafluoroacetone
684-16-2

Hexafluoroacetone

C

2-(2-Bromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

2-(2-Bromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

D

2-(2,2-Dibromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

2-(2,2-Dibromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

Conditions
ConditionsYield
at -88 - 24℃; for 12h; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;A n/a
B n/a
C 31%
D n/a
at -88 - 24℃; for 12h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
C4BrF9O
178984-96-8

C4BrF9O

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

Hexafluoroacetone
684-16-2

Hexafluoroacetone

C

2-(2-Bromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

2-(2-Bromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

D

2-(2,2-Dibromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

2-(2,2-Dibromo-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

Conditions
ConditionsYield
at -88 - 24℃; for 12h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
CH3C6H3CH2OS(OC(CF3)3)2

CH3C6H3CH2OS(OC(CF3)3)2

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

A

CH3C6H3CH2OSCO(CF3)3(1+)*CF3SO3(1-)

CH3C6H3CH2OSCO(CF3)3(1+)*CF3SO3(1-)

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

bis(nonafluoro-tert-butoxy)(pentafluorophenylsulfanyl)trifluorophenylsulfur(IV)
71212-59-4

bis(nonafluoro-tert-butoxy)(pentafluorophenylsulfanyl)trifluorophenylsulfur(IV)

water
7732-18-5

water

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

bis(pentafluorophenyl) disulfide
1494-06-0

bis(pentafluorophenyl) disulfide

C

pentafluorophenyl pentafluorobenzenethiosulfonate
63113-87-1

pentafluorophenyl pentafluorobenzenethiosulfonate

Conditions
ConditionsYield
hydrolysis at 25°C;
bis(nonafluoro-tert-butoxy)(trifluoromethyl)trifluoromethylsulfanylsulfur(IV)
71192-83-1

bis(nonafluoro-tert-butoxy)(trifluoromethyl)trifluoromethylsulfanylsulfur(IV)

water
7732-18-5

water

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

Trifluoro-methanethiosulfonic acid S-trifluoromethyl ester
358-15-6

Trifluoro-methanethiosulfonic acid S-trifluoromethyl ester

C

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
hydrolysis at 25°C;
nanofluoro-tert-butylamine
2809-92-9

nanofluoro-tert-butylamine

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

1,1,1,3,3,3-hexafluoro-2-nitroso-2-trifluoromethyl-propane
354-93-8

1,1,1,3,3,3-hexafluoro-2-nitroso-2-trifluoromethyl-propane

Conditions
ConditionsYield
With sodium nitrite In sulfuric acid At 0°C then at -10°C;
With NaNO2 In sulfuric acid aq. H2SO4; At 0°C then at -10°C;
nonafluoro-tert-butyl trifluoromethanesulfinate
52225-54-4

nonafluoro-tert-butyl trifluoromethanesulfinate

A

Carbonyl fluoride
353-50-4

Carbonyl fluoride

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

C

silicon tetrafluoride
7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
byproducts: SO2; hydrolyzes in moist air at 25°C;
CrO2{(CF3)3CO}2
88391-99-5

CrO2{(CF3)3CO}2

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

chromic acid
7738-94-5

chromic acid

Conditions
ConditionsYield
With water detected by NMR;
C16H12F9NO4
1192744-27-6

C16H12F9NO4

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
With NADPH:cytochrome P450 reductase; NADPH In water-d2; water; acetonitrile at 37℃; for 0.25h; pH=7.6; Kinetics; Concentration; Reagent/catalyst; aq. phosphate buffer; Inert atmosphere; Enzymatic reaction;
C3H7NO*C4HF9O

C3H7NO*C4HF9O

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

Conditions
ConditionsYield
In octanol at 24.84℃; Equilibrium constant;
C4HF9O*C4H9NO

C4HF9O*C4H9NO

A

N,N-dimethyl acetamide
127-19-5

N,N-dimethyl acetamide

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
In octanol at 24.84℃; Equilibrium constant;
C2H6OS*C4HF9O

C2H6OS*C4HF9O

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

B

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

Conditions
ConditionsYield
In octanol at 24.84℃; Equilibrium constant;
C4HF9O*C6H15O4P

C4HF9O*C6H15O4P

A

triethyl phosphate
78-40-0

triethyl phosphate

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
In octanol at 24.84℃; Equilibrium constant;
C4HF9O*C6H18N3OP

C4HF9O*C6H18N3OP

A

N,N,N,N,N,N-hexamethylphosphoric triamide
680-31-9

N,N,N,N,N,N-hexamethylphosphoric triamide

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Conditions
ConditionsYield
In octanol at 24.84℃; Equilibrium constant;
PhF-Al(OC(CF3)3)3
1086659-07-5

PhF-Al(OC(CF3)3)3

water
7732-18-5

water

A

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

C

C8HAlF18O3

C8HAlF18O3

Conditions
ConditionsYield
In fluorobenzene Schlenk technique;
C15H9AlF28O3Si

C15H9AlF28O3Si

tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

B

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

C

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

D

C15H10AlF27O4Si

C15H10AlF27O4Si

Conditions
ConditionsYield
In dichloromethane; dichloromethane-d2 at -30 - 20℃; Inert atmosphere; Schlenk technique; Glovebox;
tert-butyldimethylsilanol
18173-64-3

tert-butyldimethylsilanol

C15H9AlF28O3Si

C15H9AlF28O3Si

A

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

B

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

C

tert-butyldimethylfluorosilane
2357-76-8

tert-butyldimethylfluorosilane

D

C18H16AlF27O4Si

C18H16AlF27O4Si

E

C15H10AlF27O4Si

C15H10AlF27O4Si

Conditions
ConditionsYield
In dichloromethane; dichloromethane-d2 at -78℃; Inert atmosphere; Schlenk technique; Glovebox;
1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

nonafluoro-tert-butyl hypofluorite
2203-56-7

nonafluoro-tert-butyl hypofluorite

Conditions
ConditionsYield
With fluorine; cesium fluoride at -196 - 10℃; for 3 - 4h; Inert atmosphere;100%
With cesium fluoride; fluorine at -78℃; for 0.333333h;98%
Stage #1: 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol With cesium fluoride at -196 - 20℃;
Stage #2: With fluorine at -78℃; for 0.333333h;
97%
With fluorine
With fluorine; cesium fluoride at -78 - 20℃; under 225.023 Torr;
1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

sodium 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-olate

sodium 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-olate

Conditions
ConditionsYield
With sodium hydroxide In water at 20℃; for 0.5h;100%
With sodium hydride In diethyl ether at 20℃; for 2h; Inert atmosphere; Glovebox;84%
With sodium hydride In diethyl ether at 20℃; for 3h; Inert atmosphere; Glovebox; Cooling with ice;80%
With sodium hydride In diethyl ether
lithium aluminium tetrahydride
16853-85-3

lithium aluminium tetrahydride

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Li[AlPFTB4]
274933-96-9

Li[AlPFTB4]

Conditions
ConditionsYield
In pentane at 20℃;100%
In diethyl ether; toluene for 21h; Inert atmosphere; Reflux;
1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

1,2,3,4-tetra-O-acetyl-β-D-glucopyranose
13100-46-4

1,2,3,4-tetra-O-acetyl-β-D-glucopyranose

C18H19F9O10

C18H19F9O10

Conditions
ConditionsYield
Stage #1: 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol; 1,2,3,4-tetra-O-acetyl-β-D-glucopyranose With triphenylphosphine In tetrahydrofuran at 20 - 75℃; for 0.0833333h; Inert atmosphere;
Stage #2: With di-isopropyl azodicarboxylate In tetrahydrofuran at 75℃; for 3.3h; Inert atmosphere;
99.9%
Re(C3(OH)(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3)
380907-37-9

Re(C3(OH)(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3)

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Re(CCHC(OH)(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3)(1+)

Re(CCHC(OH)(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3)(1+)

Conditions
ConditionsYield
In dichloromethane-d2 under N2, in NMR tube; 10 equiv. of HOC(CF3)3 syringed into soln. of Re complex in CD2Cl2 cooled to -78°C (dry ice-acetone bath); not isolated; detd. by (31)P NMR spectroscopy;99%
1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

potassium perfluoro-tert-butoxide
29646-16-0

potassium perfluoro-tert-butoxide

Conditions
ConditionsYield
With potassium hydride In diethyl ether at -78 - 20℃; Inert atmosphere;99%
With potassium hydroxide In ethanol at 0 - 20℃; for 0.5h; Glovebox;93%
With potassium hydride In diethyl ether Inert atmosphere; Glovebox;
With potassium hydride In diethyl ether
1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Nb(N-2,6-Me2C6H3)(CH2SiMe3)3

Nb(N-2,6-Me2C6H3)(CH2SiMe3)3

Nb(N-2,6-Me2C6H3)(CH2SiMe3)2[OC(CF3)3]

Nb(N-2,6-Me2C6H3)(CH2SiMe3)2[OC(CF3)3]

Conditions
ConditionsYield
In hexane at -30 - 20℃;99%
1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

Nb(N-2,6-iPr2C6H3)(CH2SiMe3)3

Nb(N-2,6-iPr2C6H3)(CH2SiMe3)3

Nb(N-2,6-iPr2C6H3)(CH2SiMe3)2[OC(CF3)3]

Nb(N-2,6-iPr2C6H3)(CH2SiMe3)2[OC(CF3)3]

Conditions
ConditionsYield
In hexane at -30 - 20℃;99%

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