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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesis.

manufacturer of 2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:100 Gram

Negotiable

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Jinan Finer Chemical Co., Ltd

Product description: Product name 2,7-Dibromo-9,9-dimethylfluorene CAS number 28320-32-3 Assay ≥99% Appearance White powder Capacity 100mt/year Application OLED intermediate

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:100 Gram

FOB Price: $12.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

Located in Zhengdong New District, Zhengzhou of Henan province, Henan Allgreen Chemical Co.,Ltd is comprehensive high-tech modern enterprises integrating professional R&D, production and sales. Strong technical force, with a long-term profes

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Wuhan Kemi-Works Chemical Co., Ltd

ISO9001 Exporting Japan, Korea regularly. Appearance:white powder Storage:store in dry and cool place Package:25kg/ fibre drum Application:OLED intermediates Transportation:-- Port:Chinese port

9,9-Dimethyl-2,7-dibromofluorene

Cas:28320-32-3

Min.Order:10 Gram

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 28320-32-3 9H-Fluorene, 2,7-dibromo-9,9-dimethyl- Manufacturer

Cas:28320-32-3

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

chengdu and import and export trade co., LTD., who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do res

2,7-DibroMo-9,9-diMethylfluorene

Cas:28320-32-3

Min.Order:5 Metric Ton

FOB Price: $1100.0 / 1500.0

Type:Trading Company

inquiry

Leader Biochemical Group

About Product Technical Details 2,7-Dibromo-9,9-dimethylfluo

China Largest factory Manufacturer Supply 2,7-Dibromo-9,9-dimethylfluorene CAS 28320-32-3

Cas:28320-32-3

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

2,7-Dibromo-9,9-dimethylfluorene--

Cas:28320-32-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can be

2,7-Dibromo-9,9-dimethylfluorene CAS:28320-32-3

Cas:28320-32-3

Min.Order:1 Kilogram

FOB Price: $250.0 / 280.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 28320-32-3 with best quality

Cas:28320-32-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Name: 2,7-Dibromo-9,9'-Dimethylfluorene Synonyms: 2,7-Dibromo-9,9-dimethyl-9H-fluorene CAS:28320-32-3 MF: C15H12Br2 Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg Application:OLED organic electro

2,7-Dibromo-9,9'-Dimethylfluorene CAS:28320-32-3

Cas:28320-32-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

9H-Fluorene,2,7-dibromo-9,9-dimethyl- 28320-32-3

Cas:28320-32-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2,7-Dibromo-9,9-dimethylfluorene CAS:28320-32-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality

2,7-Dibromo-9,9-dimethylfluorene CAS:28320-32-3

Cas:28320-32-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

9H-Fluorene,2,7-dibromo-9,9-dimethyl-

Cas:28320-32-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

9H-Fluorene,2,7-dibromo-9,9-dimethyl-

Cas:28320-32-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2,7-Dibromo-9,9-Dimethylfluorene

Cas:28320-32-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2,7-DIBROMO-9,9-DIMETHYL FLUORENE

Cas:28320-32-3

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

9H-Fluorene,2,7-dibromo-9,9-dimethyl-

Cas:28320-32-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Sourcing Leveraging our vast network of suppliers and local industry expertise we can source quality industrial and speciality chemicals, supporting you through the entire sales cycle to ensure you receive the perfect Chemlyte solution. Market

Featured products 2,7-Dibromo-9,9-dimethylfluoren

Cas:28320-32-3

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 2,7-Dibromo-9,9-dimethylfluorene Synonyms: 9,9-Dimethyl-2,7-dibromofluorenone;2,7-Dibromo-9,9-dimethyl-fluororene;2,7-Dibromo-9,9-dimethylfluorene;9H-Fluorene,2,7-dibromo-9,9-dimethyl-;9,9-Dimethyl-2,7-Dibromofluorene;2,7-Dibromo-9,9-di

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2,7-Dibromo-9,9-dimethylfluorene

Cas:28320-32-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2,7-dibromo-9H-fluorene
16433-88-8

2,7-dibromo-9H-fluorene

methyl iodide
74-88-4

methyl iodide

2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

Conditions
ConditionsYield
With tetrabutylammomium bromide; sodium hydroxide In dimethyl sulfoxide for 5h; Sonication;99%
With tetrabutylammomium bromide; sodium hydroxide In dimethyl sulfoxide at 20℃; for 5h; Sonication;99%
With tetrabutylammomium bromide; sodium hydroxide In dimethyl sulfoxide for 5h; Sonication;99%
2,7-dibromo-9H-fluorene
16433-88-8

2,7-dibromo-9H-fluorene

2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

Conditions
ConditionsYield
With tetrabutylammomium bromide; sodium hydroxide In dimethyl sulfoxide at 20℃; for 5h;99%
9,9-dimethyl-9H-fluorene
4569-45-3

9,9-dimethyl-9H-fluorene

2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

Conditions
ConditionsYield
With bromine In chloroform for 4h; Cooling with ice;76%
With bromine
methyl iodide
74-88-4

methyl iodide

2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9H-fluorene With potassium tert-butylate In dimethyl sulfoxide at 5℃;
Stage #2: methyl iodide In dimethyl sulfoxide at 5℃;
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

3,5-bis-trifluromethylphenylboronic acid
73852-19-4

3,5-bis-trifluromethylphenylboronic acid

C31H18F12

C31H18F12

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 80℃; for 1.5h; Suzuki Coupling;98%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

trimethyltin(IV)chloride
1066-45-1

trimethyltin(IV)chloride

2,7-bis(trimethylstannyl)-9,9-dimethylfluorene
1228237-11-3

2,7-bis(trimethylstannyl)-9,9-dimethylfluorene

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran; hexane at -70℃; for 1.25h;
Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane at -78 - 20℃; for 6.08333h;
97%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

dimesitylfluoroborane
436-59-9

dimesitylfluoroborane

(7-bromo-9,9-dimethyl-9H-fluoren-2-yl)dimesitylborane
1254106-26-7

(7-bromo-9,9-dimethyl-9H-fluoren-2-yl)dimesitylborane

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran at -78℃; for 2h; Inert atmosphere;
Stage #2: dimesitylfluoroborane In tetrahydrofuran at -78 - 20℃; Inert atmosphere;
94%
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h;
Stage #2: dimesitylfluoroborane In tetrahydrofuran; hexane at 20℃; for 6h;
80%
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran; hexane at -78℃;
Stage #2: dimesitylfluoroborane In tetrahydrofuran; hexane for 12h;
63%
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran
Stage #2: dimesitylfluoroborane
4-trifluoromethylphenylamine
455-14-1

4-trifluoromethylphenylamine

2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

C22H17BrF3N
676625-76-6

C22H17BrF3N

Conditions
ConditionsYield
With sodium t-butanolate; C30H48FeP2; palladium dichloride In 1,4-dioxane for 3h; Heating / reflux;92%
With sodium t-butanolate; C30H48FeP2; palladium dichloride In 1,4-dioxane for 3h; Heating / reflux;92 %Chromat.
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
61676-62-8

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

4,4,5,5-tetramethyl-2-[7-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-9,9-dimethyl-9H-fluoren-2-yl]-[1,3,2]dioxaborolane
325129-69-9

4,4,5,5-tetramethyl-2-[7-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-9,9-dimethyl-9H-fluoren-2-yl]-[1,3,2]dioxaborolane

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane at 20℃; for 2h;
90%
With n-butyllithium In diethyl ether at -78 - 20℃; for 14h; Inert atmosphere;60.5%
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran at -78 - 0℃;
Stage #2: 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane In tetrahydrofuran at 20℃;
33%
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran at -78℃; for 2h; Inert atmosphere;
Stage #2: 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane In tetrahydrofuran for 25h;
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

7-bromo-9,9-dimethyl-9H-fluorene-2-carbaldehyde
944940-90-3

7-bromo-9,9-dimethyl-9H-fluorene-2-carbaldehyde

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran at -78℃; for 1h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at 20℃; for 2h;
90%
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran at -78℃; for 1h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at -78 - 20℃;
90%
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran; hexane at -78 - 25℃; for 10h; Inert atmosphere; Schlenk technique;
90%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

7-bromo-9,9-dimethyl-9H-fluorene-2-carbaldehyde
944940-90-3

7-bromo-9,9-dimethyl-9H-fluorene-2-carbaldehyde

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: With N,N-dimethyl-formamide In tetrahydrofuran at -78 - 25℃; for 10h; Inert atmosphere; Schlenk technique;
90%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

C15H6(2)H6Br2

C15H6(2)H6Br2

Conditions
ConditionsYield
With water-d2; potassium carbonate; silver carbonate; cyclohexyldiphenylphosphine In toluene at 120℃; for 12h;90%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

1-pyrenylboronic acid
164461-18-1

1-pyrenylboronic acid

1,1'-(9,9-dimethyl-9H-fluorene-2,7-diyl)bis-pyrene

1,1'-(9,9-dimethyl-9H-fluorene-2,7-diyl)bis-pyrene

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 20 - 77℃; for 5.5h; Suzuki Coupling;89%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 4h; Suzuki Coupling; Reflux;73%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

N-methylaniline
100-61-8

N-methylaniline

N2,N7,9,9-tetramethyl-N2,N7-diphenyl-9H-fluorene-2,7-diamine

N2,N7,9,9-tetramethyl-N2,N7-diphenyl-9H-fluorene-2,7-diamine

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With palladium diacetate; johnphos; sodium t-butanolate In toluene at 20℃; for 0.75h; Buchwald-Hartwig Coupling; Inert atmosphere; Schlenk technique;
Stage #2: N-methylaniline In toluene at 180℃; for 1h; Reagent/catalyst; Buchwald-Hartwig Coupling; Inert atmosphere; Schlenk technique; Microwave irradiation;
89%
((10-(naphthalen-1-yl)anthracen-9-yl)boronic acid)
400607-46-7

((10-(naphthalen-1-yl)anthracen-9-yl)boronic acid)

2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

10-(9,9-dimethyl-2-(10-(naphthalen-1-yl)anthracen-9-yl)-9H-fluoren-7-yl)-9-(naphthalen-1-yl)anthracene

10-(9,9-dimethyl-2-(10-(naphthalen-1-yl)anthracen-9-yl)-9H-fluoren-7-yl)-9-(naphthalen-1-yl)anthracene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 4h; Suzuki Coupling; Reflux;86%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

N-methylaniline
100-61-8

N-methylaniline

7-bromo-N,9,9-trimethyl-N-phenyl-9H-fluoren-2-amine

7-bromo-N,9,9-trimethyl-N-phenyl-9H-fluoren-2-amine

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With palladium diacetate; (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine); sodium t-butanolate In toluene at 20℃; for 0.5h; Buchwald-Hartwig Coupling; Inert atmosphere; Schlenk technique;
Stage #2: N-methylaniline In toluene at 180℃; for 0.75h; Reagent/catalyst; Solvent; Buchwald-Hartwig Coupling; Microwave irradiation; Schlenk technique; Inert atmosphere;
86%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

aniline
62-53-3

aniline

C27H24N2

C27H24N2

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene; aniline In benzene at 50℃; for 0.333333h; Inert atmosphere;
Stage #2: With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In benzene Reflux; Inert atmosphere;
85.63%
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene for 12h; Inert atmosphere;
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene for 12h; Inert atmosphere;
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrene
349666-24-6

1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrene

1-(7-bromo-9,9-dimethyl-9H-fluoren-2-yl)pyrene
872705-65-2

1-(7-bromo-9,9-dimethyl-9H-fluoren-2-yl)pyrene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene for 12h; Inert atmosphere; Reflux;85%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

C24H13NO2

C24H13NO2

C63H36N2O4

C63H36N2O4

Conditions
ConditionsYield
With tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate In toluene at 82℃; for 11h;85%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

C19H14N2O

C19H14N2O

C53H38N4O2

C53H38N4O2

Conditions
ConditionsYield
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene for 2h; Inert atmosphere; Reflux;85%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

9,9-dimethyl-9H-fluoren-2-yl-2-boronic acid
333432-28-3

9,9-dimethyl-9H-fluoren-2-yl-2-boronic acid

9,9-dimethylfluorene trimer

9,9-dimethylfluorene trimer

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In tetrahydrofuran; water for 14h; Reflux; Inert atmosphere; Schlenk technique;84%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

4,4,5,5-tetramethyl-2-[7-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-9,9-dimethyl-9H-fluoren-2-yl]-[1,3,2]dioxaborolane
325129-69-9

4,4,5,5-tetramethyl-2-[7-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-9,9-dimethyl-9H-fluoren-2-yl]-[1,3,2]dioxaborolane

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane for 4h; Inert atmosphere; Heating;83%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate at 90℃; for 48h; Inert atmosphere;78%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate at 90℃; for 48h;78%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

diphenylamine
122-39-4

diphenylamine

2-bromo-7-N,N’-diphenylamino-9,9’-dimethyl-9H-fluorene
302579-16-4

2-bromo-7-N,N’-diphenylamino-9,9’-dimethyl-9H-fluorene

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 80℃; for 2h; Schlenk technique;83%
With 18-crown-6 ether; copper; potassium carbonate; potassium iodide In 1,2-dichloro-benzene at 200℃; for 24h; Inert atmosphere;79%
With 18-crown-6 ether; copper; potassium carbonate In 1,2-dichloro-benzene at 20 - 200℃; for 24h; Inert atmosphere;79%
pyrrolidine
123-75-1

pyrrolidine

2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

1-(7-bromo-9,9-dimethyl-9H-fluoren-2-yl)pyrrolidine

1-(7-bromo-9,9-dimethyl-9H-fluoren-2-yl)pyrrolidine

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With palladium diacetate; (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine); sodium t-butanolate In toluene at 20℃; for 0.5h; Buchwald-Hartwig Coupling; Inert atmosphere; Schlenk technique;
Stage #2: pyrrolidine In toluene at 180℃; for 0.75h; Buchwald-Hartwig Coupling; Microwave irradiation; Schlenk technique; Inert atmosphere;
83%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

phenylboronic acid
98-80-6

phenylboronic acid

9,9-dimethyl-2,7-diphenyl-9H-fluorene
1009629-20-2

9,9-dimethyl-2,7-diphenyl-9H-fluorene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); tetrabutylammomium bromide; potassium carbonate In water; toluene at 90℃; Inert atmosphere; Schlenk technique;82.6%
With potassium carbonate In ethanol; water; toluene at 120℃; for 3h; Inert atmosphere;
With potassium carbonate; tetrabutylammomium bromide; palladium diacetate In water at 70℃; for 24h;
Suzuki Coupling;
styrene
292638-84-7

styrene

2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

9,9-dimethyl-2,7-di((E)-styryl)-9H-fluorene

9,9-dimethyl-2,7-di((E)-styryl)-9H-fluorene

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); N-Methyldicyclohexylamine; tetrabutylammomium bromide In toluene at 80℃; Inert atmosphere; Schlenk technique;82.5%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

9,9-dimethyl-9H-fluorene-2,7-dicarbaldehyde
1313886-42-8

9,9-dimethyl-9H-fluorene-2,7-dicarbaldehyde

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran; N,N-dimethyl-formamide at -78 - 25℃; for 10h; Inert atmosphere; Schlenk technique;
82%
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With magnesium In tetrahydrofuran for 16h; Grignard reaction; Reflux;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at 20℃; for 5h; Cooling with ice;
66%
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran at -78℃; for 1h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at 20℃; for 3h;
62%
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran at -78℃; for 1h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran for 12h;
60%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

aniline
62-53-3

aniline

7-bromo-9,9-dimethyl-N-phenyl-9H-fluoren-2-amine

7-bromo-9,9-dimethyl-N-phenyl-9H-fluoren-2-amine

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With palladium diacetate; (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine); sodium t-butanolate In toluene at 20℃; for 0.5h; Buchwald-Hartwig Coupling; Inert atmosphere; Schlenk technique;
Stage #2: aniline In toluene at 180℃; for 0.75h; Buchwald-Hartwig Coupling; Microwave irradiation; Schlenk technique; Inert atmosphere;
82%
2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

9,9-dimethyl-9H-fluorene-2,7-dicarbaldehyde
1313886-42-8

9,9-dimethyl-9H-fluorene-2,7-dicarbaldehyde

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9,9-dimethyl-9H-fluorene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: With N,N-dimethyl-formamide In tetrahydrofuran at -78 - 25℃; for 10h; Inert atmosphere; Schlenk technique;
82%
indium tri(4-methylbenzenethiolate)

indium tri(4-methylbenzenethiolate)

2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

2,7-di(p-tolylthio)-9,9-dimethyl-9H-fluorene
1263672-65-6

2,7-di(p-tolylthio)-9,9-dimethyl-9H-fluorene

Conditions
ConditionsYield
With palladium diacetate; N-ethyl-N,N-diisopropylamine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 100℃; for 4h; Inert atmosphere;81%
1H-imidazole
288-32-4

1H-imidazole

2,7-dibromo-9,9-dimethyl-9H-fluorene
28320-32-3

2,7-dibromo-9,9-dimethyl-9H-fluorene

2,7-bis(1H-imidazol-1-yl)-9,9-dimethyl-9H-fluorene
1588929-66-1

2,7-bis(1H-imidazol-1-yl)-9,9-dimethyl-9H-fluorene

Conditions
ConditionsYield
With copper(l) iodide; caesium carbonate In N,N-dimethyl-formamide at 120℃; for 8h; Inert atmosphere;81%
With copper(l) iodide; caesium carbonate In N,N-dimethyl-formamide at 119.84℃; for 36h; Inert atmosphere;76.1%
With copper(l) iodide; caesium carbonate In N,N-dimethyl-formamide at 120℃; for 8h;76%

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