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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesis.

high quality of 2-Bromo-9,9-dimethylfluorene

Cas:28320-31-2

Min.Order:100 Gram

Negotiable

Type:Manufacturers

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized in phar

2-Bromo-9,9-dimethylfluorene CAS NO.28320-31-2

Cas:28320-31-2

Min.Order:1 Kilogram

FOB Price: $6.0

Type:Lab/Research institutions

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Bromo-9,9-dimethylfluorene Manufacturer/High quality/Best price/In stock

Cas:28320-31-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Bromo-9,9-Dimethylfluorene supplier in China

Cas:28320-31-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Jinan Finer Chemical Co., Ltd

Product description: Product name 2-Bromo-9,9-dimethylfluorene CAS number 28320-31-2 Assay ≥99% Appearance White crystalline powder Capacity 100mt/year Application OLED inter

2-Bromo-9,9-dimethylfluorene

Cas:28320-31-2

Min.Order:100 Gram

FOB Price: $12.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:off white solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:Shanghai, Qingdao

2-Bromo-9,9-dimethylfluorene

Cas:28320-31-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 9H-Fluorene,2-bromo-9,9-dimethyl-

Cas:28320-31-2

Min.Order:1

Negotiable

Type:Other

inquiry

Wuhan Kemi-Works Chemical Co., Ltd

ISO9001 Exporting Japan, Korea regularly. Appearance:white powder Storage:-- Package:25kg/ fibre drum Application:OLED intermediates Transportation:--- Port:China port

2-Bromo-9,9-dimethylfluorene

Cas:28320-31-2

Min.Order:10 Gram

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 28320-31-2 9H-Fluorene, 2-bromo-9,9-dimethyl- Manufacturer

Cas:28320-31-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

2-Bromo-9,9-dimethylfluorene CAS 28320-31-2 9,9-Dimethyl-2-bromofluorenone CAS no 28320-31-2 9H-Fluorene,2-bromo-9,9-dimethyl- 2-Bromo-9,9-dimethylfluorene Manufacturer High quality Best price In stock factory CAS 28320-31-2 2-Bromo-9,9-dimethy

Henan Tianfu Chemical Co., Ltd.

Product Name: 2-Bromo-9,9-dimethylfluorene Synonyms: 2-broMo-9,9-diMethyl-9H-fluorene (2BDMF);2--9,9-two MethylbroMidefluorene;9H-Fluorene,2-broMo-9,9-diMethyl-;9,9-Dimethyl-2-bromofluorenone;2-bromo-9,9-dimethyl-fluororene;2-Bromo-9,9

28320-31-2 2-Bromo-9,9-dimethylfluorene

Cas:28320-31-2

Min.Order:1 Gram

FOB Price: $8900.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 28320-31-2 with best quality

Cas:28320-31-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

2-Bromo-9,9-dimethylfluoreneCAS28320-31-2

Cas:28320-31-2

Min.Order:1 Kilogram

FOB Price: $10.0 / 20.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Product Name 2-Bromo-9,9-dimethylfluorene Synonyms 2-Bromo-9,9-dimethylfluorene;2-broMo-99-diMethyl-9H-fluorene (2BDMF) CAS: 28320-31-2 MF: C15H13Br

2-Bromo-9,9-dimethylfluorene CAS 28320-31-2

Cas:28320-31-2

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

2-Bromo-9,9-dimethylfluorene 28320-31-2

Cas:28320-31-2

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

2-Bromo-9,9-dimethylfluorene 99%

Cas:28320-31-2

Min.Order:1 Kilogram

FOB Price: $76.0 / 85.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

2-Bromo-9,9-dimethylfluorene CAS:28320-31-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality orga

2-Bromo-9,9-dimethylfluorene CAS:28320-31-2

Cas:28320-31-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:28320-31-2

Cas:28320-31-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

2-Bromo-9,9-dimethylfluorene CAS: 28320-31-2 Specification Product name 2-Bromo-9,9-dimethylfluorene CAS number 28320-31-2 Assay ≥99% Appearance White crystalline powder Capacity 100mt/

Factory supply 2-Bromo-9,9-dimethylfluorene

Cas:28320-31-2

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Bromo-9,9-Dimethylfluorene

Cas:28320-31-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

2-BroMo-9,9-diMethylfluorene

Cas:28320-31-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly quali

28320-31-2 2-Bromo-9,9-dimethylfluorene CAS 28320-31-2

Cas:28320-31-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

9H-Fluorene,2-bromo-9,9-dimethyl-

Cas:28320-31-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Bromo-9,9-dimethyl-9H-fluorene

Cas:28320-31-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

2-Bromo-9,9-dimethylfluorene

Cas:28320-31-2

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Bromo-9,9-dimethylfluorene

Cas:28320-31-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 2-Bromo-9,9-dimethylfluorene

Cas:28320-31-2

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2-Bromo-9,9-dimethylfluorene/High quality/Best price

Cas:28320-31-2

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

9H-Fluorene, 2-bromo-9, 9-dimethyl

Cas:28320-31-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers 3.Safe a

2-Bromo-9,9-dimethylfluorene

Cas:28320-31-2

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-bromo-9H-fluorene
1133-80-8

2-bromo-9H-fluorene

methyl iodide
74-88-4

methyl iodide

2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

Conditions
ConditionsYield
Stage #1: 2-bromo-9H-fluorene With potassium tert-butylate In tetrahydrofuran at 0℃; for 0.166667h;
Stage #2: methyl iodide In tetrahydrofuran at 0 - 20℃;
99%
With N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide In dimethyl sulfoxide at 0℃; for 0.5h;99%
With potassium hydroxide; potassium iodide In dimethyl sulfoxide at 20℃; for 48h;97%
9,9-dimethyl-9H-fluorene
4569-45-3

9,9-dimethyl-9H-fluorene

2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

Conditions
ConditionsYield
With sodium bromate; hydrogen bromide; trimethylbenzylammonium bromide In dichloromethane; water at 10 - 20℃; under 760.051 Torr; for 1.5h;90%
With N-Bromosuccinimide In dichloromethane at 20℃; for 24h;78%
With bromine; iron(III) chloride In water at 20℃; for 13h; Heating / reflux;20%
With bromine
C15H17Br

C15H17Br

2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In benzene67%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

acetyl chloride
75-36-5

acetyl chloride

1-(7-bromo-9,9-dimethyl-9H-fluoren-2-yl)ethanone
899444-03-2

1-(7-bromo-9,9-dimethyl-9H-fluoren-2-yl)ethanone

Conditions
ConditionsYield
With aluminum (III) chloride In dichloromethane at 0 - 20℃; for 16h;99.3%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

methyl iodide
74-88-4

methyl iodide

2,9,9-trimethyl-9H-fluorene
69535-83-7

2,9,9-trimethyl-9H-fluorene

Conditions
ConditionsYield
Stage #1: 2-bromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: methyl iodide In tetrahydrofuran; hexane at -78 - 20℃; for 2h;
99%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

(2R*,3aR*,8bR*)-2-methyl-1,2,3,3a,4,8b-hexahydropenta[b]- indole

(2R*,3aR*,8bR*)-2-methyl-1,2,3,3a,4,8b-hexahydropenta[b]- indole

(2R*,3aR*,8bR*)-2-methyl-4-(9,9-dimethyl-9H-fluorenene-2-yl)- 1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole

(2R*,3aR*,8bR*)-2-methyl-4-(9,9-dimethyl-9H-fluorenene-2-yl)- 1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; sodium t-butanolate; tert-butyl XPhos In toluene Buchwald-Hartwig Coupling; Reflux; Inert atmosphere;98%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

(1R*,3aR*,8bR*)-1-methyl-1,2,3,3a,4,8b-hexahydropenta[b]- indole

(1R*,3aR*,8bR*)-1-methyl-1,2,3,3a,4,8b-hexahydropenta[b]- indole

(1R*,3aR*,8bR*)-1-methyl-4-(9,9-dimethyl-9H-fluorenene-2-yl)- 1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole

(1R*,3aR*,8bR*)-1-methyl-4-(9,9-dimethyl-9H-fluorenene-2-yl)- 1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; sodium t-butanolate; tert-butyl XPhos In toluene Buchwald-Hartwig Coupling; Reflux; Inert atmosphere;98%
N-phenyl-9H-carbazol-3-boronic acid
854952-58-2

N-phenyl-9H-carbazol-3-boronic acid

2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

C33H25N

C33H25N

Conditions
ConditionsYield
With potassium phosphate tribasic trihydrate; C44H43B10Br2P; palladium diacetate In ethanol; toluene at 120℃; for 36h; Kinetics; Reagent/catalyst; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;98%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

2-bromo-7-iodo-9,9-dimethyl-9H-fluorene
319906-45-1

2-bromo-7-iodo-9,9-dimethyl-9H-fluorene

Conditions
ConditionsYield
With potassium iodate; sulfuric acid; iodine; acetic acid In water at 80℃; for 2.5h;96%
With sulfuric acid; iodine; acetic acid; periodic acid In water at 50℃; for 5h;85%
With periodic acid dihydrate; sulfuric acid; iodine; acetic acid at 65 - 90℃; for 6.5h; Inert atmosphere;76%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

aniline
62-53-3

aniline

N-phenyl-(9,9-dimethyl-9H-fluoren-2-yl)amine
355832-04-1

N-phenyl-(9,9-dimethyl-9H-fluoren-2-yl)amine

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate In toluene for 20h; Buchwald-Hartwig Coupling; Reflux; Inert atmosphere;95%
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene at 110℃; for 3.58333h; Inert atmosphere;93%
With sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine In toluene at 90℃; for 3h;92%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

2-phenylaniline
90-41-5

2-phenylaniline

N‐{[1,1'‐biphenyl]‐2‐yl}‐9,9‐dimethylfluoren‐2‐amine

N‐{[1,1'‐biphenyl]‐2‐yl}‐9,9‐dimethylfluoren‐2‐amine

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate In toluene for 20h; Buchwald-Hartwig Coupling; Reflux; Inert atmosphere;95%
With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate In toluene for 20h; Reflux;95%
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene at 110℃; for 12h;94%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

3,4-(methylenedioxy)-benzeneboronic acid
94839-07-3

3,4-(methylenedioxy)-benzeneboronic acid

C22H18O2

C22H18O2

Conditions
ConditionsYield
With C24H31Br2N3O9Pd; potassium carbonate In ethanol; water at 80℃; for 1.5h; Suzuki Coupling;95%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

2-(2"-methoxyphenyl)-9,9'-dimethylfluorene

2-(2"-methoxyphenyl)-9,9'-dimethylfluorene

Conditions
ConditionsYield
With potassium phosphate; palladium diacetate; triphenylphosphine In 1,2-dimethoxyethane at 20℃; for 6h;94%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

C39H27NO

C39H27NO

C54H39NO

C54H39NO

Conditions
ConditionsYield
With tributylphosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 100℃; for 25h; Inert atmosphere;93%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

C21H17Cl

C21H17Cl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 8h; Inert atmosphere;93%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 8h; Inert atmosphere;90%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In tetrahydrofuran at 80℃; for 5h; Inert atmosphere;85%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

C15H9(2)H4Br

C15H9(2)H4Br

Conditions
ConditionsYield
With water-d2; potassium carbonate; silver carbonate; cyclohexyldiphenylphosphine In toluene at 120℃; for 12h;93%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

1-(9,9-dimethylfluorene-2-yl)-2-(trimethylsilyl)acetylene
950181-08-5

1-(9,9-dimethylfluorene-2-yl)-2-(trimethylsilyl)acetylene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 60℃; for 48h; Inert atmosphere;92%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine Sonogashira Cross-Coupling;
Triphenylsilyl chloride
76-86-8

Triphenylsilyl chloride

2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

triphenyl-(9,9-dimethylfluoren-2-yl)silane
1208005-82-6

triphenyl-(9,9-dimethylfluoren-2-yl)silane

Conditions
ConditionsYield
Stage #1: 2-bromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
Stage #2: Triphenylsilyl chloride In tetrahydrofuran; hexane at 20℃; Inert atmosphere;
92%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

2-(4-chlorophenyl)-9,9-dimethyl-9H-fluorene
1221237-82-6

2-(4-chlorophenyl)-9,9-dimethyl-9H-fluorene

Conditions
ConditionsYield
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In water; toluene at 100℃; for 2h; Inert atmosphere; Sealed tube;91%
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; water for 5h; Heating;88%
With palladium diacetate; sodium hydrogencarbonate; tris-(o-tolyl)phosphine In 1,2-dimethoxyethane; water at 90℃; for 5h; Schlenk technique; Inert atmosphere;75%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

4-Aminobiphenyl
92-67-1

4-Aminobiphenyl

N‑(biphenyl‑4‑yl)‑9,9‑dimethyl‑9H‑fluorene‑2‑amine
897671-69-1

N‑(biphenyl‑4‑yl)‑9,9‑dimethyl‑9H‑fluorene‑2‑amine

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate In toluene for 24h; Reflux;91%
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene for 24h; Reflux;91%
With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 110℃;91%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

C39H27NS

C39H27NS

C54H39NS

C54H39NS

Conditions
ConditionsYield
With tributylphosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 100℃; for 23h; Inert atmosphere;91%
3-bromo-9H-carbazole
1592-95-6

3-bromo-9H-carbazole

2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

3-bromo-9-(9',9'-dimethyl-9H-fluoren-2-yl)-9H-carbazole
1207672-45-4

3-bromo-9-(9',9'-dimethyl-9H-fluoren-2-yl)-9H-carbazole

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; potassium hydroxide In para-xylene Reflux;91%
benzo[b]thiophene-2-boronic acid
98437-23-1

benzo[b]thiophene-2-boronic acid

2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

2-(9,9-dimethyl-9H-fluoren-2-yl)benzo[b]thiophene

2-(9,9-dimethyl-9H-fluoren-2-yl)benzo[b]thiophene

Conditions
ConditionsYield
Stage #1: benzo[b]thiophene-2-boronic acid; 2-bromo-9,9-dimethyl-9H-fluorene With potassium carbonate In 1,2-dimethoxyethane; water for 0.333333h; Inert atmosphere;
Stage #2: With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium(0) In 1,2-dimethoxyethane; water at 80℃; for 15h; Inert atmosphere;
91%
1,3,5-trichloro-2,4,6-triazine
108-77-0

1,3,5-trichloro-2,4,6-triazine

2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

3,5-bis(9,9-dimethyl-9H-fluoren-2-yl)-1-chlorotriazine

3,5-bis(9,9-dimethyl-9H-fluoren-2-yl)-1-chlorotriazine

Conditions
ConditionsYield
Stage #1: 2-bromo-9,9-dimethyl-9H-fluorene With iodine; magnesium In tetrahydrofuran at 55℃; for 1h; Glovebox;
Stage #2: 1,3,5-trichloro-2,4,6-triazine In tetrahydrofuran at 55℃; Glovebox;
90%
Stage #1: 2-bromo-9,9-dimethyl-9H-fluorene With iodine; magnesium In tetrahydrofuran for 1h; Reflux;
Stage #2: 1,3,5-trichloro-2,4,6-triazine In tetrahydrofuran at 50℃; for 12h; Cooling with ice;
75%
Stage #1: 2-bromo-9,9-dimethyl-9H-fluorene With magnesium In tetrahydrofuran for 2h; Reflux;
Stage #2: 1,3,5-trichloro-2,4,6-triazine In tetrahydrofuran at -10 - 20℃;
48%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

9,9-dimethyl-9H-fluoren-2-ol
959246-70-9

9,9-dimethyl-9H-fluoren-2-ol

Conditions
ConditionsYield
With water; sodium hydroxide at 100℃; for 8h;90%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

C22H17N

C22H17N

C37H29N

C37H29N

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium t-butanolate In toluene at 100℃; for 16h; Inert atmosphere;90%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

9H-carbazole
86-74-8

9H-carbazole

9-(9',9'-dimethyl-9H-fluoren-2-yl)-9H-carbazole
866100-16-5

9-(9',9'-dimethyl-9H-fluoren-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 18-crown-6 ether; copper; potassium carbonate In 1,2-dichloro-benzene at 200℃; for 30h; Ullmann reaction;89.15%
With palladium diacetate; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate In 5,5-dimethyl-1,3-cyclohexadiene for 15h; Reflux; Inert atmosphere;84%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

2-iodo-9,9-dimethyl-9H-fluorene
144981-85-1

2-iodo-9,9-dimethyl-9H-fluorene

Conditions
ConditionsYield
Stage #1: 2-bromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran at -78℃; for 24.5h; Inert atmosphere;
Stage #2: With iodine In tetrahydrofuran at -78 - 20℃; for 12h; Inert atmosphere;
89%
Stage #1: 2-bromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran at -78 - 20℃; for 24h; Inert atmosphere;
Stage #2: With iodine In tetrahydrofuran at -78 - 20℃; for 12h; Inert atmosphere;
89%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

bis(biphenyl-4-yl)amine
102113-98-4

bis(biphenyl-4-yl)amine

C39H31N

C39H31N

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 4h; Inert atmosphere; Reflux;88%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

C18H10N4

C18H10N4

C48H34N4

C48H34N4

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 110℃; for 24h; Inert atmosphere;88%
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

N-phenyl-N-(11,11’-dimethylbenzo[a]fluoren-9-yl)amine

N-phenyl-N-(11,11’-dimethylbenzo[a]fluoren-9-yl)amine

C40H33N

C40H33N

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate In toluene at 100℃;88%
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